scholarly journals Effect of Maleic Anhydride Modification on the Mechanical Properties of a Highly Filled Glass Fibre Reinforced, Low-Viscosity Polypropylene for Injection Moulding

2016 ◽  
Vol 5 (2) ◽  
pp. 105
Author(s):  
Jurgen Troltzsch ◽  
Jonas Stiller ◽  
Katja Hase ◽  
Isabelle Roth ◽  
Frank Helbig ◽  
...  

<p class="1Body">Short glass fibre reinforcement is one of the most important measures to improve the mechanical properties of injection moulded parts. The need for increasing performance leads to high fibre contents which is a critical fact due to the contrasting behaviour of strength, stiffness and impact properties. In this study a high-fluidity polypropylene (PP) is compounded with short glass fibres up to 70 weight percent and comparatively investigated with the adding of maleic anhydride (MAH) as compatibilizer. Due to the high fluidity of the PP, which ensures a good embedding of the fibres, the tensile modulus increases up to 65 weight percent, tensile strength up to 50 weight percent of glass fibre content. Adding the MAH increases strength and impact properties, while the tensile modulus only shows an improvement at high fibre content. The influence of the compatibilizer effect diminishes at higher fibre contents, especially for the impact strength which could so far not be clarified exactly. Reasons could be the reduction of fibre length at higher fibre contents and the increasing influence of the brittle fibre component. With the adding of MAH the contrasting behaviour of the impact properties in comparison to strength and stiffness can be reduced and the optimum over all mechanical properties can be shifted to higher fibre contents.</p>

2016 ◽  
Vol 5 (2) ◽  
pp. 111 ◽  
Author(s):  
Jurgen Troltzsch ◽  
Jonas Stiller ◽  
Katja Hase ◽  
Isabelle Roth ◽  
Frank Helbig ◽  
...  

<p class="1Body">Short glass fibre reinforcement is one of the most important measures to improve the mechanical properties of injection moulded parts. The need for increasing performance leads to high fibre contents which is a critical fact due to the contrasting behaviour of strength, stiffness and impact properties. In this study a high-fluidity polypropylene (PP) is compounded with short glass fibres up to 70 weight percent and comparatively investigated with the adding of maleic anhydride (MAH) as compatibilizer. Due to the high fluidity of the PP, which ensures a good embedding of the fibres, the tensile modulus increases up to 65 weight percent, tensile strength up to 50 weight percent of glass fibre content. Adding the MAH increases strength and impact properties, while the tensile modulus only shows an improvement at high fibre content. The influence of the compatibilizer effect diminishes at higher fibre contents, especially for the impact strength which could so far not be clarified exactly. Reasons could be the reduction of fibre length at higher fibre contents and the increasing influence of the brittle fibre component. With the adding of MAH the contrasting behaviour of the impact properties in comparison to strength and stiffness can be reduced and the optimum over all mechanical properties can be shifted to higher fibre contents.</p>


e-Polymers ◽  
2011 ◽  
Vol 11 (1) ◽  
Author(s):  
Ji-Nian Yang ◽  
Zi-Quan Li ◽  
Jin-Song Liu

AbstractThe short glass fiber (SGF)/polypropylene (PP) and ethylene-1-octene copolymer (POE)/SGF/PP foam composites were prepared by extrusion and subsequent post-foaming process in designed dies. The compatilizers, maleic anhydride grafted PP (PP-g-MAH) and maleic anhydride grafted POE (POE-g- MAH), were employed to improve the performance of the foam composites, respectively, and their influences on the cellular structures, interfacial morphologies and mechanical properties of PP foam composites were investigated. It was found that the compatilizers resulted in modified PP foam composites characterized by uniform cell size distribution, reduced cell size and increased cell density except POE/SGF/PP with POE-g-MAH. The obvious enhanced SGF-matrix interfacial bonding was observed from the SEM examination, and POE-g-MAH also facilitated the compatibility between elastomeric particles and matrix. Testing results indicated that, by the introduction of PP-g-MAH or POE-g-MAH, the mechanical properties of PP foam composites were significantly improved, and it seemed that the PP-g-MAH was more effective in strengthening the flexural and compressive strength while POE-g-MAH greatly increased the impact toughness.


2013 ◽  
Vol 393 ◽  
pp. 88-93 ◽  
Author(s):  
Mohd Shahneel Saharudin ◽  
Aidah Jumahat ◽  
Amir Z.A. Kahar ◽  
Shaharudin Ahmad

mpact resistance is one of the main consideration in measuring service life, liability and safety of polymer composite structures or products. Impact resistance of a composite material can be measured in terms of energy absorption, depth of penetration and total impact time. In this study, the influence of alumina Al2O3on impact properties of short glass fiber reinforced polymer was investigated. The drop weight impact tests were performed in accordance to ASTM D7136 standard using Dynatup impact tester. Based on the results, the incorporation of micronsize alumina filler enhanced the energy absorbed during crushing, reduced the depth of penetration of the impactor and expanded the total impact time hence improved the impact properties of the composites.


2011 ◽  
Vol 197-198 ◽  
pp. 1100-1103
Author(s):  
Jian Li

A polyurethane/clay (PU/clay) composite was synthesized. The microstructure of the composite was examined by scanning electron microscopy. The impact properties of the composite were characterized by impact testing. The study on the structure of the composite showed that clays could be dispersed in the polymer matrix well apart from a few of clusters. The results from mechanical analysis indicated that the impact properties of the composite were increased greatly in comparison with pure polyurethane. The investigation on the mechanical properties showed that the impact strength could be obviously increased by adding 20 wt% (by weight) clay to the matrix.


2011 ◽  
Vol 19 (9) ◽  
pp. 725-732
Author(s):  
Shigeki Hikasa ◽  
Kazuya Nagata ◽  
Yoshinobu Nakamura

The influences of combined elastomers on impact properties and morphology of polypropylene (PP)/elastomer/CaCO3 ternary composites were investigated. In the case that polystyrene- block-poly(ethylene-butene)- block-polystyrene triblock copolymer (SEBS) and poly(ethylene- co-octene) (EOR) were used as elastomers, a sea-island structure consisting of EOR dispersed phase and SEBS continuous phase was formed. The elastomer and the CaCO3 particles were separately dispersed in PP matrix. In the case that carboxylated SEBS (C-SEBS) and EOR were used, the C-SEBS particles were dispersed in the EOR particles. Almost all of the CaCO3 particles were dispersed in the PP matrix, although some of the CaCO3 particles were dispersed in the C-SEBS/EOR combined particles. Impact strength improved with an increase of incorporated CaCO3 particles. The effect of elastomer on the impact strength was SEBS ≥ SEBS/EOR > EOR = C-SEBS/EOR > C-SEBS. The morphology formed by elastomer and CaCO3 particles strongly affected the impact properties of the ternary composites.


2018 ◽  
Vol 774 ◽  
pp. 410-415 ◽  
Author(s):  
Kazuto Tanaka ◽  
Ken Uzumasa ◽  
Tsutao Katayama

Carbon fiber reinforced thermoplastics (CFRTP) are expected to be used as a structural material for aircraft and automobiles not only for their mechanical properties such as high specific strength and high specific rigidity but also for their high recyclability and short molding time. Generally, in a composite material having a laminated structure, interlaminar delamination is often caused by an out-of-plane impact, so the interlayer property plays an important role in the mechanical properties. It has been reported that the fiber/matrix interfacial strength increases by grafting carbon nanotubes (CNT) on the carbon fiber surface. In this study, CNT grafted carbon fibers were used for reinforcement of CFRTP laminate for the improvement of impact properties of CFRTP laminates. The impact absorbed energy of the CFRTP laminate using CNT grafted carbon fibers as reinforcing fiber was higher than that using untreated CF.


Materials ◽  
2019 ◽  
Vol 12 (22) ◽  
pp. 3786 ◽  
Author(s):  
Abubaker A. M. Ahmed ◽  
Yanmin Jia

A comprehensive program of experiments consisting of compression, uniaxial compression, direct shear, flexural as well as splitting tensile and air permeability tests were performed to analyse the effect of the level of fibre dosage and the water–cement ratio on the physical properties of hybrid fibre-reinforced concrete (HFRC). Two types of fibres were studied in terms of their effect on the properties of HFRC. The results indicated that the mechanical properties of concrete were significantly improved by increasing the fibre content. However, increasing the percentage fibre content past a certain peak performance limit (0.9% glass fibre (GF) and 0.45% polypropylene fibre (PPF)) led to a decrease in strength compared to reference mixes. Additionally, the incorporation of hybrid fibres yielded an increase in air permeability in the tested specimens. The results showed that the strength-related properties of HFRC were superior to the properties of single fibre-reinforced concrete.


2020 ◽  
pp. 152808372096074
Author(s):  
Mohamed A Attia ◽  
Marwa A Abd El-baky ◽  
Mostafa M Abdelhaleem ◽  
Mohamed A Hassan

An experimental investigation on the mechanical performance of interlayer hybrid flax-basalt-glass woven fabrics reinforced epoxy composite laminates has been performed. The tensile, flexural, in-plane shear, interlaminar shear, bearing, and impact properties of the fabricated laminates were investigated. Test specimens were fabricated using vacuum bagging process. Failure modes of all specimens were recorded and discussed. Results proved that the mechanical properties of flax-basalt-glass hybrid laminates are highly dominated by the reinforcement combinations and plies stacking sequence. Hybridizing flax fiber reinforced composite with basalt and/or glass fabrics provides an effective method for enhancing its tensile, flexural, in-plane shear, interlaminar shear, and bearing properties as well as controls the impact strength of the composite. The fabricated hybrids are found to have good specific mechanical properties benefits. Amongst the studied flax/basalt/glass hybrids, FBGs has the highest tensile properties, GBFs has the highest flexural and impact properties, and GFBs has the best shear and bearing properties. Flax-basalt-glass hybrid composites with different layering sequence seem to be an appropriate choice for lightweight load bearing structures.


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