scholarly journals Bio-availability and Bio-accessibility of Lead and Zinc in Contaminated Soil from Cwymystwyth Lead Mine Site

2021 ◽  
pp. 10-18
Author(s):  
Y. Abdullahi ◽  
A. S. Aska ◽  
C. Roberts ◽  
M. S. Abdu ◽  
J. Gambo
Keyword(s):  
Contaminated Soil ◽  
Inductively Coupled Plasma ◽  
Scientific Evidence ◽  
Research Area ◽  
Soil Samples ◽  
Wire Mesh ◽  
Mine Site ◽  
Bottom Soil ◽  
Lead And Zinc ◽  
Significant Difference

Cwmystwyth Lead Mine was an abundant mine site with pugh’s and kingside water drainages shows contaminated water in the research area with no much scientific evidence to ascertain the level of the pollution. Hence this research was designed to study level of lead and zinc in contaminated soil in which the bio-availability and bio-accessibility were measured. Sixteen (16) soil samples were taken at random using soil auger and a hand trowel. The samples were dried using an oven set at a constant temperature of 400oC for 72 hours. Wire mesh (250 microns) was used to sift the samples. The Unified (BARGE) method was used. The mimics mixtures of saliva, gastric, duodenal, and bile fluids. Three-stage mimic processes were performed, in the mouth, the stomach and intestinal cavities. All mimic digestive fluids were placed in the rotator water bath for 1hr at 37oC. The bioaccessibility of the soil Samples were analyzed by inductively coupled plasma-optical emission spectrophotometer (ICP-OES) method. The results were obtained using XRF and ICP methods. The percentage concentration of lead in the topsoil was 0.64% and in the bottom soil was 1.47%, with a total mean concentration of 1.06% in combined top and bottom soil. Zinc concentrations in the top and bottom soils were 0.22 and 0.45%, respectively, with a computed total mean of 0.34%. The findings revealed a highly significant difference between lead and zinc in both the top and bottom soil samples (LSD = P0.05). The average concentrations of lead and zinc extracted in both the stomach and intestinal stages were 15.98% and 1.23%, respectively

scholarly journals ICP/XRF Analysis for Trace Elements in Soil Samples from Gezira and Suki Schemes, Sudan

2021 ◽  
Vol 9 (02) ◽  
pp. 32-39
Author(s):  
Marwa M Adam ◽  
Mustafa M Osman ◽  
Ahmed Salih Elhag ◽  
Mohamed A Elsheikh
Keyword(s):  
Inductively Coupled Plasma ◽  
Optical Emission ◽  
Hierarchical Cluster ◽  
Soil Samples ◽  
Emission Spectrometry ◽  
Inductively Coupled ◽  
Elemental Concentrations ◽  
Accuracy Of Measurements ◽  
Significant Difference ◽  
Plasma Optical Emission Spectrometry

In the present study, soil samples have been collected from two different agriculture areas: Gezira and Suki schemes in Sudan, The elemental concentrations for Cr, Ni, Cu, Zn, and Pb have been determined using Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) and X-ray Fluorescence spectrometry (XRF). The accuracy of measurements has been investigated by using ISE (PT) 1&4 and fortified samples for ICP, IAEA-Soil-7 XRF, respectively. A good agreement was found between certified and measured values. The average elemental concentrations by ICP of these elements Cr, Ni, Cu, Zn, and Pb in loc1 were found as follows: 84.7, 48.15, 33.5, 65.43, and 12.57 ppm, respectively. While the results obtained in loc2 were found as follows: 105, 65.1, 41.3, 55.4, and 12.74 ppm, respectively. The average elemental concentrations by XRF of these elements Cr, Ni, Cu, Zn, and Pb in loc1 were found as follows: 77.21, 43.72, 27.62, 86.96, and 18.74 ppm, respectively. While the results obtained in loc2 were found as follows: 123.33, 57.41, 35.99, 98.85, and 16.43 ppm, respectively. A statistical test (t-test) was applied to the data of both methods without any significant difference between the two techniques. The results obtained were compared to WHO permissible limits. Correlations between different elements were performed. Hierarchical cluster analysis was done for the data. The average elemental concentrations were calculated and compared with data from the literature. 

Soil structure of pistachio cultivation areas in Turkey and comparison with border lines

2017 ◽  
Vol 51 (04) ◽  
Author(s):  
D. Isler Ceyhan ◽  
C. Can ◽  
K. Sarpkaya ◽  
N. Kalkancý
Keyword(s):  
Soil Structure ◽  
Cultural Practices ◽  
Research Area ◽  
Soil Samples ◽  
Soil Tillage ◽  
Extractive Content ◽  
Physical Chemical ◽  
Metal Contents ◽  
Significant Difference ◽  
Long Time

Pistachio orchards and the frontier zone which had been laid with mines for a long time were determined as research area. Soil samples from mined area, cultural practices applied (use of pesticides, soil tillage and artificial fertilizers) and naturally growing pistachio orchards were taken to compare physical, chemical, biological characteristics and heavy metal contents. Experimental soils generally consisted of clay, clayey-loamy, silted-loamy, sandy loamy clay and loamy, included alkali-reaction and were limy. The soil samples were salt-free and inadequate in terms of organic substances and total amount of N. The amount of K and Mg was fairly at high-levels and soil samples were poor in terms of extractive content of Fe. Moreover, amount of Mn and Zn was very low. Soil samples of our research area included high toxic level of lead. While there was a significant difference (P less than 0.05) among all areas in respect to the number of total aerobic mesophilic viable, it was found that the least number was in the mine fields and the highest number was in fields which were treated. The data obtained through this study is the first report on detailed soil structure analyses of the pistachio orchards and their comparison with mined area in Turkey.

Estimation of Trace Elements in Gingival Crevicular Fluid and Serum-Comparative Study in Healthy and Periodontitis

2017 ◽  
Vol 9 (5) ◽  
Author(s):  
Bhagavathami Meenaksh ◽  
Chitraa R. Chandran ◽  
Aravindhan Thathchari Ranganathan ◽  
Kavindapadi Venkateswaran Rama ◽  
Valarmathy Srinivasan
Keyword(s):  
Trace Elements ◽  
Inductively Coupled Plasma ◽  
Gingival Crevicular Fluid ◽  
Serum Zinc ◽  
Cross Sectional Study ◽  
Serum Copper ◽  
Cross Sectional ◽  
Inductively Coupled ◽  
Significant Difference ◽  
Copper Zinc

Background: This study aims to determine and compare the levels of trace elements copper, zinc, selenium and chromium in GCF and serum of patients with periodontitis and healthy individuals. Methods: This cross sectional study includes 24 study subjects recruited from the patients reporting to the Department of Periodontics , Tagore Dental College Chennai. All the selected patients were subjected to a clinical examination done by a single examiner. The estimation of trace elements Copper, Zinc, Selenium and Chromium in GCF and serum is performed using Perkin Elmer optima 5300 Inductively Coupled Plasma Emission Spectrometer (ICPOES). Results: GCF and serum copper levels showed no significant difference in both periodontitis and healthy groups . Selenium levels tend to be the same in both groups. Serum zinc levels are more in periodontitis patients than healthy subjects (p less than 0.01). GCF chromium levels are found to be more in patients with periodontitis than healthy. Conclusions : More research is therefore needed to monitor the role of these trace elements C with an increased sample size to ascertain whether they are associated with a reduced risk of periodontitis.

High Parasitic Contamination of Soil Samples in the North of Iran: a Potential Risk of Parasitic Infection for Tourists

2020 ◽  
Vol 20 ◽  
Author(s):  
Beheshteh Haghparast-kenari ◽  
Tooran Nayeri ◽  
Shahabeddin Sarvi ◽  
Mohammad Taghi Rahimi ◽  
Ehsan Ahmadpour ◽  
...  
Keyword(s):  
Contaminated Soil ◽  
Urban Areas ◽  
Intestinal Parasites ◽  
Parasitic Infection ◽  
Animal Husbandry ◽  
Soil Samples ◽  
Human Society ◽  
Public Parks ◽  
The North ◽  
North Of Iran

Background: Soil-transmitted parasites (STPs) are significant intestinal parasites that infect humans and animals and impose considerable burdens on human society and animal husbandry industries. Therefore, the present study aimed to determine the prevalence of parasitic elements of soil samples collected from the north of Iran. Methods: A total of 256 soil samples were collected from public parks, public places, vegetable gardens, sand heaps, and shadow areas near houses in the north of Iran and examined using the sucrose flotation method. Results: Out of 256 examined samples, 131 (51.2%) ones showed parasitic contamination including larvae (43%), oocysts (14.1%), and different eggs (6.6%). According to the results, the most and least common parasites observed in the samples were larvae (43%), as well as Toxascaris leonina, and Trichuris trichiura (0.4%), respectively. Moreover, the most and least contaminated locations were sand heaps (62.5%) and shadow areas near houses (45.6%), respectively. Regarding cities, Behshahr (68.3%) and Sari (67.5%) had the highest contaminated soil samples, whereas Chalus (37.5%) showed the lowest contamination. On the other hand, rural samples showed more contamination, compared to urban areas (P< 0.05). Conclusion: The findings of the present study indicate that the overall prevalence of STPs in examined areas and highly contaminated soil samples can be considered as a potential source of human contamination particularly tourists with STPs.

Evaluation of Nanotechniques and Conventional Techniques for the Removal of Dioxins

2018 ◽  
Vol 9 (1) ◽  
pp. 79-84
Author(s):  
Vaishali V. Shahare ◽  
Rajni Grover ◽  
Suman Meena
Keyword(s):  
Soil Sample ◽  
Human Health ◽  
Surface Area ◽  
Contaminated Soil ◽  
Conventional Treatment ◽  
Volume Ratio ◽  
Soil Samples ◽  
Dioxins And Furans ◽  
Palladized Iron ◽  
The Impact

Background: The persistent dioxins/furans has caused a worldwide concern as they influence the human health. Recent research indicates that nonmaterial may prove effective in the degradation of Dioxins/furans. The nanomaterials are very reactive owing to their large surface area to volume ratio and large number of reactive sites. However, nanotechnology applications face both the challenges and the opportunities to influence the area of environmental protection. Objective: i) To study the impact of oil mediated UV-irradiations on the removal of 2,3,7,8-TCDD, 2,3,7,8-TCDF, OCDD and OCDF in simulated soil samples. ii) To compare the conventional treatment methods with the modern available nanotechniques for the removal of selected Dioxins/furans from soil samples. Methods: The present work has investigated an opportunity of the degradation of tetra and octachlorinated dioxins and furans by using oil mediated UV radiations with subsequent extraction of respective dioxins/furans from soils. The results have been compared with the available nanotechniques. Results: The dioxin congeners in the simulated soil sample showed decrease in concentration with the increase in the exposure time and intensity of UV radiations. The dechlorination of PCDD/Fs using palladized iron has been found to be effective. Conclusion: Both the conventional methods and nanotechnology have a dramatic impact on the removal of Dioxins/furans in contaminated soil. However, the nanotechniques are comparatively costlier and despite the relatively high rates of PCDDs dechlorination by Pd/nFe, small fraction of the dioxins are recalcitrant to degradation over considerable exposure times.

scholarly journals Development of a Tellurium Speciation Study Using IC-ICP-MS on Soil Samples Taken from an Area Associated with the Storage, Processing, and Recovery of Electrowaste

Molecules ◽  
2021 ◽  
Vol 26 (9) ◽  
pp. 2651
Author(s):  
Magdalena Jabłońska-Czapla ◽  
Katarzyna Grygoyć
Keyword(s):  
Inductively Coupled Plasma ◽  
Total Concentration ◽  
Soil Samples ◽  
Chemical Extraction ◽  
Soil Extraction ◽  
Inductively Coupled ◽  
Sequential Chemical Extraction ◽  
Icp Ms ◽  
Speciation Study ◽  
Plasma Mass Spectrometry

The optimization and validation of a methodology for determining and extracting inorganic ionic Te(VI) and Te(IV) forms in easily-leached fractions of soil by Ion Chromatography-Inductively Coupled Plasma-Mass Spectrometry (IC-ICP-MS) were studied. In this paper, the total concentration of Te, pH, and red-ox potential were determined. Ions were successfully separated in 4 min on a Hamilton PRPX100 column with 0.002 mg/kg and 0.004 mg/kg limits of detection for Te(VI) and Te(IV), respectively. Soil samples were collected from areas subjected to the influence of an electrowaste processing and sorting plant. Sequential chemical extraction of soils showed that tellurium was bound mainly with sulphides, organic matter, and silicates. Optimization of soil extraction allowed 20% average extraction efficiency to be obtained, using 100 mM citric acid as the extractant. In the tested soil samples, both tellurium species were present. In most cases, the soils contained a reduced Te form, or the concentrations of both species were similar.

scholarly journals Rural Development Through Non-State Actors in Highlands of Pakistan

SAGE Open ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 215824402110071
Author(s):  
Muhammad Luqman ◽  
Saleem Ashraf ◽  
Babar Shahbaz ◽  
Tahir Munir Butt ◽  
Raheel Saqib
Keyword(s):  
Rural Development ◽  
Mixed Methods Research ◽  
Religious Faith ◽  
Research Area ◽  
Working Mechanism ◽  
Test Analysis ◽  
State Institutions ◽  
Significant Difference ◽  
State Actors ◽  
Household Heads

We explored the contribution and effectiveness of state and non-state institutions in rural development efforts in highlands (Khyber Pakhtunkhwa [KPK] province) of Pakistan. This study employed mixed-methods research design and data were collected from 300 household heads, randomly selected from six villages from two purposively selected districts Mansehra and Nowshehra. Findings showed people in KPK were deprived of due to conflicts, conspiracies and terrorism, poor governance, small landholdings and subsistence farming followed by sluggish marketing system, insufficient education and training for people, and inadequate employment opportunities. Regarding contribution, non-state institutions had more contribution as compared to state institutions. T-test analysis showed that the non-state institutions had an effective provision of agricultural extension and forestry advisory services, education, health services in remote areas, skill development, and provision of microcredit schemes. The results of F-test statistics showed highly significant difference among the perceived effectiveness of rural development activities of different types of non-state actors (localite, cosmopolite, and religious/faith-based) working in the research area. This study recommends state-owned rural development departments revisit their working mechanism and develop synergistic working relationship with the non-state institutions in discharging rural development efforts.

Efficacy of Benson’s Relaxation Technique on Anxiety and Depression among Patients Undergoing Hemodialysis: A Systematic Review

2021 ◽  
pp. 105477382110247
Author(s):  
Haya Ibrahim Ali Abu Maloh ◽  
Kim Lam Soh ◽  
Mohannad Eid AbuRuz ◽  
Seng Choi Chong ◽  
Siti Irma Fadhilah Ismail ◽  
...  
Keyword(s):  
Systematic Review ◽  
Randomized Controlled Trials ◽  
Scientific Evidence ◽  
Relaxation Technique ◽  
Anxiety And Depression ◽  
Controlled Trials ◽  
Randomized Controlled ◽  
Significant Difference ◽  
Depression Level ◽  
Ebsco Host

This study aimed to evaluate the efficacy of Benson’s relaxation technique on anxiety and depression among patients undergoing hemodialysis. A systematic review of randomized controlled trials was conducted. Searching databases included EBSCO Host, PubMed, ProQuest, Science Direct, Sage Journals, Ovid, and Google Scholar from January 2000 to September 2020. Five randomized controlled trials were identified. Findings revealed a statistically significant decrease in anxiety score. Concerning depression; one RCT showed a statistically significant decrease and two RCTs revealed a non-significant difference in depression level. The overall quality of the RCTs was not high. Despite that the RCTs showed benefits of BRT in managing anxiety. However, this is not the same for depression. The lack of high-quality scientific evidence supporting its retinue use indicates that additional well designed randomized controlled trials in multiple countries are warranted to support the efficacy of Benson’s relaxation technique on anxiety and depression among patients undergoing hemodialysis.

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