Mechanical Properties of Volcanic Ash Based Geopolymer Concrete

2016 ◽  
Vol 857 ◽  
pp. 377-381 ◽  
Author(s):  
Puput Risdanareni ◽  
Adjib Karjanto ◽  
Januarti Jaya Ekaputri ◽  
Poppy Puspitasari ◽  
Febriano Khakim

This paper presents the result of study on using volcanic ash which obtained from Mount Kelud as fly ash replacement material to produce geopolymer concrete. Test was conducted on geopolymer concrete mixture with 0%, 25%, 50% and 100% fly ash replacement with Kelud volcanic ash. Sodium hydroxide (NaOH) and Sodium Silicate (Na2SiO3) were applied as alkaline activator. The mechanical properties was assessed by compressive strength while workability of fresh concrete by slump test. Producing geopolymer concrete with volcanic ash is possible with maximum replacement of up to 50%. Research and development on eco-friendly material such as volcanic ash is very useful to help reconstruction process of volcanic disaster around the world.

2021 ◽  
Vol 11 (7) ◽  
pp. 3032
Author(s):  
Tuan Anh Le ◽  
Sinh Hoang Le ◽  
Thuy Ninh Nguyen ◽  
Khoa Tan Nguyen

The use of fluid catalytic cracking (FCC) by-products as aluminosilicate precursors in geopolymer binders has attracted significant interest from researchers in recent years owing to their high alumina and silica contents. Introduced in this study is the use of geopolymer concrete comprising FCC residue combined with fly ash as the requisite source of aluminosilicate. Fly ash was replaced with various FCC residue contents ranging from 0–100% by mass of binder. Results from standard testing methods showed that geopolymer concrete rheological properties such as yield stress and plastic viscosity as well as mechanical properties including compressive strength, flexural strength, and elastic modulus were affected significantly by the FCC residue content. With alkali liquid to geopolymer solid ratios (AL:GS) of 0.4 and 0.5, a reduction in compressive and flexural strength was observed in the case of geopolymer concrete with increasing FCC residue content. On the contrary, geopolymer concrete with increasing FCC residue content exhibited improved strength with an AL:GS ratio of 0.65. Relationships enabling estimation of geopolymer elastic modulus based on compressive strength were investigated. Scanning electron microscope (SEM) images and X-ray diffraction (XRD) patterns revealed that the final product from the geopolymerization process consisting of FCC residue was similar to fly ash-based geopolymer concrete. These observations highlight the potential of FCC residue as an aluminosilicate source for geopolymer products.


2016 ◽  
Vol 857 ◽  
pp. 400-404
Author(s):  
Tian Yu Xie ◽  
Togay Ozbakkaloglu

This paper presents the results of an experimental study on the behavior of fly ash-, bottom ash-, and blended fly and bottom ash-based geopolymer concrete (GPC) cured at ambient temperature. Four bathes of GPC were manufactured to investigate the influence of the fly ash-to-bottom ash mass ratio on the microstructure, compressive strength and elastic modulus of GPC. All the results indicate that the mass ratio of fly ash-to-bottom ash significantly affects the microstructure and mechanical properties of GPCs


2019 ◽  
Vol 270 ◽  
pp. 01004
Author(s):  
Rachmansyah ◽  
Harianto Hardjasaputra ◽  
Meilanie Cornelia

The Earth Summit 1997 in Kyoto (Japan), industrialized countries agreed to reduce gas emissions by 21% to avoid global warming due to greenhouse effect with the release of CO2 into the air. From the research result, cement industry sector all over the world contributes about 8 - 10% of total CO2 emission. This number is quite high and if there is not a special action to reduce, CO2 emissions will continue to increase along with the rapid development of infrastructure in various parts of the world including in Indonesia. To support greenhouse effect reduction efforts due to CO2 emissions and environmental conservation, civil engineers in the world are taking steps to achieve Sustainable Concrete Technology, in order to create “Green Concrete”. For that reason in the direction of “Green Concrete”, innovation is needed to reduce or replace cement in the concrete mixing. The ash waste electrical power generating plants of fly ash is a material containing many SiO2 and Al2O3 which can be used to replace the overall of cement in concrete. Geopolymer concrete is a fly ash-based concrete that replaces the entire cement in its manufacture. Workability in mixing geopolymer concrete is very low, due to the rapid reaction of the alkaline solution when it reacts with fly ash. To improve the workability can be added water at the time of mixing. The fly ash used in the mixing from the Paiton power plant in East Java with grain size 12.06 μm with round granules and chemical composition of fly ash containing SiO2, Al2O3 and Fe2O3 with a total of 75.151%. The planned compressive strength of the concrete is 45 MPa, with a variation of 8M, 12M and 16M NaOH molarity and the ratio of NaOH and Na2SiO3 is 1. Addition of water in concrete mixing with variations of 15, 17.5, 20, 22.5 and 25 liters / m3. The results of this study indicate that the more addition of water in the manufacture of geopolymer concrete can also increase the value of slump, but the excessive addition of water will result in a decrease in the compressive strength of the concrete caused by a decrease in the concentration of the alkaline solution. High molarity values will require additional water to reach the same slump value compared to lower NaOH molarity. With the same mix design, the optimal compressive strength at 8M NaOH was 48.18 MPa with 17.5 liters/m3 of water added with a slump of 12 cm, for 12M NaOH the optimal compressive strength was 51.65 MPa with the addition of 20 liter/m3 with 10 cm slump, while for 16M NaOH the optimum compressive strength is 59.70 MPa with 22.5 liters/m3 of water added with a 5 cm slump. The higher the NaOH molarity will result in a higher compressive strength value and geopolymer concrete compressive strength at early age is higher than conventional concrete.


2021 ◽  
Vol 30 (3) ◽  
pp. 464-476
Author(s):  
Haider Owaid ◽  
Haider Al-Baghdadi ◽  
Muna Al-Rubaye

Large quantities of paper and wood waste are generated every day, the disposal of these waste products is a problem because it requires huge space for their disposal. The possibility of using these wastes can mitigate the environmental problems related to them. This study presents an investigation on the feasibility of inclusion of waste paper ash (WPA) or wood ash (WA) as replacement materials for fly ash (FA) class F in preparation geopolymer concrete (GC). The developed geopolymer concretes for this study were prepared at replacement ratios of FA by WPA or WA of 25, 50, 75 and 100% in addition to a control mix containing 100% of FA. Sodium hydroxide (NaOH) solutions and sodium silicate (Na2SiO3) are used as alkaline activators with 1M and 10M of sodium hydroxide solution.The geopolymer concretes have been evaluated with respect to the workability, the compressive strength, splitting tensile strength and flexural strength. The results indicated that there were no significant differences in the workability of the control GC mix and the developed GC mixes incorporating WPA or WA. Also, the results showed that, by incorporating of 25–50% PWA or 25% WA, the mechanical properties (compressive strength, splitting tensile strength and flexural strength) of GC mixes slightly decreased. While replacement with 75–100% WPA or with 50–100% WA has reduced these mechanical properties of GC mixes. As a result, there is a feasibility of partial replacement of FA by up to 50% WPA or 25% WA in preparation of the geopolymer concrete.


Materials ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 6890
Author(s):  
Muhammad Ibraheem ◽  
Faheem Butt ◽  
Rana Muhammad Waqas ◽  
Khadim Hussain ◽  
Rana Faisal Tufail ◽  
...  

The purpose of this research is to study the effects of quarry rock dust (QRD) and steel fibers (SF) inclusion on the fresh, mechanical, and microstructural properties of fly ash (FA) and ground granulated blast furnace slag (SG)-based geopolymer concrete (GPC) exposed to elevated temperatures. Such types of ternary mixes were prepared by blending waste materials from different industries, including QRD, SG, and FA, with alkaline activator solutions. The multiphysical models show that the inclusion of steel fibers and binders can enhance the mechanical properties of GPC. In this study, a total of 18 different mix proportions were designed with different proportions of QRD (0%, 5%, 10%, 15%, and 20%) and steel fibers (0.75% and 1.5%). The slag was replaced by different proportions of QRD in fly ash, and SG-based GPC mixes to study the effect of QRD incorporation. The mechanical properties of specimens, i.e., compressive strength, splitting tensile strength, and flexural strength, were determined by testing cubes, cylinders, and prisms, respectively, at different ages (7, 28, and 56 days). The specimens were also heated up to 800 °C to evaluate the resistance of specimens to elevated temperature in terms of residual compressive strength and weight loss. The test results showed that the mechanical strength of GPC mixes (without steel fibers) increased by 6–11%, with an increase in QRD content up to 15% at the age of 28 days. In contrast, more than 15% of QRD contents resulted in decreasing the mechanical strength properties. Incorporating steel fibers in a fraction of 0.75% by volume increased the compressive, tensile, and flexural strength of GPC mixes by 15%, 23%, and 34%, respectively. However, further addition of steel fibers at 1.5% by volume lowered the mechanical strength properties. The optimal mixture of QRD incorporated FA-SG-based GPC (QFS-GPC) was observed with 15% QRD and 0.75% steel fibers contents considering the performance in workability and mechanical properties. The results also showed that under elevated temperatures up to 800 °C, the weight loss of QFS-GPC specimens persistently increased with a consistent decrease in the residual compressive strength for increasing QRD content and temperature. Furthermore, the microstructure characterization of QRD blended GPC mixes were also carried out by performing scanning electron microscopy (SEM), X-ray diffraction (XRD), and energy dispersive spectroscopy (EDS).


2021 ◽  
Vol 11 (18) ◽  
pp. 8722
Author(s):  
Rana Muhammad Waqas ◽  
Faheem Butt ◽  
Xulong Zhu ◽  
Tianshui Jiang ◽  
Rana Faisal Tufail

Geopolymer concrete (GPC), also known as an earth friendly concrete, has been under continuous study due to its environmental benefits and potential as a sustainable alternative to conventional concrete construction. However, there is still a lack of comprehensive studies focusing on the influence of all the design mix variables on the fresh and strength properties of GPC. GPC is still a relatively new material in terms of field application and has yet to secure international acceptance as a construction material. Therefore, it is important that comprehensive studies be carried out to collect more reliable information to expand this relatively new material technology to field and site applications. This research work aims to provide a comprehensive study on the factors affecting the fresh and hardened properties of ambient cured fly ash and slag based geopolymer concrete (FS-GPC). Industrial by-products, fly ash from thermal power plants, and ground granulated blast furnace slag from steel industries were utilized to produce ambient cured FS-GPC. A series of experiments were conducted to study the effect of various parameters, i.e., slag content (10%, 20%, 30%, and 50%), amount of alkaline activator solution (AAS) (35% and 40%), sodium silicate (SS) to sodium hydroxide (SH) ratio (SS/SH = 2.0, 2.5 and 3.0), sodium hydroxide concentration (10 M, 12 M, and 14 M) and addition of extra water on fresh and mechanical properties of FS-GPC. The workability of the fresh FS-GPC mixes was measured by the slump cone test. The mechanical properties of the mixes were evaluated by compressive strength, split tensile strength, flexure strength, and static modulus tests. The results revealed that workability of FS-GPC is greatly reduced by increasing slag content, molarity of NaOH solution, and SS/SH ratio. The compressive strength was improved with an increase in the molarity of NaOH solution and slag content and a decrease in AAS content from 40% to 35%. However, the influence of SS/SH ratio on mechanical properties of FS-GPC has a varying effect. The addition of extra water to enhance the workability of GPC matrix caused a decrease in the compressive strength. The validity of the equations suggested by previous studies to estimate the tensile and flexural strength and elastic modulus of FS-GPC mixes were also evaluated. Based on the test results of this study, empirical equations are proposed to predict the splitting tensile strength, flexural strength, and elastic modulus of ambient cured FS-GPC. The optimal mixtures of FS-GPC in terms of workability and mechanical properties were also proposed for the field applications.


2022 ◽  
Vol 955 (1) ◽  
pp. 012010
Author(s):  
A Kustirini ◽  
Antonius ◽  
P Setiyawan

Abstract Geopolymer concrete is concrete that uses environmentally friendly materials, using fly ash from waste materials from the coal industry as a substitute for cement. To produce geopolymer concrete, an alkaline activator is required, with a mixture of Sodium Hydroxide and Sodium Silicate. This research is an experimental study to determine the effect of variations in the concentration of sodium hydroxide (NaOH) 8 Mol, 10 Mol, 12 Mol, and 14 Mol on the compressive strength of geopolymer concrete. Mortar Geopolymer uses a mixture of 1: 3 for the ratio of fly ash and sand, 2.5: 0.45 for the ratio of sodium silicate and sodium hydroxide as an alkaline solution. The specimens used a cube mold having dimension 5 cm x 5 cm x 5 cm, then tested at 7 days and 28 days. The test resulted that concentration of NaOH 12 Mol obtained the maximum compressive strength of geopolymer concrete, that is 38.54 MPa. At concentrations of 12 Mol NaOH and exceeding 12M, the compressive strength of geopolymer concrete decreased.


2020 ◽  
Vol 26 (1) ◽  
pp. 9-16
Author(s):  
Yulita Arni Priastiwi ◽  
Arif Hidayat ◽  
Dwi Daryanto ◽  
Zidny Salamsyah Badru

The presence of white soil in a geopolymer mortar affects the physical and mechanical properties of the mortar itself, especially in compressive strength, density and modulus of elasticity produced. Geopolymer mortar composed of fly ash, sand, water, and NaOH which acts as an alkaline activator compared to mortar from the same material, but white soil from Kupang is added as a substitution of fly ash. Specimens are made in six variations. Geopolymer mortar composers using a ratio of 1 binder: 3 sand with w/b of 0.5. Binder composed of fly ash with white soil substitution of 0; 5; 10; 15; 20 and 30% by weight of fly ash. An activator NaOH 8M solution was added to the mixture. Both white soil and fly ash pass of sieve no. 200 with a moisture content of 0%. Mortar made measuring 5x5x5 cm. The mortar was treated by the oven of method at 60 oC for 24 hours until the mortar does not change in weight. The test results show geopolymer mortar with 15% substitution of white soil to fly ash has the highest compressive strength, density and modulus of elasticity among other variations. In all mortar variations, compressive strength at 14 days has reached 75% of strength at 28 days.


2018 ◽  
Vol 26 (2) ◽  
pp. 30-34 ◽  
Author(s):  
M. Venu ◽  
T. D. Gunneswara Rao

AbstractThis paper focuses on the mechanical properties and modulus of elasticity of fly ash and GGBS based geopolymer concrete. In this study an 8 molarity concentration of NaOH and alkaline liquid ratio in a ratio of 2.5 was used. This study includes the stress-strain behaviour along with the flexural strength, compressive strength and split tensile strengths for the GPC20, GPC40 and GPC60 grades. Tests were carried out on 150 mm × 150 mm × 150 mm cubes and 100 × 100 × 500 mm prisms and 150 × 300 mm cylindrical geopolymer concrete specimens. The test results not- ed the good mechanical properties and measured stress-strain relations of fly ash and GGBS based geopolymer concrete under ambient curing conditions. The elastic modulus was significantly varied with increases in the grade of the concrete. An equation was proposed to determine the modulus of elasticity based on the compressive strength of the geopolymer concrete.


2015 ◽  
Vol 754-755 ◽  
pp. 406-412 ◽  
Author(s):  
Puput Risdanareni ◽  
Januarti Jaya Ekaputri ◽  
Mohd Mustafa Al Bakri Abdullah

This paper describes the effect of alkaline activator ratio (Na2SiO3/NaOH) to mechanical properties of geopolymer concrete. The mechanical properties of geopolymer concrete were assessed by setting time, split tensile strength and porosity. Fly ash was used as a cement substitute, and trass used as filler. While, Natrium hydroxide (NaOH) and Sodium Silicate (Na2SiO3) was applied as alkaline activator. In this study, NaOH concentration eight and ten molar with an alkaline activator ratio Na2SiO3/ NaOH by mass: 0.5, 1, 1.5, 2 and 2.5 were used. The test result showed that setting time, porosity and split tensile strength of geopolymer concrete were hardly influenced by NaOH concentration and the alkaline activator ratio. The alkaline activator ratio of Na2SiO3/NaOH has an optimum value at 2 and 2.5. Test result showed that the fastest setting time was 25 minute, the highest amount of closed porosity was 9.035 % and the highest split tensile strength was 2.86 MPa.


Sign in / Sign up

Export Citation Format

Share Document