Effects of Ultrasonic Melt Processing on Microstructure, Mechanical Properties, and Electrical Conductivity of Hypereutectic Al–Si, Al–Fe, and Al–Ni Alloys with Zr Additions

Author(s):  
Suwaree Chankitmunkong ◽  
Dmitry G. Eskin ◽  
Chaowalit Limmaneevichitr
Polymers ◽  
2021 ◽  
Vol 13 (21) ◽  
pp. 3819
Author(s):  
Hamed Peidayesh ◽  
Katarína Mosnáčková ◽  
Zdenko Špitalský ◽  
Abolfazl Heydari ◽  
Alena Opálková Šišková ◽  
...  

Conductive polymer composites (CPC) from renewable resources exhibit many interesting characteristics due to their biodegradability and conductivity changes under mechanical, thermal, chemical, or electrical stress. This study is focused on investigating the physical properties of electroconductive thermoplastic starch (TPS)–based composites and changes in electroconductive paths during cyclic deformation. TPS–based composites filled with various carbon black (CB) contents were prepared through melt processing. The electrical conductivity and physicochemical properties of TPS–CB composites, including mechanical properties and rheological behavior, were evaluated. With increasing CB content, the tensile strength and Young’s modulus were found to increase substantially. We found a percolation threshold for the CB loading of approximately 5.5 wt% based on the rheology and electrical conductivity. To observe the changing structure of the conductive CB paths during cyclic deformation, both the electrical conductivity and mechanical properties were recorded in parallel using online measurements. Moreover, the instant electrical conductivity measured online during mechanical deformation of the materials was taken as the parameter indirectly describing the structure of the conductive CB network. The electrical conductivity was found to increase during five runs of repeated cyclic mechanical deformations to constant deformation below strain at break, indicating good recovery of conductive paths and their new formation.


2019 ◽  
Vol 3 (2) ◽  
pp. 37 ◽  
Author(s):  
Helga Seyler ◽  
Marián Gómez-Fatou ◽  
Horacio Salavagione

The use of polyolefins in structural components requires the simultaneous improvement of stiffness and toughness of the matrix, whilst in the case of sensing components during operation, additional functions are needed such as electrical conductivity. However, providing various desired properties without impairing those intrinsic to the materials can be somewhat challenging. In this study we report the preparation of an isotactic polypropylene (iPP)/styrene–ethylene–butylene–styrene triblock copolymer (SEBS)/graphene system that combines enhanced mechanical properties with electrical conductivity. Blends were prepared by solution mixing (SoM) and solution/solid state mixing (SoM/SSM) formulation routes prior to melt processing. The nanocomposites were characterized by scanning electron microscopy (SEM) and thermogravimetric analysis (TGA) and the electrical and mechanical properties were evaluated. The materials prepared via the SoM/SSM route displayed good electrical conductivity while retaining the mechanical properties of iPP, making them attractive materials for low cost and high throughput structural components with sensing capacity.


2021 ◽  
Author(s):  
Zhanyu Jia ◽  
Guangyao Li ◽  
Juan Wang ◽  
shouhua Su ◽  
Jie Wen ◽  
...  

Conductivity, self-healing and moderate mechanical properties are necessary for multifunctional hydrogels which have great potential in health-monitor sensor application. However, the combination of electrical conductivity, self-healing and good mechanical properties...


Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3140
Author(s):  
Kamil Dydek ◽  
Anna Boczkowska ◽  
Rafał Kozera ◽  
Paweł Durałek ◽  
Łukasz Sarniak ◽  
...  

The main aim of this work was the investigation of the possibility of replacing the heavy metallic meshes applied onto the composite structure in airplanes for lightning strike protection with a thin film of Tuball single-wall carbon nanotubes in the form of ultra-light, conductive paper. The Tuball paper studied contained 75 wt% or 90 wt% of carbon nanotubes and was applied on the top of carbon fibre reinforced polymer before fabrication of flat panels. First, the electrical conductivity, impact resistance and thermo-mechanical properties of modified laminates were measured and compared with the reference values. Then, flat panels with selected Tuball paper, expanded copper foil and reference panels were fabricated for lightning strike tests. The effectiveness of lightning strike protection was evaluated by using the ultrasonic phased-array technique. It was found that the introduction of Tuball paper on the laminates surface improved both the surface and the volume electrical conductivity by 8800% and 300%, respectively. The impact resistance was tested in two directions, perpendicular and parallel to the carbon fibres, and the values increased by 9.8% and 44%, respectively. The dynamic thermo-mechanical analysis showed higher stiffness and a slight increase in glass transition temperature of the modified laminates. Ultrasonic investigation after lightning strike tests showed that the effectiveness of Tuball paper is comparable to expanded copper foil.


Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 404
Author(s):  
Nur Sharmila Sharip ◽  
Hidayah Ariffin ◽  
Tengku Arisyah Tengku Yasim-Anuar ◽  
Yoshito Andou ◽  
Yuki Shirosaki ◽  
...  

The major hurdle in melt-processing of ultra-high molecular weight polyethylene (UHMWPE) nanocomposite lies on the high melt viscosity of the UHMWPE, which may contribute to poor dispersion and distribution of the nanofiller. In this study, UHMWPE/cellulose nanofiber (UHMWPE/CNF) bionanocomposites were prepared by two different blending methods: (i) melt blending at 150 °C in a triple screw kneading extruder, and (ii) non-melt blending by ethanol mixing at room temperature. Results showed that melt-processing of UHMWPE without CNF (MB-UHMWPE/0) exhibited an increment in yield strength and Young’s modulus by 15% and 25%, respectively, compared to the Neat-UHMWPE. Tensile strength was however reduced by almost half. Ethanol mixed sample without CNF (EM-UHMWPE/0) on the other hand showed slight decrement in all mechanical properties tested. At 0.5% CNF inclusion, the mechanical properties of melt-blended bionanocomposites (MB-UHMWPE/0.5) were improved as compared to Neat-UHMWPE. It was also found that the yield strength, elongation at break, Young’s modulus, toughness and crystallinity of MB-UHMWPE/0.5 were higher by 28%, 61%, 47%, 45% and 11%, respectively, as compared to the ethanol mixing sample (EM-UHMWPE/0.5). Despite the reduction in tensile strength of MB-UHMWPE/0.5, the value i.e., 28.4 ± 1.0 MPa surpassed the minimum requirement of standard specification for fabricated UHMWPE in surgical implant application. Overall, melt-blending processing is more suitable for the preparation of UHMWPE/CNF bionanocomposites as exhibited by their characteristics presented herein. A better mechanical interlocking between UHMWPE and CNF at high temperature mixing with kneading was evident through FE-SEM observation, explains the higher mechanical properties of MB-UHMWPE/0.5 as compared to EM-UHMWPE/0.5.


2021 ◽  
Vol 2 (1) ◽  
Author(s):  
Qingzhong Mao ◽  
Yusheng Zhang ◽  
Yazhou Guo ◽  
Yonghao Zhao

AbstractThe rapid development of high-speed rail requires copper contact wire that simultaneously possesses excellent electrical conductivity, thermal stability and mechanical properties. Unfortunately, these are generally mutually exclusive properties. Here, we demonstrate directional optimization of microstructure and overcome the strength-conductivity tradeoff in copper wire. We use rotary swaging to prepare copper wire with a fiber texture and long ultrafine grains aligned along the wire axis. The wire exhibits a high electrical conductivity of 97% of the international annealed copper standard (IACS), a yield strength of over 450 MPa, high impact and wear resistances, and thermal stability of up to 573 K for 1 h. Subsequent annealing enhances the conductivity to 103 % of IACS while maintaining a yield strength above 380 MPa. The long grains provide a channel for free electrons, while the low-angle grain boundaries between ultrafine grains block dislocation slip and crack propagation, and lower the ability for boundary migration.


2013 ◽  
Vol 706-708 ◽  
pp. 95-98
Author(s):  
Mi Dan Li ◽  
Dong Mei Liu ◽  
Lu Lu Feng ◽  
Huan Niu ◽  
Yao Lu

Polymer matrix composites made from phenolic resin are filled with natural graphite powders. They are fabricated by compression molding technique. The density, electrical conductivity and flexural strength of composite are analyzed to determine the influences of mould pressure and mould pressing time on the physical, electrical and mechanical properties of composite. It is found that the density, electrical conductivity and flexural strength of composites increased with increasing mould pressure. Under pressure of 40 MPa for 60 min, the density, electrical conductivity and flexural strength of composites were 1.85 g/cm3, 4.35  103 S/cm and 70 MPa, respectively. The decreased gaps could be the main reason for the increasing of density, electrical conductivity and flexural strength as mould pressure increases. The results also show that the density of composites increased with increasing mould pressing time.


2014 ◽  
Vol 607 ◽  
pp. 505-510 ◽  
Author(s):  
Isao Matsui ◽  
Hiroki Mori ◽  
Tomo Kawakatsu ◽  
Yorinobu Takigawa ◽  
Tokuteru Uesugi ◽  
...  

2010 ◽  
Vol 638-642 ◽  
pp. 273-278 ◽  
Author(s):  
Xi Wu Li ◽  
Bai Qing Xiong ◽  
Yon Gan Zhang ◽  
Guo Jun Wang ◽  
Zhi Hui Li ◽  
...  

In this study, the effect of various aging treatment (T6 and T7 treatment) on the mechanical properties, electrical conductivity and the microstructure of an Al-7.5Zn-1.3Mg-1.4Cu-0.12Zr alloy has been investigated. The results show that with elevating the aging treatment temperatures, the aging response rate is greatly accelerated. When T6 temper is performed at 140°C for 12h, as compared to peak aging for 24h at 120°C, the UTS and the corresponding Elongation values keep the same level, whereas the TYS and the electrical conductivity obviously increase by 5% and 9%, which is up to 560 MPa and 22.6 MS/m, respectively. And there are clear PFZs along the grain boundary and slightly coarser precipitates inside the grain. GPI zones, GPII zones and η' phases are major precipitates for the alloy under T6 condition. When T7 temper is performed on the alloy, the main precipitates are GPII zones, η′ and η phases. The coarser precipitates inside the grain and discontinuous grain boundary precipitates are favorable to electrical conductivity, which decrease the strength of 5~17% compared to T6 treatment. After T76 treatment (i.e., 110°C/6 h + 160°C/6 h), the UTS, TYS, Elongation and electrical conductivity values were 540 MPa, 510 MPa, 16.7% and 23.5 MS/m, respectively.


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