Tribochemical Interactions of Moly Dimer and ZDDP Additives With CrN Coating and Bearing Steel While Sliding Against Cast Iron in Boundary Lubrication Conditions

2007 ◽  
Author(s):  
Anne Neville ◽  
Tabassamul Haque ◽  
Ardian Morina
Keyword(s):  
Boundary Lubrication ◽  
Photoelectron Spectroscopy ◽  
Bearing Steel ◽  
Antagonistic Effect ◽  
Low Friction ◽  
Crn Coating ◽  
Atomic Force ◽  
Lubrication Condition ◽  
Increasing Demand ◽  
Lubrication Conditions

In recent years, use of low friction non-ferrous coatings under boundary lubrication condition has become a challenge to meet the increasing demand of fuel economy in automotive applications. In this study, chromium nitride (CrN) was chosen as a non-ferrous coating and experiments were performed in a pin-on-plate reciprocating tribotester to produce the tribofilm. An atomic force microscope (AFM) was used to record high resolution topographical images while chemical analysis of the tribofilm was performed using X-ray photoelectron spectroscopy (XPS). Both AFM and XPS analyses give evidence of the formation of ZDDP and Moly Dimer derived tribofilm. This paper will also focus on the synergistic or antagonistic effect of ZDDP with Moly Dimer additive in the tribological performance of CrN coating.

Tribochemical Interactions of Friction Modifier and Antiwear Additives With CrN Coating Under Boundary Lubrication Conditions

2008 ◽  
Vol 130 (4) ◽  
Author(s):  
T. Haque ◽  
A. Morina ◽  
A. Neville ◽  
S. Arrowsmith
Keyword(s):  
Boundary Lubrication ◽  
Photoelectron Spectroscopy ◽  
Antiwear Additives ◽  
Low Friction ◽  
Friction Modifier ◽  
Crn Coating ◽  
Atomic Force ◽  
Surface Analysis Techniques ◽  
Positive Effect ◽  
Lubrication Conditions

In recent years, the optimized use of low friction nonferrous coatings under boundary lubrication conditions has become a challenge to meet the demands of improved fuel economy in automotive applications. This study presents the tribological performance of chromium nitride (CrN) coating using conventional friction modifier (moly dimer) and/or antiwear additive (zinc dialkyl dithiophosphate (ZDDP)) containing lubricants in a pin-on-plate tribometer. Using surface analysis techniques such as the atomic force microscope (AFM) and X-ray photoelectron spectroscopy (XPS), both topographical and chemical analyses of tribofilms were performed. This paper shows that ZDDP and moly dimer both give a positive effect for both low friction and antiwear performance in CrN/cast iron system. Both AFM and XPS analyses give evidence of the formation of ZDDP and moly dimer derived tribofilms on the CrN coating and thus support friction and wear results.

TRIBOLOGICAL CHARACTERISTICS OF RADIAL JOURNAL BEARINGS BY ULTRASONIC NANOCRYSTAL SURFACE MODIFICATION TECHNOLOGY

2010 ◽  
Vol 24 (15n16) ◽  
pp. 3011-3016 ◽  
Author(s):  
YOUNG SHIK PYOUN ◽  
JEONG HYUN PARK ◽  
CHANG MIN SUH ◽  
INHO CHO ◽  
CHANG-SOON LEE ◽  
...  
Keyword(s):  
Surface Modification ◽  
Boundary Lubrication ◽  
Transition Period ◽  
Hydrodynamic Lubrication ◽  
Peak Torque ◽  
Bearing Steel ◽  
Journal Bearings ◽  
Mixed Lubrication ◽  
Stribeck Curve ◽  
Lubrication Condition

Ultrasonic nanocrystal surface modification (UNSM) has applied to a radial journal bearings made of bearing steel SUJ2. Mechanical characteristics are compared between UNSM treated and untreated bearings. Friction torque is measured at the boundary lubrication condition, the mixed lubrication condition, and the full hydrodynamic lubrication condition. The peak torque at the boundary lubrication condition and the transition period to mixed lubrication condition on the UNSM treated samples are reduced. These effects are very useful to improve the service life of journal bearings. The Stribeck curve at the mixed and full hydrodynamic lubrication is derived and compared. The friction coefficient at these two regimes is reduced by more than 50%, which will do effective role for improvement of energy efficiency. The major effects for this reduction at three lubrication regimes could be explained in the terms of micro dimple surface.

Towards Superlubricity Under Boundary Lubrication

2005 ◽  
Author(s):  
J. M. Martin ◽  
M. I. De Barros Bouchet ◽  
T. Le Mogne ◽  
M. Kano
Keyword(s):  
Boundary Lubrication ◽  
Automotive Industry ◽  
Research Field ◽  
Low Friction ◽  
Carbon Coatings ◽  
Dlc Coatings ◽  
New Research ◽  
Engine Components ◽  
Potential Use ◽  
Lubrication Conditions

Fuel economy and reduction of harmless elements in lubricant are becoming crucial in the automotive industry. An approach to respond these requirements in engine components is the potential use of low friction coatings exposed to specific boundary lubrication conditions. Superlubricity is a new research field in tribology, dealing with very low friction values, typically below 0.01, and this even in dry or vacuum conditions. It is to be noticed that any friction coefficient below 0.001 is hardly measurable with the equipment at hand. Superlow friction was already experimentally observed only in ultrahigh vacuum and inert gas environment, with pure molybdenite (MoS2) coatings [1] and in presence of some hydrogenated DLC coatings [2]. Under boundary lubrication, we show here that the coupling of hydrogen-free carbon coatings and selected organic lubricant additives permits to reach friction values approaching superlubricity and also a wearless behavior.

Tribological Properties of ZrO2 Ceramics under Vacuum Condition

2010 ◽  
Vol 139-141 ◽  
pp. 121-124
Author(s):  
Rui Peng Tong
Keyword(s):  
Photoelectron Spectroscopy ◽  
Sliding Wear ◽  
Applied Load ◽  
High Vacuum ◽  
Optical Microscope ◽  
Bearing Steel ◽  
Vacuum Condition ◽  
Force Microscopy ◽  
Atomic Force ◽  
High Vacuum Condition

Sliding wear was investigated for ZrO2 ceramics against M50 bearing steel under vacuum condition. The research was studied on the ball-disk machine under different loads and steady sliding velocity. The worn surfaces of tested samples were examined using optical microscope, scanning electron microscopy, atomic force microscopy and X-ray photoelectron spectroscopy. The results showed that the friction coefficient of ZrO2 was decided by the applied load, the critical load of ZrO2 was 10N applied load under vacuum condition, the specific wear rate of ZrO2 drop rapidly with exceeded applied critical loads. The ZrO2 ceramics materials have transferred on the M50 bearing steel surface under high vacuum condition. The dominant wear mechanisms of ZrO2 ceramics were mico-adhesion, tribochemical wear, brittle scraps and micro-furrow wear under vacuum condition.

Process Development and Tribochemical Evaluation of Seed Oil Based Antiwear/Antifriction Additive

2005 ◽  
Author(s):  
Atanu Adhvaryu ◽  
Brajendra K. Sharma ◽  
Sevim Z. Erhan
Keyword(s):  
Boundary Lubrication ◽  
Seed Oil ◽  
Process Development ◽  
Mechanical Stresses ◽  
Lubricant Additives ◽  
Government Regulations ◽  
Antifriction Additive ◽  
Increasing Demand ◽  
Interacting Surfaces ◽  
Lubrication Conditions

Antiwear / antifriction additives enhance the ability of lubricant to withstand mechanical stresses of interacting surfaces under boundary lubrication conditions. Majority of the lubricants and additives currently used are petroleum based that are toxic to environment, making it increasingly difficult for safe and easy disposal. There has been an increasing demand for “green” lubricants and lubricant additives in recent years due to concerns about lubricants lost to the environment and increasingly strict government regulations controlling their use.

Investigation of the Effect of Uv-Assisted Oxidation and Nitridation of Hafnium Metal Films

2003 ◽  
Vol 780 ◽  
Author(s):  
C. Essary ◽  
V. Craciun ◽  
J. M. Howard ◽  
R. K. Singh
Keyword(s):  
Uv Radiation ◽  
Photoelectron Spectroscopy ◽  
Grazing Angle ◽  
X Ray Diffraction ◽  
Metal Thin Films ◽  
X Ray ◽  
Force Microscopy ◽  
Si Substrates ◽  
Atomic Force ◽  
Silicon Interface

AbstractHf metal thin films were deposited on Si substrates using a pulsed laser deposition technique in vacuum and in ammonia ambients. The films were then oxidized at 400 °C in 300 Torr of O2. Half the samples were oxidized in the presence of ultraviolet (UV) radiation from a Hg lamp array. X-ray photoelectron spectroscopy, atomic force microscopy, and grazing angle X-ray diffraction were used to compare the crystallinity, roughness, and composition of the films. It has been found that UV radiation causes roughening of the films and also promotes crystallization at lower temperatures.Furthermore, increased silicon oxidation at the interface was noted with the UVirradiated samples and was shown to be in the form of a mixed layer using angle-resolved X-ray photoelectron spectroscopy. Incorporation of nitrogen into the film reduces the oxidation of the silicon interface.

scholarly journals Photocatalytic reduction of graphene oxide with cuprous oxide film under UV-vis irradiation

2020 ◽  
Vol 59 (1) ◽  
pp. 207-214 ◽  
Author(s):  
Yao Wang ◽  
Jianqing Feng ◽  
Lihua Jin ◽  
Chengshan Li
Keyword(s):  
Graphene Oxide ◽  
Photoelectron Spectroscopy ◽  
Low Cost ◽  
Photocatalytic Reduction ◽  
Force Microscopy ◽  
Atomic Force ◽  
Reduced Graphene ◽  
Reduction Efficiency ◽  
Metal Organic ◽  
Reduction Effect

AbstractWe have grown Cu2O films by different routes including self-oxidation and metal-organic deposition (MOD). The reduction efficiency of Cu2O films on graphene oxide (GO) synthesized by modified Hummer’s method has been studied. Surface morphology and chemical state of as-prepared Cu2O film and GO sheets reduced at different conditions have also been investigated using atomic force microscopy (AFM) and x-ray photoelectron spectroscopy (XPS). Results show that self-oxidation Cu2O film is more effective on phtocatalytic reduction of GO than MOD-Cu2O film. Moreover, reduction effect of self-oxidation Cu2O film to GO is comparable to that of environmental-friendly reducing agent of vitamin C. The present results offer a potentially eco-friendly and low-cost approach for the manufacture of reduced graphene oxide (RGO) by photocatalytic reduction.

scholarly journals Interface Structures and Electronic States of Epitaxial Tetraazanaphthacene on Single-Crystal Pentacene

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1088
Author(s):  
Yuki Gunjo ◽  
Hajime Kamebuchi ◽  
Ryohei Tsuruta ◽  
Masaki Iwashita ◽  
Kana Takahashi ◽  
...  
Keyword(s):  
Single Crystal ◽  
Photoelectron Spectroscopy ◽  
Grazing Incidence ◽  
Force Microscopy ◽  
Interface Dipole ◽  
Atomic Force ◽  
Interfacial Structures ◽  
Donor And Acceptor ◽  
A Charge ◽  
Interface Structures

The structural and electronic properties of interfaces composed of donor and acceptor molecules play important roles in the development of organic opto-electronic devices. Epitaxial growth of organic semiconductor molecules offers a possibility to control the interfacial structures and to explore precise properties at the intermolecular contacts. 5,6,11,12-tetraazanaphthacene (TANC) is an acceptor molecule with a molecular structure similar to that of pentacene, a representative donor material, and thus, good compatibility with pentacene is expected. In this study, the physicochemical properties of the molecular interface between TANC and pentacene single crystal (PnSC) substrates were analyzed by atomic force microscopy, grazing-incidence X-ray diffraction (GIXD), and photoelectron spectroscopy. GIXD revealed that TANC molecules assemble into epitaxial overlayers of the (010) oriented crystallites by aligning an axis where the side edges of the molecules face each other along the [1¯10] direction of the PnSC. No apparent interface dipole was found, and the energy level offset between the highest occupied molecular orbitals of TANC and the PnSC was determined to be 1.75 eV, which led to a charge transfer gap width of 0.7 eV at the interface.

scholarly journals Silane-Coating Strategy for Titanium Functionalization Does Not Impair Osteogenesis In Vivo

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1814
Author(s):  
Plinio Mendes Senna ◽  
Carlos Fernando de Almeida Barros Mourão ◽  
Rafael Coutinho Mello-Machado ◽  
Kayvon Javid ◽  
Pietro Montemezzi ◽  
...  
Keyword(s):  
Bone Formation ◽  
Photoelectron Spectroscopy ◽  
Titanium Surface ◽  
Rabbit Model ◽  
Biologically Active ◽  
Force Microscopy ◽  
Atomic Force ◽  
Silane Coating ◽  
Titanium Screws

Silane-coating strategy has been used to bind biological compounds to the titanium surface, thereby making implant devices biologically active. However, it has not been determined if the presence of the silane coating itself is biocompatible to osseointegration. The aim of the present study was to evaluate if silane-coating affects bone formation on titanium using a rabbit model. For this, titanium screw implants (3.75 by 6 mm) were hydroxylated in a solution of H2SO4/30% H2O2 for 4 h before silane-coating with 3-aminopropyltriethoxysilane (APTES). A parallel set of titanium screws underwent only the hydroxylation process to present similar acid-etched topography as a control. The presence of the silane on the surface was checked by x-ray photoelectron spectroscopy (XPS), with scanning electron microscopy (SEM) and atomic force microscopy (AFM). A total of 40 titanium screws were implanted in the tibia of ten New Zealand rabbits in order to evaluate bone-to-implant contact (BIC) after 3 weeks and 6 weeks of healing. Silane-coated surface presented higher nitrogen content in the XPS analysis, while micro- and nano-topography of the surface remained unaffected. No difference between the groups was observed after 3 and 6 weeks of healing (p > 0.05, independent t-test), although an increase in BIC occurred over time. These results indicate that silanization of a titanium surface with APTES did not impair the bone formation, indicating that this can be a reliable tool to anchor osteogenic molecules on the surface of implant devices.

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