The rheology and microstructure of concentrated non-colloidal suspensions of deformable capsules

2011 ◽  
Vol 685 ◽  
pp. 202-234 ◽  
Author(s):  
Jonathan R. Clausen ◽  
Daniel A. Reasor ◽  
Cyrus K. Aidun
Keyword(s):  
Normal Stress ◽  
Three Dimensional ◽  
Colloidal Suspensions ◽  
Elastic Membrane ◽  
Normal Stresses ◽  
Particle Deformation ◽  
Self Diffusion ◽  
Sign Change ◽  
Stress Changes ◽  
Particle Level

AbstractA detailed study into the rheology and microstructure of dense suspensions of initially spherical capsules is presented, where capsules are composed of a fluid-filled interior surrounded by an elastic membrane. This study couples a lattice-Boltzmann fluid solver to a finite-element membrane model creating a robust and scalable method for the simulation of these suspensions. A Lees–Edwards boundary condition is used to simulate periodic simple shear to obtain bulk rheological properties, and three-dimensional results are presented for capsules in the regime of negligible inertia, Brownian motion and colloidal interparticle forces. The simulation results focus on describing the suspension rheology as a function of the particle concentration and deformability, and relating these macroscopic rheological findings to changes at the particle level, i.e. the suspension microstructure. Several important findings are made: suspensions of deformable capsules are found to be shear thinning, and the initially compressive normal stresses associated with rigid spherical suspensions undergo rapid changes with moderate levels of particle deformation. These normal stress changes are particularly evident in the first normal stress difference, which undergoes a sign change at fairly minor levels of deformation, and the particle pressure, which decreases rapidly with increasing particle deformability. Changes in the microstructure as quantified by the single-body microstructure and the pair distribution function are reported. Also, results calculating particle self-diffusion are presented and related to changes in the normal stresses.

scholarly journals Programmable colloidal molecules from sequential capillarity-assisted particle assembly

2016 ◽  
Vol 2 (4) ◽  
pp. e1501779 ◽  
Author(s):  
Songbo Ni ◽  
Jessica Leemann ◽  
Ivo Buttinoni ◽  
Lucio Isa ◽  
Heiko Wolf
Keyword(s):  
Single Molecule ◽  
Three Dimensional ◽  
Colloidal Suspensions ◽  
Building Blocks ◽  
Level Control ◽  
Particle Assembly ◽  
Bar Codes ◽  
Filling Sequence ◽  
Particle Level ◽  
Multifunctional Molecules

The assembly of artificial nanostructured and microstructured materials which display structures and functionalities that mimic nature’s complexity requires building blocks with specific and directional interactions, analogous to those displayed at the molecular level. Despite remarkable progress in synthesizing “patchy” particles encoding anisotropic interactions, most current methods are restricted to integrating up to two compositional patches on a single “molecule” and to objects with simple shapes. Currently, decoupling functionality and shape to achieve full compositional and geometrical programmability remains an elusive task. We use sequential capillarity-assisted particle assembly which uniquely fulfills the demands described above. This is a new method based on simple, yet essential, adaptations to the well-known capillary assembly of particles over topographical templates. Tuning the depth of the assembly sites (traps) and the surface tension of moving droplets of colloidal suspensions enables controlled stepwise filling of traps to “synthesize” colloidal molecules. After deposition and mechanical linkage, the colloidal molecules can be dispersed in a solvent. The template’s shape solely controls the molecule’s geometry, whereas the filling sequence independently determines its composition. No specific surface chemistry is required, and multifunctional molecules with organic and inorganic moieties can be fabricated. We demonstrate the “synthesis” of a library of structures, ranging from dumbbells and triangles to units resembling bar codes, block copolymers, surfactants, and three-dimensional chiral objects. The full programmability of our approach opens up new directions not only for assembling and studying complex materials with single-particle-level control but also for fabricating new microscale devices for sensing, patterning, and delivery applications.

scholarly journals Rheology of sheared suspensions of rough frictional particles

2014 ◽  
Vol 757 ◽  
pp. 514-549 ◽  
Author(s):  
Stany Gallier ◽  
Elisabeth Lemaire ◽  
François Peters ◽  
Laurent Lobry
Keyword(s):  
Normal Stress ◽  
Three Dimensional ◽  
Normal Stress Difference ◽  
Normal Stresses ◽  
Fictitious Domain Method ◽  
Concentrated Suspensions ◽  
Physical Description ◽  
Normal Stress Differences ◽  
Sheared Suspensions ◽  
Effective Friction

AbstractThis paper presents three-dimensional numerical simulations of non-Brownian concentrated suspensions in a Couette flow at zero Reynolds number using a fictitious domain method. Contacts between particles are modelled using a discrete element method (DEM)-like approach, which allows for a more physical description, including roughness and friction. This work emphasizes the effect of friction between particles and its role on rheological properties, especially on normal stress differences. Friction is shown to notably increase viscosity and second normal stress difference $\def \xmlpi #1{}\def \mathsfbi #1{\boldsymbol {\mathsf {#1}}}\let \le =\leqslant \let \leq =\leqslant \let \ge =\geqslant \let \geq =\geqslant \def \Pr {\mathit {Pr}}\def \Fr {\mathit {Fr}}\def \Rey {\mathit {Re}}|N_2|$ and decrease $|N_1|$, in better agreement with experiments. The hydrodynamic and contact contributions to the overall particle stress are particularly investigated. This shows that the effect of friction is mostly due to the additional contact stress since the hydrodynamic stress remains unaffected by friction. Simulation results are also compared with experiments, such as normal stresses or effective friction coefficient $\mu (I_v)$, and the agreement is improved when friction is accounted for. This suggests that friction is operative in actual suspensions.

scholarly journals Effect of confinement in wall-bounded non-colloidal suspensions

2016 ◽  
Vol 799 ◽  
pp. 100-127 ◽  
Author(s):  
Stany Gallier ◽  
Elisabeth Lemaire ◽  
Laurent Lobry ◽  
Francois Peters
Keyword(s):  
Normal Stress ◽  
Volume Fraction ◽  
Three Dimensional ◽  
Colloidal Suspensions ◽  
Wall Slip ◽  
Hexagonal Structure ◽  
Normal Stress Difference ◽  
Contact Forces ◽  
Wall Region ◽  
Stress Difference

This paper presents three-dimensional numerical simulations of non-colloidal dense suspensions in a wall-bounded shear flow at zero Reynolds number. Simulations rely on a fictitious domain method with a detailed modelling of particle–particle and wall–particle lubrication forces, as well as contact forces including particle roughness and friction. This study emphasizes the effect of walls on the structure, velocity and rheology of a moderately confined suspension (channel gap to particle radius ratio of 20) for a volume fraction range $0.1\leqslant {\it\phi}\leqslant 0.5$. The wall region shows particle layers with a hexagonal structure. The size of this layered zone depends on volume fraction and is only weakly affected by friction. This structure implies a wall slip which is in good accordance with empirical models. Simulations show that this wall slip can be mitigated by reducing particle roughness. For ${\it\phi}\lessapprox 0.4$, wall-induced layering has a moderate impact on the viscosity and second normal stress difference $N_{2}$. Conversely, it significantly alters the first normal stress difference $N_{1}$ and can result in positive $N_{1}$, in better agreement with some experiments. Friction enhances this effect, which is shown to be due to a substantial decrease in the contact normal stress $|{\it\Sigma}_{xx}^{c}|$ (where $x$ is the velocity direction) because of particle layering in the wall region.

scholarly journals The Influence of Initial Normal Stress Assumption of Slip Surface on Safety Factor of Symmetrical Three-Dimensional Slopes

2019 ◽  
Vol 2019 ◽  
pp. 1-8
Author(s):  
Huali Liu
Keyword(s):  
Stress Distribution ◽  
Normal Stress ◽  
Safety Factor ◽  
Slip Surface ◽  
Three Dimensional ◽  
Normal Stresses ◽  
Equilibrium Conditions ◽  
Normal Stress Distribution ◽  
A Value ◽  
Force Equilibrium

By using the explicit solution of three-dimensional slope stability based on modification of normal stress distribution over the slip surface, the influence of assumption of the three-dimensional initial normal stress on the safety factor is investigated. The initial normal stress distribution over the 3D slip surface was assumed, and then it was modified by a function with 2 parameters to satisfy two force equilibrium conditions about two axes and one moment equilibrium condition around one axis. An iterative equation was derived that would yield a value to 3D safety factor. The values of three-dimensional safety factor of symmetrical slopes are computed with different assumptions of initial normal stresses. The computation results show that the influence of assumption of initial normal stress on the safety factor of symmetrical three-dimensional slopes is negligible because the maximum different value of the three-dimensional safety factor is below 5%.

scholarly journals Picosecond time-resolved photon antibunching measures nanoscale exciton motion and the true number of chromophores

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Gordon J. Hedley ◽  
Tim Schröder ◽  
Florian Steiner ◽  
Theresa Eder ◽  
Felix J. Hofmann ◽  
...  
Keyword(s):  
Rational Design ◽  
Three Dimensional ◽  
Dna Origami ◽  
Fluorescent Nanoparticles ◽  
Time Resolved ◽  
Exciton Diffusion ◽  
Polymer Aggregates ◽  
True Number ◽  
Particle Level ◽  
Photon Antibunching

AbstractThe particle-like nature of light becomes evident in the photon statistics of fluorescence from single quantum systems as photon antibunching. In multichromophoric systems, exciton diffusion and subsequent annihilation occurs. These processes also yield photon antibunching but cannot be interpreted reliably. Here we develop picosecond time-resolved antibunching to identify and decode such processes. We use this method to measure the true number of chromophores on well-defined multichromophoric DNA-origami structures, and precisely determine the distance-dependent rates of annihilation between excitons. Further, this allows us to measure exciton diffusion in mesoscopic H- and J-type conjugated-polymer aggregates. We distinguish between one-dimensional intra-chain and three-dimensional inter-chain exciton diffusion at different times after excitation and determine the disorder-dependent diffusion lengths. Our method provides a powerful lens through which excitons can be studied at the single-particle level, enabling the rational design of improved excitonic probes such as ultra-bright fluorescent nanoparticles and materials for optoelectronic devices.

scholarly journals Rock Stress Measurements for Unlined Pressure Tunnels: A True Triaxial Laboratory Experiment to Investigate the Ability of a Simplified Hydraulic Jacking Test to Assess Fracture Normal Stress

2021 ◽  
Author(s):  
Henki Ødegaard ◽  
Bjørn Nilsen
Keyword(s):  
Normal Stress ◽  
Test Method ◽  
Sudden Increase ◽  
Normal Stresses ◽  
True Triaxial ◽  
Step Rate ◽  
Stress Measurements ◽  
Fracture Closure ◽  
Rate Test ◽  
Hydraulic Jacking

AbstractTo avoid hydraulic failure of unlined pressure tunnels, knowledge of minimum principal stress is needed. Such knowledge is only obtainable from in situ measurements, which are often time-consuming and relatively costly, effectively limiting the number of measurements typically performed. In an effort to enable more stress measurements, the authors propose a simplified and cost-effective stress measuring method; the Rapid Step-Rate Test (RSRT), which is based on existing hydraulic testing methods. To investigate the ability of this test to measure fracture normal stresses in field-like conditions, a true triaxial laboratory test rig has been developed. Hydraulic jacking experiments performed on four granite specimens, each containing a fracture, have been performed. Interpretation of pressure-, flow- and acoustic emission (AE) data has been used to interpret fracture behaviour and to assess fracture normal stresses. Our experimental data suggest that the proposed test method, to a satisfactory degree of reliability, can measure the magnitude of fracture normal stress. In addition, a clear correlation has been found between fracture closure and sudden increase in AE rate, suggesting that AE monitoring during testing can serve as a useful addition to the test. The rapid step-rate test is also considered relevant for field-scale measurements, with only minor adaptions. Our findings suggest that the RSRT can represent a way to get closer to the ideal of performing more testing along the entire length of pressure tunnel, and not only at key locations, which requires interpolation of stress data with varying degree of validity.

Stress-strain curve of paper revisited

2012 ◽  
Vol 27 (2) ◽  
pp. 318-328 ◽  
Author(s):  
Svetlana Borodulina ◽  
Artem Kulachenko ◽  
Mikael Nygårds ◽  
Sylvain Galland
Keyword(s):  
Three Dimensional ◽  
Strain Curve ◽  
Failure Behavior ◽  
Three Dimensional Model ◽  
Stress Strain Curve ◽  
Stress Strain ◽  
Fiber Network ◽  
Bonding Parameters ◽  
Particle Level ◽  
The Impact

Abstract We have investigated a relation between micromechanical processes and the stress-strain curve of a dry fiber network during tensile loading. By using a detailed particle-level simulation tool we investigate, among other things, the impact of “non-traditional” bonding parameters, such as compliance of bonding regions, work of separation and the actual number of effective bonds. This is probably the first three-dimensional model which is capable of simulating the fracture process of paper accounting for nonlinearities at the fiber level and bond failures. The failure behavior of the network considered in the study could be changed significantly by relatively small changes in bond strength, as compared to the scatter in bonding data found in the literature. We have identified that compliance of the bonding regions has a significant impact on network strength. By comparing networks with weak and strong bonds, we concluded that large local strains are the precursors of bond failures and not the other way around.

Reduction of Free-Edge Stress Concentration

1985 ◽  
Vol 52 (4) ◽  
pp. 801-805 ◽  
Author(s):  
P. R. Heyliger ◽  
J. N. Reddy
Keyword(s):  
Finite Element ◽  
Stress Concentration ◽  
Finite Element Model ◽  
Three Dimensional ◽  
Element Model ◽  
Free Edge ◽  
Shear Stresses ◽  
Normal Stresses ◽  
Interlaminar Shear ◽  
Three Dimensional Elasticity

A quasi-three dimensional elasticity formulation and associated finite element model for the stress analysis of symmetric laminates with free-edge cap reinforcement are described. Numerical results are presented to show the effect of the reinforcement on the reduction of free-edge stresses. It is observed that the interlaminar normal stresses are reduced considerably more than the interlaminar shear stresses due to the free-edge reinforcement.

Shear strength and dilative characteristics of an unsaturated compacted completely decomposed granite soil

2010 ◽  
Vol 47 (10) ◽  
pp. 1112-1126 ◽  
Author(s):  
Md. Akhtar Hossain ◽  
Jian-Hua Yin
Keyword(s):  
Shear Strength ◽  
Normal Stress ◽  
Matric Suction ◽  
Water Retention Curve ◽  
Direct Shear ◽  
Normal Stresses ◽  
Soil Water Retention Curve ◽  
Strength Data ◽  
Decomposed Granite ◽  
Completely Decomposed Granite

Shear strength and dilative characteristics of a re-compacted completely decomposed granite (CDG) soil are studied by performing a series of single-stage consolidated drained direct shear tests under different matric suctions and net normal stresses. The axis-translation technique is applied to control the pore-water and pore-air pressures. A soil-water retention curve (SWRC) is obtained for the CDG soil from the equilibrium water content corresponding to each applied matric suction value for zero net normal stress using a modified direct shear apparatus. Shear strength increases with matric suction and net normal stress, and the failure envelope is observed to be linear. The apparent angle of internal friction and cohesion intercept increase with matric suction. A greater dilation angle is found at higher suctions with lower net normal stresses, while lower or zero dilation angles are observed under higher net normal stresses with lower suctions, also at a saturated condition. Experimental shear strength data are compared with the analytical shear strength results obtained from a previously modified model considering the SWRC, effective shear strength parameters, and analytical dilation angles. The experimental shear strength data are slightly higher than the analytical results under higher net normal stresses in a higher suction range.

Self‐diffusion in colloidal suspensions. Intermediate times

1993 ◽  
Vol 98 (9) ◽  
pp. 7521-7526 ◽  
Author(s):  
M. D. Carbajal‐Tinoco ◽  
J. L. Arauz‐Lara
Keyword(s):  
Colloidal Suspensions ◽  
Self Diffusion
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