Techno-Functional and Gelling Properties of Acha (Fonio) (Digitaria exilis stapf) Flour: A Study of Its Potential as a New Gluten-Free Starch Source in Industrial Applications

Fonio (Digitaria exilis Stapf) is an ancient African cereal that represents a rich source of carbohydrate, fat, fiber, vitamins, minerals, and sulfur-containing amino acids. Processing and utilization of fonio require adequate knowledge of its structural, chemical, and nutritional characteristics. The present work evaluates the structural, techno-functional, and gelling properties of fonio and compares them to other major gluten-free cereals (rice, maize, sorghum, and millet). Fonio flour presented significantly higher water absorption index and swelling power, while it scored a lower water solubility index than the reference flours. The pasting viscosity profile of fonio was similar to that of rice, with equivalent peak viscosity but a breakdown viscosity 24% lower than rice, indicative of higher stability and resistance to shearing and heating. Rheological properties demonstrated that fonio generates gels with remarkably strong structures. At 15% concentration, fonio gel withstood stress 579% higher than those observed in the reference flours without breaking its structure. Fonio flour presented the highest gelatinization enthalpy (11.45 J/g) and a narrow gelatinization temperature range (9.96 °C), indicative of a better-packed starch structure than the other analyzed flours. The texture of the gels made with fonio showed higher firmness over the evaluated period. These combined results suggest that fonio is a suitable ingredient for gel-like food formulations.

Reinvestigating the Parabolic-Shaped Eddy Viscosity Profile for Free Surface Flows

The flow in rivers is turbulent. The main parameter related to turbulence in rivers is the eddy viscosity, which is used to model a turbulent flow and is involved in the determination of both velocities and sediment concentrations. A well-known and largely used vertical distribution of eddy viscosity in free surface flows (open channels and rivers) is given by the parabolic profile that is based on the logarithmic velocity profile assumption and is valid therefore only in the log-law layer. It was improved thanks to the log-wake law velocity profile. These two eddy viscosities are obtained from velocity profiles, and the main shortcoming of the log-wake profile is the empirical Coles’ parameter. A more rigorous and reliable analytical eddy viscosity model is needed. In this study, we present two analytical eddy viscosity models based on the concepts of velocity and length scales, which are related to the exponentially decreasing turbulent kinetic energy (TKE) function and mixing length, namely, (1) the exponential-type profile of eddy viscosity and (2) an eddy viscosity based on an extension of von Karman’s similarity hypothesis. The eddy viscosity from the second model is -independent, while the eddy viscosity from the first model is -dependent (where is the friction Reynolds number). The proposed analytical models were validated through computation of velocity profiles, obtained from the resolution of the momentum equation and comparisons to experimental data. With an additional correction function related to the damping effect of turbulence near the free surface, both models are similar to the log-wake-modified eddy viscosity profile but with different values of the Coles’ parameter, i.e., for the first model and for the second model. These values are similar to those found in open-channel flow experiments. This provides an explanation about the accuracy of these two analytical models in the outer part of free surface flows. For large values of ( > 2000), the first model becomes independent, and the two coefficients reach asymptotic values. Finally, the two proposed eddy viscosity models are validated by experimental data of eddy viscosity.

Use of Micronized Weighting Agents for High Density Completion Fluids: A Case Study

A unique invert emulsion fluid (IEF) weighted up with treated micronized weighting agent (MWA) slurries has been developed and successfully implemented in the field as a completion and testing fluid. The utilization of this unique IEF by design allowed the fluid properties to be lower on viscosity and superior suspension characteristics, which allowed for thermally stable fluid and provided excellent downhole hydraulics performance. Much of the earlier development and deployment of this type of IEF was focused on drilling for sections in narrow mud weight and fracture gradient windows, coiled tubing operations, managed pressure drilling, and extended reach wells. Many of these drilling challenges are also encountered in high pressure and high temperature (HTHP) and ultra-deepwater field developments and mature, depleted fields. Early fluid developments focused on designing the fluids chemistry and physics interactions and the optimization of mineralogy of the weighing agent used. There was also some concern on variability of the results seen on the return permeability as well as standard fluid loss experiments. The paper describes the laboratory and field and rigsite data generated while using the MWA in IEFs during completion operations with a client in India. The paper will briefly describe the laboratory work before the application and the associated results observed on the rig site. It will also outline all the challenges which were faced during the execution and mixing of the MWA IEFs. Each separate operation required a high-density reservoir fluid solution above 15.5 ppg [1.85 sg]. Because corrosion, sag potential, and scale were the operator's main concerns, a solids-free brine or other type of weighting agent (for e.g. Calcium Carbonate and/or Tri-Manganese Tetra Oxide) solution was not favored. A high-density IEF designed with MWA allowed us to provide a solution that mitigated against the risks identified in each operation. The thin viscosity profile enabled completion activities to proceed with minimal fluid consumption at surface, reducing the overall environmental impact. The high-density (15.6 ppg [1.86 SG] and 16.2 ppg [1.94 SG]) invert emulsion fluid was designed to minimize sag potential with minimal reservoir damage potential. With a thinner viscosity profile compared to conventional IEFs at equivalent densities, the fluid enabled completion activities with minimal fluid volumes lost over shakers and reduced the environmental impact. The MWA that was used to build the IEF used for drilling and completion fluid enabled maintenance of extremely low-shear rate viscosities when compared to conventional barite-laden fluids. This fluid was used for suspending and abandoning the well in Case Study A, where the reentry and intervention of the well was planned to be after 2 years. After exposure of the fluid in Case Study A, the fluid showed minimum sag after re-entry of the well and the intervention activities were done without any problems. Case Study B showed that the fluid was mixed to the density of 16.2 ppg and was used to perforate and test two different zones. The bottom hole static temperature (BHST) reported were 356 degF (180 degC) for Case Study A and 376 degF (191 degC) for Case Study B respectively. The paper attempts to show the effects of using this alternative weighing agent as a completion fluid instead of a high-density solids-free brine or other solids-laden high-density brines and the associated success, which could be managed if the fluid design is carefully planned.

Effect of viscosity transition on oil flow in shale and tight rocks

It has been frequently hypothesized that there is an “effective immobile layer” attached at the solid-liquid interface to represent the hindering effect because of the complicated composition on the flow of crude oil in nanopores. Nevertheless, the resulting viscosity discontinuity is physically problematic, and the effect of viscosity transition was not incorporated. In this paper, based on the reduced form of the continuous viscosity profile, the numerical and analytical models for reduced velocity profiles (quantifying the magnitude and the shape) and the reduced pore radius (the ratio of equivalent and actual pore radii) are obtained and compared with each other, respectively. The reduced pore radius establishes a link between the “effective immobile layer” simplification and the viscosity transition. Detailed sensitivity analysis is conducted to study the impact of viscosity transition (indicated by the curvature constant and the viscosity ratio) on the reduced viscosity profile, reduced velocity profiles and the reduced pore radius, separately. Results show the microscale flow patterns that cannot be reflected by the existing body of methodology. This work is important for understanding the flow characteristics of crude oil in shale and tight rocks, where nanopores are dominating and the effect of the interfacial viscosity transition can be significant.

Rheology Impact of Various Hydrophilic-Hydrophobic Balance (HLB) Index Non-Ionic Surfactants on Cyclopentane Hydrates

In this study, series of non-ionic surfactants from Span and Tween are evaluated for their ability to affect the viscosity profile of cyclopentane hydrate slurry. The surfactants; Span 20, Span 40, Span 80, Tween 20, Tween 40 and Tween 80 were selected and tested to provide different hydrophilic–hydrophobic balance values and allow evaluation their solubility impact on hydrate formation and growth time. The study was performed by using a HAAKE ViscotesterTM 500 at 2 °C and a surfactant concentration ranging from 0.1 wt%–1 wt%. The solubility characteristic of the non-ionic surfactants changed the hydrate slurry in different ways with surfactants type and varying concentration. The rheological measurement suggested that oil-soluble Span surfactants was generally inhibitive to hydrate formation by extending the hydrate induction time. However, an opposite effect was observed for the Tween surfactants. On the other hand, both Span and Tween demonstrated promoting effect to accelerate hydrate growth time of cyclopentane hydrate formation. The average hydrate crystallization growth time of the blank sample was reduced by 86% and 68% by Tween and Span surfactants at 1 wt%, respectively. The findings in this study are useful to understand the rheological behavior of surfactants in hydrate slurry.

Antibiotic Activity Screened by the Rheology of S. aureus Cultures

Multidrug resistant bacteria are one of the most serious public health threats nowadays. How bacteria, as a population, react to the presence of antibiotics is of major importance to the outcome of the chosen treatment. In this study we addressed the impact of oxacillin, a β-lactam, the most clinically relevant class of antibiotics, in the viscosity profile of the methicillin resistant Staphylococcus aureus (MRSA) strain COL. In the first approach, the antibiotic was added, at concentrations under the minimum inhibitory concentration (sub-MIC), to the culture of S. aureus and steady-state shear flow curves were obtained for discrete time points during the bacterial growth, with and without the presence of the antibiotic, showing distinct viscosity progress over time. The different behaviors obtained led us to test the impact of the sub-inhibitory concentration and a concentration that inhibited growth. In the second approach, the viscosity growth curves were measured at a constant shear rate of 10 s−1, over time. The obtained rheological behaviors revealed distinctive characteristics associated to the presence of each concentration of the tested antibiotic. These results bring new insights to the bacteria response to a well-known bacteriolytic antibiotic.

The evolution and distribution of recycled oceanic crust in the Earth’s mantle: Insight from geodynamic models

<p>A better understanding of the Earth’s compositional structure is needed to place the geochemical record of surface rocks into the context of Earth accretion and evolution. Cosmochemical constraints imply that lower-mantle rocks may be enriched in silica relative to upper-mantle pyrolite, whereas geophysical observations support whole-mantle convection and mixing. To resolve this discrepancy, it has been suggested that subducted mid-ocean ridge basalt (MORB) segregates from subducted harzburgite to accumulate in the mantle transition zone (MTZ) and/or the lower mantle. However, the key parameters that control basalt segregation and accumulation remain poorly constrained. Here, we use global-scale 2D thermochemical convection models to investigate the influence of mantle-viscosity profile, planetary-tectonic style and bulk composition on the evolution and distribution of mantle heterogeneity. Our models robustly predict that, for all cases with Earth-like tectonics, a basalt-enriched reservoir is formed in the MTZ, and a harzburgite-enriched reservoir is sustained at 660~800 km depth, despite ongoing whole-mantle circulation. The enhancement of basalt and harzburgite in and beneath the MTZ, respectively, are laterally variable, ranging from ~30% to 50% basalt fraction, and from ~40% to 80% harzburgite enrichment relative to pyrolite. Models also predict an accumulation of basalt near the core mantle boundary (CMB) as thermochemical piles, as well as moderate enhancement of most of the lower mantle by basalt. While the accumulation of basalt in the MTZ does not strongly depend on the mantle-viscosity profile (explained by a balance between basalt delivery by plumes and removal by slabs at the given MTZ capacity), that of the lowermost mantle does: lower-mantle viscosity directly controls the efficiency of basalt segregation (and entrainment) near the CMB; upper-mantle viscosity has an indirect effect through controlling slab thickness. Finally, the composition of the bulk-silicate Earth may be shifted relative to that of upper-mantle pyrolite, if indeed significant reservoirs of basalt exist in the MTZ and lower mantle.</p>

Pasting properties of raw and extruded cowpea cotyledons flours

There is little research on the viscosity profile analysis of cowpea cotyledon flour (CCF). Due to the new ways of using pulses grains in the diet, it is important to evaluate the viscoamylographic behavior of raw and processed CCF. The CCF was obtained from the cultivars BRS Guariba and BRS Novaera and evaluated in the Rapid Visco Analyzer (RVA). For raw CCF it was used the “Standard 1” program. The extruded CCF was obtained from the cultivar BRS Guariba, which was processed following a central rotational composite design, combining thermoplastic extrusion temperatures (124; 130; 145; 160; 166 °C) and conditioning moisture (16.2%; 17%; 19%; 21%, 21.8%). The obtained extrusions were ground (Ø > 0.5 mm) and evaluated in the RVA using the program “Extrusion 2”. The raw CCF from BRS Guariba presented higher protein, lipid and mineral content and lower carbohydrate content than BRS Novaera. The raw CCF from BRS Guariba showed lower values of pasting temperature (79.35 °C), viscosity breakdown (103.00 cP) and seatback (1447.33 cP) compared to raw CCF from BRS Novaera. The extrusion process drastically changed all viscosity parameters, increasing the initial viscosity value and decreasing the value of other parameters. The extruded CCF had different pasting properties. CCF extruded at 166 °C and 19% moisture resulted in flours with higher initial viscosity and lower retrogradation values, which can be used as a thickener in food products, in addition to increase nutritional value.