scholarly journals Organic magnetoelectric and optomagnetic couplings: perspectives for organic spin optoelectronics

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Zhongxuan Wang ◽  
Wei Qin

AbstractOver the past years, the development of organic ferromagnetic materials has been investigated worldwide for potential applications. Due to the couplings among the charge, orbit, spin, and phonon in organic ferromagnetic materials, magnetoelectric, and optomagnetic couplings have been realized and observed. In this review, progress in organic magnetoelectric and optomagnetic couplings is presented, and the mechanisms behind the phenomena are also briefly summarized. Hopefully, the understanding of magnetoelectric and optomagnetic couplings could provide guidance for the further development of organic spin optoelectronics.

Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1248 ◽  
Author(s):  
Lingna Sun ◽  
Jie Guan ◽  
Qin Xu ◽  
Xiaoyu Yang ◽  
Juan Wang ◽  
...  

Titanium dioxide (TiO2) nanomaterials have caused a widespread concern in the past several decades for their bulk characteristics and potential applications in many different areas. Lately, the combination between molecularly imprinted polymers (MIPs) and TiO2 nanomaterials have been proven to improve the relative adsorption capacity, selectivity and accelerate the rate of mass transfer of analyte which is not possible using TiO2 alone. Considering the unique performance of the MIPs modified TiO2 nanomaterials, this review intends to give an overview of the recent progresses in the development of MIPs modified TiO2 nanomaterials, the potential applications of their tailor-made characteristics. The limitations and challenges in this practically promising nanomaterials have also been raised and summarized. By means of the points raised in this article, we would like to provide some assistance for further development of preparation methodologies and the expansion of some potential applications in the field of MIPs modified TiO2 nanomaterials.


GeroPsych ◽  
2011 ◽  
Vol 24 (3) ◽  
pp. 143-154 ◽  
Author(s):  
Elmar Gräßel ◽  
Raffaela Adabbo

The burden of caregivers has been intensively researched for the past 30 years and has resulted in a multitude of individual findings. This review illustrates the significance of the hypothetical construct of perceived burden for the further development and design of the homecare situation. Following explanations regarding the term informal caregiver, we derive the construct burden from its conceptual association with the transactional stress model of Lazarus and Folkman. Once the extent and characteristics of burden have been set forth, we then present the impact of perceived burden as the care situation. The question of predictors of burden will lead into the last section from which implications can be derived for homecare and relief of caregivers.


2011 ◽  
pp. 90-101 ◽  
Author(s):  
N. Shumsky

The article assesses the effectiveness and outcomes of cooperation of the Commonwealth participating states over the past 20 years. It reviews perspectives and directions for further development of the CIS taking into account the conditions and characteristics of integration processes of the post-Soviet states, implementation of the principles of multilevel and multispeed integration of the Commonwealth participating states.


2020 ◽  
Vol 26 (29) ◽  
pp. 3508-3521 ◽  
Author(s):  
Xiaochen Jia ◽  
Mijanur R. Rajib ◽  
Heng Yin

Background: Application of chitin attracts much attention in the past decades as the second abundant polysaccharides in the world after cellulose. Chitin oligosaccharides (CTOS) and its deacetylated derivative chitosan oligosaccharides (COS) were shown great potentiality in agriculture by enhancing plant resistance to abiotic or biotic stresses, promoting plant growth and yield, improving fruits quality and storage, etc. Those applications have already served huge economic and social benefits for many years. However, the recognition mode and functional mechanism of CTOS and COS on plants have gradually revealed just in recent years. Objective: Recognition pattern and functional mechanism of CTOS and COS in plant together with application status of COS in agricultural production will be well described in this review. By which we wish to promote further development and application of CTOS and COS–related products in the field.


Molecules ◽  
2021 ◽  
Vol 26 (10) ◽  
pp. 2852
Author(s):  
Paul A. Foster

Steroid sulphatase (STS), involved in the hydrolysis of steroid sulphates, plays an important role in the formation of both active oestrogens and androgens. Since these steroids significantly impact the proliferation of both oestrogen- and androgen-dependent cancers, many research groups over the past 30 years have designed and developed STS inhibitors. One of the main contributors to this field has been Prof. Barry Potter, previously at the University of Bath and now at the University of Oxford. Upon Prof. Potter’s imminent retirement, this review takes a look back at the work on STS inhibitors and their contribution to our understanding of sulphate biology and as potential therapeutic agents in hormone-dependent disease. A number of potent STS inhibitors have now been developed, one of which, Irosustat (STX64, 667Coumate, BN83495), remains the only one to have completed phase I/II clinical trials against numerous indications (breast, prostate, endometrial). These studies have provided new insights into the origins of androgens and oestrogens in women and men. In addition to the therapeutic role of STS inhibition in breast and prostate cancer, there is now good evidence to suggest they may also provide benefits in patients with colorectal and ovarian cancer, and in treating endometriosis. To explore the potential of STS inhibitors further, a number of second- and third-generation inhibitors have been developed, together with single molecules that possess aromatase–STS inhibitory properties. The further development of potent STS inhibitors will allow their potential therapeutic value to be explored in a variety of hormone-dependent cancers and possibly other non-oncological conditions.


2021 ◽  
Vol 22 (9) ◽  
pp. 4803
Author(s):  
Eduardo Gomez ◽  
Ichiro Hisaki ◽  
Abderrazzak Douhal

Hydrogen-bonded organic frameworks (HOFs) are the focus of intense scientific research due their potential applications in science and technology. Here, we report on the synthesis, characterization, and photobehavior of a new HOF (T12F-1(124TCB)) based on a dehydrobenzoannulene derivative containing fluorine atoms (T12F-COOH). This HOF exhibits a 2D porous sheet, which is hexagonally networked via H-bonds between the carboxylic groups, and has an interlayers distance (4.3 Å) that is longer than that of a typical π–π interaction. The presence of the fluorine atoms in the DBA molecular units largely increases the emission quantum yield in DMF (0.33, T12F-COOH) when compared to the parent compound (0.02, T12-COOH). The time-resolved dynamics of T12F-COOH in DMF is governed by the emission from a locally excited state (S1, ~ 0.4 ns), a charge-transfer state (S1(CT), ~ 2 ns), and a room temperature emissive triplet state (T1, ~ 20 ns), in addition to a non-emissive triplet structure with a charge-transfer character (T1(CT), τ = 0.75 µs). We also report on the results using T12F-ester. Interestingly, FLIM experiments on single crystals unravel that the emission lifetimes of the crystalline HOF are almost twice those of the amorphous ones or the solid T12F-ester sample. This shows the relevance of the H-bonds in the photodynamics of the HOF and provides a strong basis for further development and study of HOFs based on DBAs for potential applications in photonics.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Zhihao Fang ◽  
Yiqiu Hu ◽  
Jinhui Hu ◽  
Yanqin Huang ◽  
Shu Zheng ◽  
...  

AbstractAs the predominant modification in RNA, N6-methyladenosine (m6A) has attracted increasing attention in the past few years since it plays vital roles in many biological processes. This chemical modification is dynamic, reversible and regulated by several methyltransferases, demethylases and proteins that recognize m6A modification. M6A modification exists in messenger RNA and affects their splicing, nuclear export, stability, decay, and translation, thereby modulating gene expression. Besides, the existence of m6A in noncoding RNAs (ncRNAs) could also directly or indirectly regulated gene expression. Colorectal cancer (CRC) is a common cancer around the world and of high mortality. Increasing evidence have shown that the changes of m6A level and the dysregulation of m6A regulatory proteins have been implicated in CRC carcinogenesis and progression. However, the underlying regulation laws of m6A modification to CRC remain elusive and better understanding of these mechanisms will benefit the diagnosis and therapy. In the present review, the latest studies about the dysregulation of m6A and its regulators in CRC have been summarized. We will focus on the crucial roles of m6A modification in the carcinogenesis and development of CRC. Moreover, we will also discuss the potential applications of m6A modification in CRC diagnosis and therapeutics.


2021 ◽  
Author(s):  
Juqing Liu ◽  
Zhengdong Liu ◽  
Yuhang Yin ◽  
Mustafa Eginligil ◽  
Laiyuan Wang ◽  
...  

Two-dimensional conjugated microporous polymers (2D CMPs) are the sheet/film-like CMPs with amorphous, permanent porous and π-conjugated structures, which have attracted considerable attention over the past few years. Owing to the...


Author(s):  
O. Morhuniuk

An article is devoted to the analysis of the functions and formats of political parties in consociational democracies. In particular, it is defined that parties that represent the interests of certain subcultures in society and that reach a consensus among themselves at the level of political agreements are called segmental. At the same time, parties that encapsulate different subgroups of the society that cooperate inside the party within main features of the consociational theory (grand coalition, mutual veto, proportionality in representations, and independence of segments or society subcultures) are called consociational. The theory of consociationalism has received a wide range of theoretical additions and criticism from political scientists over the past fifty years. And while political parties should have been, by definition, one of the key aspects of research within such democratic regimes (parties are part of large coalitions and agents of representation of certain subcultures), there is very scarce number of literature that focuses on this aspect. Therefore, the presented article provides a description of the functions of political parties that could be observed as inside their subcultures as well as in interaction with other segmental parties. Based on the experience of two European countries in the period of “classical” consociationalism (Belgium and the Netherlands), we explain the functions of the parties we have defined in such societies with examples of relevant consociational practices in them. Simultaneously with the analysis of segmental parties, the article also offers the characteristics of consociational parties. The emergence of such parties has its own institutional and historical features. The way of further development of the party system and the level of preservation of consociational practices makes it possible to understand the nature of changes in the societies. Similarly, the analysis of the forms of party competition and interaction between segmental parties makes it possible to outline the forms of those consociational changes that are taking place in the research countries.


Author(s):  
Антон Андреевич Ракитский ◽  
Борис Яковлевич Рябко

В работе исследуется процесс разработки компьютеров за последние десятилетия с целью определения наиболее влияющих на него факторов. Описываются сами факторы, которые используются для предсказания направления будущих разработок. Для решения этой задачи применяется концепция Вычислительной Способности, которая позволяет оценить производительность компьютеров теоретически, опираясь исключительно на описание их архитектуры. In this article we are investigating the computers development process in the past decades in order to identify the factors that influence it the most. We describe such factors and use them to predict the direction of further development. To solve these problems, we use the concept of the Computer Capacity, which allows us to estimate the performance of computers theoretically, relying only on the description of its architecture.


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