scholarly journals Evaluation of Changes in Some Physico-Chemical Properties of Bottled Water Exposed to Sunlight in Bauchi, Nigeria

2020 ◽  
Author(s):  
Rose E. Daffi ◽  
Fwangmun B. Wamyil
Keyword(s):  
Drinking Water ◽  
Bisphenol A ◽  
Environmental Protection Agency ◽  
Daily Intake ◽  
Control Sample ◽  
Bottled Water ◽  
Guideline Values ◽  
The Us ◽  
Us Epa ◽  
Control Samples

Abstract. It is common for bottled water and other assorted drinks to be seen displayed outside stores and in the sun in most parts of Nigeria. The country is mostly hot year-round and over the course of the year temperatures can rise to as high as 40 °C around March–April in the study area. The leaching effect of chemicals from polyethylene terephthalate (PET) bottled water was investigated for five (5) commercially available bottled water brands. Temperature, pH, Antimony, Bisphenol A and Nitrate levels were measured on day zero, 14 and 28 for control samples and samples exposed to direct sunlight, using destructive sampling technique. The study found that pH for brands B and D were lower than the Nigerian Standard for Drinking Water Quality (NSDWQ) and United States Environmental Protection Agency (US EPA) regulations at day zero. The control sample for Brand A maintained pH within the guideline values for 0–28 days while all Brands exposed to sunlight for 14 and 28 days had lower values than specified. Antimony was not detected in brands A, B and E in the baseline measurement at day zero while brands C and D had low values; after 28 days all the control samples still had Antimony levels within the US EPA standard. Meanwhile all the samples exposed to sunlight exceeded US EPA standard levels at 14 and 28days except brand A which was within limit at 14 days with value of 4.59 µg/L. All control and exposed samples were below the European Union Drinking Water Directive (EU DWD) total daily intake (TDI) of Bisphenol A (0.05 mg/kg body weight/day). Values obtained for Nitrate showed that all control samples did not exceed the US EPA guideline level for Nitrates in drinking water for 0, 14 ad 28 days while three (3) of the samples, Brands C, D and E, exceeded the guideline level at 28 days. Expose of bottled water to sunlight was seen to impair the quality of the water for consumption. It is recommended that regulators and practitioners drive implementation of proper storage/retailing of bottled water products and improve legislation on manufacture of plastics for food contact products.

scholarly journals Evaluation of changes in some physico-chemical properties of bottled water exposed to sunlight in Bauchi State, Nigeria

2021 ◽  
Vol 14 (1) ◽  
pp. 73-80
Author(s):  
Rose E. Daffi ◽  
Fwangmun B. Wamyil
Keyword(s):  
Drinking Water ◽  
Environmental Protection Agency ◽  
Daily Intake ◽  
Chemical Properties ◽  
Sampling Technique ◽  
The United States ◽  
Bottled Water ◽  
The European Union ◽  
Us Epa ◽  
Control Samples

Abstract. It is common for bottled water and other assorted drinks to be seen displayed outside stores and in the sun in most parts of Nigeria. The country is mostly hot year-round, and over the course of the year, temperatures can rise to as high as 40 ∘C around March–April in the study area. The leaching effect of chemicals from polyethylene terephthalate (PET) bottled water was investigated for five commercially available bottled water brands. Temperature, pH, antimony, bisphenol A (BPA), and nitrate levels were measured on days 0, 14, and 28 for control samples and samples exposed to direct sunlight, using destructive sampling technique. Antimony was not detected in brands A, B, and E in the baseline measurement at day 0, while brands C and D had low values; after 28 d all the control samples still had antimony levels within the United States Environmental Protection Agency (US EPA) standard. Meanwhile, all the samples exposed to sunlight exceeded US EPA standard levels at 14 and 28 d, except brand A which was within limit at 14 d with value of 4.59 µg L−1. All control and exposed samples were below the European Union Drinking Water Directive (EU DWD) total daily intake (TDI) of BPA (0.05 mg per kilogram of body weight)−1 d−1. Values obtained for nitrate showed that all control samples did not exceed the US EPA guideline level for nitrates in drinking water for days 0, 14, and 28, while three of the samples, i.e. brands C, D, and E, exceeded the guideline level at day 28. Exposure of bottled water to sunlight was seen to impair the quality of the water for consumption.

Potential Regulatory Problems Associated with Atrazine, Cyanazine, and Alachlor in Surface Water Source Drinking Water

1994 ◽  
Vol 8 (4) ◽  
pp. 852-861 ◽  
Author(s):  
Henry Nelson ◽  
R. David Jones
Keyword(s):  
Drinking Water ◽  
Surface Waters ◽  
Environmental Protection Agency ◽  
Water Source ◽  
The United States ◽  
Corn Belt ◽  
Annual Average ◽  
The Us ◽  
Us Epa ◽  
Lakes And Reservoirs

Post-application seasonal (May-July) average concentrations of atrazine, cyanazine, and, to a lesser extent, alachlor sometimes exceed their Maximum Contaminant Levels (MCLs) (3 ug/L for atrazine and 2 ug/L for alachlor) or Maximum Contaminant Level Goal (MCLG) (1 ug/L for cyanazine) in surface waters of the Mississippi and Great Lakes Basins. These three chemicals are among the primary pre-emergent herbicides applied to corn. MCLs and MCLGs are compared to annual average concentrations for regulatory purposes. However, annual average concentrations are much less frequently reported than post-application seasonal averages. In most cases, both seasonal and annual average concentrations are substantially less than the MCLs or MCLG. However, actual and estimated annual mean concentrations occasionally exceed the MCLs or MCLG. Actual or estimated exceedences occur more frequently for atrazine and cyanazine than for alachlor, and may occur more frequently in lakes or reservoirs with long retention times than in streams and rivers. Additional year round data, and data for lakes and reservoirs, are needed to determine the extent to which such exceedences occur throughout the corn belt. The American Water Works Association (AWWA) believes that substantial numbers of Community Water Systems (CWSs) within the corn belt are currently, or will be, in violation of the revised Safe Drinking Water Act (SDWA) with respect to atrazine and cyanazine. They are concerned that such violations could result in numerous CWSs having to implement expensive tertiary treatment systems such as granular activated carbon to decrease herbicide concentrations. The United States Environmental Protection Agency, (US EPA) is continuing to review data on the pesticide concentrations in reservoirs and lakes that registrants have been submitting over the last 18 mo under the 6(a)(2) adverse impact provision of the Federal Insecticide, Fungicide and Rodenticide Act (FIFRA). The US EPA is also currently using computer modeling and other methods to evaluate potential alternative and/or supplemental herbicides to reduce atrazine use. In June 1992, the US EPA approved revised labeling that is designed to reduce indirect atrazine loadings to surface waters. Additional mitigation methods have been proposed and are being considered.

scholarly journals Simulation of a biogas cleaning process using different amines

2018 ◽  
Vol 27 (47) ◽  
Author(s):  
Guillermo Sepúlveda ◽  
Luis Eduardo Jaimes ◽  
Leonardo Pacheco ◽  
Carlos Alirio Díaz
Keyword(s):  
Environmental Protection Agency ◽  
Landfill Gas ◽  
Cleaning Process ◽  
Fuel Gas ◽  
Combustion Properties ◽  
The Us ◽  
Us Epa ◽  
Combustible Gases ◽  
Combustion Processes ◽  
Landfill Gas Emissions

The use of biogas generated in landfills has gained importance in developing countries like Colombia. Taking into account that this biogas presents poor combustion properties that make interchangeability with other combustible gases difficult, the elimination of gases and vapors, such as CO2 and H2O, through a cleaning process, in which the biogas is converted to biomethane, improves the biogas properties as a fuel gas for general use. In this work, we simulated the generation of biogas at El Carrasco sanitary landfill in Bucaramanga, using the US EPA (United States Environmental Protection Agency) landfill gas emissions model. Additionally, we simulated the biogas cleaning process to extract the remaining moisture using the ProMax software; for this, we used three different amines (MDEA, MEA, and DEA), followed by a glycol dehydration process. The results showed that the amine MEA produced the largest increase in the concentration of CH4 (90.37 %) for the biogas generated in the landfill. Furthermore, dehydration with glycol was an efficient process to obtain a gas with a high percentage of methane (91.47 %) and low water presence (1.27 %); this would allow the use of biomethane in conventional industrial combustion processes and power generation.

scholarly journals Geochemical Behavior of Uranium and Radon in Groundwater of Jurassic Granite Area, Icheon, Middle Korea

Water ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 1278 ◽  
Author(s):  
Byong Wook Cho ◽  
Chang Oh Choo
Keyword(s):  
Standard Deviation ◽  
Environmental Protection Agency ◽  
Maximum Contaminant Level ◽  
Contaminant Level ◽  
Low Concentrations ◽  
Wide Range ◽  
The Us ◽  
Us Epa ◽  
Independent Behavior ◽  
Radon Concentrations

Uranium concentrations (a total of 82 samples) in groundwater in Icheon, middle Korea, showed a wide range from 0.02 to 1640 μg/L with a mean of 56.77 μg/L, a median of 3.03 μg/L, and a standard deviation of 228.63 μg/L. Most groundwater samples had quite low concentrations: 32.9% were below 1 μg/L, while 15.9% exceeded 30 μg/L, the maximum contaminant level (MCL) of the US EPA (Environmental Protection Agency). Radon concentrations also ranged widely from 1.48 to 865.8 Bq/L. Although the standard deviation of radon was large (151.8 Bq/L), the mean was 211.29 Bq/L and the median was 176.86 Bq/L. Overall, 64.6% of the samples exceeded the alternative maximum contaminant level (AMCL) of the US EPA (148 Bq/L). According to statistical analyses, there was no close correlations between uranium and radon, but there were correlations between uranium and redox potential (Eh) (−0.54), dissolved oxygen (DO) (−0.50), HCO3− (0.45), Sr (0.65), and SiO2 (−0.44). Radon showed independent behavior with respect to most components in groundwater. Uranium concentrations in groundwater increased with increasing water–rock interactions. Anomalously high uranium and radon concentrations in groundwater are preferentially localized in granite areas and spatial distributions are remarkably heterogeneous.

scholarly journals Arsenic in Drinking Water and Lung Cancer Mortality in the United States: An Analysis Based on US Counties and 30 Years of Observation (1950–1979)

2016 ◽  
Vol 2016 ◽  
pp. 1-13 ◽  
Author(s):  
Hamid Ferdosi ◽  
Elisabeth K. Dissen ◽  
Nana Ama Afari-Dwamena ◽  
Ji Li ◽  
Rusan Chen ◽  
...  
Keyword(s):  
Lung Cancer ◽  
Drinking Water ◽  
Cancer Risk ◽  
Lung Cancer Risk ◽  
The United States ◽  
Risk Estimates ◽  
Unit Risk ◽  
The Us ◽  
Us Epa ◽  
Us Counties

Background.To examine whether the US EPA (2010) lung cancer risk estimate derived from the high arsenic exposures (10–934 µg/L) in southwest Taiwan accurately predicts the US experience from low arsenic exposures (3–59 µg/L).Methods. Analyses have been limited to US counties solely dependent on underground sources for their drinking water supply with median arsenic levels of ≥3 µg/L.Results. Cancer risks (slopes) were found to be indistinguishable from zero for males and females. The addition of arsenic level did not significantly increase the explanatory power of the models. Stratified, or categorical, analysis yielded relative risks that hover about 1.00. The unit risk estimates were nonpositive and not significantly different from zero, and the maximum (95% UCL) unit risk estimates for lung cancer were lower than those in US EPA (2010).Conclusions. These data do not demonstrate an increased risk of lung cancer associated with median drinking water arsenic levels in the range of 3–59 µg/L. The upper-bound estimates of the risks are lower than the risks predicted from the SW Taiwan data and do not support those predictions. These results are consistent with a recent metaregression that indicated no increased lung cancer risk for arsenic exposures below 100–150 µg/L.

scholarly journals Contamination Level, Source Identification and Health Risk Assessment of Potentially Toxic Elements in Drinking Water Sources of Mining and Non-mining Areas of Khyber Pakhtunkhwa, Pakistan

2021 ◽  
Author(s):  
Zahid Imran Bhatti ◽  
Muhammad Ishtiaq ◽  
Said Akbbar Khan ◽  
javed nawab ◽  
Sardar Khan ◽  
...  
Keyword(s):  
Risk Assessment ◽  
Drinking Water ◽  
Surface Water ◽  
Health Risk ◽  
Toxic Elements ◽  
Water Sources ◽  
Potentially Toxic Elements ◽  
Mining Areas ◽  
The Us ◽  
Us Epa

Abstract Accelerated mining activities have increased water contamination with potentially toxic elements (PTEs) and their associated human health risk in developing countries. The current study investigated the distribution of PTEs, their potential sources and health risk assessment in both ground and surface water sources in mining and non–mining areas of Khyber Pakhtunkhwa, Pakistan. Water samples (n=150) were taken from selected sites and were analyzed for six PTEs (Ni, Cr, Zn, Cu, Pb and Mn). Among PTEs, Cr showed high mean concentration (497) μg L–1, followed by Zn (414) μg L–1 in mining area, while Zn showed lowest mean value (4.44) μg L–1 in non-mining areas. Elevated concentrations of Ni, Cr and moderate level of Pb in ground and surface water of Mohmand District exceeded the permissible limits set by WHO (2017). Multivariate statistical analyses showed that pollution sources of PTEs were mainly from mafic-ultramafic rocks, acid mine drainage, open dumping of mine-wastes and mine tailings. The hazard quotient (HQ) was highest for children relatively to adults, but not higher than the US-EPA limits. The hazard index (HI) for ingestions of all selected PTEs were lower than the threshold value (HIing <1), except Mohmand District which showed (HI >1) in mining areas through ingestion. Moreover, the carcinogenic risk (CR) values exceeded the threshold limits for Ni and Cr set by the US-EPA (1.0E−04 to 1.0E−06). In order to protect the drinking water sources of the study areas from more contamination, the management techniques and policy for mining operations need to be implemented.

scholarly journals Principles and techniques towards successful development of enzyme-linked immunosorbent assay (ELISA) for dioxin analysis

2021 ◽  
Author(s):  
Wei Zhang
Keyword(s):  
Immunosorbent Assay ◽  
Environmental Protection Agency ◽  
High Resolution Mass Spectrometry ◽  
Enzyme Linked Immunosorbent Assay ◽  
Environmental Matrices ◽  
Successful Development ◽  
Trace Level ◽  
The Us ◽  
Us Epa ◽  
Technical Details

Dioxins are highly toxic, persistent and bio-accumulative compounds. Laboratory detection of dioxins in various environmental matrices is one of the most technically demanding and expensive tasks in analytical chemistry.The cost to analyze a soil sample by conventional gas chromatography-high resolution mass spectrometry (GC-HRMS) is approximately $1,900 USC accordign to the Unisted States Environmental Protection Agency (US EPA) (Billets, 2005). As an alternative, enzyme-linked immunosorbent assay (ELISA) for dioxin analysis has been commercially available for over a decade and recognized as the US EPA Method 3025. However, assay attributes need to be examined, especially at trace level detection. In this study, sources of error in ELISA, such as background contamination and dioxin-like polycholrinated biphenyl (dl-BCB) cross-reactions have been investigated. Quality assurance data on spikes have been reviewed and the recovery was estimated to be 70%. Technical details that are crucial for the performance of dioxin in ELISA were also identified and addressed.

scholarly journals Disinfection by-products and extractable organic compounds in South African tap water

2008 ◽  
Vol 4 (1) ◽  
Author(s):  
Carien Nothnagel ◽  
Karsten Kotte ◽  
J J Pienaar ◽  
P G Van Zyl ◽  
J P Beukes
Keyword(s):  
Drinking Water ◽  
South African ◽  
Tap Water ◽  
Target Range ◽  
Preliminary Results ◽  
The Us ◽  
Microbiological Parameters ◽  
Us Epa ◽  
Micro Organisms ◽  
By Products

An important step in urban purification of drinking water is disinfection by e.g. chlorination where potential pathogenic micro-organisms in the water supply are killed. The presence of organic material in natural water leads to the formation of organic by- products during disinfection. Over 500 of these disinfection by-products (DBPs) have been identified and many more are estimated to form during the disinfection step. Several DBPs such as trihalomethanes (THMs), which is carcinogenic, poses serious health risks to the community. There is very few quantitative data available which realizes the actual levels of these compounds present in drinking water. The levels of four THMs present in drinking water were measured. It included chloroform, bromodichloromethane, chlorodibromomethane and bromoform. Although microbiological parameters are considered to get more attention than disinfection by-products, the measurement of the levels of these compounds in South-African drinking water is essential together with establishing minimum acceptable concentration levels. The target range for total trihalomethanes (TTHMs) established by the US EPA at the end of 2003 is 0-0.08ug/mL. The aim of this paper is to create an awareness of the problem as well as presenting preliminary results obtained with the method of analysis. Preliminary results indicate that urgent attention must be given to the regulation and monitoring of DBPs in South African drinking water.

scholarly journals Regulation of Perfluorooctanoic Acid (PFOA) and Perfluorooctane Sulfonic Acid (PFOS) in Drinking Water: A Comprehensive Review

Water ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 2003 ◽  
Author(s):  
Pontius
Keyword(s):  
Drinking Water ◽  
Environmental Protection Agency ◽  
Sulfonic Acid ◽  
Current Knowledge ◽  
Perfluorooctanoic Acid ◽  
Regulatory Agencies ◽  
Water Regulation ◽  
Biological Degradation ◽  
The Us ◽  
Legal Constraints

Perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS) are receiving global attention due to their persistence in the environment through wastewater effluent discharges and past improper industrial waste disposal. They are resistant to biological degradation and if present in wastewater are discharged into the environment. The US Environmental Protection Agency (USEPA) issued drinking water Health Advisories for PFOA and PFOS at 70 ng/L each and for the sum of the two. The need for an enforceable primary drinking water regulation under the Safe Drinking Water Act (SDWA) is currently being assessed. The USEPA faces stringent legal constraints and technical barriers to develop a primary drinking water regulation for PFOA and PFOS. This review synthesizes current knowledge providing a publicly available, comprehensive point of reference for researchers, water utilities, industry, and regulatory agencies to better understand and address cross-cutting issues associated with regulation of PFOA and PFOS contamination of drinking water.

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