scholarly journals Study on the Electrical Conductivity of Inorganic Conductive Network in Sediments

2021 ◽  
Vol 2065 (1) ◽  
pp. 012012
Author(s):  
R Y Zhao ◽  
Z W Zhao ◽  
Z J Weng ◽  
Y Fang ◽  
H L Jiang

Abstract The inorganic conductive network provides an essential channel for electron transport and supports the biogeochemical process in sediments, but the conductive mechanism of conductive network is not well understood. In this work, theory of circuit and electronics was applied to build a three-dimensional (3D) resistivity network simulation model for exploring the conductive mechanism and analysing the effect of the particle size on the conductive characteristic of inorganic conductive network. In order to simulate the real sediment environment, inorganic composites with silica (SiO2) particles as matrix using magnetite (Fe3O4) particles as fillers are constructed. The simulation results reveal that the electrical conductivity of these composites rises nonlinearly with the increasing volume fraction of conductive fillers, which is consistent with the percolation theory. Moreover, small-sized conductive particles or large-sized matrix particles are confirmed to exert a positive part in enhancing electrical conductivity of composites.

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 404 ◽  
Author(s):  
Yasser Zare ◽  
Kyong Yop Rhee

The interphase layer surrounding nanoparticles can reflect the tunneling effect as the main mechanism of charge transferring in polymer/carbon nanotube (CNT) nanocomposites (PCNT). In this paper, the percolation threshold, effective volume fraction of CNT, and the portion of percolated filler after percolation are expressed by interphase and CNT waviness. Moreover, the developed terms are used to suggest the influences of CNT dimensions, interphase thickness, and waviness on the electrical conductivity of PCNT by conventional and developed models. Thin and long CNT, thick interphase, and low waviness obtain a high fraction of percolated CNT. However, the highest level of effective filler fraction is only calculated by the thinnest CNT and the thickest interphase. Furthermore, both models show that the thinnest and the longest CNT as well as the thickest interphase and the least CNT waviness cause the highest conductivity in PCNT, because they positively contribute to the formation and properties of the conductive network.


Nanomaterials ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 1228 ◽  
Author(s):  
Chereches ◽  
Minea

In this research, the electrical conductivity of simple and hybrid nanofluids containing Al2O3, TiO2 and SiO2 nanoparticles and water as the base fluid was experimentally studied at ambient temperature and with temperature variation in the range of 20–60 °C. A comparison of the experimental data with existing theoretical models demonstrated that the theoretical models under-predict the experimental data. Consequently, several correlations were developed for nanofluid electrical conductivity estimation in relation to temperature and volume concentration. The electrical conductivity of both simple and hybrid nanofluids increased linearly with both volume concentration and temperature upsurge. More precisely, by adding nanoparticles to water, the electrical conductivity increased from 11 times up to 58 times for both simple and hybrid nanofluids, with the maximum values being attained for the 3% volume concentration. Plus, a three-dimensional regression analysis was performed to correlate the electrical conductivity with temperature and volume fraction of the titania and silica nanofluids. The thermo-electrical conductivity ratio has been calculated based on electrical conductivity experimental results and previously determined thermal conductivity. Very low figures were noticed. Concluding, one may affirm that further experimental work is needed to completely elucidate the behavior of nanofluids in terms of electrical conductivity.


2021 ◽  
Vol 896 ◽  
pp. 39-44
Author(s):  
Yuan Zheng Luo ◽  
You Qi Wan ◽  
Wei Hong

In this paper, we developed a three-dimensional percolation model to investigate the effects of the concentration and morphology of CNTs (carbon nanotubes) on the electrical conductivity of the nanocomposites. In the model, we judged the connections between CNTs by range search algorithm based on KD-Tree structure. At the same time, DIJKSTRA-Melissa algorithm was applied to efficiently find all the conductive paths instead of finding conductive network in traditional methods. From the simulation results, CNTs with higher aspect ratio were easier to form the conductive network. In a certain range of CNT’s concentration, the relationship between the conductivity of the conductive network and the carbon nanotubes was basically consistent with the classical percolation theory. To verify our simulation model, the morphological, electrical properties of Carbon nanotubes (CNTs)/poly(dimethyl siloxane) (PDMS) nanocomposites with different aspect ratio (AR) of MWNTs were systematically studied. In conclusion, these unique advantageous properties could be exploited to suggest potential applications of artificial electronic skin.


Author(s):  
B. Ralph ◽  
A.R. Jones

In all fields of microscopy there is an increasing interest in the quantification of microstructure. This interest may stem from a desire to establish quality control parameters or may have a more fundamental requirement involving the derivation of parameters which partially or completely define the three dimensional nature of the microstructure. This latter categorey of study may arise from an interest in the evolution of microstructure or from a desire to generate detailed property/microstructure relationships. In the more fundamental studies some convolution of two-dimensional data into the third dimension (stereological analysis) will be necessary.In some cases the two-dimensional data may be acquired relatively easily without recourse to automatic data collection and further, it may prove possible to perform the data reduction and analysis relatively easily. In such cases the only recourse to machines may well be in establishing the statistical confidence of the resultant data. Such relatively straightforward studies tend to result from acquiring data on the whole assemblage of features making up the microstructure. In this field data mode, when parameters such as phase volume fraction, mean size etc. are sought, the main case for resorting to automation is in order to perform repetitive analyses since each analysis is relatively easily performed.


2021 ◽  
pp. 152808372110013
Author(s):  
Vivek R Jayan ◽  
Lekhani Tripathi ◽  
Promoda Kumar Behera ◽  
Michal Petru ◽  
BK Behera

The internal geometry of composite material is one of the most important factors that influence its performance and service life. A new approach is proposed for the prediction of internal geometry and tensile behavior of the 3 D (three dimensional) woven fabrics by creating the unit cell using mathematical coding. In many technical applications, textile materials are subjected to rates of loading or straining that may be much greater in magnitude than the regular household applications of these materials. The main aim of this study is to provide a generalized method for all the structures. By mathematical coding, unit cells of 3 D woven orthogonal, warp interlock and angle interlock structures have been created. The study then focuses on developing code to analyze the geometrical parameters of the fabric like fabric thickness, areal density, and fiber volume fraction. Then, the tensile behavior of the coded 3 D structures is studied in Ansys platform and the results are compared with experimental values for authentication of geometrical parameters as well as for tensile behavior. The results show that the mathematical coding approach is a more efficient modeling technique with an acceptable error percentage.


2019 ◽  
Vol 71 (1) ◽  
Author(s):  
Tohru Watanabe ◽  
Miho Makimura ◽  
Yohei Kaiwa ◽  
Guillaume Desbois ◽  
Kenta Yoshida ◽  
...  

AbstractElastic wave velocity and electrical conductivity in a brine-saturated granitic rock were measured under confining pressures of up to 150 MPa and microstructure of pores was examined with SEM on ion-milled surfaces to understand the pores that govern electrical conduction at high pressures. The closure of cracks under pressure causes the increase in velocity and decrease in conductivity. Conductivity decreases steeply below 10 MPa and then gradually at higher pressures. Though cracks are mostly closed at the confining pressure of 150 MPa, brine must be still interconnected to show observed conductivity. SEM observation shows that some cracks have remarkable variation in aperture. The aperture varies from ~ 100 nm to ~ 3 μm along a crack. FIB–SEM observation suggests that wide aperture parts are interconnected in a crack. Both wide and narrow aperture parts work parallel as conduction paths at low pressures. At high pressures, narrow aperture parts are closed but wide aperture parts are still open to maintain conduction paths. The closure of narrow aperture parts leads to a steep decrease in conductivity, since narrow aperture parts dominate cracks. There should be cracks in various sizes in the crust: from grain boundaries to large faults. A crack must have a variation in aperture, and wide aperture parts must govern the conduction paths at depths. A simple tube model was employed to estimate the fluid volume fraction. The fluid volume fraction of 10−4–10−3 is estimated for the conductivity of 10−2 S/m. Conduction paths composed of wide aperture parts are consistent with observed moderate fluctuations (< 10%) in seismic velocity in the crust.


2019 ◽  
Vol 6 (3) ◽  
pp. 233-242 ◽  
Author(s):  
Sohail Nadeem ◽  
Muhammad Naveed Khan ◽  
Noor Muhammad ◽  
Shafiq Ahmad

Abstract The present investigation concentrates on three dimensional unsteady forced bio-convection flow of a viscous fluid. An incompressible flow of a micropolar nanofluid encloses micro-organisms past an exponentially stretching sheet with magnetic field is analyzed. By employing convenient transformation the partial differential equations are converted into the ordinary differential equations which are non-linear. By using shooting method to solved these equations numerically. The influence of the determining parameters on the velocity, temperature, micro-rotation, nanoparticle volume fraction, microorganism are incorporated. The skin friction, heat transfer rate, and the microorganism rate are analyzed. The results depicts that the value of the wall shear stress and Nusselt number are declined while an enhancement take place in the microorganism number. The slip parameters increases the velocity, thermal energy, and microorganism number consequentially. The present investigation are important in improving achievement of microbial fuel cells.


2008 ◽  
Vol 47-50 ◽  
pp. 714-717 ◽  
Author(s):  
Xin Lan ◽  
Jin Song Leng ◽  
Yan Ju Liu ◽  
Shan Yi Du

A new system of thermoset styrene-based shape-memory polymer (SMP) filled with carbon black (CB) is investigated. To realize the electroactive stimuli of SMP, the electrical conductivity of SMP filled with various amounts of CB is characterized. The percolation threshold of electrically conductive SMP filled with CB is about 3% (volume fraction of CB), which is much lower than many other electrically conductive polymers. When applying a voltage of 30V, the shape recovery process of SMP/CB(10 vol%) can be realized in about 100s. In addition, the thermomechanical properties are also characterized by differential scanning calorimetery (DSC).


2012 ◽  
Vol 182-183 ◽  
pp. 254-258
Author(s):  
Zhong Li Zhao ◽  
Zun Li Mo ◽  
Zhong Yu Chen

Cellulose/Ag/polyaniline conductive composite with rather excellent electrical conductivity was heterogeneously synthesized in this paper. The UV-Vis analysis indicated that homogeneous nanoAg particles deposited on the surface of cellulose in the form of globe particles. They offered some electrons to polyaniline chains. This behavior resulted to the facts that more polyaniline embedded on cellulose and an integrated electrically conductive network formed. Consequently, the high electrical conductivity of the composite was observed. The value was 3.48 S/cm, which was higher two magnitudes than the electrical conductivity of cellulose/polyaniline composite (2.15×10-2S/cm), and even was higher than the electrical conductivity of pure polyaniline (0.142 S/cm). This paper provided a facile method for the preparation of cellulose/Ag/ polyaniline composite with favorable electrical conductivity.


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