Adsorption of Cesium Radionuclides by the Composite Sorbents Carbon Fiber/Transition Metals Ferrocyanides

2011 ◽  
Author(s):  
Irina V. Sheveleva ◽  
Veniamin V. Zheleznov ◽  
Svetlana Yu. Bratskaya ◽  
Valery G. Kuryavyi ◽  
Valentin A. Avramenko
Keyword(s):  
Composite Materials ◽  
Carbon Fiber ◽  
Transition Metals ◽  
Crystal Size ◽  
Porous Matrix ◽  
Cesium Ions ◽  
Preparation Conditions ◽  
Composite Sorbents ◽  
Cesium Radionuclides ◽  
Carboxylic Groups

Among various methods of cesium removal from aqueous solutions, sorption using transition metals ferrocyanides is the most efficient method due to extremely high affinity of cesium ions to ferrocyanides. The efficiency of transition metals ferrocyanides application is known to depend on the crystal size being the highest for nanocrystals. Although nanocrystals are difficult to handle in direct application, they can be used in composite materials. In this case two main problems arise: how to control the crystal size of transition metals ferrocyanides and fix them reliably in the supporting matrix. Here we suggest a new route to preparation of composite materials selective to cesium ions using transition metals ferrocyanides stabilized by siloxane-acrylate latexes. The size of transition metals ferrocyanides is controlled by the size of latex particles and their stability is determined by ionization of polyacrylic acid carboxylic groups on the functionalized latex surface. These functionalized particles can be used as precursors in preparation of composite materials by sedimentation and polymerization of latexes on the solid surface of porous matrix, e.g. carbon fibers. Several routes of preparation of carbon fiber based composite materials using functionalized latexes and sorption properties of the obtained materials are discussed. The effect of preparation conditions (method used, carbon fiber polarization potential, concentration of latexes functionalized with transition metals ferrocyanides) on cesium uptake by composite sorbents from solutions of various salinity is reported.

scholarly journals Survey Summary on Salts Hydrates and Composites Used in Thermochemical Sorption Heat Storage: A Review

Energies ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3105
Author(s):  
Mohamed Zbair ◽  
Simona Bennici
Keyword(s):  
Composite Materials ◽  
Energy Density ◽  
Low Temperature ◽  
Mass Transport ◽  
Lower Energy ◽  
Heat Storage ◽  
Porous Matrix ◽  
Salt Hydrates ◽  
Sorption Heat ◽  
The Stability

To improve the proficiency of energy systems in addition to increasing the usage of renewable energies, thermal energy storage (TES) is a strategic path. The present literature review reports an overview of the recent advancements in the utilization of salt hydrates (single or binary mixtures) and composites as sorbents for sorption heat storage. Starting by introducing various heat storage systems, the operating concept of the adsorption TES was clarified and contrasted to other technologies. Consequently, a deep examination and crucial problems related to the different types of salt hydrates and adsorbents were performed. Recent advances in the composite materials used in sorption heat storage were also reviewed and compared. A deep discussion related to safety, price, availability, and hydrothermal stability issues is reported. Salt hydrates display high theoretical energy densities, which are promising materials in TES. However, they show a number of drawbacks for use in the basic state including low temperature overhydration and deliquescence (e.g., MgCl2), high temperature degradation, sluggish kinetics leading to a low temperature rise (e.g., MgSO4), corrosiveness and toxicity (e.g., Na2S), and low mass transport due to the material macrostructure. The biggest advantage of adsorption materials is that they are more hydrothermally stable. However, since adsorption is the most common sorption phenomenon, such materials have a lower energy content. Furthermore, when compared to salt hydrates, they have higher prices per mass, which reduces their appeal even further when combined with lower energy densities. Economies of scale and the optimization of manufacturing processes may help cut costs. Among the zeolites, Zeolite 13X is among the most promising. Temperature lifts of 35–45 °C were reached in lab-scale reactors and micro-scale experiments under the device operating settings. Although the key disadvantage is an excessively high desorption temperature, which is problematic to attain using heat sources, for instance, solar thermal collectors. To increase the energy densities and enhance the stability of adsorbents, composite materials have been examined to ameliorate the stability and to achieve suitable energy densities. Based on the reviewed materials, MgSO4 has been identified as the most promising salt; it presents a higher energy density compared to other salts and can be impregnated in a porous matrix to prepare composites in order to overcome the drawbacks connected to its use as pure salt. However, due to pore volume reduction, potential deliquescence and salt leakage from the composite as well as degradation, issues with heat and mass transport can still exist. In addition, to increase the kinetics, stability, and energy density, the use of binary salt deposited in a porous matrix is suitable. Nevertheless, this solution should take into account the deliquescence, safety, and cost of the selected salts. Therefore, binary systems can be the solution to design innovative materials with predetermined sorption properties adapted to particular sorption heat storage cycles. Finally, working condition, desorption temperature, material costs, lifetime, and reparation, among others, are the essential point for commercial competitiveness. High material costs and desorption temperatures, combined with lower energy densities under normal device operating conditions, decrease their market attractiveness. As a result, the introduction of performance metrics within the scientific community and the use of economic features on a material scale are suggested.

scholarly journals High Mechanic Enhancement of Chopped Carbon Fiber Reinforced-Low-Density Unsaturated Polyester Resin Composite at Low Preparation Temperature with Facile Polymerization

Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4273
Author(s):  
Jian Zhang ◽  
Xiaojun Wang ◽  
Xinjun Fu
Keyword(s):  
Composite Materials ◽  
Carbon Fiber ◽  
Low Temperature ◽  
Surface Defect ◽  
Polyester Resin ◽  
Unsaturated Polyester ◽  
Unsaturated Polyester Resin ◽  
Low Density ◽  
Fiber Reinforced ◽  
Preparation Temperature

Chopped carbon fiber-reinforced low-density unsaturated polyester resin (CCFR-LDUPR) composite materials with light weight and high mechanical properties were prepared at low temperature and under the synergistic action of methyl ethyl ketone peroxide (MEKP-II) and cobalt naphthenate. Optimal preparation conditions were obtained through an orthogonal experiment, which were preparation temperature at 58.0 °C, 2.00 parts per hundred of resin (phr) of NH4HCO3, 4.00 phr of chopped carbon fibers (CCFs) in a length of 6.0 mm, 1.25 phr of initiator and 0.08 phr of cobalt naphthenate. CCFR-LDUPR composite sample presented its optimal properties for which the density (ρ) was 0.58 ± 0.02 g·cm−3 and the specific compressive strength (Ps) was 53.56 ± 0.83 MPa·g−1·cm3, which is 38.9% higher than that of chopped glass fiber-reinforced low-density unsaturated polyester resin (CGFR-LDUPR) composite materials. Synergistic effects of initiator and accelerator accelerated the specific polymerization of resin in facile preparation at low temperature. Unique “dimples”, “plate microstructure” and “surface defect” fabricated the specific microstructure of the matrix of CCFR-LDUPR composite samples, which was different from that of cured unsaturated polyester resin (UPR) with “body defect” or that of CGFR-LDUPR with coexistence of “surface defect” and “body defect”.

A DEVICE AND TOOL FOR MAKING SAMPLE FROM POLYMER COMPOSITE MATERIALS ON A CNC MACHINE (review)

2021 ◽  
pp. 100-109
Author(s):  
M.I. Minibaev ◽  
◽  
M.N. Usacheva ◽  
V.S. Dyshenko ◽  
V.A. Goncharov ◽  
...  
Keyword(s):  
Wear Resistance ◽  
Composite Materials ◽  
Carbon Fiber ◽  
Sheet Metal ◽  
Polymer Composite ◽  
Carbon Fiber Reinforced Plastic ◽  
Cnc Machine ◽  
Fiber Reinforced Plastic ◽  
Advantages And Disadvantages ◽  
Reinforced Plastic

The article discusses devices for fixing sheet metal blanks from PCM: a perforated vacuum table, its design features, advantages and disadvantages. Based on these data, the upper part of the vacuum table was made for cutting samples for Iosipescu tests and dielectric tests. The article describes various types of tools for PCM processing and an experiment on the wear resistance of a diamond-like coated rasp cutter when milling carbon fiber reinforced plastic, carried out by foreign researchers.

scholarly journals Optimizing of system "column-cfrp lamellas" with the strengthening of civil structures

2021 ◽  
Vol 9 (1) ◽  
pp. 1-5
Author(s):  
Irina Mayackaya ◽  
Batyr Yazyev ◽  
Anastasia Fedchenko ◽  
Denis Demchenko
Keyword(s):  
Reinforced Concrete ◽  
Composite Materials ◽  
Carbon Fiber ◽  
Concrete Structures ◽  
Polymeric Composite ◽  
Concrete Columns ◽  
Reinforced Concrete Structures ◽  
Structural Elements ◽  
Civil Structures ◽  
Concrete Elements

Reinforced concrete elements of structures in the form of columns, beams, ceilings are widely used in the construction of buildings and structures of industrial and civil construction. In most cases, the columns serve as supports for other building elements, for example, crossbars, slabs, girders, beams. One of the cycles of the work of reinforced concrete structures is the state of their repair and reconstruction, including the stages of strengthening the elements. There is a problem of strengthening of reinforced concrete columns. The article deals with the issue of reinforcing columns and other structural elements having a cylindrical surface, with polymeric composite materials in the form of carbon fiber lamellae. The use of composite materials allows to increase the service life and strength of reinforced concrete structures used in construction.

scholarly journals TFP Technology As Theadvanced Method Of Manufacture Of 3D Reinforced Preforms Frompolymer Composite Materials

2021 ◽  
Vol 12 (5) ◽  
pp. 84-91
Author(s):  
Nelyub Vladimir Aleksandrovich Et al.
Keyword(s):  
Composite Materials ◽  
Carbon Fiber ◽  
3D Printing ◽  
Large Scale ◽  
Research Trends ◽  
Carbon Fiber Reinforced Plastics ◽  
Reinforced Plastics ◽  
Fiber Reinforced Plastics ◽  
Prospective Research ◽  
Further Development

This paper contains an overview of world trends in the development of the TFP technologyenabling 3D printing of carbon fiber reinforced plastics. The review of the equipment used for the automated preformpatching is included. Primary factors restraining the large-scale implementation of the TFP technology in the manufacture are identified, and prospective research trends for further development of the technology are proposed.

scholarly journals REDUCING THE INFLUENCE OF ENVIRONMENTAL FACTORS ON THE BENDING DEFORMATION OF CURED CARBON FIBER BY MICROWAVE PROCESSING

2021 ◽  
pp. 56-58
Author(s):  
I. V. Zlobina
Keyword(s):  
Electromagnetic Field ◽  
Composite Materials ◽  
Carbon Fiber ◽  
Environmental Factors ◽  
Flux Density ◽  
Environmental Conditions ◽  
Climatic Factors ◽  
Transverse Load ◽  
Bending Deformation ◽  
Energy Flux Density

The article discusses the results of a study of bending deformation and creep under transverse load of cured polymer composite materials (PCM), which were located for 8 months in full-scale environmental conditions in Saratov. It was found that being under the influence of natural climatic factors for the specified time leads to an increase in the bending deformation of samples from 13,5 to 25,4%, depending on the load. Processing in a microwave electromagnetic field with a frequency of 2450 MHz with an energy flux density of (17-18) x10 mW / cm for 2 minutes reduces bending deformation by (9-18)%, and creep - up to 4 times.

CORRELATION DEPENDENCES OF THE BENDING STRENGTH OF POLYMER COMPOSITE MATERIALS MODIFIED IN A MICROWAVE ELECTROMAGNETIC FIELD ON THE MOISTURE CONTENT DURING EXPOSURE IN FULL-SCALE CONDITIONS

2021 ◽  
pp. 3-9
Author(s):  
I. V. Zlobina ◽  
I. S. Katsuba
Keyword(s):  
Electromagnetic Field ◽  
Composite Materials ◽  
Carbon Fiber ◽  
Moisture Content ◽  
Bending Strength ◽  
Climatic Factors ◽  
Experimental Studies ◽  
Three Point Bending ◽  
Treated Carbon ◽  
Control Samples

Experimental studies of the influence of external climatic factors, taking into account exposure, on the change in the bending strength of control and microwave – treated carbon and fiberglass samples in the cured state were performed. An increase in the limit stresses of three – point bending of experimental carbon fiber samples compared to the control ones was found by 7…12 %, and fiberglassby 4…7 %. It is shown that with an increase in exposure to 14 months, the strength of control samples of carbon and fiberglass decreases by an average of 10 %. At the same time, the strength of the prototypes is reduced only by 4.4 %. With an increase in the moisture content of both control and experimental samples, a decrease in their strength is observed. In this case, the linear correlation is average (from– 0.44 to – 0.615). It is established that for experimental samples, the influence of the amount of absorbed moisture on the strength is manifested to a much lesser extent. For carbon fiber, the reduction is 16.6 %, for fiberglass – 12 %.

Sign in / Sign up

Export Citation Format

Share Document