scholarly journals Solventless synthesis of ZIF-L and ZIF-8 with hydraulic press and high temperature

2021 ◽  
pp. 111487
Author(s):  
Marta Pérez-Miana ◽  
Javier U. Reséndiz-Ordóñez ◽  
Joaquín Coronas
Keyword(s):  
High Temperature ◽  
Hydraulic Press ◽  
Solventless Synthesis

Long Term Degradation Behavior of Impact Properties of Hydraulic Forged Superalloy 718 during Exposure at High Temperature

2007 ◽  
Vol 26-28 ◽  
pp. 1071-1074
Author(s):  
Young Seok Song ◽  
M.R. Lee ◽  
Jeong Tae Kim
Keyword(s):  
High Temperature ◽  
Impact Energy ◽  
Melting Process ◽  
Hydraulic Press ◽  
Degradation Behavior ◽  
Impact Properties ◽  
Hardness Tests ◽  
Temperature Exposure ◽  
The Impact

To check long term degradation behavior of hydraulic forged superalloy 718 during exposure at high temperature, an Alloy 718 ingot with a diameter of 400mm was manufactured by the vacuum melting process, VIM followed by VAR. The ingot was broken down for uniform microstructure and mechanical properties by a controlled cogging process using a hydraulic press. To investigate long term degradation behavior of impact properties and hardness, the specimens were exposed to 600oC, 650oC and 700oC for holding times up to 12,112 hours. Impact energy absorption tests were performed at room temperature. The fractured area and the microstructure of the impact specimens were observed by OEM and SEM and Brinell hardness tests were also performed. The changes of impact energy and hardness are remarkably different for each temperature condition. The results suggest that the impact properties and hardness of Ni based superalloy 718 is strongly related to temperature and time during high temperature exposure.

An Investigation of Direct Powder Forging of Nickel Superalloy FGH96

2016 ◽  
Vol 716 ◽  
pp. 793-799
Author(s):  
Shuang Fang ◽  
Zhusheng Shi ◽  
Qian Bai ◽  
Jia Ying Jiang ◽  
Shu Yun Wang ◽  
...  
Keyword(s):  
High Temperature ◽  
Tensile Properties ◽  
Hot Isostatic Pressing ◽  
Nickel Superalloy ◽  
Hydraulic Press ◽  
Full Density ◽  
Boundary Misorientation ◽  
Nickel Based Superalloy ◽  
Long Time ◽  
Grain Boundary Misorientation

Powder metallurgy (PM) nickel-based superalloy has been widely used in high temperature applications and is most commonly manufactured using hot isostatic pressing (HIP). However, HIP is an expensive process and takes a long time at high temperature which leads to the formation of networks of prior particle boundaries (PPBs). In this study, a recently developed processing method - direct powder forging (DPF) was employed to produce a PM nickel-based superalloy component, using a single acting hydraulic press under normal atmosphere. EBSD study has been conducted for its microstructure, grains size distribution, and grain boundary misorientation; and mechanical testing has been carried out for its hardness and tensile properties at room temperature and 650°C. It has been found that the DPFed material has reached full density in the whole component. Networks of PPBs have been broken in the direct powder forged FGH96 alloy. Compared with HIPed FGH96 alloy, the DPFed material has a substantially higher recystallisation nucleation degree and more recrystallised sub-grains. After heat treatment, the tensile properties of the direct powder forged FGH96 alloy match or surpass those of the material produced by HIP plus isothermal forging.

Methane and hydrogen in mid-ocean-ridge basalt glasses: analysis by vacuum crushing

1988 ◽  
Vol 25 (1) ◽  
pp. 38-48 ◽  
Author(s):  
J. A. Welhan
Keyword(s):  
High Temperature ◽  
Gas Adsorption ◽  
Hydraulic Press ◽  
Hydrothermal Fluids ◽  
Rock Powder ◽  
Ridge Basalt ◽  
Metal Metal ◽  
Mid Ocean Ridge ◽  
Basalt Glasses ◽  
Ocean Ridge

A comparative study of vacuum crushing methods for analyzing reactive gases in basaltic glasses shows that ball milling is an efficient means of releasing occluded gases but that blank production represents a potentially serious problem that must be accounted for when determining reactive-gas compositions. Production of H2 and CH4 in a stainless-steel ball mill in the absence of rock material increases with length of crushing time. However, test results presented here indicate that blank levels are reduced during the actual crushing process by the presence of rock powder, which may act as a cushion to reduce metal–metal contact. Crushing in copper tubes under a hydraulic press produces no blanks for these gases, but crushing efficiency and gas release are very low, and gas adsorption on rock powder becomes a significant problem. Experiments with methane adsorption on crushed basalt suggest that the loss of methane is a chemisorption process that is, for the most part, irreversible.Applying corrections for these effects, we find that H2/CH4 ratios (~3 – 30) in mid-ocean-ridge basalt glasses are similar to those seen in high-temperature mid-ocean-ridge hydrothermal fluids. These data, arguments based on the similarity of water/rock mass ratios calculated from basalt gas data, and the uniformity of methane/helium ratios in divers high-temperature mid-ocean-ridge hydrothermal fluids support the contention that dissolved CH4 and H2 in these fluids are predominantly derived from leaching of mid-ocean-ridge basalt.

Influence of Thermo-Mechanical Processing on the Microstructure of Beryllia Dispersed Nickel Alloys

1973 ◽  
Vol 31 ◽  
pp. 184-185
Author(s):  
M.S. Grewal ◽  
S.A. Sastri ◽  
N.J. Grant
Keyword(s):  
High Temperature ◽  
Nickel Alloys ◽  
Thermomechanical Processing ◽  
Cold Work ◽  
High Temperature Strength ◽  
Strengthening Effect ◽  
Mechanical Processing ◽  
Uniform Dispersion ◽  
Oxide Particles ◽  
Nickel Base

Currently there is a great interest in developing nickel base alloys with fine and uniform dispersion of stable oxide particles, for high temperature applications. It is well known that the high temperature strength and stability of an oxide dispersed alloy can be greatly improved by appropriate thermomechanical processing, but the mechanism of this strengthening effect is not well understood. This investigation was undertaken to study the dislocation substructures formed in beryllia dispersed nickel alloys as a function of cold work both with and without intermediate anneals. Two alloys, one Ni-lv/oBeo and other Ni-4.5Mo-30Co-2v/oBeo were investigated. The influence of the substructures produced by Thermo-Mechanical Processing (TMP) on the high temperature creep properties of these alloys was also evaluated.

Application of TEM to Deformation, Wear, and Fracture of Ceramics

1974 ◽  
Vol 32 ◽  
pp. 472-473
Author(s):  
B. J. Hockey
Keyword(s):  
Wear Resistance ◽  
High Temperature ◽  
Mechanical Behavior ◽  
Brittle Materials ◽  
High Temperature Strength ◽  
Wide Range ◽  
Corrosive Environments ◽  
Further Development

Ceramics, such as Al2O3 and SiC have numerous current and potential uses in applications where high temperature strength, hardness, and wear resistance are required often in corrosive environments. These materials are, however, highly anisotropic and brittle, so that their mechanical behavior is often unpredictable. The further development of these materials will require a better understanding of the basic mechanisms controlling deformation, wear, and fracture.The purpose of this talk is to describe applications of TEM to the study of the deformation, wear, and fracture of Al2O3. Similar studies are currently being conducted on SiC and the techniques involved should be applicable to a wide range of hard, brittle materials.

Lattice Imaging of Grain Boundaries in Ceramics

1977 ◽  
Vol 35 ◽  
pp. 114-115
Author(s):  
D. R. Clarke ◽  
G. Thomas
Keyword(s):  
Mechanical Properties ◽  
High Temperature ◽  
Silicon Nitride ◽  
Grain Boundaries ◽  
High Temperature Strength ◽  
Current Interest ◽  
Lattice Imaging ◽  
Special Significance ◽  
Structural Applications ◽  
Refractory Ceramics

Grain boundaries have long held a special significance to ceramicists. In part, this has been because it has been impossible until now to actually observe the boundaries themselves. Just as important, however, is the fact that the grain boundaries and their environs have a determing influence on both the mechanisms by which powder compaction occurs during fabrication, and on the overall mechanical properties of the material. One area where the grain boundary plays a particularly important role is in the high temperature strength of hot-pressed ceramics. This is a subject of current interest as extensive efforts are being made to develop ceramics, such as silicon nitride alloys, for high temperature structural applications. In this presentation we describe how the techniques of lattice fringe imaging have made it possible to study the grain boundaries in a number of refractory ceramics, and illustrate some of the findings.

Effect of Improved ThO2 Particle Dispersion in Nickel on High-Temperature Strength

1970 ◽  
Vol 28 ◽  
pp. 444-445
Author(s):  
E. R. Kimmel ◽  
H. L. Anthony ◽  
W. Scheithauer
Keyword(s):  
High Temperature ◽  
Metal Matrix ◽  
Oxide Particle ◽  
Oxide Phase ◽  
Dislocation Motion ◽  
Particle Dispersion ◽  
High Temperature Strength ◽  
Strengthening Effect ◽  
Oxide Particles ◽  
The Stability

The strengthening effect at high temperature produced by a dispersed oxide phase in a metal matrix is seemingly dependent on at least two major contributors: oxide particle size and spatial distribution, and stability of the worked microstructure. These two are strongly interrelated. The stability of the microstructure is produced by polygonization of the worked structure forming low angle cell boundaries which become anchored by the dispersed oxide particles. The effect of the particles on strength is therefore twofold, in that they stabilize the worked microstructure and also hinder dislocation motion during loading.

The Ordered Phase Formation in Ti-Al-Ga Alloys

1970 ◽  
Vol 28 ◽  
pp. 440-441
Author(s):  
Shiro Fujishiro ◽  
Harold L. Gegel
Keyword(s):  
Thermal Stability ◽  
High Temperature ◽  
Titanium Alloys ◽  
Growth Kinetics ◽  
Stoichiometric Composition ◽  
Good Potential ◽  
Alpha Titanium ◽  
Cold Rolled ◽  
Kinetics Of ◽  
Thermal Stability Of

Ordered-alpha titanium alloys having a DO19 type structure have good potential for high temperature (600°C) applications, due to the thermal stability of the ordered phase and the inherent resistance to recrystallization of these alloys. Five different Ti-Al-Ga alloys consisting of equal atomic percents of aluminum and gallium solute additions up to the stoichiometric composition, Ti3(Al, Ga), were used to study the growth kinetics of the ordered phase and the nature of its interface.The alloys were homogenized in the beta region in a vacuum of about 5×10-7 torr, furnace cooled; reheated in air to 50°C below the alpha transus for hot working. The alloys were subsequently acid cleaned, annealed in vacuo, and cold rolled to about. 050 inch prior to additional homogenization

Albumins as Embedding Media for Electron Microscopy

1969 ◽  
Vol 27 ◽  
pp. 422-423 ◽  
Author(s):  
J. L. Farrant ◽  
J. D. McLean
Keyword(s):  
Electron Microscopy ◽  
Electron Microscope ◽  
High Temperature ◽  
Biological Material ◽  
Globular Proteins ◽  
The Past ◽  
Antibody Staining ◽  
Thin Sectioning ◽  
Embedding Medium

For electron microscope techniques such as ferritin-labeled antibody staining it would be advantageous to have available a simple means of thin sectioning biological material without subjecting it to lipid solvents, impregnation with plastic monomers and their subsequent polymerization. With this aim in view we have re-examined the use of protein as an embedding medium. Gelatin which has been used in the past is not very satisfactory both because of its fibrous nature and the high temperature necessary to keep its solutions fluid. We have found that globular proteins such as the serum and egg albumins can be cross-linked so as to yield blocks which are suitable for ultrathin sectioning.

An Environmental Wet Cell For High Voltage Electron Microscopy

1973 ◽  
Vol 31 ◽  
pp. 18-19
Author(s):  
N.J. Tighe ◽  
H.M. Flower ◽  
P.R. Swann
Keyword(s):  
Electron Microscopy ◽  
High Temperature ◽  
Image Quality ◽  
Inelastic Scattering ◽  
High Voltage ◽  
High Voltage Electron Microscopy ◽  
Voltage Electron ◽  
Environmental Cell ◽  
Water Saturated ◽  
High Temperature Gas

A differentially pumped environmental cell has been developed for use in the AEI EM7 million volt microscope. In the initial version the column of gas traversed by the beam was 5.5mm. This permited inclusion of a tilting hot stage in the cell for investigating high temperature gas-specimen reactions. In order to examine specimens in the wet state it was found that a pressure of approximately 400 torr of water saturated helium was needed around the specimen to prevent dehydration. Inelastic scattering by the water resulted in a sharp loss of image quality. Therefore a modified cell with an ‘airgap’ of only 1.5mm has been constructed. The shorter electron path through the gas permits examination of specimens at the necessary pressure of moist helium; the specimen can still be tilted about the side entry rod axis by ±7°C to obtain stereopairs.

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