Characterization of Fracture in Asphaltic Mixes Based on a Molecular Approach

1996 ◽  
Vol 1535 (1) ◽  
pp. 22-28
Author(s):  
Maarten M. J. Jacobs ◽  
Piet C. Hopman ◽  
André A. A. Molenaar
Keyword(s):  
Crack Growth ◽  
Mechanical Tests ◽  
Theoretical Background ◽  
Cohesive Crack ◽  
Rate Theory ◽  
Initiation Phase ◽  
Parallel Processes ◽  
Free Activation Energy ◽  
The Difference

In contradiction to the fracture mechanics approach, the fundamental absolute rate theory (ART) model describes the macroscopic behavior of processes on the molecular level. Attention is given to the theoretical background of the ART and its application to describing the crack growth process in asphalt concrete mixes. From the analyses, it is concluded that in the crack propagation phase, three parallel processes are distinguished: cohesive crack growth, adhesive crack growth, and a crack-retardant process. In the crack initiation phase, only cohesive crack growth is present. The difference between the mixes is specified by the free activation energy Qa: increase in crack growth resistance increases the Qa-value. This Qa-value, determined from mechanical tests, is close to the energy that bonds the bitumen to the aggregate, determined from chemical tests.

Effect of silver nitrate on some mechanical properties of heat polymerizing acrylic resins

2019 ◽  
Vol 14 (1) ◽  
pp. 110
Author(s):  
Assiss. Prof. Dr. Sabiha Mahdi Mahdi ◽  
Dr. Firas Abd K. Abd K.
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Silver Nitrate ◽  
Surface Hardness ◽  
Mechanical Tests ◽  
Hardness Tester ◽  
Acrylic Resins ◽  
The Difference

Aim: The aimed study was to evaluate the influence of silver nitrate on surfacehardness and tensile strength of acrylic resins.Materials and methods: A total of 60 specimens were made from heat polymerizingresins. Two mechanical tests were utilized (surface hardness and tensile strength)and 4 experimental groups according to the concentration of silver nitrate used.The specimens without the use of silver nitrate were considered as control. Fortensile strength, all specimens were subjected to force till fracture. For surfacehardness, the specimens were tested via a durometer hardness tester. Allspecimens data were analyzed via ANOVA and Tukey tests.Results: The addition of silver nitrate to acrylic resins reduced significantly thetensile strength. Statistically, highly significant differences were found among allgroups (P≤0.001). Also, the difference between control and experimental groupswas highly significant (P≤0.001). For surface hardness, the silver nitrate improvedthe surface hardness of acrylics. Highly significant differences were statisticallyobserved between control and 900 ppm group (P≤0.001); and among all groups(P≤0.001)with exception that no significant differences between control and150ppm; and between 150ppm and 900ppm groups(P>0.05).Conclusion: The addition of silver nitrate to acrylics reduced significantly the tensilestrength and improved slightly the surface hardness.

Analisis Karakterisasi Teknologi Direct Sequence Spread Spectrum Dan Frequency Hopping Spread Spectrum

2019 ◽  
Vol 2 (2) ◽  
pp. 129-138
Author(s):  
Fawzan Galib Abdul Karim Bawahab ◽  
Elvan Yuniarti ◽  
Edi Kurniawan
Keyword(s):  
Spread Spectrum ◽  
Communication Systems ◽  
Multiple Access ◽  
Frequency Hopping ◽  
Direct Sequence Spread Spectrum ◽  
Direct Sequence ◽  
Frequency Hopping Spread Spectrum ◽  
Two Systems ◽  
The Difference

Abstrak. Pada penelitian ini, telah dilakukan analisa karakterisasi pada teknologi Direct Sequence Spread Spectrum dan Frequency Hopping Spread Spectrum, sebagai salah satu teknik multiple-access pada sistem komunikasi. Karakterisasi dilakukan untuk mencari bagaimana cara meningkatkan keoptimalan kedua sistem tersebut, dalam mengatasi masalah interferensi dengan sistem dan channel yang sama. Dan juga untuk menentukan veriabel apa yang mempengaruhi keoptimalan kedua sistem tersebut. Karakterisasi dilakukan dengan menentukan variabel-variabel yang mempengaruhi keoptimalan keduanya. Hasil dari karakterisasi, diketahui variabel-variabel yang mempengaruhi kemampuan sistem DSSS yaitu nilai frekuensi spreading (). Sedangkan untuk sistem FHSS yaitu nilai frekuensi spreading ( dan ) dan selisih antara frekuensi hopping data dengan frekuensi hopping interferensi . Kata Kunci: BER, DSSS, FHSS, Interference, Spread spectrum. Abstract. In this study, characterization of Direct Sequence Spread Spectrum and Frequency Hopping Spread Spectrum technologies have been done, as one of the multiple-access techniques in communication systems. Characterization is done to find out how to improve the ability of the two systems, in solving interference problems with the same system and channel. And also to determine what veriabel affects the ability of the two systems. Characterization is done by determining the variables that affect the ability of both. The results of the characterization, known variables that affect the ability of the DSSS system are the spreading frequency value (). As for the FHSS system, the spreading frequency value ( and ) and the difference between frequency hopping data with frequency hopping interference .

Characterization of the surface of hydrodesulphurization catalysts by adsorption of hydrocarbons

1984 ◽  
Vol 49 (2) ◽  
pp. 410-420
Author(s):  
Eva Hillerová ◽  
Miroslav Zdražil
Keyword(s):  
Hydrogen Sulphide ◽  
Chromatographic Method ◽  
Supported Catalysts ◽  
Alumina Surface ◽  
Reversible Adsorption ◽  
The Difference

Reversible adsorption of heptane and benzene on model and industrial hydrodesulphurization molybdena catalysts has been studied by elution chromatographic method at 150 °C. An increase in the adsorption of heptane on sulphidation of adsorbents was small for Al2O3 and great for MoO3. Supported catalysts behaved as mixture of Al2O3 and MoO3.The portion of surface which can be transformed by sulphidation into MoS2 ranged from 0 to 65% for individual commercial catalysts, as determined from the change in heptane adsorption after sulphidation of a given sample. The polarity of catalysts, including their acidity, was estimated from the difference between adsorption of benzene and heptane. The polarity of model and industrial catalysts in oxidic form was similar to that of alumina in most cases. The decrease in the polarity after sulphidation of the adsorbents was small for Al2O3 and great for MoO3. The decrease in polarity resulting from sulphidation of supported catalysts was relatively small, since the reaction of MoO3 monolayer with hydrogen sulphide leads to partial reformation of the alumina surface. The acidity of supported sulphided hydrodesulphurization catalysts has been shown by this method to be comparable with the acidity of the support itself.

Synthesis and characterization of a series of 1-methyl-4-[2-aryl-1-diazenyl]piperazines and a series of ethyl 4-[2-aryl-1-diazenyl]-1-piperazinecarboxylates

2004 ◽  
Vol 82 (8) ◽  
pp. 1294-1303 ◽  
Author(s):  
Vanessa Renée Little ◽  
Keith Vaughan
Keyword(s):  
Free Energy ◽  
Chemical Shifts ◽  
Linear Free Energy Relationship ◽  
Piperazine Ring ◽  
Linear Free Energy ◽  
In Series ◽  
Methylene Groups ◽  
Diazonium Coupling ◽  
The Difference

1-Methylpiperazine was coupled with a series of diazonium salts to afford the 1-methyl-4-[2-aryl-1-diazenyl]piperazines (2), a new series of triazenes, which have been characterized by 1H and 13C NMR spectroscopy, IR spectroscopy, and elemental analysis. Assignment of the chemical shifts to specific protons and carbons in the piperazine ring was facilitated by comparison with the chemical shifts in the model compounds piperazine and 1-methylpiperazine and by a HETCOR experiment with the p-tolyl derivative (2i). A DEPT experiment with 1-methylpiperazine (6) was necessary to distinguish the methyl and methylene groups in 6, and a HETCOR spectrum of 6 enabled the correlation of proton and carbon chemical shifts. Line broadening of the signals from the ring methylene protons is attributed to restricted rotation around the N2-N3 bond of the triazene moiety in 2. The second series of triazenes, the ethyl 4-[2-phenyl-1-diazenyl]-1-piperazinecarboxylates (3), have been prepared by similar diazonium coupling to ethyl 1-piperazinecarboxylate and were similarly characterized. The chemical shifts of the piperazine ring protons are much closer together in series 3 than in series 2, resulting in distortion of the multiplets for these methylenes. It was noticed that the difference between these chemical shifts in 3 exhibited a linear free energy relationship with the Hammett substituent constants for the substituents in the aryl ring. Key words: triazene, piperazine, diazonium coupling, NMR, HETCOR, linear free energy relationship.

scholarly journals Grounding semantic transparency in context

Morphology ◽  
2021 ◽  
Author(s):  
Rossella Varvara ◽  
Gabriella Lapesa ◽  
Sebastian Padó
Keyword(s):  
Large Scale ◽  
Point Of View ◽  
Distributional Semantics ◽  
Semantic Transparency ◽  
Inclusion Measure ◽  
The Difference ◽  
Semantic Point ◽  
The Many ◽  
The Relationship

AbstractWe present the results of a large-scale corpus-based comparison of two German event nominalization patterns: deverbal nouns in -ung (e.g., die Evaluierung, ‘the evaluation’) and nominal infinitives (e.g., das Evaluieren, ‘the evaluating’). Among the many available event nominalization patterns for German, we selected these two because they are both highly productive and challenging from the semantic point of view. Both patterns are known to keep a tight relation with the event denoted by the base verb, but with different nuances. Our study targets a better understanding of the differences in their semantic import.The key notion of our comparison is that of semantic transparency, and we propose a usage-based characterization of the relationship between derived nominals and their bases. Using methods from distributional semantics, we bring to bear two concrete measures of transparency which highlight different nuances: the first one, cosine, detects nominalizations which are semantically similar to their bases; the second one, distributional inclusion, detects nominalizations which are used in a subset of the contexts of the base verb. We find that only the inclusion measure helps in characterizing the difference between the two types of nominalizations, in relation with the traditionally considered variable of relative frequency (Hay, 2001). Finally, the distributional analysis allows us to frame our comparison in the broader coordinates of the inflection vs. derivation cline.

scholarly journals Acoustic Characterization of Some Steel Industry Waste Materials

2021 ◽  
Vol 11 (13) ◽  
pp. 5924
Author(s):  
Elisa Levi ◽  
Simona Sgarbi ◽  
Edoardo Alessio Piana
Keyword(s):  
Thermal Characteristic ◽  
Environmental Benefits ◽  
Acoustic Properties ◽  
Physical Parameters ◽  
Industry Waste ◽  
Acoustic Characterization ◽  
Minimization Procedure ◽  
The Difference ◽  
By Products

From a circular economy perspective, the acoustic characterization of steelwork by-products is a topic worth investigating, especially because little or no literature can be found on this subject. The possibility to reuse and add value to a large amount of this kind of waste material can lead to significant economic and environmental benefits. Once properly analyzed and optimized, these by-products can become a valuable alternative to conventional materials for noise control applications. The main acoustic properties of these materials can be investigated by means of a four-microphone impedance tube. Through an inverse technique, it is then possible to derive some non-acoustic properties of interest, useful to physically characterize the structure of the materials. The inverse method adopted in this paper is founded on the Johnson–Champoux–Allard model and uses a standard minimization procedure based on the difference between the sound absorption coefficients obtained experimentally and predicted by the Johnson–Champoux–Allard model. The results obtained are consistent with other literature data for similar materials. The knowledge of the physical parameters retrieved applying this technique (porosity, airflow resistivity, tortuosity, viscous and thermal characteristic length) is fundamental for the acoustic optimization of the porous materials in the case of future applications.

A macroscopic theory of microcrack growth in brittle materials

1991 ◽  
Vol 335 (1639) ◽  
pp. 455-485 ◽  
Keyword(s):  
Crack Growth ◽  
Brittle Materials ◽  
Macroscopic Theory ◽  
Rate Of Increase ◽  
Inelastic Behaviour ◽  
Constitutive Response ◽  
Macroscopic Plasticity ◽  
Microcrack Growth ◽  
Vector Valued

This paper is concerned with the development of a macroscopic theory of crack growth in fairly brittle materials. Average characteristics of the cracks are described in terms of an additional vector-valued variable in the macroscopic theory, which is determined by an additional momentum-like balance law associated with the rate of increase of the area of the cracks and includes the effects of forces maintaining the crack growth and the inertia of microscopic particles surrounding the cracks. The basic developments represent an idealized characterization of inelastic behaviour in the presence of crack growth, which accounts for energy dissipation without explicit use of macroscopic plasticity effects. A physically plausible constraint on the rate of crack growth is adopted to simplify the theory. To ensure that the results of the theory are physically reasonable, the constitutive response of the dependent variables are significantly restricted by consideration both of the energetic effects and of the microscopic processes that give rise to crack growth. These constitutive developments are in conformity with many of the standard results and observations reported in the literature on fracture mechanics. The predictive nature of the theory is illustrated with reference to two simple examples concerning uniform extensive and compressive straining.

Relation between Magnetic, Spectroscopic and Structural Properties of Binuclear Copper(II) Complexes of Pentadentate Schiff-base Ligand, Semi-empirical and ab-initio Calculations

2003 ◽  
Vol 58 (5-6) ◽  
pp. 363-372 ◽  
Author(s):  
Y. Elerman ◽  
H. Kara ◽  
A. Elmali
Keyword(s):  
Ab Initio ◽  
Coupling Constants ◽  
Antiferromagnetic Coupling ◽  
X Ray Diffraction ◽  
Hartree Fock ◽  
Ligand Orbital ◽  
Rhf Calculations ◽  
The Difference ◽  
Semi Empirical

The synthesis and characterization of [Cu2(L1)(3,5 prz)] (L1=1,3-Bis(2-hydroxy-3,5-chlorosalicylideneamino) propan-2-ol) 1 and of [Cu2(L2)(3,5 prz)] (L2=1,3-Bis(2-hydroxy-bromosalicylideneamino) propan-2-ol) 2 are reported. The compounds were studied by elemental analysis, infrared and electronic spectra. The structure of the Cu2(L1)(3,5 prz)] complex was determined by x-ray diffraction. The magnetochemical characteristics of these compounds were determined by temperaturedependent magnetic susceptibility measurements, revealing their antiferromagnetic coupling. The superexchange coupling constants are 210 cm−1 for 1 and 440 cm−1 for 2. The difference in the magnitude of the coupling constants was explained by the metal-ligand orbital overlaps and confirmed by ab-initio restricted Hartree-Fock (RHF) calculations. In order to determine the nature of the frontier orbitals, Extended Hückel Molecular Orbital (EHMO) calculations are also reported.

Effect of Flaw Dimensions on Ductile Fracture Behavior of Non-Aligned Multiple Flaws in a Plate

2011 ◽  
Author(s):  
Katsumasa Miyazaki ◽  
Kunio Hasegawa ◽  
Koichi Saito
Keyword(s):  
Ductile Fracture ◽  
Flat Plate ◽  
Fracture Behavior ◽  
Maximum Load ◽  
Surface Flaws ◽  
Fracture Tests ◽  
The Difference ◽  
Almost All ◽  
Maximum Minimum

The fitness-for-service codes require the characterization of non-aligned multiple flaws for flaw evaluation, which is performed using a flaw proximity rule. Worldwide, almost all such codes provide their own proximity rule, often with unclear technical bases of the application of proximity rule to ductile or fully plastic fracture. In particular, the effect of flaw dimensions of multiple surface flaws on fully plastic fracture of non-aligned multiple flaws had not been clear. To clarify the effect of the difference of part through-wall and through-wall flaws on the behavior of fully plastic fracture, the fracture tests of flat plate specimens with non-aligned multiple part through-wall flaws were conducted. When the flaw depth a was shallow with 0.4 in ratio of a to thickness t, the maximum load Pmax occurred at penetration of multiple flaws and the effect of vertical distance of non-aligned multiple flaws H on Pmax was not so significant. However, when flaw depth was deep with 0.8 in a/t, Pmax occurred after penetration of flaws and the effect of H on Pmax could be seen clearly. It was judged that the through-wall flaw tests were appropriate for discussion of the effect of H on Pmax and the alignment rule of multiple flaws. In addition, in order to clarify the appropriate length parameter to estimate Pmax of test specimens with dissimilar non-aligned through-wall multiple flaws, the fracture tests of plate specimens were also conducted. The effect of different flaw length on Pmax was discussed with maximum, minimum and averages of dissimilar non-aligned multiple flaw lengths. Experimental results showed that the maximum length lmax would be an appropriate length parameter to estimate Pmax, when the non-aligned multiple through-wall flaws were dissimilar.

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