Pore Structure Regulation in Refractory Grog with Alumina Content over 45 %

2020 ◽  
Vol 834 ◽  
pp. 75-81
Author(s):  
Lenka Nevřivová
Keyword(s):  
Mineralogical Composition ◽  
Refractory Product ◽  
Raw Material ◽  
Alumina Content ◽  
High Alumina ◽  
Refractory Materials ◽  
Dense Refractory ◽  
Alkali Oxides ◽  
Structure Regulation ◽  
Basic Characteristics

Increased alumina content in refractory grog is a product of the grog’s firing and, at the same time, it is a raw material used for the production of dense or insulating, shaped or monolithic refractories. Grog characteristics determine the properties of the final product. The specific characteristics of the grog are therefore optimized to suit the refractory product as close as possible. The basic characteristics determining the nature of the grog include its mineralogical composition, chemical composition, and apparent porosity. The present study focuses on ways of reducing the porosity of a high-alumina grog and thus obtaining a raw material suitable for the production of dense refractory materials. The experiments have shown that it is possible to regulate porosity by using clay with better sinterability and phosphoric acid in the production of grog from claystone with alumina content over 40 %, a minimal Fe2O3 content, a minimal content of CaO and alkali oxides.

Analysis of Alkali Oxides Influence on the Microstructure of Refractory Grog

2021 ◽  
Vol 325 ◽  
pp. 188-193
Author(s):  
Lenka Nevřivová ◽  
David Zemánek
Keyword(s):  
Mechanical Properties ◽  
Czech Republic ◽  
Experimental Work ◽  
Raw Materials ◽  
Physical And Mechanical Properties ◽  
Special Kind ◽  
Alumina Content ◽  
Refractory Materials ◽  
The Czech Republic ◽  
Alkali Oxides

The development and subsequent production of these special kind of grog from raw materials available in the Czech Republic is one of the possibilities how to reduce income costs for the production of refractory materials with specific properties. The experimental work is focused on verifying the possibility of producing grog with increased alumina content from available raw materials. The raw materials are kaolins and claystones. To achieve a higher content of alumina in the grog, waste mullite dust is used. In order to improve the physical and mechanical properties of the grog, modifiers are used. Selected modifiers are expected to affect positively on the resulting density while maintaining the heat properties.

scholarly journals Perspective raw materials of Uzbekistan for the production of refractory materials

2019 ◽  
pp. 8-11
Author(s):  
Z. R. Kadyrova ◽  
R. Kh. Pirmatov ◽  
A. A. Eminov
Keyword(s):  
Raw Materials ◽  
Raw Material ◽  
High Alumina ◽  
Refractory Materials ◽  
Processing Industry ◽  
Gas Processing ◽  
Material Resources ◽  
Chemical Indicators ◽  
Physico Chemical ◽  
Materials Used

The results of studies of promising raw material resources of Uzbekistan (enriched kaolins, bauxite-like rock, highalumina waste from the gas processing industry) to obtain high-alumina aggregates are presented. It is established that these raw materials in terms of their physico-chemical indicators meet the requirements for aluminosilicate and high-alumina materials used in metallurgical units. Ref. 13. Tab. 3.

scholarly journals Geochemistry and Mineralogy of Ice-Dammed Lake Sediments of the Lębork Deposit

2021 ◽  
Author(s):  
Radosław Rogoziński ◽  
Alina Maciejewska
Keyword(s):  
Chemical Composition ◽  
Lake Sediments ◽  
Inductively Coupled Plasma ◽  
Mineralogical Composition ◽  
Raw Material ◽  
Element Analysis ◽  
X Ray ◽  
Dominant Component ◽  
Clay Deposits ◽  
Dammed Lake

AbstractVarved clay deposits from ice-dammed lakes are a particularly important and broadly applied raw material used for the production of high-quality ceramics (red bricks, roof tiles, etc.), but the mineralogy and geochemistry of these sediments are not fully understood. The aim of the present study was to determine the chemical and mineralogical composition of ice-dammed lake sediments of the Lębork deposit. Major-element analysis of the compositions of selected samples from the ice-dammed lake clays was performed by X-ray fluorescence (XRF) and trace elements were determined by inductively coupled plasma-mass spectrometry. The mineralogical composition of clay samples was determined by X-ray diffraction (XRD). Analyses of the chemical composition of the ice-dammed lake clays of the Lębork deposit showed that the dominant component was SiO2 with a mean content of 56.13 wt.%; the second most abundant component was Al2O3, with a mean content for the entire deposit of 11.61 wt.%. Analysis by ICP-MS indicated the presence of rare earth elements (REE), e.g. cerium, neodymium, lanthanum, and praseodymium; their mean contents are: 56.9, 27.0, 26.3, and 7.3 ppm, respectively. Mineralogical analysis of the varved clays identified quartz, muscovite, calcite, and clay minerals – illite, kaolinite, and montmorillonite. The material filling the Lębork basin is characterized by small lateral and vertical variability in chemical composition. The results of the present study may be of considerable importance in determining the parent igneous, metamorphic, and sedimentary rocks, the weathering products of which supplied material to the ice-dammed lake, as well as in determining the mechanisms and character of the sedimentation process itself.

Ceramic Proppants Based on Ultrabasic Rocks of Kazakhstan Chromite Ore Deposits

2019 ◽  
Vol 946 ◽  
pp. 169-173
Author(s):  
A.A. Biryukova ◽  
T.D. Dzhienalyev ◽  
A.V. Boronina
Keyword(s):  
Oil And Gas ◽  
Mineralogical Composition ◽  
Magnesium Silicate ◽  
Gas Production ◽  
Ore Deposits ◽  
Raw Material ◽  
Chrome Spinel ◽  
Overburden Rock ◽  
Oil And Gas Production ◽  
Silicate Ceramic

The purpose of the work is the obtaining of magnesium silicate ceramic proppants, based on ultrabasic overburden rocks of Kempirsai deposits of chromite ores (Kazakhstan). The chemical and mineralogical composition of ultrabasic overburden rock was studied by chemical, microscopic and X-ray diffraction analyzes. It is established that the main mineral of ultrabasic overburden rocks is serpentine, present in the form of fibrous chrysotile and lamellar antigorite. In the impurities are iron oxides and hydroxides, chrome spinel, carbonates, quartz. Assessment of the use of overburden rocks as a raw material for the production of ceramic proppants was carried out. The sintering interval of overburden rocks was determined at 1280-1300 °C. The sintering firing optimum temperature of ceramics, based on this type of raw material is 1300 °C. It is established that to harden the structure of magnesium silicate ceramic it is necessary to activate the raw material thermally at a temperature of 1000 °C. The influence of binder type on the properties of magnesium silicate proppants, based on the Kempirsai serpentinites was studied. Magnesium silicate proppants, based on ultrabasic overburden rocks, were obtained with the following properties: apparent density – 1.6 g/cm3, strength resistance (52 MPa) – 14%, sphericity and roundness – 0.8; chemical resistance (hydrochloric acid) – 98%, static strength of the fraction 16/20 - 72–118 N/granule. The field of application is oil and gas production, metallurgy and ceramic industries.

Sedimentary Clays as Geopolymer Precursor

2018 ◽  
Vol 39 ◽  
pp. 97-111
Author(s):  
F. Mostefa ◽  
Nasr Eddine Bouhamou ◽  
H.A. Mesbah ◽  
Salima Aggoun ◽  
D. Mekhatria
Keyword(s):  
Sodium Hydroxide ◽  
Mineralogical Composition ◽  
Cementitious Materials ◽  
Raw Material ◽  
X Ray Diffraction ◽  
Calcination Time ◽  
Calorimetric Analysis ◽  
X Ray ◽  
Before And After ◽  
Mechanical Performances

This work aims to study the feasibility of making a geopolymer cement based on dredged sediments, from the Fergoug dam (Algeria) and to evaluate their construction potential particularly interesting in the field of special cementitious materials. These sediments due to their mineralogical composition as aluminosilicates; are materials that can be used after heat treatment. Sedimentary clays were characterized before and after calcination by X-ray diffraction, ATG / ATD, spectroscopy (FTIR) and XRF analysis. The calcination was carried out on the raw material sieved at 80 μm for a temperature of 750 ° C, for 3.4 and 5 hours. The reactivity of the calcined products was measured using isothermal calorimetric analysis (DSC) on pastes prepared by mixing an alkaline solution of sodium hydroxide (NaOH) 8 M in an amount allowing to have a Na / Al ratio close to 1 (1: 1). Also, cubic mortar samples were prepared with a ratio L / S: 0.8, sealed and cured for 24 hours at 60 ° C and then at room temperature until the day they were submited to mechanical testing. to check the extent of geopolymerization. The results obtained allowed to optimize the calcination time of 5 hours for a better reactivity of these sediments, and a concentration of 8M of sodium hydroxide and more suitable to have the best mechanical performances.

scholarly journals Characterization and Analysis of the Carbonation Process of a Lime Mortar Obtained from Phosphogypsum Waste

2021 ◽  
Vol 18 (12) ◽  
pp. 6664
Author(s):  
María Isabel Romero-Hermida ◽  
Antonio María Borrero-López ◽  
Vicente Flores-Alés ◽  
Francisco Javier Alejandre ◽  
José María Franco ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Mineralogical Composition ◽  
Barium Sulphate ◽  
Negative Influence ◽  
Raw Material ◽  
Porous System ◽  
Waste Products ◽  
Liesegang Rings ◽  
Carbonation Process ◽  
Ultrasonic Propagation

This work addresses the reuse of waste products as a raw material for lime putties, which are one of the components of mortar. 1:3 Lime/sand mortars very similar to conventional construction mortars were prepared using a lime putty obtained from the treatment of phosphogypsum with sodium hydroxide. The physical, rheological and mechanical properties of this phosphogypsum-derived mortar have been studied, as well as the mineralogical composition, microstructure by scanning electron microscope (SEM) and curing process by monitoring carbonation and ultrasonic propagation velocity. Considering the negative influence of sulphates on the hardened material, the behaviour of the material after sulphates precipitation by adding barium sulphate was additionally tested. Carbonation progressed from the outside to the inside of the specimen through the porous system by Liesegang rings patterns for mortars with soluble sulphates, while the carbonation with precipitated sulphates was controlled by diffusion-precipitation. Overall, the negative influence of low-sulphate contents on the mechanical properties of mortars was verified. It must be highlighted the importance of their precipitation to obtain adequate performance.

scholarly journals MATHEMATICAL MODELING OF LEACHING PROCESS OF RED MUD IN ORDER TO OBTAIN THE KINETICS PARAMETERS

2015 ◽  
Vol 14 (2) ◽  
pp. 90 ◽  
Author(s):  
K. L. M. Dos Passos ◽  
B. M. Viegas ◽  
E. N. Macêdo ◽  
J. A. S. Souza ◽  
E. M. Magalhães
Keyword(s):  
Experimental Data ◽  
Mathematical Model ◽  
Red Mud ◽  
Mineralogical Composition ◽  
Raw Material ◽  
Data Conversion ◽  
Kinetics Parameters ◽  
Leaching Process ◽  
Iron Leaching ◽  
The Mathematical Model

The use of the waste of the Bayer process, red mud, is due to its chemical and mineralogical composition that shows a material rich in oxides of iron, titanium and aluminum. Some studies conducted show that this waste can be applied as a source of alternative raw material for concentration and subsequent recovery of titanium compounds from an iron leaching process, which is present in higher amounts, about 30% by weight. To obtain a greater understanding about the leaching kinetics, the information of the kinetic data of this process is very important. In this context, the main objective of this work is the development of a mathematical model that is able to fit the experimental data (conversion / extraction iron, titanium and aluminum) of the leaching process by which is possible to obtain the main kinetic parameters such as the activation energy and the velocity of chemical reactions as well as the controlling step of the process. The development of the mathematical model was based on the model of core decreasing. The obtained model system of ordinary differential equations was able to fit the experimental data obtained from the leaching process, enabling the determination of the controlling step, the rate constants and the activation energies of the leaching process.

Chemical Alumina Preparation by Using High Alumina Content Fly Ash

2017 ◽  
pp. 115-120 ◽  
Author(s):  
Guozhi Lv ◽  
Ting-an Zhang ◽  
Weiguang Zhang ◽  
Xiaofeng Zhu ◽  
Yan Liu ◽  
...  
Keyword(s):  
Fly Ash ◽  
Alumina Content ◽  
High Alumina ◽  
High Alumina Content
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