Measurement of dispersible clay is important for the diagnosis of structural
stability problems in soil. However, clay dispersibility is known to change
with water content and time. The purpose of the present study was to determine
how incubation of sodic soil under different water content regimes influences
clay dispersibility. Two topsoils (depth 0-0·1 m), one sodic
[exchangeable sodium percentage (ESP) 9 · 7] and the other
non-sodic (ESP 3·8), were collected from an experimental pasture at
Kyabram, Victoria, and 2 soils, a sodic topsoil (depth 0-0·1 m, ESP
6·9) and the corresponding subsoil (depth 0·2-0 m, ESP
25·7), were collected from a cropped field at Two Wells, South
Australia. The soils were incubated for 264 days in a split-plot design. The
main treatments were soil type and incubation water content: continuously
air-dry, continuously wet (-50 kPa), or with wet/dry cycles. The
subtreatment was water content at analysis: air dry or wet (-50 kPa). Clay
dispersion was greater when measured on wet soils than dry soils, irrespective
of water contents during the prior incubation. Electrical conductivity
increased, and sodium adsorption ratio (SAR), pH, and organic carbon content
decreased as a function of the time for which the soils were wet. In the
Kyabram soils that were wet when analysed, easily dispersible clay content
increased with SAR. Decreases in moderately dispersible clay under the
wetting/drying regime were not related to electrolyte composition, and
were attributed to particle rearrangement and cementation. The decreases in
clay dispersibility with time occurred despite net losses of carbohydrate and
aliphatic materials. An implication of the work is that the decomposition of
soil organic matter, even in the absence of fresh additions, may reduce clay
dispersion in sodic soils by altering electrolyte concentration and
composition.