Microelement mobile forms in southern taiga landscapes of the Central Forest State Biosphere Nature Reserve (Russia)

2020 ◽  
Author(s):  
Polina Enchilik ◽  
Elena Aseeva ◽  
Ivan Semenkov ◽  
Olga Samonova ◽  
Anastasia Iovcheva ◽  
...  
Keyword(s):  
Spatial Distribution ◽  
Cross Sections ◽  
Chemical Elements ◽  
Total Concentration ◽  
High Mobility ◽  
Mobile Element ◽  
Total Content ◽  
Southern Taiga ◽  
Slope Position ◽  
Plant Soil

<p>We investigated the vertical and spatial distribution of chemical elements (ChEs) in four cross-sections within a catena formed in typical southern taiga on Retiosols , underlying loess  loams and carbonate moraine deposits. Catena located in the Tver' region (Russia). In plants (70 samples, 19 species) and soils (31 samples), the total content of the ChEs was determined by mass spectrometry. In soil samples, we measured pH, grain size and levels of ChE mobile fractions (exchangeable (F1), bound to organic complexes (F2) and bound to Fe and Mn hydroxides (F3).</p><p>In the A-horizons the average total concentration of Fe is 1,2%, Ti – 0,33%; Mn – 482 mg‧kg-1, Zr–292, Sr–90, Zn–39, Cr–21, Pb–21, Ni–9, Cu–8. The concentration of metal F1 diminishes in order: Fe>Mn>Sr>Zn, Pb>Ti, Cr, Ni, Cu, Co, Zr. The concentrations of F2 and F3 show the following order: Fe>Mn>>Ti, Zr, Pb>Co>Ni, Cu, Zn>Cr, Sr and Fe>Mn>Ti>Zn, Sr, Pb>Cr>Cu, Ni, Co>Zr, respectively.</p><p>In all studied Retisols, vertical distribution of the total Pb and Zr, F1 of Co, Fe, Mn, Pb and Zn, F2 of Cu, Fe, Pb and Zn, F3 of Pb accumulate in topsoil. For the total Co, Fe, Ni, Sr and Zn, F1 of Co, Cr, Cu, Mn, Pb, Zn and Zr, F2 of Co, Cr, Cu, Fe, Mn, Ni, Pb, Zn and Zr and F3 of Co, Cr, Cu, Ti, Zn, Zr the loss from the albic horizons and/or the accumulation in the argic horizons were registered.</p><p>Spatial distribution of the total concentration of ChEs increases in the A-horizon in the upper part of the catena slope position. In the A-horizons at footslope and toeslope positions, the concentration of F1 Ni, Cu, Sr and Zr, F2 Ni, Cu and Zn increases, and the concentration F2 of Co, Cr, Pb, Ti and Zn, F2 of Cr, Ti and Co, F3 of Mn, Ni, Zn, Pb, Zr decreases.</p><p>Ratios calculated on the basis of the total and mobile element content were applied to evaluate biogenic migration of ChEs with different biophilicity in the "plant-soil" system. According to soil-to-plant transfer ratios, Mn, Zn and Cd are actively involved in biological accumulation. Participation in biological accumulation of Mn and Zn was noted in many works (Avessalomova, 2007; Isachenkova, Tarzayeva, 2006, Kadata-Pendias, Szteke, 2015)</p><p>Mn and Zn have important physiological significance in plants; they actively migrate in plant tissues. Cd is not a necessary ChEs for plants but is easily absorbed by the root system and leaves (Kabata-Pendias, 2011). Cationic elements (Cd and Zn) have high mobility in the soils (Jen-How Huang, 2011). Our results indicate that in the reference forest communities, tree species play the major role in the uptake and turnover of biophilic microelements (Mn, Zn, Co) while sphagnum moss and grassy covers mostly absorb the elements with low biophilicity (Fe, Ti, Cr, Zr, Pb). Metabolic pathways carry out the absorption of Fe and Cr (Kabata-Pendias, 2011).</p>

scholarly journals Data on the elemental composition (mobile fractions and total content) of soils in catena at the SE Valdai Hills, Russia

2021 ◽  
Author(s):  
Polina Enchilik ◽  
Ivan Semenkov ◽  
Nikolay Kasimov
Keyword(s):  
Deciduous Forest ◽  
Ph Value ◽  
Chemical Elements ◽  
Total Concentration ◽  
Total Content ◽  
Residual Fraction ◽  
Organic Carbon Content ◽  
Acer Platanoides ◽  
Forest Reserve ◽  
Particle Size Classes

Abstract. This study presents a dataset on seasonal soils sampling from September 2016 to May 2018 in the southern part of the Central Forest Reserve (SE Valdai Hills) within a catena with Endocalcaric Albic Glossic Stagnic Profondic Retisols (Cutanic, Loamic) and Albic Gleyic Histic Retisols (Cutanic, Loamic) under coniferous-deciduous forest (Tília cordáta, Pícea ábies, Ácer platanoídes) on loess-like loams underlain by carbonate moraine deposits. 152 soil samples were taken to define total concentration of 67 chemical elements (ChEs), content of three mobile fractions (exchangeable, bound within organo-mineral complexes, bound with Fe and Mn hydroxides) of 69 ChEs and content of residual fraction, including macro elements (Al, Ca, Fe, K, Mg, Mn, Na, P, Ti, S, Si), heavy metals (Ba, Co, Cr, Cu, Ni, Pb, Rb, Sr, Th, U, V, Zn), trace elements (Ag, As, B, Be, Bi, Br, Cd, Cs, Ge, Hf, Li, Mo, Nb, Pd, Sb, Sc, Se, Sn, Ta, Te, Tl,W, Zr) and rare earth elements (Ce, Er, Eu, Gd, La, Lu, Nd, Pr, Sm, Tb, Tm, Dy, Ho, Y, Yb). We measured pH-value, total organic carbon content (TOC), seven particle-size classes (

scholarly journals Functional Morphology of the Cardiac Jelly in the Tubular Heart of Vertebrate Embryos

2019 ◽  
Author(s):  
Jörg Männer ◽  
Talat Mesud Yelbuz
Keyword(s):  
Spatial Distribution ◽  
Cross Sections ◽  
Embryonic Heart ◽  
Endocardial Cushions ◽  
Valveless Pumping ◽  
Matrix Layer ◽  
Heart Looping ◽  
Biological Aspects ◽  
Vertebrate Embryos ◽  
Heart Wall

The early embryonic heart is a multi-layered tube consisting of (1) an outer myocardial tube; (2) an inner endocardial tube; and (3) an extracellular matrix layer interposed between myocardium and endocardium, called “cardiac jelly” (CJ). During the past decades, research on CJ has mainly focused on its molecular and cell biological aspects. This review focuses on the morphological and biomechanical aspects of CJ. Special attention is given to (1) the spatial distribution and fiber architecture of CJ; (2) the morphological dynamics of CJ during the cardiac cycle; and (3) the removal/remodeling of CJ during advanced heart looping stages, which leads to the formation of ventricular trabeculations and endocardial cushions. CJ acts as a hydraulic skeleton displaying striking structural and functional similarities with the mesoglea of jellyfish. CJ not only represents a filler substance, facilitating end-systolic occlusion of the embryonic heart lumen. Its elastic components antagonize the systolic deformations of the heart wall and thereby power the refilling phase of the ventricular tube. Non-uniform spatial distribution of CJ generates non-circular cross sections of the opened endocardial tube (initially elliptic, later deltoid), which seem to be advantageous for valveless pumping. Endocardial cushions arise from non-removed remnants of the original CJ.

scholarly journals Study Relating to the Spatial Distribution of Ground Water Quality for Different Elements using Legacy Data of RWS&S, Andhra Pradesh, India

2014 ◽  
Vol XL-8 ◽  
pp. 383-390
Author(s):  
P. Prakash ◽  
A. Kumar Das ◽  
C. V. S. Sandilya
Keyword(s):  
Water Quality ◽  
Drinking Water ◽  
Spatial Distribution ◽  
Ground Water ◽  
Andhra Pradesh ◽  
Chemical Elements ◽  
Groundwater Resources ◽  
Water Levels ◽  
Contamination Level ◽  
Ground Water Quality

The state of Andhra Pradesh, India falls in water stress<sup>4</sup> area. The primary objective of this study is to examine the spatial distribution of different chemical elements with respect to its contamination level. About 70 % of drinking water needs in rural areas and 40 % drinking water needs in urban areas are met from groundwater resources. In the last decades, rapid population growth coupled with agricultural expansion due to subsidized power to agriculture has significantly increased demand on groundwater resources. Combined to this, the effect of Global warming has put stress on ground water which is resulting in declines in water levels and deterioration of ground water quality. This may be evidenced by the fact that the phreatic aquifer which was in use two decades ago, is existing no more now in some of the parts of the study area and the water is being drawn from deeper aquifers beyond phreatic aquifers. The study has been carried out for which one or more elements are contaminated and to study its spatial distribution.

scholarly journals Neutron capture data for unstable nuclei – Astrophysical quests and experimental challenges

2019 ◽  
Vol 23 ◽  
pp. 1
Author(s):  
F. Käppeler
Keyword(s):  
Cross Sections ◽  
Reaction Path ◽  
Chemical Elements ◽  
Neutron Sources ◽  
Unstable Nuclei ◽  
Quantitative Studies ◽  
Branching Points ◽  
Supernova Explosions ◽  
R Process ◽  
Pulsed Neutron

The abundances of the chemical elements heavier than iron can be attributed in about equal parts to the r and s processes, which are taking place in supernova explosions and during the He and C burning phases of stellar evolution, respectively. So far, quantitative studies of the r-process are out of reach, because it involves reactions on extremely short-lived neutron-rich nuclei. On the contrary, the situation for the s-process is far advanced, thanks to a comprehensive database of experimental (n,γ) cross sections for most isotopes along the reaction path from 12C to the Pb/Bi region. For the stable isotopes last gaps in the data are presently closed, but further studies are clearly needed to reach the required accuracy and to resolve remaining discrepancies. The quest for cross sections of unstable isotopes remains a persisting challenge though. In particular, nuclei which act as branching points are of prime interest, because they provide key information on the deep stellar interior. While the activation method is limited to a few exceptional branch-point nuclei, successful measurements via the time-of- flight technique are depending on intense pulsed neutron sources and elaborate methods for sample production. Current developments in Europe are providing promising perspectives in both areas.

scholarly journals Transient Responses of the Hepatic Lipidome to Acute Exercise Bouts in Mice

2020 ◽  
Author(s):  
Gregory C Henderson ◽  
Valeria P Martinez Tenorio ◽  
Marc A Tuazon
Keyword(s):  
Acute Exercise ◽  
Total Concentration ◽  
Acyl Chain ◽  
Total Content ◽  
Lipid Classes ◽  
Hepatic Lipid Metabolism ◽  
Interval Exercise ◽  
Single Bout ◽  
High Intensity Interval ◽  
The Relationship

Abstract BACKGROUND: The content of triacylglycerol (TAG) in the liver is known to rapidly increase after a single bout of exercise followed by recovery to sedentary levels. The response of other hepatic lipids, and acyl chain composition of lipid classes, would provide a deeper understanding of the response of hepatic lipid metabolism to acute exercise. METHODS: Female mice performed a single bout of continuous exercise (CE), high-intensity interval exercise (HIIE), or no exercise (CON). The total content of various lipids in the liver, and fatty acids within lipid classes, were measured in tissues collected 3 hours after exercise (Day 1) and the day following exercise (Day 2). RESULTS: The total concentration of TAG rose on Day 1 after exercise (P < 0.05), with a greater elevation in HIIE than CE (P < 0.05), followed by a decline toward CON levels on Day 2. The total concentration of other measured lipid classes was not significantly altered by exercise. However, n-6 polyunsaturated fatty acid relative abundance in diacylglycerol (DAG) was increased by HIIE (P < 0.05). In CON liver, TAG content was positively correlated with DAG and phosphatidylethanolamine (P < 0.05), while these statistical associations were disrupted in exercised mice on Day 1. CONCLUSIONS: Overall, the results characterize flexibility of the hepatic TAG pool size in the liver, and the relationship between TAG and other lipid abundances is altered during the transient TAG pool expansion after exercise. The transient expansion of the hepatic TAG pool and remodeling of the DAG pool may be fundamental components of the physiological response to intense exercise.

scholarly journals Development of a method for assessing the structural heterogeneity of a population of different strains of tick-borne encephalitis virus

2018 ◽  
pp. 108-111
Author(s):  
К.К. Тучинская ◽  
В.П. Волок ◽  
В.В. Илларионова ◽  
О.И. Ковалева
Keyword(s):  
Total Concentration ◽  
Surface Protein ◽  
Total Content ◽  
Culture Fluid ◽  
Structural Heterogeneity ◽  
Encephalitis Virus ◽  
Virus Particles ◽  
Tick Borne Encephalitis ◽  
Tick Borne Encephalitis Virus ◽  
Different Strains

Вирус клещевого энцефалита (ВКЭ) является возбудителем тяжелого неврологического заболевания человека и широко распространен на территории Евразии. При репродукции флавивирусов помимо инфекционных вирионов накапливается набор неинфекционных вирусных структур: незрелые формы вирионов, пустые формы (не содержащие геном вирусные частицы), а также агрегаты поверхностного белка Е, способные оказывать влияние на иммунный ответ, и патогенез. Штаммы ВКЭ могут различаться по соотношению этих форм в инфекционном материале, т.е. по характеру структурной гетерогенности. Цель: подобрать комплекс методов, способных выявить данные различия. Методы. Общую концентрацию белка Е определяли методом ИФА, число частиц, содержащих геном (ГСЧ) - ПЦР в реальном времени, а для выявления инфекционных вирусных частиц - титрование в культуре клеток. Результаты. Разработан метод оценки структурной гетерогенности популяции ВКЭ. Было показано, что повышенное содержание неинфекционных вирусных частиц, содержащих геном, и несвязанных с ними белка Е не зависит от подтипа вируса. Выводы. Штаммы ВКЭ отличились по соотношению общего числа ГСЧ к числу инфекционных вирионов и по содержанию белка Е, связанного и несвязанного с ГСЧ. Tick-borne encephalitis virus (TBEV) is widespread in Europe and Asia and causes severe neurological disease in humans. It has been established that the reproduction of flaviviruses leads to the accumulation of a whole set of non-infectious viral structures aside from infectious virions. These structures include immature virions, empty forms (containing no genome) and aggregates of the surface protein E. These structures, despite being non-infectious, are able to influence the immune response and, consequently, the pathogenesis of TBEV infection. The aim of this work was to select a set of methods which can be implemented to identify these differences. Methods. Virus samples were analised for protein E concentration, number of genome-containing particles and infectivity. The total concentration of protein E in samples was evaluated using ELISA. The number of genome-containing particles was determined by a real-time PCR, and to assess the number of infectious virus particles titration in PEK cell culture was used. Results. An assay for total concentration of protein E in culture fluid of cells infected with different strains of TBEV based on the commertially available ELISA kit was developed. TBEV strains used in the study varied by the ratio of genome-containing particles to infectious virions. The amount of protein E not associated with genome-containing virions was calculated as a difference between total content of protein E and the amount of protein E bound to genome-containing particles. This amount was also different for studied samples of TBEV strains. Conclusion. No correlation was observed between the increased content of non-infectious genome-containing particles or the amount of residual protein E and TBEV subtypes.

scholarly journals Using natural aluminosilicate (vermiculite) sorbent for purifying waste water from antibiotics

2022 ◽  
Vol 6 (4) ◽  
pp. 387-394
Author(s):  
D. S. Galchenko ◽  
M. G. Smirnova ◽  
L. I. Sokolova
Keyword(s):  
Waste Water ◽  
Total Concentration ◽  
Total Content ◽  
Fish Farming ◽  
Model System ◽  
Fish Processing ◽  
Dynamic Conditions ◽  
Natural Aluminosilicate ◽  
Antibiotics Detection ◽  
Static Conditions

The problem of wastewater treatment from residual antibiotics is of particular relevance, since these drugs are used in many agricultural sectors. Antibiotics get into water, animal and human bodies, where they can accumulate negatively affecting health. The aim of this article is to study the possibility of using natural aluminosilicate vermiculite sorbent from the Koksharovskoye field (Primorsky Region) for purifying fish processing and fish farming enterprises’ waste water from antibiotics (chloramphenicol, tetracycline, cefazolin, cefuroxime, ceftriaxone, cefepime and and ciprofloxacin) under static and dynamic conditions. The study was carried out on a model wastewater system with injected antibiotics. The purification ability of the model system using the method of spectrophotometric antibiotics detection is analyzed. Under static conditions, the total content of antibiotics varied from 0.25 mg to 1.00 mg per 1 g of sorbent. Under dynamic conditions, the antibiotic content was 0.025 mg per 1 g of sorbent. High values of absorption for all studied antibiotics, except for chloramphenicol, were achieved both in static and dynamic modes. For chloramphenicol, when examined under static conditions, the maximum absorption rate was 45% with the minimum total concentration of antibiotics. With an increase in the load on the sorbent, the degree of absorption decreased to 3%. Thus, vermiculite modified with 7% hydrochloric acid is a promising sorbent for cleaning water bodies from residual antibiotics.

scholarly journals Biogeochemical peculiarities of accumulation of chemical elements by plants of the Svydovets Massif of the Ukrainian Carpathians

2021 ◽  
Vol 30 (1) ◽  
pp. 78-89
Author(s):  
Nataliya O. Kryuchenko ◽  
Edward Ya. Zhovinsky ◽  
Petr S. Paparyga
Keyword(s):  
Chemical Elements ◽  
Total Concentration ◽  
Abies Alba ◽  
Herbaceous Plants ◽  
Silver Fir ◽  
Field Surveys ◽  
Vaccinium Myrtillus L ◽  
Bog Bilberry ◽  
Selection Of

he objective of the paper was determining biogeochemical peculiarities of ac- cumulation of chemical elements (Mn, Ni, Сo, V, Cr, Zr, Cu, Pb, Zn, Ba, P) by wild-grow- ing shrubs (stems and leaves) – bog bilberry (Vaccіnium uliginоsum), European blueberry (Vaccinium myrtillus L.), alpine juniper (J. communis subsp. alpina); perennial herbaceous plants (flowers and leaves) – common tormentil (Potentіlla erecta (L.) Hampe), willow gentian (Gentiana asclepiadea), true sedges (Carex); and trees (needles) of European silver fir (Abies alba) on nine plots in the Svy- dovets Massif of the Ukrainian Carpathians. The results we obtained based on field surveys (selection of samples of soil and vegeta- tion) and interpretation of their analysis allowed us to determine the total regional background of chemical elements in soils and ash of plants using emission spectral analysis. We assessed the total concentration of chemical elements in soils of the plots (least to highest): the Apshynets Ridge – the Herashaska Polonyna – Drahobratske Lake – the Svydovets stream – Apshynets Lake – Herashaske Lake – the Zhuravlyne Bog – Vorozheske Lake (group of small lakes) – Vorozheske Lake (large) and determined the dependence on type of soil and pH. We determined that for wild-growing herbaceous plants the biogeochemical activity of species increases in the following sequence: true sedges - willow gentian - common tormentil; for wild-growing shrubs (bog bilberry, European blueberry, alpine juniper) such a sequence is impossible to determine due to the great difference between the values on different plots. We determined the role of each plant as medicinal for treating microelement deficiency in Cu, Zn, Co. We determined that in the plot of the Herashaska Polonyna, the needles of alpine juniper contain a maximum amount of Zn and Co, the needles and leaves of bog bilberry – Cu, Zn, Co; the flowers and leaves of common tormentil by Apshynets Lake and European silver fir near the area of the Svydovets stream – Cu. We calculated the daily dose of each element according to species of plants to overcome microelementosis. The results of biogeochemical surveys may be the basis for determining and recommending plants as medicinal, and also of geochemical and biogeochemical monitoring studies.

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