The Effect of Adjuvants and Oil Carriers on Photodecomposition of 2,4-D, Bentazon, and Haloxyfop

Weed Science ◽  
1986 ◽  
Vol 34 (1) ◽  
pp. 81-87 ◽  
Author(s):  
S. Kent Harrison ◽  
Loyd M. Wax
Keyword(s):  
Soybean Oil ◽  
Ultraviolet Light ◽  
Mineral Oil ◽  
Propanoic Acid ◽  
Sorbitan Monolaurate ◽  
Photolysis Rates ◽  
Dilute Aqueous Solution ◽  
Dichlorophenoxy Acetic Acid ◽  
Petroleum Oil ◽  
White Mineral

Laboratory photolysis rates of 2,4-D [(2,4-dichlorophenoxy)acetic acid], bentazon [3-(1-methylethyl)-(1H)-2,1,3-benzothiadiazin-4(3H)-one 2,2-dioxide], and haloxyfop {2-[4-[[3-chloro-5-(trifluoromethyl)-2-pyridinyl] oxy] phenoxy] propanoic acid} in dilute aqueous solution were enhanced by the presence of adjuvants. Addition of 1.0% (v/v) petroleum oil concentrate (POC), 1.0% (v/v) soybean oil concentrate (SBOC), and 0.15% (v/v) emulsifier package (EP) enhanced herbicide photolysis rates more than addition of 0.15% (v/v) oxysorbic (20 POE) (polyoxyethylene sorbitan monolaurate). Bioassays showed that phytotoxicity of photolyzed herbicide solutions was negatively correlated with time of exposure to ultraviolet light. Addition of 0.85% (v/v) acetophenone to aqueous herbicide solutions containing 0.15% (v/v) oxysorbic strongly sensitized photodegradation of 2,4-D, and to a lesser extent, haloxyfop. Acetophenone had no effect on bentazon photolysis in the presence of oxysorbic. In another study, herbicides were dissolved in white mineral oil or once-refined soybean oil and exposed to ultraviolet light. After a 6-h exposure, there was 92% loss of haloxyfop in mineral oil and 36% loss in soybean oil. There was no difference between oils in affecting the photolysis rate of 2,4-D or bentazon.

SOYBEAN OIL PLASTICIZERS AS REPLACEMENT OF PETROLEUM OIL IN RUBBER

2013 ◽  
Vol 86 (2) ◽  
pp. 233-249 ◽  
Author(s):  
Zoran S. Petrović ◽  
Mihail Ionescu ◽  
Jelena Milić ◽  
James R. Halladay
Keyword(s):  
Soybean Oil ◽  
Vegetable Oils ◽  
Cationic Polymerization ◽  
Dynamic Properties ◽  
Mineral Oil ◽  
Cross Linking ◽  
Double Bonds ◽  
Soybean Oils ◽  
Molecular Weights ◽  
Petroleum Oil

ABSTRACT Polymerized soybean oils of different molecular weights were used as plasticizers in NR/SBR compositions. The oils of different molecular weights and viscosities were synthesized by cationic polymerization using a proprietary technology. Because vegetable oils have double bonds, they are not only viscosity depressants but also active participants in cross-linking reactions. Properties of elastomers extended with different concentrations of mineral oil or pure soybean oil were compared with elastomers extended by polymerized oils of different molecular weights at the same concentrations. It was found that polymerized soybean oil could be substituted for naphthenic process oil with minimal differences in mechanical and dynamic properties.

Adjuvant Effects on Absorption, Translocation, and Metabolism of Haloxyfop-Methyl in Corn (Zea mays)

Weed Science ◽  
1986 ◽  
Vol 34 (2) ◽  
pp. 185-195 ◽  
Author(s):  
S. Kent Harrison ◽  
Loyd M. Wax
Keyword(s):  
Zea Mays ◽  
Methyl Ester ◽  
Propanoic Acid ◽  
Sorbitan Monolaurate ◽  
Foliar Absorption ◽  
Polar Metabolite ◽  
Average Percentage ◽  
Adjuvant Effects ◽  
Layer Chromatography ◽  
Petroleum Oil

The effects of adjuvants and relative humidity (RH) on absorption, translocation, and metabolism of the methyl ester of14C-haloxyfop {2-[4-[[3-chloro-5-(trifluoromethyl)-2-pyridinyl]oxy]phenoxy] propanoic acid} in corn (Zea maysL. ‘B73 X Mo17’ hybrid) were evaluated. Addition of 1.0% (v/v) petroleum oil concentrate (POC) to the treatment solution resulted in greater foliar absorption and translocation of14C than addition of 1.0% (v/v) soybean oil concentrate (SBOC), 0.1% (v/v) oxysorbic (20 POE) (polyoxyethylene sorbitan monolaurate) (OXY), or no adjuvant (NONE). The least amount of14C absorption occurred in the treatment containing OXY. Absorption and translocation of radioactivity were significantly greater at 70% RH than at 30% RH. Thin-layer chromatography revealed that most of the14C recovered from treated plants was in haloxyfop-methyl 5 h after treatment (HAT). The remaining14C recovered was haloxyfop and an unidentified polar metabolite. The average percentage of14C-haloxyfop in the nonabsorbed fraction was 5, 39, 7, and 7% for treatments containing NONE, OXY, POC, and SBOC, respectively. The ratio of haloxyfop-methyl to haloxyfop and the percentage of polar metabolite in the absorbed14C fraction was not different among adjuvant treatments or between levels of RH.

Absorption and Translocation of Fluazifop with Additives

Weed Science ◽  
1986 ◽  
Vol 34 (4) ◽  
pp. 572-576 ◽  
Author(s):  
John D. Nalewaja ◽  
Grzegorz A. Skrzypczak
Keyword(s):  
Glycine Max ◽  
Soybean Oil ◽  
Avena Sativa ◽  
Linum Usitatissimum ◽  
Butyl Ester ◽  
Carthamus Tinctorius ◽  
Propanoic Acid ◽  
Seed Oils ◽  
Oil Additives ◽  
Petroleum Oil

The influence of various additives on the absorption and translocation of fluazifop {(±)-2-[4-[[5-(trifluoromethyl)-2-pyridinyl]oxy]phenoxy]propanoic acid} butyl ester in oats (Avena sativaL. var. ‘Lyon’) was determined. Fluazifop absorption and translocation by oats 48 h after application were less when applied with safflower (Carthamus tinctoriusL.), sunflower (Helianthus annuusL.), soybean [Glycine max(L.) Merr.], linseed (Linum usitatissimumL.), and palm (Eleais quineeneisJacq.) oil than with petroleum oil. However, fluazifop absorption and translocation continued to increase for the 96-h duration of the experiment when applied with soybean oil but only for 24 h when applied with petroleum oil. The14C-fluazifop-label recovery was higher when applied with oils than when applied alone, which may have been due to reduced fluazifop volatility when it was emulsified with the oils. Absorption and translocation of fluazifop applied with glycerol or various emulsifiers were equal to or less than fluazifop absorption and translocation when applied with petroleum oils but were greater than fluazifop absorption and translocation when applied with seed oils 48 h after application. Fluazifop absorption and translocation were similar whether soybean or petroleum oil additives were applied with or without emulsifiers. Totally refined seed oils only slightly increased fluazifop absorption and translocation compared to fluazifop with once-refined or degummed seed oils.

Soybean Oil Used as an Alternative Pesticide on Nursery Stock

HortScience ◽  
1998 ◽  
Vol 33 (3) ◽  
pp. 485d-485
Author(s):  
A.L. Lancaster ◽  
D.E. Deyton ◽  
C.E. Sams ◽  
C.D. Pless ◽  
D.C. Fare ◽  
...  
Keyword(s):  
Soybean Oil ◽  
Blue Color ◽  
Water Control ◽  
White Pine ◽  
Blue Star ◽  
Red Cedar ◽  
Japanese Garden ◽  
Nursery Stock ◽  
Fine Spray ◽  
Petroleum Oil

Research was conducted to determine if soybean oil sprays may substitute for petroleum oil for control of insects on nursery crops. Dormant field-grown `Globe' arborvitae shrubs infested with Fletcher scale were sprayed on 9 Mar. 1997 with 0%, 2%, 3%, or 4% soybean oil. One hundred scales per plant were evaluated on 4 Apr. 1997. Spraying 2% to 4% soybean oil on dormant arborvitae caused ≥97% mortality of Fletcher scale compared to only 7% mortality on untreated plants. of white pine, viburnum, `Anthony Waterer' spirea, `Green Beauty' boxwood, western red cedar, `Blue Star' juniper, `Blue Pacific' juniper, `Japanese Garden' juniper, and arborvitae plants in trade gallon pots and `Densiformus' yew and dwarf `Alberta' spruce in trade quart pots were sprayed with 0% (water control), 1%, or 2% soybean oil (emulsified with Latron B-1956) or 2% SunSpray Ultra-Fine Spray oil on 26 Aug. 1997 for phytotoxicity evaluation. No phytotoxicity occurred on western cedar, spirea, boxwood, yew, arborvitae, or viburnum. Spraying Sunspray or soybean oil caused initial loss of blue color on blue junipers and white pine. Spraying 1 or 2% soybean oil or 2% SunSpray caused phytotoxicity to `Blue Star' juniper. The `Blue Pacific' juniper, `Japanese Garden' juniper, and Alberta spruce were slightly damaged by 2% but not by 1% soybean oil.

Highly epoxidized soybean oil in replacement of mineral oil for high performance on silica-filled tread rubber compounds

2021 ◽  
pp. 009524432110290
Author(s):  
Leandro Hernán Esposito ◽  
Angel José Marzocca
Keyword(s):  
Soybean Oil ◽  
High Performance ◽  
Rolling Resistance ◽  
Wear Test ◽  
Mineral Oil ◽  
Epoxidized Soybean Oil ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Rubber Compound ◽  
The Impact

The potential replacement of a treated residual aromatic extract mineral oil (TRAE) by a highly epoxidized soybean oil (ESO) into a silica-filled styrene-butadiene rubber compound was investigated. In order to determine if ESO compounds performance are suitable for tread tire applications, processing properties cure and characteristics were evaluated. The impact of ESO amount on the silica dispersion was confirmed by Payne Effect. The presence of chemical or physical interactions between ESO and silica improves the filler dispersion, enabling the compound processability and affecting the cure kinetic rate. An adjusted rubber compound with 2 phr of ESO and 2 phr of sulfur presented the higher stiffness and strength values with lower weight loss from a wear test compared with TRAE compound at an equal amount of oil and curing package. Furthermore, wet grip and rolling resistance predictors of both compounds gave comparable results, maintaining a better performance and reducing the dependence of mineral oil for tire tread compounds.

scholarly journals Rheological and Emulsification Behavior of Xinjiang Heavy Oil and Model Oils

2016 ◽  
Vol 9 (1) ◽  
pp. 1-10 ◽  
Author(s):  
Jiaqiang Jing ◽  
Jiatong Tan ◽  
Haili Hu ◽  
Jie Sun ◽  
Peiyu Jing
Keyword(s):  
Pressure Gradient ◽  
Crude Oil ◽  
Mineral Oil ◽  
Crude Oils ◽  
Water Separation ◽  
Oil Emulsion ◽  
Silicon Oil ◽  
Oil Water ◽  
Model Oil ◽  
White Mineral

Transparent model oils are commonly used to study the flow patterns and pressure gradient of crude oil-water flow in gathering pipes. However, there are many differences between the model oil and crude oils. The existing literatures focus on the flow pattern transition and pressure gradient calculation of model oils. This paper compares two most commonly used model oils (white mineral oil and silicon oil) with Xinjiang crude oil from the perspectives of rheological properties, oil-water interfacial tensions, emulsion photomicrographs and demulsification process. It indicates that both the white mineral oil and the crude oils are pseudo plastic fluids, while silicon oil is Newtonian fluid. The viscosity-temperature relationship of white mineral oil is similar to that of the diluted crude oil, while the silicon oil presents a less viscosity gradient with the increasing temperature. The oil-water interfacial tension can be used to evaluate the oil dispersing ability in the water phase, but not to evaluate the emulsion stability. According to the Turbiscan lab and the stability test, the model oil emulsion is less stable than that of crude oil, and easier to present water separation.

scholarly journals Comparative safety and efficacy of two bivalent vaccines containing Newcastle disease LaSota and avian influenza H9N2 Sidrap isolate formulated with different oil adjuvants

2020 ◽  
Vol 13 (11) ◽  
pp. 2493-2501
Author(s):  
Jossie Intan Cahyani ◽  
Sitarina Widyarini ◽  
Michael Haryadi Wibowo
Keyword(s):  
Immune Response ◽  
Avian Influenza ◽  
Newcastle Disease ◽  
Hemagglutination Inhibition ◽  
Mineral Oil ◽  
Economic Losses ◽  
Poultry Industry ◽  
Bivalent Vaccine ◽  
Hemagglutination Inhibition Test ◽  
White Mineral

Background and Aim: Newcastle disease (ND) and avian influenza (AI) are two devastating diseases of poultry, which cause great economic losses to the poultry industry and disrupt food security in our country. The use of ND-AI inactive bivalent vaccine is very effective and economical to prevent and control ND and AI disease. Bivalent ND LaSota-AI H9N2 vaccine is not yet available in Indonesia. The inactivated vaccines used in poultry industry often require oil adjuvant to elicit a sufficient immune response. This study aimed to develop the bivalent inactive vaccines containing ND LaSota and AI H9N2 Sidrap isolate which are local isolates as poultry vaccine candidates, and formulated with two different commercial adjuvants, then compared. Materials and Methods: Two vaccines bivalent were prepared by emulsifying inactivated Newcastle disease virus (LaSota strain) and AI H9N2 Sidrap isolate viruses with Marcol white mineral oil and Montanide ISA70 adjuvants. Both of bivalent vaccines were tested for safety (physical and histopathological at the injection site) and efficacy in specific-pathogen-free chickens. Parameters used for the evaluation of the efficacy were immunogenicity by hemagglutination inhibition and protection percentage. Results: Both bivalent vaccines are safe to use. Post-vaccination (PV) immune response was observed using a hemagglutination inhibition test at 2, 3, 4, 5, 6, 7, and 8 weeks of PV. The bivalent vaccine B gives a better immune response to ND at 2, 3, and 4 weeks of PV (p<0.05) compared to the bivalent vaccine A, but in 5, 6, 7, and 8 weeks, the PV does not show differences in the immune response. The immune response to AI H9N2 showed differences at weeks 2 and 3 PV (p<0.05) with the bivalent vaccine B indicated higher immunity. A single immunization with both bivalent vaccines induces 100% protection in chickens that have been vaccinated against the deadly challenge with the virulent ND virus. Conclusion: Both of bivalent vaccines are safe to use and provide good efficacy against virulent ND viruses, but bivalent vaccine B (with Montanide ISA70 adjuvant) shows better immune response than bivalent vaccine A (Marcol white mineral oil adjuvant).

scholarly journals Licorice (Glycyrrhiza glabra (Linnaeus, 1753)) roots aqueous extract and some additives against Bactrocera zonata (Saunders, 1841) (Diptera: Tephritidae)

2021 ◽  
Vol 90 (2 - Ahead of print) ◽  
pp. 70-85
Author(s):  
Mervat Abdel-Moneauim Mostafa El-Genaidy ◽  
Mohamed Abd El-Aziz Mohamed Hindy ◽  
Nehad Abdel-Hameed Soliman
Keyword(s):  
Aqueous Extract ◽  
Sandy Soil ◽  
Clay Soil ◽  
Mineral Oil ◽  
Glycyrrhiza Glabra ◽  
Clay Soils ◽  
Insecticidal Effect ◽  
Bactrocera Zonata ◽  
Light Mineral ◽  
Petroleum Oil

Peach fruit fly, Bactrocera zonata (Saunders, 1841) is a destructive polyphagous pest threatening the horticultural production in Egypt. Licorice, Glycyrrhiza glabra (Linnaeus, 1753) is a plant growing in Egypt and many other countries and famous for saponins groups that have insecticidal effect against broad spectrum of insect pests. In the present study, the insecticidal effect of licorice roots aqueous extract (LRAE), petroleum oil, KZ light mineral oil 96% (EC), water and an emulsion (1/4 L LRAE + ¼ L petroleum oil + ½ L KZ light oil 96% (EC)) treatments in a ratio 1 L: 29 L water were used in Matabi® sprayer of 30 L capacity against B. zonata pupae in sandy and clay soils. In sandy and clay soils LRAE reduced B. zonata population by 74.44% and 87.55% while petroleum oil, KZ light mineral oil 96% (EC) prevented flies emergence (100% reduction). Water treatment suppressed B. zonata population by 78.61% in sandy soil but caused 100% population reduction in clay soil. The emulsion reduced B. zonata population by 96.94% in sandy soil and 100% in clay soil. The best method for application of the emulsion was to spray as one target spray technique for eight seconds that was sufficient to obtain suitable coverage on soil with spray speed 1.2 km / hour. The persistence of the emulsion that highly reduced B. zonata larval populations was 3.5 and 4.5 days in sandy and clay soils, respectively. The flies emerged from B. zonata pupae treated with the emulsion neither feed nor move naturally. The histological studies showed that these flies suffered changes in the eyes, labellum, muscles and midgut tissues that were different from the emerged control treatment flies.

Integrated analysis of remote sensing and numerical oil drift simulations for improved oil spill preparedness capabilities

2021 ◽  
Author(s):  
Camilla Brekke ◽  
Martine Espeseth ◽  
Knut-Frode Dagestad ◽  
Johannes Röhrs ◽  
Lars Hole ◽  
...  
Keyword(s):  
Remote Sensing ◽  
Soybean Oil ◽  
Oil Spill ◽  
Mineral Oil ◽  
The Arctic ◽  
Optical Data ◽  
Integrated Analysis ◽  
Geophysical Research ◽  
Oil Emulsion ◽  
Detection Capabilities

&lt;p&gt;&lt;strong&gt;Integrated analysis of remote sensing and numerical oil drift simulations for &lt;/strong&gt;&lt;strong&gt;improved&amp;#160;&lt;/strong&gt;&lt;strong&gt;oil spill preparedness capabilities&lt;/strong&gt;&lt;/p&gt;&lt;p&gt;Camilla Brekke&lt;sup&gt;1&lt;/sup&gt;, Martine M. Espeseth&lt;sup&gt;1&lt;/sup&gt;, Knut-Frode Dagestad&lt;sup&gt;2&lt;/sup&gt;, Johannes R&amp;#246;hrs&lt;sup&gt;2&lt;/sup&gt;, Lars Robert Hole&lt;sup&gt;2&lt;/sup&gt;, and Andreas Reigber&lt;sup&gt;3&lt;/sup&gt;&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;&lt;p&gt;&lt;sup&gt;1&lt;/sup&gt;UiT The Arctic University of Norway, Troms&amp;#248;, Norway&lt;/p&gt;&lt;p&gt;&lt;sup&gt;2&lt;/sup&gt;The Norwegian Meteorological Institute, Oslo, Norway&lt;/p&gt;&lt;p&gt;&lt;sup&gt;3&lt;/sup&gt;DLR, Microwaves and Radar Institute, Oberpfaffenhofen-We&amp;#223;ling, Germany&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;&lt;p&gt;We present results from a successfully conducted free-floating oil spill field experiment followed by an integrated analysis of remotely sensed data and drift simulations. The experiment took place in the North Sea in the summer of 2019 during Norwegian Clean Seas Association for Operating Companies&amp;#8217; annual oil-on-water exercise. Two types of oils were applied: a mineral oil emulsion and a soybean oil emulsion. The dataset collected contains a collection of close-in-time radar (aircraft and space-borne) and optical data (aircraft, aerostat, and drone) acquisitions of the slicks. We compare oil drift simulations, applying various configurations of wind, wave, and current information, with observed slick positions and shape. We describe trajectories and dynamics of the spills, slick extent, and their evolution, and the differences in detection capabilities in optical instruments versus multifrequency quad-polarimetric synthetic aperture radar (SAR) imagery acquired by DLRs large-scale airborne SAR facility (F-SAR). When using the best available forcing from in situ data and forecast models, good agreement with the observed position and extent are found in this study. The appearance in the optical images and the SAR time series from F-SAR were found to be different between the soybean and mineral oil types. Differences in mineral oil detection capabilities are found between SAR and optical imagery of thinner sheen regions. From a drifting perspective, the biological oil emulsions could replace the viscous similar mineral oil emulsion in future oil spill preparedness campaigns. However, from a remote sensing and wildlife perspective, the two oils have different properties. Depending on the practical application, further investigation on how the soybean oil impact the seabirds must be conducted in order to recommend the soybean oil as a viable substitute for mineral oil.&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;&lt;p&gt;This study is published as open access in Journalof Geophysical Research: Oceans[1], and we encourage the audience to read this article for detailed acquaintance with the work.&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;&lt;p&gt;Reference:&lt;/p&gt;&lt;p&gt;[1]Brekke, C., Espeseth, M. M., Dagestad, K.-F., R&amp;#246;hrs, J., Hole, L. R., &amp; Reigber,A. (2021). Integrated analysis of multisensor datasets and oil driftsimulations&amp;#8212;a free-floating oil experiment in the open ocean. Journalof Geophysical Research: Oceans, 126, e2020JC016499. https://doi.org/10.1029/2020JC016499&lt;/p&gt;

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