The Impact of Spacer Oxide Material on the Underlapped SOI-nFinFET Working as Charged Based Radiation Sensor

In this work, the influence of the underlap region on the electrical behavior of a SOI-nFinFET transistor has been studied with the purpose of radiation sensing. The analysis was performed by evaluating the impact of variations in the underlap region on the on-state current and by studying its sensitivity. The impact of the underlap region on the drain current and, consequently, on the devices’ sensitivity was explained by the analysis of series resistance, the fringing field and electron density. Considering the main impact of radiation in these devices, the study of sensitivity was also performed taking into consideration the variation of oxide trapped charges density. When applying the transistor to a harsh environment, the Underlapped FinFET showed to be a quite respectable radiation sensor, since the results performed with very good sensitivities when using long and narrow spacer oxide with low permittivity oxide. With thicker spacer oxide in the underlap region, the charge concentration makes the spreading field high enough to overcome the series resistance effect, which results in a less sensible device. Once presented the on-state current variation of the Underlapped FinFET, the study turns radiation-sensing purpose applicable using the excellent characteristics of this device, which is shown in detail throughout this work.

Correction: Free ion diffusivity and charge concentration on cross-linked polymeric ionic liquid iongel films based on sulfonated zwitterionic salts and lithium ions

Correction for ‘Free ion diffusivity and charge concentration on cross-linked polymeric ionic liquid iongel films based on sulfonated zwitterionic salts and lithium ions’ by David Valverde et al., Phys. Chem. Chem. Phys., 2019, 21, 17923–17932, DOI: 10.1039/C9CP01903K.

An Engineering Approach to Model Blood Cells Electrical Characteristics: From Biological to Digital-Twin

Some of the most effective methods to separate circulating tumor cells (CTCs) from normal blood cells can be implemented using ultra-filtration, and/or electro-magnetic fields. As well known, each biological cell presents, on both sides of its membrane, different concentrations of ionic species that produce an electric charge concentration with respect to the lipid double layer (impermeable to ions). In this way, the bio-cell can be seen as an electric capacitor, which has the lipid double layer acting as an insulator inserted between two conductive plates, concentrated on the lipid double layer inner and outer surfaces. In this paper, firstly, the electrical capacitor equivalent system is used to treat different types of bio-cells normally flowing in blood vessels (red blood cells, lymphocytes and various types of CTCs-like), and to transform their biological characteristics into digital twin information useful for engineering applications. After, the preliminary 3D geometric analysis of the bio-cells shapes allowed to associate each bio-cell to a different capacitor model, and to predict the electric-equivalent dimensions characterizing its electric behavior. Finally, the equivalent capacitor model is used to study the influence of bio-cells characteristics variation on human blood cells, with particular attention devoted to liver and lung CTCs-like ones.

Numerical Investigation on Influential Factors for Quality of Smooth Blasting in Rock Tunnels

The quality of smooth blasting including the volume of over-/underbreak and blasting-induced damage of surrounding rocks has been extensively considered to be highly correlated to both the cost and advancement rate of rock tunnelling excavated by the drill-blast method. A general control strategy for smooth blasting is too difficult to be available due to the uncertainties and complexity of rock masses, as well as the varying blasting operations. As prerequisite for the evaluation of the blasting quality, effective identification of the influential factors affecting smooth blasting usually plays a significant role in the improvement of smooth blasting design. Compared to the expensive and time-consuming experiments including physical modelling and field tests, numerical modelling, as a cost-efficient approach, offers an attractive alternative to investigate the influential factors in terms of weight, which might be more applicable and reliable for the optimization of smooth blasting parameters. In this case, the dominant factors and secondary factors can be quantitatively identified. Considering the dominant factors often orient the development of things; in this work, a numerical-based approach was proposed to quantitatively identify the dominant factors influencing the quality of smooth blasting. Proposed 3-dimensional blasting modelling was based on LS-DYNA to simulate the occurrence of smooth blasting in rock masses, and the erosion algorithm was also employed to determine the fracturing of jointed rocks. The orthogonal experimental design method was utilized to optimize the experimental arrangement. Seven factors with 4 levels including the perimeter hole spacing, line of least resistance, charge concentration, charging explosive, type of rock mass, detonation velocity, and drilling deviation were taken into account. The geological setting and project background of a real rock tunnel served for the Chengdu-Chongqing high-speed railway were selected as the site conditions to perform the numerical investigation. Calculated area and distance of overbreak as the observed parameters indicating the quality of smooth blasting were utilized to determine sensitivities of factors based on the range analysis of orthogonal experiments. The results suggested that the type of rock mass has the greatest influence on the blasting quality, whereas the charge concentration and detonation velocity can be considered as the secondary factors under the specific site conditions. The proposed numerical approach for assessing influential factors of quality of smooth blasting under specified geological conditions is expected to improve the parameter design and operation of smooth blasting in practical applications.

pH-Responsive Properties of Asymmetric Nanopapers of Nanofibrillated Cellulose

Inspired by plant movements driven by the arrangement of cellulose, we have fabricated nanopapers of nanofibrillated cellulose (NFC) showing actuation under pH changes. Bending was achieved by a concentration gradient of charged groups along the film thickness. Hence, the resulting nanopapers contained higher concentration of charged groups on one side of the film than on the opposite side, so that pH changes resulted in charge-dependent asymmetric deprotonation of the two layers. Electrostatic repulsions separate the nanofibers in the nanopaper, thus facilitating an asymmetric swelling and the subsequent expanding that results in bending. Nanofibrillated cellulose was modified by 2,2,6,6-tetramethylpiperidin-1-yloxyl radical (TEMPO) oxidation at two reaction times to get different surface concentrations of carboxylic acid groups. TEMPO-oxidized NFC was further chemically transformed into amine-modified NFC by amidation. The formation of graded nanopapers was accomplished by successive filtration of NFC dispersions with varying charge nature and/or concentration. The extent of bending was controlled by the charge concentration and the nanopaper thickness. The direction of bending was tuned by the layer composition (carboxylic acid or amine groups). In all cases, a steady-state was achieved within less than 25 s. This work opens new routes for the use of cellulosic materials as actuators.

Optical and Electrochemical Characterization of Nanoporous Alumina Structures: Pore Size, Porosity, and Structure Effect

Three nanoporous alumina structures (NPASs) obtained by the two-step anodization method were optically and electrochemically characterized. Two of the structures were symmetric (NPAS-Sf and NPAS-Ph) and one was asymmetric (NPAS-And); pore size ranged from 10 nm to 100 nm and porosity was 12% in the case of the symmetrical NPAS and 23% and 30% for each surface of the asymmetric structure NPAS-And(A) and (B), respectively. Optical parameters of the studied samples (refraction index and extinction coefficient) were obtained from ellypsometric spectroscopy measurements carried out for wavelengths ranging between 250 nm and 1700 nm (visible and near infrared regions), with the total average refraction indices being 1.54, 1.52, 1.14, and 1.05 for NPAS-Sf, NPAS-Ph, NPAS-And(A), and NPAS-And(B), respectively, which indicates porosity control of refraction index values. Electrochemical characterizations (concentration potential and impedance spectroscopy measurements) were performed with NaCl solutions, and they allowed us to estimate samples of effective fixed charge concentration (1.22 × 10−2 M, 1.13 × 10−3 M, and 1.15 × 10−3 M), ion transport numbers, permselectivity (33.0%, 3.1%, and 9.6%), and the electrical resistance of each solution/sample system as well as the interfacial effects associated to solution concentration–polarization, which seems to be mainly controlled by pore size and sample symmetry.

Ion Conducting studies in PEO:NaI and its composite : Carrier density approach

: The modulation in electrical conductivity of polymer electrolyte, viz., polyethylene oxide (PEO) complexed with different concentration of sodium iodide is studied. The role of mobility and charge concentration in electrical conductivity of polymer electrolytes is established. The effect on charge concentration, mobility and conductivity of PEO+NaI film by adding three different concentration of silicon is reported. The polarized optical microscopy (POM) is used to study the morphology of the surface of PEO, PEO+NaI films dispersed with Si. The complex impedance spectroscopy (CIS) method is used to measure the electrical conductivity of film.

Second ISSMGE R. Kerry Rowe Lecture: On the intrinsic, state, and fabric parameters of active clays for contaminant control

The osmotic, hydraulic and self-healing efficiency of bentonite-based barriers for the containment of subsoil pollutants is governed not only by the intrinsic chemicophysical parameters of the bentonite, i.e., the solid phase density, ρsk; the total specific surface, S; the surface density of the electric charge, σ; and the Stern layer thickness, dStern, and fraction, fStern, but also by the chemicomechanical fabric parameters that quantify the structure or texture of the solid skeleton, such as the micro, em, and nano, en, void ratios; the average number of platelets or lamellae per tactoid, Nl,AV; and the solid skeleton effective electric charge concentration, [Formula: see text]. In turn, the fabric parameters are controlled by state parameters, such as the total void ratio, e; and the salt concentration of the equilibrium solution, cs. A theoretical framework has been developed to describe the relationships between the aforementioned intrinsic, state, and fabric parameters for a bentonite barrier and its performance parameters: the hydraulic conductivity, k; the effective diffusion coefficient, [Formula: see text]; the chemico-osmotic efficiency coefficient, ω; and the osmotic swelling pressure, usw. The proposed theoretical hydrochemicomechanical model has been validated through comparison with a large amount of experimental results.

Electron spin resonance (ESR) thermochronometry of the Hida range of the Japanese Alps: validation and future potential

The electron spin resonance (ESR) of quartz has previously been shown to have potential for determining rock cooling histories; however, this technique remains underdeveloped. In this study, we explore the ESR of a suite of samples from the Hida range of the Japanese Alps. We develop measurement protocols and models to constrain the natural trapped-charge concentration as well as the parameters that govern signal growth and signal thermal decay. The thermal stability of the Al and Ti centres is similar to that of the luminescence of feldspar. Inverting the ESR data for cooling yields similar thermal histories to paired luminescence data from the same samples. However, a series of synthetic inversions shows that whereas the luminescence of feldspar can only resolve minimum cooling histories of ∼160 ∘C Myr−1 over timescales of 103−5 years, quartz ESR may resolve cooling histories as low as 25–50 ∘C Myr−1 over timescales of 103−7 years. This difference arises because quartz ESR has a higher dating limit than the luminescence of feldspar. These results imply that quartz ESR will be widely applicable in the constraint of late-stage rock cooling histories, providing new insights into landscape evolution over late Quaternary timescales.