Electrical conductivity and mechanical properties of conductive cotton fabrics

2021 ◽  
pp. 152808372098409
Author(s):  
RM Attia ◽  
NM Yousif ◽  
MH Zohdy
Keyword(s):  
Mechanical Properties ◽  
Gamma Irradiation ◽  
Irradiation Dose ◽  
Oxidative Polymerization ◽  
Cotton Fabrics ◽  
X Ray Diffraction ◽  
Untreated Cotton ◽  
Unit Space ◽  
Hyperfine Splittings ◽  
Curing Method

Functional electrically conductive fabric with acceptable mechanical properties, which could be applied in electromagnetic shielding, was developed. Conductive cotton fabrics (cotton/PANI, cotton/Mn, cotton/Cu, and cotton/Co) were prepared by in situ chemical oxidative polymerization for (cotton/PANI) and pad dry curing method was used for nanometals application. The Nano size of the metals and polyaniline inclusion were proven through both Dynamic Liquid Scattering (DLS) and X-ray diffraction (XRD) which showed an increase in crystallite density in unit space and the nanoparticles ranged from 100–200 nm. The effect of gamma irradiation on different treated cotton fabrics was investigated. The mechanical properties against irradiation dose showed an improvement up to 40 kGy, for all treated fabrics. On the other hand, Young’s modulus for untreated cotton recorded the lowest value, while cotton/Co recorded the highest one. Moreover, both AC (Alternating Current) and DC (Direct current) conductivities values can be calculated. In DC conductivity cotton/PANI was found to be more conducive than the remainder of the treated fabric by surface metallization with transition metals; while in AC conductivity cotton/Mn was found to be more conducive than the rest of the treated samples. The conductivity value increases by increasing the gamma irradiation dose for cotton/PANI fabric. Also, g-factor values can be estimated from ESR signals and vary from 0.009 up to 0.059 for conductive cotton fabrics; whilst cotton/Mn fabric has six hyperfine splittings, indicating that it is a paramagnetic element.

scholarly journals X-ray diffraction and thermodynamics kinetics of SiB6 under gamma irradiation dose

Silicon ◽  
2018 ◽  
Vol 11 (5) ◽  
pp. 2499-2504 ◽  
Author(s):  
M. N. Mirzayev ◽  
S. H. Jabarov ◽  
E. B. Asgerov ◽  
R. N. Mehdiyeva ◽  
T. T. Thabethe ◽  
...  
Keyword(s):  
Gamma Irradiation ◽  
Irradiation Dose ◽  
X Ray Diffraction ◽  
X Ray ◽  
Kinetics Of

Effect of electron-beam and gamma-irradiation on physicochemical and mechanical properties of polypropylene syringes as a function of irradiation dose: Study under vacuum

2007 ◽  
Vol 76 (7) ◽  
pp. 1147-1155 ◽  
Author(s):  
Athanasia T. Fintzou ◽  
Michael G. Kontominas ◽  
Anastasia V. Badeka ◽  
Mario R. Stahl ◽  
Kyriakos A. Riganakos
Keyword(s):  
Mechanical Properties ◽  
Electron Beam ◽  
Gamma Irradiation ◽  
Irradiation Dose ◽  
Dose Study

Effects of gamma irradiation on structural, thermal and mechanical properties of polyamide-11/halloysite nanotubes nanocomposites

2021 ◽  
pp. 089270572110319
Author(s):  
Mohamed Sahnoune ◽  
Mustapha Kaci ◽  
Hélène Garay ◽  
José-Marie Lopez-Cuesta ◽  
Mohamed Mahlous
Keyword(s):  
Mechanical Properties ◽  
Gamma Irradiation ◽  
Irradiation Dose ◽  
Chain Scission ◽  
Halloysite Nanotubes ◽  
Thermal And Mechanical Properties ◽  
Polyamide 11 ◽  
Irradiation Test ◽  
Twin Screw ◽  
Low Irradiation

The effect of gamma irradiation on neat Polyamide-11 (PA11) and PA11 filled with 3 wt% of halloysite nanotubes (HNTs) was investigated at various doses up to 100 kGy in air and at room temperature. The irradiation test was conducted on sample films prepared by a twin-screw extruder in the first step then cast extrusion. The study showed the formation of a maximum of gel fraction up to 10 and 20 kGy for neat PA11 and PA11/HNTs, respectively. Furthermore, the results indicated the occurrence of crosslinking at low irradiation dose, whereas chain scission took place at higher ones. Additionally, the results revealed that the presence of HNTs limits the impacts of gamma irradiation through a barrier effect. An optimum irradiation dose was found for thermal and mechanical properties, corresponding to the dose for maximum gel formation. Moreover, experimental design was implemented to highlight the main incidences and interactions of both halloysite incorporation and radiation dose on some relevant effects of gamma irradiation.

Mechanical properties of FeAlSi powders prepared by mechanical alloying from different initial feedstock materials

2019 ◽  
Vol 107 (2) ◽  
pp. 207 ◽  
Author(s):  
Jaroslav Čech ◽  
Petr Haušild ◽  
Miroslav Karlík ◽  
Veronika Kadlecová ◽  
Jiří Čapek ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Mechanical Alloying ◽  
Young’S Modulus ◽  
Milling Time ◽  
Young's Modulus ◽  
Element Model ◽  
X Ray Diffraction ◽  
X Ray ◽  
Powder Particles ◽  
Complete Homogenization

FeAl20Si20 (wt.%) powders prepared by mechanical alloying from different initial feedstock materials (Fe, Al, Si, FeAl27) were investigated in this study. Scanning electron microscopy, X-ray diffraction and nanoindentation techniques were used to analyze microstructure, phase composition and mechanical properties (hardness and Young’s modulus). Finite element model was developed to account for the decrease in measured values of mechanical properties of powder particles with increasing penetration depth caused by surrounding soft resin used for embedding powder particles. Progressive homogenization of the powders’ microstructure and an increase of hardness and Young’s modulus with milling time were observed and the time for complete homogenization was estimated.

Micro-Hardness and Morphology of LDPE Influenced by Beta Radiation

2014 ◽  
Vol 606 ◽  
pp. 253-256 ◽  
Author(s):  
Martin Ovsik ◽  
Petr Kratky ◽  
David Manas ◽  
Miroslav Manas ◽  
Michal Stanek ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Hardness Test ◽  
Polymer Materials ◽  
Beta Radiation ◽  
Micro Hardness ◽  
X Ray Diffraction ◽  
Depth Sensing ◽  
Surface Layers ◽  
Hardness Values ◽  
Different Doses

This article deals with the influence of different doses of Beta radiation to the structure and mico-mechanical properties of Low-density polyethylene (LDPE). Hard surface layers of polymer materials, especially LDPE, can be formed by radiation cross-linking by β radiation with doses of 33, 66 and 99 kGy. Material properties created by β radiation are measured by micro-hardness test using the DSI method (Depth Sensing Indentation). Individual radiation doses caused structural and micro-mechanical changes which have a significant effect on the final properties of the LDPE tested. The highest values of micro-mechanical properties were reached at radiation dose of 66 and 99 kGy, when the micro-hardness values increased by about 21%. The changes were examined and confirmed by X-ray diffraction.

Comparison of different curing method for mechanical properties of self-curing agent using diapers polymer

2021 ◽  
Author(s):  
Daud Mohamad ◽  
Salmia Beddu ◽  
Ibrahim ◽  
Karim Sherif ◽  
Mahyun Zainoddin ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Curing Agent ◽  
Curing Method

scholarly journals Modification of cotton fabrics with 2-diethylaminoethyl chloride for salt-free dyeing with anionic dyes

Cellulose ◽  
2021 ◽  
Author(s):  
Peixin Tang ◽  
Leilah-Marie E. Lockett ◽  
Mengxiao Zhang ◽  
Gang Sun
Keyword(s):  
Electrostatic Interactions ◽  
Light Exposure ◽  
Dye Adsorption ◽  
Cost Effective ◽  
Cotton Fabrics ◽  
Cotton Cellulose ◽  
Hydroxyl Groups ◽  
Anionic Dyes ◽  
Free System ◽  
Untreated Cotton

AbstractA chemical modification of cotton fabrics by 2-diethylaminoethyl chloride (DEAE-Cl) was achieved, and the resulted cotton fabrics demonstrated salt-free dyeing properties with anionic dyes. Nucleophilic property of hydroxyl groups in cotton cellulose was enhanced under alkaline conditions and could react with DEAE-Cl, a chemical possessing both nucleophilic and electrophilic sites. The monolayered DEAE-grafted cotton cellulose could further react with DEAE-Cl to form multiple cationic quaternary ammonium salts (denoted as DEAE@Cotton), which are highly interactive with anionic dye molecules. The strong electrostatic interactions between the DEAE@Cotton and the dyes eliminated the use of inorganic salts in cotton dyeing process. The chemical structure and property of DEAE@Cotton were characterized and compared with untreated cotton. The DEAE@Cotton can be dyed in a salt-free system, and the dye exhaustion was faster than the conventional dyeing method due to the robust electrostatic interactions of the fabrics with anionic dyes. The dyed fabrics demonstrated outstanding color fastness under repeated washing, light exposure, and crocking. The dye adsorption process on DEAE@Cotton follows Langmuir isotherm model (R2 = 0.9667). The mechanism of enhanced dyeability was experimentally proved by treating the fabric with other anionic dyes in a salt-free system, proving the process to be environmentally friendly and cost-effective. Graphic abstract

scholarly journals Enhancement of Chloroprene/Natural/Butadiene Rubber Nanocomposite Properties Using Organoclays and Their Combination with Carbon Black as Fillers

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1085
Author(s):  
Patricia Castaño-Rivera ◽  
Isabel Calle-Holguín ◽  
Johanna Castaño ◽  
Gustavo Cabrera-Barjas ◽  
Karen Galvez-Garrido ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Carbon Black ◽  
High Performance ◽  
Rubber Matrix ◽  
Butadiene Rubber ◽  
X Ray Diffraction ◽  
X Ray ◽  
Rubber Blends ◽  
Ft Ir ◽  
Chloroprene Rubber

Organoclay nanoparticles (Cloisite® C10A, Cloisite® C15) and their combination with carbon black (N330) were studied as fillers in chloroprene/natural/butadiene rubber blends to prepare nanocomposites. The effect of filler type and load on the physical mechanical properties of nanocomposites was determined and correlated with its structure, compatibility and cure properties using Fourier Transformed Infrared (FT-IR), X-ray Diffraction (XRD), Thermogravimetric Analysis (TGA) and rheometric analysis. Physical mechanical properties were improved by organoclays at 5–7 phr. Nanocomposites with organoclays exhibited a remarkable increase up to 46% in abrasion resistance. The improvement in properties was attributed to good organoclay dispersion in the rubber matrix and to the compatibility between them and the chloroprene rubber. Carbon black at a 40 phr load was not the optimal concentration to interact with organoclays. The present study confirmed that organoclays can be a reinforcing filler for high performance applications in rubber nanocomposites.

scholarly journals Novel Hydrogels of Chitosan and Poly (vinyl alcohol) Reinforced with Inorganic Particles of Bioactive Glass

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 691
Author(s):  
O. Sánchez-Aguinagalde ◽  
Ainhoa Lejardi ◽  
Emilio Meaurio ◽  
Rebeca Hernández ◽  
Carmen Mijangos ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Drug Release ◽  
Bioactive Glass ◽  
Vinyl Alcohol ◽  
Release Kinetics ◽  
The Body ◽  
Poly Vinyl Alcohol ◽  
X Ray Diffraction ◽  
Inorganic Particles ◽  
Release Studies

Chitosan (CS) and poly (vinyl alcohol) (PVA) hydrogels, a polymeric system that shows a broad potential in biomedical applications, were developed. Despite the advantages they present, their mechanical properties are insufficient to support the loads that appear on the body. Thus, it was proposed to reinforce these gels with inorganic glass particles (BG) in order to improve mechanical properties and bioactivity and to see how this reinforcement affects levofloxacin drug release kinetics. Scanning electron microscopy (SEM), X-ray diffraction (XRD), swelling tests, rheology and drug release studies characterized the resulting hydrogels. The experimental results verified the bioactivity of these gels, showed an improvement of the mechanical properties and proved that the added bioactive glass does affect the release kinetics.

scholarly journals Relationship between the Stereocomplex Crystallization Behavior and Mechanical Properties of PLLA/PDLA Blends

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1851
Author(s):  
Hye-Seon Park ◽  
Chang-Kook Hong
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
Crystallization Behavior ◽  
Mechanical Analysis ◽  
X Ray Diffraction ◽  
Nucleation Agent ◽  
Scanning Calorimetry ◽  
Nucleation Sites ◽  
Wide Range ◽  
Degree Of Crystallization

Poly (l-lactic acid) (PLLA) is a promising biomedical polymer material with a wide range of applications. The diverse enantiomeric forms of PLLA provide great opportunities for thermal and mechanical enhancement through stereocomplex formation. The addition of poly (d-lactic acid) (PDLA) as a nucleation agent and the formation of stereocomplex crystallization (SC) have been proven to be an effective method to improve the crystallization and mechanical properties of the PLLA. In this study, PLLA was blended with different amounts of PDLA through a melt blending process and their properties were calculated. The effect of the PDLA on the crystallization behavior, thermal, and mechanical properties of PLLA were investigated systematically by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), X-ray diffraction (XRD), polarized optical microscopy (POM), dynamic mechanical analysis (DMA), and tensile test. Based on our findings, SC formed easily when PDLA content was increased, and acts as nucleation sites. Both SC and homo crystals (HC) were observed in the PLLA/PDLA blends. As the content of PDLA increased, the degree of crystallization increased, and the mechanical strength also increased.

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