Chemical and Adsorptive Characterization of Adsorbents To Capture Greenhouse Gases Under Atmospheric Conditions of Temperature and Pressure

Author(s):  
B. Delgado ◽  
R. Lagace ◽  
S. Godbout ◽  
J. L. Valverde ◽  
A. Giroir-Fendler ◽  
...  
Author(s):  
S Bair

A thorough characterization of all viscous flow properties relevant to steady simple shear was carried out for five liquid lubricants of current interest to tribology. Shear stresses were generated to values significant to concentrated contact lubrication. Two types of non-Newtonian response were observed: shear-thinning as a power-law fluid and near rate-independence. Functions and parameters were obtained for the temperature and pressure dependence of the viscosity and of the time constant for the Carreau-Yasuda equation. Results are consistent with free volume and kinetic theory, but directly contradict many assumptions currently utilized for numerical simulation and for extracting rheological properties from contact measurements.


2021 ◽  
Vol 27 (1) ◽  
pp. 3-27
Author(s):  
Jeremy T. Lancaster ◽  
Brian J. Swanson ◽  
Stefani G. Lukashov ◽  
Nina S. Oakley ◽  
Jacob B. Lee ◽  
...  

ABSTRACT The post–Thomas Fire debris flows of 9 January 2018 killed 23 people, damaged 558 structures, and caused severe damage to infrastructure in Montecito and Carpinteria, CA. U.S. Highway 101 was closed for 13 days, significantly impacting transportation and commerce in the region. A narrow cold frontal rain band generated extreme rainfall rates within the western burn area, triggering runoff-driven debris flows that inundated 5.6 km2 of coastal land in eastern Santa Barbara County. Collectively, this series of debris flows is comparable in magnitude to the largest documented post-fire debris flows in the state and cost over a billion dollars in debris removal and damages to homes and infrastructure. This study summarizes observations and analyses on the extent and magnitude of inundation areas, debris-flow velocity and volume, and sources of debris-flow material on the south flank of the Santa Ynez Mountains. Additionally, we describe the atmospheric conditions that generated intense rainfall and use precipitation data to compare debris-flow source areas with spatially associated peak 15 minute rainfall amounts. We then couple the physical characterization of the event with a compilation of debris-flow damages to summarize economic impacts.


2003 ◽  
Author(s):  
Gopal D. Tejwani

Rocket engine exhaust plume is generally thermal in character arising from changes in the internal energy of constituent molecules. Radiation from the plume is attenuated in its passage through the atmosphere. In the visible and the infrared region of the spectrum for clear-sky conditions, this is caused mainly through absorption by atmospheric molecular species. The most important combustion-product molecules giving rise to emission in the IR are water vapor, carbon dioxide, and carbon monoxide. In addition, the high temperature plume reacting with the surrounding atmosphere may produce nitrogen oxides, in the boundary layer, all of which are strongly emitting molecules. Important absorbing species in the atmosphere in the engine plume environment are H2O, CO, CO2, CH4, N2O, NO, and NO2. Under normal atmospheric conditions, the concentrations of O3, SO2, and NH3 are too small to produce any significant absorption. Essentially the problem comprises of the propagation of radiation from a hot gas source through a long cool absorbing atmosphere thus combining aspects of atmospheric and combustion gas methods. Since many of the same molecular species are responsible for both emission and absorption, the high degree of line position correlation between the emission and absorption spectra precludes the decoupling of the optical path into isolated emitter and absorber regions and multiplying the source band radiance by the absorber band transmittance in order to arrive at the transmitted radiance spectrum. Also, very strong thermal gradients may be encountered. All this suggests that a layer-by-layer computation is called for. The pathlength through the plume and the atmosphere is assumed to go through a certain number of layers, each of which is considered to have all molecular species in local thermodynamic equilibrium at constant temperature and pressure within the layer. Radiative transfer problems can be visualized as a set of parallel layers orthogonal to the line of sight, each with an input radiance from the previous layer and an output radiance to the subsequent layer. The MODTRAN (MODerate resolution TRANsmission) code is ideally suited for layer-by-layer absorption/emission calculations for atmospheric molecular species. We have utilized MODTRAN 4.0 computer code, implemented on a Power Mac G3, for the radiance and transmittance computations. The MODTRAN code has been adapted for the engine plume radiance computations. If the plume composition and flowfield parameters such as the temperature and pressure values are known along the line of sight by means of the experimental measurements or (more likely) CFD simulations, one can compute the radiance from any plume with high degree of accuracy at any desired point in space. Emission and absorption characteristics of several atmospheric and combustion species have been studied and presented in this paper with reference to the rocket engine plume environments at the Stennis Space Center. In general transmittance losses can not be neglected for any pathlength of 2 m or more. We have also studied the effect of clouds, rain, and fog on the plume radiance/transmittance. The transmittance losses are severe if any of these occur along the line of sight. Preliminary results for the radiance from the exhaust plume of the space shuttle main engine are shown and discussed.


Author(s):  
Kathryn Elmer ◽  
Raymond Soffer ◽  
J. Pablo Arroyo-Mora ◽  
Margaret Kalacska

Over the past 30 years, the use of field spectroscopy has risen in importance in remote sensing studies for the characterization of the surface reflectance of materials in situ within a broad range of applications. Potential uses range from measurements of individual targets of interest (e.g. vegetation, soils, validation targets etc.), to characterizing the contributions of different materials within larger spatially-mixed areas as would be representative of the spatial resolution captured by a sensor pixel (UAV to satellite scale). As such, it is essential that a complete and rigorous assessment of both the data-acquisition procedures, and the suitability of the derived data product be carried out. The measured energy from solar-reflected range spectroradiometers is influenced by the viewing and illumination geometries and the illumination conditions which vary due to changes in solar position and atmospheric conditions. By applying corrections, the estimated absolute reflectance (Rabs) of targets can be calculated. This property is independent of illumination intensity or conditions and is the metric commonly suggested to be used to compare spectra even when data are collected by different sensors or acquired under different conditions. By standardizing the process of estimated Rabs, as is provided in the described toolkit, consistency and repeatability in processing are ensured and the otherwise labor intensive and error-prone processing steps are streamlined. The resultant end data product (Rabs) represents our best current effort to generate consistent and comparable ground spectra which have been corrected for viewing and illumination geometries as well as other factors such as the individual characteristics of the reference panel used during acquisition.


2016 ◽  
Vol 18 (4) ◽  
pp. 721-727 ◽  

<p>Odour emissions from liquid waste treatment plants (LWTPs) generally cause significant effects on the environment in terms of nuisance to exposed population. The particular and complex nature of the mixture of the volatile substances, its variability in time and the strong influence of the atmospheric conditions, are the elements that delayed their regulation and relative management.</p> <p>Limited data are available in the technical and scientific literature, regarding the odour emissions characterization from liquid waste treatment plants. Moreover there isn’t a common strategy from the different European Countries in the regulation of their emissions.</p> <p>Different methods can be used to measure odour emissions from environmental engineering plants, and currently, in Europe, the most used techniques for odour emissions characterization and quantification is the dynamic olfactometry, according to EN 13725:2003.</p> <p>The aim of this study is the characterization of the odour emissions from different liquid waste treatment plants (LWTPs), trough a case study of two large real LWTPs, in order to identify the principal odour sources and to define their related odour emissions.</p> <p>Odour Concentration Index (OCI) is proposed as a useful and simply odour management tool for the identification of the priority actions necessary to identify and control the main odorous sources. Relationship between the measured odour emissions and the types of treated liquid waste (identified in terms of EWC code, COD and NH4<sup>+</sup>) is also discussed.</p> <p>Results show that the influent collection tank is the source with the highest detected odour emissions. OCI results are useful for the definition of a clear priority action for odour control, similar for both investigated plants. Between the characterized types of liquid waste treated by LWTPs the leachate (EWC 190703) show the maximum odour emissions.</p>


2015 ◽  
Vol 17 (21) ◽  
pp. 14054-14063 ◽  
Author(s):  
A.-A. Ludl ◽  
L. E. Bove ◽  
A. M. Saitta ◽  
M. Salanne ◽  
T. C. Hansen ◽  
...  

We analyze the structural evolution of quenched aqueous NaCl solutions under pressure up to 4 GPa.


2007 ◽  
Vol 544-545 ◽  
pp. 865-868 ◽  
Author(s):  
Chil Soon Lee ◽  
Dong Sik Bae

CoFe2O4 nanoparticles were prepared in ethylene glycol solution under mild temperature and pressure conditions by precipitation from metal nitrates. The average size of the synthesized CoFe2O4 nanoparticles was in the range of 5 to 10, and they were narrowly distributed in the crystalline phase. Their magnetic property was of superparamagnetic character at room temperature. The effect of synthesis parameters is discussed such as the pH of starting solutions and reaction temperature.


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