scholarly journals Measurement report: Nitrogen isotopes (<i>δ</i><sup>15</sup>N) and first quantification of oxygen isotope anomalies (<i>Δ</i><sup>17</sup>O, <i>δ</i><sup>18</sup>O) in atmospheric nitrogen dioxide

2021 ◽  
Vol 21 (13) ◽  
pp. 10477-10497
Author(s):  
Sarah Albertin ◽  
Joël Savarino ◽  
Slimane Bekki ◽  
Albane Barbero ◽  
Nicolas Caillon
Keyword(s):  
Isotopic Composition ◽  
Nitrogen Dioxide ◽  
Diurnal Cycle ◽  
Isotope Fractionation ◽  
Nitrogen Isotopes ◽  
Tropospheric Chemistry ◽  
Peroxyl Radicals ◽  
Diurnal Variability ◽  
Bayesian Isotope Mixing Model ◽  
First Time

Abstract. The isotopic composition of nitrogen and oxygen in nitrogen dioxide (NO2) potentially carries a wealth of information about the dynamics of the nitrogen oxides (NOx = nitric oxide (NO) + NO2) chemistry in the atmosphere. While nitrogen isotopes of NO2 are subtle indicators of NOx emissions and chemistry, oxygen isotopes are believed to reflect only the O3 / NOx / VOC chemical regime in different atmospheric environments. In order to access this potential tracer of the tropospheric chemistry, we have developed an efficient active method to trap atmospheric NO2 on denuder tubes and measured, for the first time, its multi-isotopic composition (δ15N, δ18O, and Δ17O). The Δ17O values of NO2 trapped at our site in Grenoble, France, show a large diurnal cycle peaking in late morning at (39.2 ± 0.3) ‰ and decreasing at night until (20.5 ± 0.3) ‰. On top of this diurnal cycle, Δ17O also exhibits substantial daytime variability (from 29.7 ‰ to 39.2 ‰), certainly driven by changes in the O3 to peroxyl radicals (RO2) ratio. The nighttime decay of Δ17O(NO2) appears to be driven by NO2 slow removal, mostly from conversion into N2O5, and its formation from the reaction between O3 and freshly emitted NO. As expected from a nighttime Δ17O(NO2) expression, our Δ17O(NO2) measured towards the end of the night is quantitatively consistent with typical values of Δ17O(O3). Daytime N isotope fractionation is estimated using a general expression linking it to Δ17O(NO2). An expression is also derived for the nighttime N isotope fractionation. In contrast to Δ17O(NO2), δ15N(NO2) measurements exhibit little diurnal variability (−11.8 ‰ to −4.9 ‰) with negligible isotope fractionations between NO and NO2, mainly due to high NO2 / NOx ratios, excepted during the morning rush hours. The main NOx emission sources are estimated using a Bayesian isotope mixing model, indicating the predominance of traffic emissions in this area. These preliminary results are very promising for using the combination of Δ17O and δ15N of NO2 as a probe of the NOx sources and fate and for interpreting nitrate isotopic composition records.

scholarly journals Measurement report: Nitrogen isotopes (δ<sup>15</sup>N) and first quantification of oxygen isotope anomalies (Δ<sup>17</sup>O, δ<sup>18</sup>O) in atmospheric nitrogen dioxide

2020 ◽  
Author(s):  
Sarah Albertin ◽  
Joël Savarino ◽  
Slimane Bekki ◽  
Albane Barbero ◽  
Nicolas Caillon
Keyword(s):  
Isotopic Composition ◽  
Nitrogen Dioxide ◽  
Diurnal Cycle ◽  
Nitrogen Isotopes ◽  
Tropospheric Chemistry ◽  
Peroxyl Radicals ◽  
Nox Emissions ◽  
Night Time ◽  
Nitrogen Exchange ◽  
First Time

Abstract. The isotopic composition of nitrogen and oxygen in nitrogen dioxide (NO2) potentially carries a wealth of information about the dynamics of the nitrogen oxides (NOx = nitric oxide(NO) + NO2) chemistry in the atmosphere. While nitrogen isotopes of NO2 are subtle indicators of emissions, NOx chemistry and isotopic nitrogen exchange between NO and NO2, oxygen isotopes are believed to reflect only the O3/NOx/VOC chemical regime in different atmospheric environments. In order to access this potential tracer of the tropospheric chemistry, we have developed an efficient active method to trap atmospheric NO2 on denuder tubes and measured, for the first time, its multi-isotopic composition (δ15N, δ18O, and Δ17O). The δ15N values of NO2 trapped at our site in Grenoble, France, show little variability (−11.8 to −4.9 ‰) with negligible N isotope fractionations between NO and NO2 due to high NO2/NOx ratios. NOx emissions main sources are estimated using a stable isotope model indicating the predominance of traffic NOx emissions in this area. The Δ17O values, however, reveal an important diurnal cycle peaking in late morning at (39.2 ± 1.7) ‰ and decreasing at night until (20.5 ± 1.7) ‰. On top of this diurnal cycle, Δ17O also has substantial variability during the day (from 29.7 to 39.2 ‰), certainly driven by changes in the O3 to peroxyl radicals ratio. The night-time decay of Δ17O(NO2) appears to be driven by NO2 slow removal, mostly from conversion into N2O5, and its formation from the reaction between O3 and emitted NO. Our Δ17O(NO2) measured towards the end of the night is quantitatively consistent with typical values of Δ17O(O3). These preliminary results are very promising for using Δ17O of NO2 as a probe of the atmospheric oxidative activity and for interpreting NO3− isotopic composition records.

scholarly journals Alkali metal doping of black phosphorus monolayer for ultrasensitive capture and detection of nitrogen dioxide

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Azam Marjani ◽  
Mehdi Ghambarian ◽  
Mohammad Ghashghaee
Keyword(s):  
Alkali Metal ◽  
Nitrogen Dioxide ◽  
Work Function ◽  
Black Phosphorus ◽  
Research Interest ◽  
Metal Doping ◽  
Li Doping ◽  
Rational Development ◽  
Parallel Configuration ◽  
First Time

AbstractBlack phosphorus nanostructures have recently sparked substantial research interest for the rational development of novel chemosensors and nanodevices. For the first time, the influence of alkali metal doping of black phosphorus monolayer (BP) on its capabilities for nitrogen dioxide (NO2) capture and monitoring is discussed. Four different nanostructures including BP, Li-BP, Na-BP, and K-BP were evaluated; it was found that the adsorption configuration on Li-BP was different from others such that the NO2 molecule preferred a vertical stabilization rather than a parallel configuration with respect to the surface. The efficiency for the detection increased in the sequence of Na-BP < BP < K-BP < Li-BP, with the most significant improvement of + 95.2% in the case of Li doping. The Na-BP demonstrated the most compelling capacity (54 times higher than BP) for NO2 capture and catalysis (− 24.36 kcal/mol at HSE06/TZVP). Furthermore, the K-doped device was appropriate for both nitrogen dioxide adsorption and sensing while also providing the highest work function sensitivity (55.4%), which was much higher than that of BP (10.4%).

scholarly journals The diurnal cycle of cloud profiles over land and ocean between 51° S and 51° N, seen by the CATS spaceborne lidar from the International Space Station

2018 ◽  
Vol 18 (13) ◽  
pp. 9457-9473 ◽  
Author(s):  
Vincent Noel ◽  
Hélène Chepfer ◽  
Marjolaine Chiriaco ◽  
John Yorks
Keyword(s):  
High Altitude ◽  
International Space Station ◽  
Diurnal Cycle ◽  
Space Station ◽  
Cloud Fraction ◽  
Vertical Profiles ◽  
Diurnal Variability ◽  
International Space ◽  
Low Level ◽  
Diurnal Cycles

Abstract. We document, for the first time, how detailed vertical profiles of cloud fraction (CF) change diurnally between 51∘ S and 51∘ N, by taking advantage of 15 months of measurements from the Cloud-Aerosol Transport System (CATS) lidar on the non-sun-synchronous International Space Station (ISS). Over the tropical ocean in summer, we find few high clouds during daytime. At night they become frequent over a large altitude range (11–16 km between 22:00 and 04:00 LT). Over the summer tropical continents, but not over ocean, CATS observations reveal mid-level clouds (4–8 km above sea level or a.s.l.) persisting all day long, with a weak diurnal cycle (minimum at noon). Over the Southern Ocean, diurnal cycles appear for the omnipresent low-level clouds (minimum between noon and 15:00) and high-altitude clouds (minimum between 08:00 and 14:00). Both cycles are time shifted, with high-altitude clouds following the changes in low-altitude clouds by several hours. Over all continents at all latitudes during summer, the low-level clouds develop upwards and reach a maximum occurrence at about 2.5 km a.s.l. in the early afternoon (around 14:00). Our work also shows that (1) the diurnal cycles of vertical profiles derived from CATS are consistent with those from ground-based active sensors on a local scale, (2) the cloud profiles derived from CATS measurements at local times of 01:30 and 13:30 are consistent with those observed from CALIPSO at similar times, and (3) the diurnal cycles of low and high cloud amounts (CAs) derived from CATS are in general in phase with those derived from geostationary imagery but less pronounced. Finally, the diurnal variability of cloud profiles revealed by CATS strongly suggests that CALIPSO measurements at 01:30 and 13:30 document the daily extremes of the cloud fraction profiles over ocean and are more representative of daily averages over land, except at altitudes above 10 km where they capture part of the diurnal variability. These findings are applicable to other instruments with local overpass times similar to CALIPSO's, such as all the other A-Train instruments and the future EarthCARE mission.

ISOTOPE-GEOCHEMICAL FEATURES OF AUTHENIC CARBONATES OF THE YU1 PRODUCING HORIZON OF THE VERKH-TARSKOYE OIL FIELD (SOUTH OF WESTERN SIBERIA)

2020 ◽  
pp. 20-28
Author(s):  
L. G. Vakulenko ◽  
◽  
O. D. Nikolenko ◽  
D. A. Novikov ◽  
P. A. Yan ◽  
...  
Keyword(s):  
Isotopic Composition ◽  
Carbonate Rocks ◽  
Western Siberia ◽  
Oil Field ◽  
Third Generation ◽  
The Third ◽  
First Time ◽  
Different Sources ◽  
Sources Of Co2 ◽  
Comprehensive Study

A comprehensive study of the composition of sand and silt deposits of the Yu1 horizon of the Vasyuganskaya Formation upper part of the Verkh-Tarskoye oil field has been carried out. Associations of authigenic minerals have been determined in their cement, among which the calcite is the most widespread. According to petrographic parameters, three generations of calcite have been identified for which detailed isotopicgeochemical and ultramicroscopic studies were carried out for the first time. Wide and multi directional changes in the isotopic composition of carbon and oxygen and in the chemical composition of carbonate minerals were recorded, they indicate significant variations in the conditions of diagenesis and catagenesis, primarily temperature, and different sources of CO2. Significant variations in the isotopic composition of formation waters and its relationship with the isotopic composition of carbonates have been established. Thus, a narrow interval of close δ13C values was revealed, amounting to –10.5 to –9.1 ‰ in the formation waters of group II, and from –10.7 to –9.1 ‰ in calcites of the third generation. The source of CO2 in this system should be considered a carbon dioxide, which is formed in the process of metamorphism of carbonate rocks of the Paleozoic age.

scholarly journals Characterizing the diurnal cycle of South Atlantic stratocumulus cloud properties from satellite retrievals

2018 ◽  
Author(s):  
Chellappan Seethala ◽  
Jan Fokke Meirink ◽  
Ákos Horváth ◽  
Ralf Bennartz ◽  
Rob Roebeling
Keyword(s):  
Diurnal Variation ◽  
Biomass Burning ◽  
Diurnal Cycle ◽  
Near Infrared ◽  
South Atlantic ◽  
Radiation Budget ◽  
Ozone Monitoring Instrument ◽  
Liquid Water Path ◽  
Diurnal Variability ◽  
Late Afternoon

Abstract. Marine stratocumulus (Sc) clouds play an essential role in the earth radiation budget. Here, we compare liquid water path (LWP), optical thickness (COT), and effective radius (CER) retrievals from two years of collocated Spinning Enhanced Visible and InfraRed Imager (SEVIRI), MODerate resolution Imaging Spectroradiometer (MODIS), and Tropical Rainfall Measuring Mission Microwave Imager (TMI) observations, estimate the effect of biomass burning smoke on passive imager retrievals, as well as evaluate the diurnal cycle of South Atlantic marine Sc clouds. The effect of absorbing aerosols from biomass burning on the retrievals was investigated using aerosol index (AI) obtained from the Ozone Monitoring Instrument (OMI). SEVIRI and MODIS LWPs were found to decrease with increasing AI relative to TMI LWP, consistent with well-known negative visible/near-infrared retrieval biases in COT and CER. In the aerosol-affected months of July–August–September, SEVIRI LWP – based on the 1.6-µm CER – was biased low by 14 g m−2 (~ 16 %) compared to TMI in overcast scenes, while MODIS LWP showed a smaller low bias of 4 g m−2 (~ 5 %) for the 1.6-µm channel and a high bias of 8 g m−2 (~ 10 %) for the 3.7-µm channel compared to TMI. Neglecting aerosol-affected pixels reduced the mean SEVIRI-TMI LWP bias considerably. On a two-year data base, SEVIRI LWP had a correlation with TMI and MODIS LWP of about 0.86 and 0.94, respectively, and biases of only 4–8 g m−2 (5–10 %) for overcast cases. The SEVIRI LWP diurnal cycle was in good overall agreement with TMI except in the aerosol-affected months. Both TMI and SEVIRI LWP decreased from morning to late afternoon, after which a slight increase was observed. Terra and Aqua MODIS mean LWPs also suggested a similar diurnal variation. The relative amplitude of the two-year mean and seasonal mean LWP diurnal cycle varied between 35–40 % from morning to late afternoon for overcast cases. The diurnal variation in SEVIRI LWP was mainly due to changes in COT, while CER showed only little diurnal variability.

Mo mobility in lateritic weathering profiles overlying ultramafic rocks of the East Sulawesi Ophiolite, Indonesia

2021 ◽  
Author(s):  
Adrianus Damanik ◽  
Martin Wille ◽  
Martin Grosjean ◽  
Sri Yudawati Cahyarini ◽  
Hendrik Vogel
Keyword(s):  
Isotopic Composition ◽  
Chemical Weathering ◽  
Isotopic Fractionation ◽  
Reduced Form ◽  
Ultramafic Rocks ◽  
Early Earth ◽  
Atmospheric Input ◽  
First Time ◽  
Weathering Process ◽  
Mo Isotopes

&lt;p&gt;Molybdenum (Mo) isotopes are known as sensitive recorders for changes in redox conditions because the oxidized form of Mo (Mo VI) is more soluble, whereas its reduced form is more particle reactive. Previous studies suggest that Mo isotopic fractionation during the weathering process is controlled by atmospheric input, Mo host, and bedrock composition. However, Mo isotopic variation and processes influencing fractionation in weathering profiles overlying ultramafic bedrock, the early Earth analog, have yet to be explored. This study explores for the first time (1) Mo behavior and (2) isotopic fractionation in two representative and intensely-weathered lateritic profiles overlying ultramafic bedrock of the East Sulawesi Ophiolite, Indonesia. Mo concentrations measured on samples obtained from laterite successions studied here range between 60 - 537 ppb and are overall higher compared to bedrock values ranging between 9 - 45 ppb. The Mo isotope compositions of laterite samples vary between -0.043&amp;#8240; to -0.161&amp;#8240; &amp;#948;&lt;sup&gt;98&lt;/sup&gt;Mo&lt;sub&gt;NIST3134&lt;/sub&gt;. The overall close to mantle Mo isotopic composition of the laterite samples, their small Mo isotope variability, and the covariation between Mo and Ti concentrations suggest low mobility of Mo during chemical weathering and laterite formation. This low Mo mobility is likely a consequence of a) the low Mo concentration of the ultramafic protolith and b) adsorption of Mo to secondary Fe-Oxides during laterite formation under oxic weathering conditions.&lt;/p&gt;

scholarly journals Human plasma dynamically quenches the fluorescein at the initial point of oxygen radical absorption capacity (ORAC) assay

2019 ◽  
Vol 12 (1) ◽  
Author(s):  
Harshi Gunawardena ◽  
Renuka Silva ◽  
Pathmasiri Ranasinghe
Keyword(s):  
Human Plasma ◽  
Fluorescence Probe ◽  
Initial Point ◽  
Oxygen Radical ◽  
Absorption Capacity ◽  
Peroxyl Radicals ◽  
Dynamic Quenching ◽  
Initial Stage ◽  
First Time ◽  
Dose Dependent

Abstract Objective Oxygen radical absorbance capacity (ORAC) assay measures the quenching of fluorescent probe by peroxyl radicals. Antioxidants present in biological systems block the quenching of fluorescence probe. We experienced the dynamic quenching of fluorescein, the fluorescence probe used in ORAC assay by the human plasma while plasma ORAC assay was optimized. Therefore, for the first time, we report the quenching of fluorescein by human plasma at the initial point of ORAC assay. Results Aqueous whole and non-protein fractions of plasma were used in the analysis. Since the both fractions showed a similar pattern of quenching at the initial stage, quenched percentage of fluorescein was calculated and added to each sample in subsequent analysis. Addition of extra 20% fluorescein allowed plasma samples to quench the required amount of fluorescein and follow the normal decay curves afterwards. Further, change of fluorescein quenching (ΔF/F0) disclosed a dose dependent linear relationship with plasma (R2 = 0.8). It can be speculated that dynamic quenching exhibited by human plasma biomolecule/s at the initial stage would be of non-protein aqueous phase molecule/s. We suggest initiating further studies to detect, identify and quantify the fluorescein quenching biomolecules present in human plasma for further improvements in plasma ORAC assay.

Response of Seasonal Simulations of a Regional Climate Model to High-Frequency Variability of Soil Moisture during the Summers of 1988 and 1993

2007 ◽  
Vol 8 (4) ◽  
pp. 738-757 ◽  
Author(s):  
Song Yang ◽  
S-H. Yoo ◽  
R. Yang ◽  
K. E. Mitchell ◽  
H. van den Dool ◽  
...  
Keyword(s):  
Soil Moisture ◽  
Water Vapor ◽  
Diurnal Cycle ◽  
High Frequency ◽  
Large Scale ◽  
Climate Model ◽  
Regional Climate ◽  
Water Vapor Transport ◽  
Diurnal Variability ◽  
High Frequency Variability

Abstract This study employs the NCEP Eta Regional Climate Model to investigate the response of the model’s seasonal simulations of summer precipitation to high-frequency variability of soil moisture. Specifically, it focuses on the response of model precipitation and temperature over the U.S. Midwest and Southeast to imposed changes in the diurnal and synoptic variability of soil moisture in 1988 and 1993. High-frequency variability of soil moisture increases (decreases) precipitation in the 1988 drought (1993 flood) year in the central and southern-tier states, except along the Gulf Coast, but causes smaller changes in precipitation along the northern-tier states. The diurnal variability and synoptic variability of soil moisture produce similar patterns of precipitation change, indicating the importance of the diurnal cycle of land surface process. The increase (decrease) in precipitation is generally accompanied by a decrease (increase) in surface and lower-tropospheric temperatures, and the changes in precipitation and temperature are attributed to both the local effect of evaporation feedback and the remote influence of large-scale water vapor transport. The precipitation increase and temperature decrease in 1988 are accompanied by an increase in local evaporation and, more importantly, by an increase in the large-scale water vapor convergence into the Midwest and Southeast. Analogous but opposite-sign behavior occurs in 1993 (compared to 1988) in changes in precipitation, temperature, soil moisture, evaporation, and large-scale water vapor transport. Results also indicate that, in regions where the model simulates the diurnal cycle of soil moisture reasonably well, including this diurnal cycle in the simulations improves model performance. However, no notable improvement in model precipitation can be found in regions where the model fails to realistically simulate the diurnal variability of soil moisture.

scholarly journals Diurnal cycle of the dust instantaneous direct radiative forcing over the Arabian Peninsula

2015 ◽  
Vol 15 (16) ◽  
pp. 9537-9553 ◽  
Author(s):  
S. Osipov ◽  
G. Stenchikov ◽  
H. Brindley ◽  
J. Banks
Keyword(s):  
Diurnal Cycle ◽  
Radiative Forcing ◽  
Surface Albedo ◽  
Arabian Peninsula ◽  
Extreme Values ◽  
Radiation Transport ◽  
Atmospheric Composition ◽  
Diurnal Variability ◽  
Wide Range ◽  
Direct Radiative Forcing

Abstract. In this study we attempted to better quantify radiative effects of dust over the Arabian Peninsula and their dependence on input parameters. For this purpose we have developed a stand-alone column radiation transport model coupled with the Mie, T-matrix and geometric optics calculations and driven by reanalysis meteorological fields and atmospheric composition. Numerical experiments were carried out for a wide range of aerosol optical depths, including extreme values developed during the dust storm on 18–20 March 2012. Comprehensive ground-based observations and satellite retrievals were used to estimate aerosol optical properties, validate calculations and carry out radiation closure. The broadband surface albedo, fluxes at the bottom and top of the atmosphere as well as instantaneous dust radiative forcing were estimated both from the model and observations. Diurnal cycle of the shortwave instantaneous dust direct radiative forcing was studied for a range of aerosol and surface characteristics representative of the Arabian Peninsula. Mechanisms and parameters responsible for diurnal variability of the radiative forcing were evaluated. We found that intrinsic variability of the surface albedo and its dependence on atmospheric conditions, along with anisotropic aerosol scattering, are mostly responsible for diurnal effects.

scholarly journals Mechanisms controlling primary and new production in a global ecosystem model – Part II: The role of the upper ocean short-term periodic and episodic mixing events

Ocean Science ◽  
2006 ◽  
Vol 2 (2) ◽  
pp. 267-279 ◽  
Author(s):  
E. E. Popova ◽  
A. C. Coward ◽  
G. A. Nurser ◽  
B. de Cuevas ◽  
T. R. Anderson
Keyword(s):  
Primary Production ◽  
Diurnal Cycle ◽  
Ecosystem Dynamics ◽  
Light Limitation ◽  
Biogeochemical Model ◽  
Late Winter ◽  
Short Term ◽  
New Production ◽  
Storm Activity ◽  
Diurnal Variability

Abstract. The use of 6 h, daily, weekly and monthly atmospheric forcing resulted in dramatically different predictions of plankton productivity in a global 3-D coupled physical-biogeochemical model. Resolving the diurnal cycle of atmospheric variability by use of 6 h forcing, and hence also diurnal variability in UML depth, produced the largest difference, reducing predicted global primary and new production by 25% and 10% respectively relative to that predicted with daily and weekly forcing. This decrease varied regionally, being a 30% reduction in equatorial areas primarily because of increased light limitation resulting from deepening of the mixed layer overnight as well as enhanced storm activity, and 25% at moderate and high latitudes primarily due to increased grazing pressure resulting from late winter stratification events. Mini-blooms of phytoplankton and zooplankton occur in the model during these events, leading to zooplankton populations being sufficiently well developed to suppress the progress of phytoplankton blooms. A 10% increase in primary production was predicted in the peripheries of the oligotrophic gyres due to increased storm-induced nutrient supply end enhanced winter production during the short term stratification events that are resolved in the run forced by 6 h meteorological fields. By resolving the diurnal cycle, model performance was significantly improved with respect to several common problems: underestimated primary production in the oligotrophic gyres; overestimated primary production in the Southern Ocean; overestimated magnitude of the spring bloom in the subarctic Pacific Ocean, and overestimated primary production in equatorial areas. The result of using 6 h forcing on predicted ecosystem dynamics was profound, the effects persisting far beyond the hourly timescale, and having major consequences for predicted global and new production on an annual basis.

Sign in / Sign up

Export Citation Format

Share Document