LATE EOCENE BIOSTRATIGRAPHIC AGE FOR ANDESITIC VOLCANIC HOST ROCKS FORMED IN AN ISLAND ENVIRONMENT AT THE COBRE PANAMA PORPHYRY Cu-Mo-Au-Ag DEPOSIT, PANAMA

2020 ◽  
Author(s):  
Stewart D. Redwood ◽  
Jonathan R. Bryan ◽  
David M. Buchs ◽  
Colin Burge

Abstract The giant Cobre Panama porphyry Cu-Mo-Au-Ag deposit in western Panama is hosted by an undated andesitic volcanic sequence, the Petaquilla batholith (32.20 ± 0.76–28.28 ± 0.61 Ma), and porphyry stocks (28.96 ± 0.62–27.48 ± 0.68 Ma). Here we present a biostratigraphic age for the volcanic sequence based on stratigraphically diagnostic large foraminifera from thin limestone beds within kilometer-thick andesitic rocks. These yield a late middle to late Eocene biostratigraphic age (41.2–33.9 Ma), with a probable late Eocene age (Priabonian stage, 37.8–33.9 Ma), which is slightly older than the age of the batholith and porphyry intrusions. The volcanic sequence is dominated by fine-grained, massive basalt to andesite lavas with subordinate volcaniclastic deposits. A preliminary description of volcanic textures based on macroscopic observation of drill core and quarry/road exposures supports the occurrence of lavas, fallout tuffs, volcanic breccias, and possible pyroclastic density current deposits. Rare polymictic conglomerates with well-rounded clasts of igneous rocks attest to minor sedimentary reworking from a nearby subaerial volcanic environment. The dated limestone that is interbedded with the submarine volcanic sequence was deposited in an estimated water depth of 50 to 80 m, probably in a middle- to outer-shelf large foraminiferal shoal. These results support deposition on the flank of an active volcanic island during early shallowing of the Isthmus of Panama. The Cobre Panama volcanic center is interpreted to have formed in the final stages of the latest Cretaceous-Eocene volcanic arc before, or possibly during, the 175-km sinistral offset of the Panama volcanic front in the late Eocene-Oligocene. However, it remains unclear whether the volcanic center formed on the western continuation of the San Blas-Chagres arc segment or the eastern termination of the Azuero-Soná arc segment and whether it was emplaced during broadening of the pre-Oligocene volcanic front or in a back-arc setting.

2020 ◽  
Vol 115 (4) ◽  
pp. 841-870 ◽  
Author(s):  
Kevin Byrne ◽  
Robert B. Trumbull ◽  
Guillaume Lesage ◽  
Sarah A. Gleeson ◽  
John Ryan ◽  
...  

Abstract The Highland Valley Copper porphyry Cu (±Mo) district is hosted in the Late Triassic Guichon Creek batholith in the Canadian Cordillera. Fracture-controlled sodic-calcic alteration is important because it forms a large footprint (34 km2) outside of the porphyry Cu centers. This alteration consists of epidote ± actinolite ± tourmaline veins with halos of K-feldspar–destructive albite (1–20 XAn) ± fine-grained white mica ± epidote. The distribution of sodic-calcic alteration is strongly influenced by near-orthogonal NE- and SE-trending fracture sets and by proximity to granodiorite stocks and porphyry dikes. Multiple stages of sodic-calcic alteration occurred in the district, which both pre- and postdate Cu mineralization at the porphyry centers. The mineral assemblages and chemical composition of alteration minerals suggest that the fluid that caused sodic-calcic alteration in the Guichon Creek batholith was Cl bearing, at near-neutral pH, and oxidized, and had high activities of Na, Ca, and Mg relative to propylitic and fresh-rock assemblages. The metasomatic exchange of K for Na, localized removal of Fe and Cu, and a paucity of secondary quartz suggest that the fluid was thermally prograding in response to magmatic heating. Calculated δ18Ofluid and δDfluid values of mineral pairs in isotopic equilibrium from the sodic-calcic veins and alteration range from 4 to 8‰ and −20 to −9‰, respectively, which contrasts with the whole-rock values for least altered magmatic host rocks (δ18O = 6.4–9.4‰ and δD = −99 to −75‰). The whole-rock values are suggested to reflect residual magma values after D loss by magma degassing, while the range of hydrothermal minerals requires a mixed-fluid origin with a contribution of magmatic water and an external water source. The O-H isotope results favor seawater as the source but could also reflect the ingress of Late Triassic meteoric water. The 87Sr/86Srinital values of strongly Na-Ca–altered rocks range from 0.703416 to 0.703508, which is only slightly higher than the values of fresh and potassic-altered rocks. Modeling of those data suggests the Sr is derived predominantly from a magmatic source, but the system may contain up to 3% seawater Sr. Supporting evidence for a seawater-derived fluid entrained in the porphyry Cu systems comes from boron isotope data. The calculated tourmaline δ11Bfluid values from the sodic-calcic domains reach 18.3‰, which is consistent with a seawater-derived fluid source. Lower tourmaline δ11Bfluid values from the other alteration facies (4–10‰) suggest mixing between magmatic and seawater-derived fluids in and around the porphyry centers. These results imply that seawater-derived fluids can infiltrate batholiths and porphyry systems at deep levels (4–5 km) in the crust. Sodic ± calcic alteration may be more common in rocks peripheral to porphyry Cu systems hosted in island-arc terranes and submarine rocks than currently recognized.


Minerals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 85
Author(s):  
Mónica Arias ◽  
Pablo Nuñez ◽  
Daniel Arias ◽  
Pablo Gumiel ◽  
Cesar Castañón ◽  
...  

The Touro volcanogenic massive sulfide (VMS) deposit is located in the NW of the Iberian Variscan massif in the Galicia-Trás-os-Montes Zone, an amalgamation of several allochthonous terrains. The Órdenes complex is the most extensive of the allochthone complexes, and amphibolites and paragneisses host the deposit, characterized as being massive or semimassive (stringers) sulfides, mostly made up of pyrrhotite and chalcopyrite. The total resources are 103 Mt, containing 0.41% copper. A 3D model of the different orebodies and host rocks was generated using data from 1090 drill core logs. The model revealed that the structure of the area is a N–S-trending antiform. The orebodies crop out in the limbs and in the hinge zone. The mineralized structures are mostly tabular, up to 100 m in thickness and subhorizontal. Based on the petrography, geochemistry and the 3D model, the Touro deposit is classified as a VMS of the mafic-siliciclastic type formed in an Ordovician back-arc setting, which was buried and metamorphosed in Middle Devonian.


2021 ◽  
Author(s):  
Qingqing Zhao ◽  
Degao Zhai ◽  
Ryan Mathur ◽  
Jiajun Liu ◽  
David Selby ◽  
...  

Abstract Whether giant porphyry ore deposits are the products of single, short-lived magmatic-hydrothermal events or multiple events over a prolonged interval is a topic of considerable debate. Previous studies, however, have all been devoted to porphyry Cu and Cu-Mo deposits. In this paper, we report high-precision isotope dilution-negative-thermal ionization mass spectrometric (ID-N-TIMS) molybdenite Re-Os ages for the newly discovered, world-class Chalukou porphyry Mo deposit (reserves of 2.46 Mt @ 0.087 wt % Mo) in NE China. Samples were selected based on a careful evaluation of the relative timing of the different vein types (i.e., A, B, and D veins), thereby ensuring that the suite of samples analyzed could be used to reliably determine the age and duration of mineralization. The molybdenite Re-Os geochronology reveals that hydrothermal activity at Chalukou involved two magmatic-hydrothermal events spanning an interval of 6.92 ± 0.16 m.y. The first event (153.96 ± 0.08/0.63/0.79 Ma, molybdenite ID-N-TIMS Re-Os age) was associated with the emplacement of a granite porphyry dated at 152.1 ± 2.2 Ma (zircon laser ablation-inductively coupled plasma-microscopic [LA-ICP-MS] U-Pb ages), and led to only minor Mo mineralization, accounting for <10% of the overall Mo budget. The bulk of the Mo (>90%) was deposited in less than 650 kyr, between 147.67 ± 0.10/0.60/0.76 and 147.04 ± 0.12/0.72/0.86 Ma (molybdenite ID-N-TIMS Re-Os ages), coincident with the emplacement of a fine-grained porphyry at 148.1 ± 2.6 Ma (zircon LA-ICP-MS U-Pb ages). The high-precision Re-Os age determinations presented here show, contrary to the finding of a number of studies of porphyry Cu and Cu-Mo systems, that the giant Chalukou porphyry Mo deposit primarily formed in a single, short-lived (<650 kyr) hydrothermal event, suggesting that this may also have been the case for other giant porphyry Mo deposits.


2015 ◽  
Vol 79 (6) ◽  
pp. 1353-1367 ◽  
Author(s):  
J. Quirke ◽  
C. M. B. Henderson ◽  
R. A. D. Pattrick ◽  
K. M. Rosso ◽  
A. Dent ◽  
...  

AbstractGeological disposal facilities (GDF) are intended to isolate and contain radioactive waste within multiple protective barriers, deep underground, to ensure that no harmful quantities of radioactivity reach the surface environment. The last line of defense in a multi-barrier GDF is the geosphere, where iron is present in the host rock mineralogy as either Fe(II) or Fe(III), and in groundwater as Fe(II) under reducing conditions. The mobility of risk-driving radionuclides, including uranium and technetium, in the environment is affected significantly by their valence state. Due to its low redox potential, Fe(II) can mediate reduction of these radionuclides from their oxidized, highly mobile, soluble state to their reduced, insoluble state, preventing them from reaching the biosphere. Here a study of five types of potential host rocks, two granitoids, an andesite, a mudstone and a clay-rich carbonate, is reported. The bulk rocks and their minerals were analysed for iron content, Fe(II/III) ratio, and for the speciation and fine-grained nature of alteration product minerals that might have important controls on groundwater interaction. Total iron content varies between 0.9% in clays to 5.6% in the andesite. X-ray absorption spectroscopy reveals that Fe in the granitoids and andesite is predominantly Fe(II), and in mudstones, argillaceous limestone and terrestrial sandstone is predominantly Fe(III). The redox reactivity of the potential host rocks both in the presence and absence of Fe(II)-containing 'model' groundwater was investigated using an azo dye as a probe molecule. Reduction rates as determined by reactivity with the azo dye were correlated with the ability of the rocks to uptake Fe(II) from groundwater rather than with initial Fe(II) content. Potential GDF host rocks must be characterized in terms of mineralogy, texture, grain size and bulk geochemistry to assess how they might interact with groundwater. This study highlights the importance of redox reactivity, not just total iron and Fe(II)/(III) ratio, when considering the host rock performance as a barrier material to limit transport of radionuclides from the GDF.


2001 ◽  
Vol 34 (3) ◽  
pp. 1015 ◽  
Author(s):  
Β. ΜΕΛΦΟΣ ◽  
Π. ΒΟΥΔΟΥΡΗΣ ◽  
Κ. ΑΡΙΚΑΣ ◽  
Μ. ΒΑΒΕΛΙΔΗΣ

The present study correlates both the mineralogy of the hydrothermal alteration and the mineral chemistry of molybdenites from three porphyry Mo ± Cu occurrences in Thrace: Melitena, Pagoni Rachi/Kirki and Ktismata/ Maronia. The mineralisations are genetically related to calcalkaline, subvolcanic bodies of Tertiary age. According to their mineralogical and chemical composition the host rocks are characterized as dacite (Melitena), dacitic andésite (Pagoni Rachi) and porphyry microgranite (Ktismata/Maronia). The molybdenites occur in disseminated form, as fracture fillings, as well within quartz stockworks crosscuting the central alteration zones of the intrusives. They are accompanied by the following mineral assemblages: quartz, sericite, pyrophyllite, diaspore, Ca-Ba-rich alunite, pyrite (Melitena); quartz, albite/K-feldspar, biotite, actinolite, magnetite (Pagoni Rachi); and sericite, kaolinite, pyrophyllite, chlorite (Ktismata). Preliminary microthermometric results showed homogenisation temperatures from 352° to 390 °C for Pagoni Rachi area and from 295° to 363 °C for Melitena area. The salinities range between 4.5 and 6.1 wt% eq. NaCl and between 2.7 and 3.4 wt% eq. NaCl, respectively. Detailed study on over 400 fluid inclusions from the porphyry Cu-Mo deposit in Maronia area revealed formation temperatures from 300° to 420 °C, whereas salinities are distincted in two different groups from 6 to 16 wt% eq. NaCl and from 28 to 55 wt% eq. NaCl. The chemical composition of the molybdenites from the three porphyry Mo±Cu deposits in Thrace was studied with 155 microprobe analyses. The results revealed unusual high and variable Re concentrations in the studied molybdenites. Re content in molybdenite from Melitena area vary from 0.21 to 1.74 wt%, 0.79 wt% on average. The highest values were measured in samples from Pagoni Rachi (0.45-4.21 wt%, 1.98 wt% on average). Finally, microprobe analyses from molybdenite in Ktismata/Maronia showed Re content between 0.12 and 2.88 wt% (0.76 wt% on average). Rhenium is a very rare element with many definite uses, and is mainly associated with molybdenite in porphyry type deposits. According to the data published so far the Re content in molybdenite reaches up to 0.42 wt%. It is obvious therefore that such high Re concentrations (0.12 to 4.22 wt%) from the studied molybdenites in Thrace, are very ineresting for a possible future exploitation.


2001 ◽  
Vol 34 (3) ◽  
pp. 1185 ◽  
Author(s):  
Π. A. ΑΝΤΩΝΙΑΔΗΣ ◽  
Α. ΒΛΑΧΟΥ ◽  
Σ. Μ. ΑΜΠΑΤΖΗ ◽  
Ρ. KHANAGA ◽  
W. RIEGEL

The present paper is a first stage study of the Achlada lignite deposit (Fiorina Domain) from the coal petrography aspect, aiming at the lignite classification in lithotypes and the extraction of initial conclusions concerning the paleoenvironment of the lignite formation. The Achlada deposit spreads at the NE end of the east borderlands of the Fiorina basin of a SW-NE axis, occupies an area of approximately 7,2 Km2 and is a part of the broader tectonic trench of Monastirion-Florina- Ptolemais-Kozani-Servia, which is ΝW-SE directed and of Miocene age. Due to erosion processes, the lignite deposit with its host rocks is separated into two areas, the Northeastern, where greater thicknesses occur, and the Southwestern (KOTIS TH. et al., 1995). The lignite deposit consists of alternations of mostly thin lignite layers (of approximate thickness up to 23 m) with sediments. The sediments of the lignitiferous suite are mainly sands; mostly fine grained and every now and then clayey, rarely medium grained and including psephit. Besides the lignite layers, layers of humic clays often occur with fragments of xylite and flora residues every now and then. During the present study, which aimed at a forerunning coal pétrographie examination of the deposit, 12 lignite samples have been taken from two representative boreholes. This initial stage of the research shows that the primal macérais of the Achlada deposit basically belong to the huminite group and secondarily to the liptinite group, while the third corresponding category of the inertinite group almost vanishes. From the first category greater percentages are occupied by the macerai densinite (=31%) followed by attrinite (=25%), textoulminite (=22%) and eu-ulminite (=3%), while the second corresponding category gives cutinite (=8%), liptodetrinite (=3%), sporinite (=2,5%) and relatively low percentages of resinite and alginite. The participation of inorganic components is mainly characterized by the relatively low presence of pyrite and clay. According to the results of the coal pétrographie study and their quantative evaluation the following indexes have been calculated; gelification index (GI), vegetation index (VI), groundwater influence index (GWI) and tissue preservation index (TPI). With the correlation between these indexes and the use of diagrams, conclusions are derived concerning the paleoenvironment and the conditions of the lignite formation. From the VI/GWI relationship conclusions are derived concerning the hydrologie status and the nutritient components supply and from the TPI/GI relationship the paleoenvironment in relation to the groundwater level. The evaluation of the data shows that the host environment of the maternal flora was telmatic with mainly mesotrophic and partly rheotrophic conditions (swamp), while for a time period -at least- just before the end of the mire, the environment has changed into a wet area with more intensely telmatic conditions. The conditions of the peat formation were, of course, repeating -frequent alternations with sediments periodically- but always within the scope of a similar environment


2021 ◽  
Vol 72 (3) ◽  
Author(s):  
Serdar Akgündüz ◽  
Hayrettin Koral

The Thrace Basin consists of Paleogene–Neogene deposits that lie in the lowland south of the Strandja highlands in NW Turkey, where metagranitic and metasedimentary rocks occur. The Akalan Formation consisting of colluvial fan/debris flow deposits represents the base of the sequence in the northern Thrace basin where it is bounded by a right lateral strike-slip oblique fault called “The Western Strandja Fault Zone”. This formation exhibits a coarse-grained, angular and grain-supported character close to the fault zone which has releasing-bends. Fine-grained, rounded, and matrix-supported sediments occur away from the contact. During this study, the Akalan Formation is described for the first time as having larger benthic foraminifera (LBF) of Coskinolina sp of Ypresian–Lutetian, Nummulites obesus of early Lutetian, Dictyoconus egyptiensis of Lutetian, Orbitolites sp. of Ypresian–Bartonian, Miliola sp of early–middle Eocene, Idalina grelaudae of early Lutetian–Priabonian, Ammobaculites agglutinans, Amphimorphina crassa, Dentalina sp., Nodosaria sp., Operculina sp., Lenticulina sp., Quinqueloculina sp. and Amphistegina sp. of Eocene. This unit passes upward with a conformity into reefal limestones of the middle/late Eocene–early Oligocene Soğucak Formation. At times, the limestone overlies the conformity, there is an indication of a prograding sedimentary sequence. The new stratigraphic, paleontological, sedimentological and structural findings related to the NW Thrace Basin suggest a strong transtensional/extensional tectonic control for the initial Paleogene sedimentary deposition during the Ypresian–Lutetian period as shown by fossil content of the Akalan Formation. Right lateral-slip extensional tectonics appears to have had activity during the middle–late Eocene transgressive deposition of the Soğucak Formation when the basin became deepened and enlarged.


1975 ◽  
Vol 15 (1) ◽  
pp. 55 ◽  
Author(s):  
N. C. Tallis

Marine seismic studies combined with wildcat drilling in the Gulf of Papua have provided a comprehensive insight into the geology of the offshore Papuan Basin. The Basin adjoins a downwarped but structurally rigid segment of the Australian continental shield in the west, and the Coral Sea Basin in the southeast. It incorporates arcuate geosynclinal development eastward and northward beyond the continental margin. The pre-Tertiary history is relatively obscure. Jurassic-Lower Cretaceous clastic sediments overlie granites and volcanics of the continental shield in the west. Eastward, the record is masked by great thicknesses of Tertiary strata, and the pre-Tertiary may be represented in outcrop by a metamorphic series of indeterminate age.The Tertiary offshore basin developed in three distinct phases, commencing in Late Cretaceous/Early Eocene time, when seas transgressed from east to west across a peneplaned surface. An eastward-thickening wedge of argillaceous limestones and cherts was deposited. Regression and erosion occurred in Late Eocene/Early Oligocene time, possibly in association with upwarp of the oceanic crust, which created an eastern volcanic borderland. Typical orthogeosynclinal sedimentation followed in Early Miocene time, with reef, shoal and pelagic limestones deposited marginal to the stable western (continental) shelf, and with prolific volcanism associated with the eastern (oceanic) flank. This volcanism was the source for a thick pile of mudstone-greywacke sediments which was deposited in an intermediate eugeosyncline.This second phase was modified in Late Miocene time by regional uplift, and by development of the Central Mountain geanticlinal belt. This created an immense southeasterly pro-grading system which rapidly buried the Early Miocene profile. These fine grained clastic Plio-Pleistocene sediments have been highly deformed by gravitational and diapiric influences in the east-central portion of the basin. Huge volumes of sediment are still being transported southeastward into the Coral Sea Basin.


1999 ◽  
Vol 94 (8) ◽  
pp. 1231-1247 ◽  
Author(s):  
Jeremy P. Richards ◽  
Stephen R. Noble ◽  
Malcolm S. Pringle

2004 ◽  
Vol 175 (4) ◽  
pp. 361-381 ◽  
Author(s):  
Jacky Ferrière ◽  
Jean-Yves Reynaud ◽  
Andreas Pavlopoulos ◽  
Michel Bonneau ◽  
Georges Migiros ◽  
...  

Abstract The Meso-Hellenic Basin (MHB) is a large, narrow and elongated basin containing up to c. 5 km of Cenozoic sediments, which partially covers the tectonic boundary between the external, western zones (Pindos) and the internal, eastern zones (Pelagonian) of the Hellenide fold-and-thrust belt. New results, based on micropaleontologic, sedimentologic and tectonic field data from the southern half of the MHB, suggest that the MHB originated as a forearc basin during the first stages of a subduction (Pindos basin), and evolved into a true piggyback basin as a result of the collision of thicker crustal units (Gavrovo-Tripolitsa). The late Eocene forearc stage is marked by sharply transgressive, deep sea turbiditic deposition on the subsiding active margin. At this stage, large scale structures of the Pelagonian basement (i.e. the newly defined “Pelagonian Indentor”) control deposition and location of two main subsiding sub-basins located on both sides of the MHB. The Eocene-Oligocene boundary corresponds to a brief tectonic inversion of the basin, at the onset of collision (main compressive event). The true piggyback stage (Oligo-Miocene) is recorded by slope deposition and dominated by gravity processes (from slumped, fine grained turbidites to conglomeratic fan- or Gilbert-deltas). The new elongated geometry of the MHB is controlled by the underthrusted, NNW-SSE trending, thick external zones. During this stage, the locus of subsidence migrates in the same direction (eastward) as underthrusting. This subsidence, favoured by thick dense ophiolitic basement, is attributed to basal tectonic erosion of the upper Pelagonian unit while the tectonic structures of this upper unit control the stepped migration of subsidence. Growing duplexes in the Gavrovo underthrusted unit, which formed local uplifts, were mainly situated on the eastern side of the subsiding areas and associated with normal faulting (late Oligocene–early Miocene). They constituted new loads that could also have been responsible for minor but widespread lithospheric subsidence. The development of the local and regional uplifts explains the basin evolution toward shallow, dominantly conglomeratic deposits and its final emergence at the end of the middle Miocene. This trend toward emersion is emphasized by the late Miocene global sea-level fall. The MHB was subsequently overprinted by neotectonic deformation associated with the development of a continental basin (Ptolemais) and uplift attributed to the evolution of the Olympos structure that developed further east as the underthrusting moved in this direction. These results demonstrate that the Meso-Hellenic Basin evolves as a large scale piggyback Basin and that its sedimentary infill is largely controled by tectonic activity rather than only eustatic sea-level variations.


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