scholarly journals Spinnability and characteristics of polyoxymethylene-based core–sheath bicomponent fibers

2019 ◽  
Vol 14 ◽  
pp. 155892501985944
Author(s):  
Jitlada Boonlertsamut ◽  
Supaphorn Thumsorn ◽  
Toshikazu Umemura ◽  
Hiroyuki Hamada ◽  
Atsushi Sakuma
Keyword(s):  
Lactic Acid ◽  
Structural Characteristics ◽  
Core Material ◽  
Poly Lactic Acid ◽  
Bicomponent Fibers ◽  
Fiber Properties ◽  
The Core ◽  
The Impact ◽  
Fiber Processing ◽  
Selection Of

In this work, the spinning abilities of polyoxymethylene-based core–sheath bicomponent fibers were investigated. Bicomponent fibers were prepared using polyoxymethylene as the core material and poly(lactic acid) blended with polyoxymethylene or pure polyoxymethylene as sheath materials, and their characteristics were investigated and compared. Fiber properties such as elongation are important because they directly relate to the spinning performance during fiber processing. This work reports the impact of the composition designation of the core–sheath bicomponent fibers on the controllable stability of poly(lactic acid) in polyoxymethylene–poly(lactic acid) blends in the fibers, as well as the influence of the core–sheath material on the structure, fiber diameter and distribution, thermal stability, and mechanical properties of the core–sheath bicomponent fibers. It was found that the selection of core and sheath materials affected the structural characteristics of the fibers. The polyoxymethylene core–polyoxymethylene sheath (FV) fiber showed dimensional stability. However, the polyoxymethylene core–poly(lactic acid)/polyoxymethylene sheath (FT30) fiber provided the optimum limit of poly(lactic acid) content for controlling the stable properties of the core–sheath bicomponent fibers.

scholarly journals Poly(Lactic Acid)–Poly(Butylene Succinate)–Sugar Beet Pulp Composites; Part I: Mechanics of Composites with Fine and Coarse Sugar Beet Pulp Particles

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2531
Author(s):  
Rodion Kopitzky
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
Sugar Beet ◽  
Cell Structure ◽  
Sugar Beet Pulp ◽  
Poly Lactic Acid ◽  
Butylene Succinate ◽  
Fracture Patterns ◽  
Beet Pulp ◽  
The Impact

Sugar beet pulp (SBP) is a residue available in large quantities from the sugar industry, and can serve as a cost-effective bio-based and biodegradable filler for fully bio-based compounds based on bio-based polyesters. The heterogeneous cell structure of sugar beet suggests that the processing of SBP can affect the properties of the composite. An “Ultra-Rotor” type air turbulence mill was used to produce SBP particles of different sizes. These particles were processed in a twin-screw extruder with poly(lactic acid) (PLA) and poly(butylene succinate) (PBS) and fillers to granules for possible marketable formulations. Different screw designs, compatibilizers and the use of glycerol as a thermoplasticization agent for SBP were also tested. The spherical, cubic, or ellipsoidal-like shaped particles of SBP are not suitable for usage as a fiber-like reinforcement. In addition, the fineness of ground SBP affects the mechanical properties because (i) a high proportion of polar surfaces leads to poor compatibility, and (ii) due to the inner structure of the particulate matter, the strength of the composite is limited to the cohesive strength of compressed sugar-cell compartments of the SBP. The compatibilization of the polymer–matrix–particle interface can be achieved by using compatibilizers of different types. Scanning electron microscopy (SEM) fracture patterns show that the compatibilization can lead to both well-bonded particles and cohesive fracture patterns in the matrix. Nevertheless, the mechanical properties are limited by the impact and elongation behavior. Therefore, the applications of SBP-based composites must be well considered.

The effect of surface modifications on sisal fiber properties and sisal/poly (lactic acid) interface adhesion

2015 ◽  
Vol 73 ◽  
pp. 132-138 ◽  
Author(s):  
A. Orue ◽  
A. Jauregi ◽  
C. Peña-Rodriguez ◽  
J. Labidi ◽  
A. Eceiza ◽  
...  
Keyword(s):  
Lactic Acid ◽  
Surface Modifications ◽  
Sisal Fiber ◽  
Poly Lactic Acid ◽  
Interface Adhesion ◽  
Fiber Properties ◽  
Effect Of Surface

Injectivity and Propagation of Sulfonated Acrylamide-Based Copolymers in Low Permeability Carbonate Reservoir Cores in Harsh Salinity and Temperature Conditions : Challenges and Learnings from a Middle East Onshore Case Study

2021 ◽  
Author(s):  
Nicolas Gaillard ◽  
Matthieu Olivaud ◽  
Alain Zaitoun ◽  
Mahmoud Ould-Metidji ◽  
Guillaume Dupuis ◽  
...  
Keyword(s):  
Middle East ◽  
Polymer Solutions ◽  
Carbonate Reservoir ◽  
Core Material ◽  
Low Permeability ◽  
The Core ◽  
Reservoir Conditions ◽  
Carbonate Cores ◽  
The Impact ◽  
Mobility Reduction

Abstract Polymer flooding is one of the most mature EOR technology applied successfully in a broad range of reservoir conditions. The last developments made in polymer chemistries allowed pushing the boundaries of applicability towards higher temperature and salinity carbonate reservoirs. Specifically designed sulfonated acrylamide-based copolymers (SPAM) have been proven to be stable for more than one year at 120°C and are the best candidates to comply with Middle East carbonate reservoir conditions. Numerous studies have shown good injectivity and propagation properties of SPAM in carbonate cores with permeabilities ranging from 70 to 150 mD in presence of oil. This study aims at providing new insights on the propagation of SPAM in carbonate reservoir cores having permeabilities ranging between 10 and 40 mD. Polymer screening was performed in the conditions of ADNOC onshore carbonate reservoir using a 260 g/L TDS synthetic formation brine together with oil and core material from the reservoir. All the experiments were performed at residual oil saturation (Sor). The experimental approach aimed at reproducing the transport of the polymer entering the reservoir from the sand face up to a certain depth. Three reservoir coreflood experiments were performed in series at increasing temperatures and decreasing rates to mimic the progression of the polymer in the reservoir with a radial velocity profile. A polymer solution at 2000 ppm was injected in the first core at 100 mL/h and 40°C. Effluents were collected and injected in the second core at 20 mL/h and 70°C. Effluents were collected again and injected in the third core at 4 mL/h and 120°C. A further innovative approach using reservoir minicores (6 mm length disks) was also implemented to screen the impact of different parameters such as Sor, molecular weight and prefiltration step on the injectivity of the polymer solutions. According to minicores data, shearing of the polymer should help to ensure good propagation and avoid pressure build-up at the core inlet. This result was confirmed through an injection in a larger core at Sor and at 120°C. When comparing the injection of sheared and unsheared polymer at the same concentration, core inlet impairment was suppressed with the sheared polymer and the same range of mobility reduction (Rm) was achieved in the internal section of the core although viscosity was lower for the sheared polymer. Such result indicates that shearing is an efficient way to improve injectivity while maximizing the mobility reduction by suppressing the loss of product by filtration/retention at the core inlet. This paper gives new insights concerning SPAM rheology in low permeability carbonate cores. Additionally, it provides an innovative and easier approach for screening polymer solutions to anticipate their propagation in more advanced coreflooding experiments.

scholarly journals Moisture Absorption Effects on the Mechanical Properties of Sandwich Biocomposites with Cork Core and Flax/PLA Face Sheets

Molecules ◽  
2021 ◽  
Vol 26 (23) ◽  
pp. 7295
Author(s):  
Hom Nath Dhakal ◽  
Chulin Jiang ◽  
Moumita Sit ◽  
Zhongyi Zhang ◽  
Moussa Khalfallah ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Failure Modes ◽  
Moisture Absorption ◽  
Mechanical Performance ◽  
Core Sample ◽  
Environmental Benefits ◽  
Matrix Cracking ◽  
Core Material ◽  
Poly Lactic Acid ◽  
The Core

The aim of this study was to evaluate the moisture absorption behaviour and its influence on the mechanical properties of newly developed sandwich biocomposites with flax fibre-reinforced poly-lactic acid (PLA) face sheets and soft cork as the core material. Three different types of sandwich biocomposite laminates comprised of different layup configurations, namely, non-woven flax/PLA (Sample A), non-woven flax/PLA and cork as core (Sample B) and non-woven flax/paper backing/PLA, cork as core (Sample C), were fabricated. In order to evaluate the influence of moisture ingress on the mechanical properties, the biocomposites were immersed in seawater for a period of 1200 h. The biocomposites (both dry and water immersed) were then subjected to tensile, flexural and low-velocity falling weight impact tests. It was observed from the experimental results that the moisture uptake significantly influenced the mechanical properties of the biocomposites. The presence of the cork and paper in sample C made it more susceptible to water absorption, reaching a value of 34.33%. The presence of cork in the core also has a considerable effect on the mechanical, as well as energy dissipation, behaviours. The results of sample A exhibited improved mechanical performance in both dry and wet conditions compared to samples B and C. Sample A exhibits 32.6% more tensile strength and 81.4% more flexural strength in dry conditions than that in sample C. The scanning electron microscopy (SEM) and X-ray micro-CT images revealed that the failure modes observed are a combination of matrix cracking, core crushing and face core debonding. The results from this study suggest that flax/PLA sandwich biocomposites can be used in various lightweight applications with improved environmental benefits.

scholarly journals The combined plasticization of jute and tung oil anhydride for jute fiber reinforced poly(lactic acid) composites

2021 ◽  
pp. 096739112110576
Author(s):  
Ying Zhou ◽  
Can Chen ◽  
Lan Xie ◽  
Xiaolang Chen ◽  
Guangqiang Xiao ◽  
...  
Keyword(s):  
Lactic Acid ◽  
Physical And Mechanical Properties ◽  
Complex Viscosity ◽  
Poly Lactic Acid ◽  
Melt Blending ◽  
Sem Images ◽  
Pseudoplastic Fluid ◽  
Tung Oil ◽  
Biodegradable Poly ◽  
The Impact

In this work, novel plasticizing biodegradable poly (lactic acid) (PLA) composites were prepared by melt blending of jute and tung oil anhydride (TOA), and the physical and mechanical properties of PLA/jute/TOA composites were tested and characterized. The impact strength of PLA/jute/TOA composites significantly increases with increasing the content of TOA. The SEM images of fracture surface of PLA/jute/TOA composites become rough after the incorporation of TOA. In addition, TOA changes the crystallization temperature and decomposition process of PLA/jute/TOA composites. With increasing the amount of TOA, the value of storage modulus (E′) of PLA/jute/TOA composites gradually increases. The complex viscosity (η*) values for all samples reduce obviously with increasing the frequency, which means that the pure PLA and PLA/jute/TOA composites is typical pseudoplastic fluid. This is attributed to the formation of crosslinking, which restricts the deformation of the composites.

scholarly journals Impact Toughness and Ductility Enhancement of Biodegradable Poly(lactic acid)/Poly(ε-caprolactone) Blends via Addition of Glycidyl Methacrylate

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Wei Kit Chee ◽  
Nor Azowa Ibrahim ◽  
Norhazlin Zainuddin ◽  
Mohd Faizal Abd Rahman ◽  
Buong Woei Chieng
Keyword(s):  
Lactic Acid ◽  
Impact Strength ◽  
Glycidyl Methacrylate ◽  
Interfacial Adhesion ◽  
Tensile Modulus ◽  
Sem Analysis ◽  
Poly Lactic Acid ◽  
Biodegradable Poly ◽  
Interfacial Compatibility ◽  
The Impact

Poly(lactic acid) (PLA)/poly(ε-caprolactone) (PCL) blends were prepared via melt blending technique. Glycidyl methacrylate (GMA) was added as reactive compatibilizer to improve the interfacial adhesion between immiscible phases of PLA and PCL matrices. Tensile test revealed that optimum in elongation at break of approximately 327% achieved when GMA loading was up to 3wt%. Slight drop in tensile strength and tensile modulus at optimum ratio suggested that the blends were tuned to be deformable. Flexural studies showed slight drop in flexural strength and modulus when GMA wt% increases as a result of improved flexibility by finer dispersion of PCL in PLA matrix. Besides, incorporation of GMA in the blends remarkably improved the impact strength. Highest impact strength was achieved (160% compared to pure PLA/PCL blend) when GMA loading was up to 3 wt%. SEM analysis revealed improved interfacial adhesion between PLA/PCL blends in the presence of GMA. Finer dispersion and smooth surface of the specimens were noted as GMA loading increases, indicating that addition of GMA eventually improved the interfacial compatibility of the nonmiscible blend.

scholarly journals Investigation on compatibility of PLA/PBAT blends modified by epoxy-terminated branched polymers through chemical micro-crosslinking

e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 39-54 ◽  
Author(s):  
Bo Wang ◽  
Yujuan Jin ◽  
Kai’er Kang ◽  
Nan Yang ◽  
Yunxuan Weng ◽  
...  
Keyword(s):  
Lactic Acid ◽  
Glass Transition ◽  
Sem Analysis ◽  
Branched Polymers ◽  
Poly Lactic Acid ◽  
Elongation At Break ◽  
Butylene Terephthalate ◽  
The Difference ◽  
Physical And Chemical ◽  
The Impact

AbstractIn this study, a type of epoxy-terminated branched polymer (ETBP) was used as an interface compati- bilizer to modify the poly lactic acid (PLA)/poly(butylene adipate-co-butylene terephthalate) (PBAT) (70/30) blends. Upon addition of ETBP, the difference in glass transition temperature between PLA and PBAT became smaller. By adding 3.0 phr of ETBP, the elongation at break of the PLA/PBAT blends was found increased from 45.8% to 272.0%; the impact strength increased from 26.2 kJ·m−2 to 45.3 kJ·m−2. In SEM analysis, it was observed that the size of the dispersed PBAT particle decreased with the increasing of ETBP content. These results indicated that the compatibility between PLA and PBAT can be effectively enhanced by using ETBP as the modifier. The modification mechanism was discussed in detail. It proposes that both physical and chemical micro-crosslinking were formed, the latter of which was confirmed by gel content analysis.

Influence of temperature dependence on the structural characteristics of polyoxymethylene/poly(lactic acid) blends by injection molding

2019 ◽  
Vol 39 (10) ◽  
pp. 944-953
Author(s):  
Jitlada Boonlertsamut ◽  
Suchalinee Mathurosemontri ◽  
Supaphorn Thumsorn ◽  
Toshikazu Umemura ◽  
Atsushi Sakuma
Keyword(s):  
Lactic Acid ◽  
Injection Molding ◽  
Crystal Size ◽  
Structural Characteristics ◽  
Growth Direction ◽  
Poly Lactic Acid ◽  
Injection Molding Process ◽  
Mechanical And Thermal Properties ◽  
Molding Process ◽  
Microscopy Images

Abstract In this research, different strategies to modify the structure of polymer blends were investigated with the objective of adjusting the composition of polyoxymethylene (POM) and poly(lactic acid) (PLA) under typical processing conditions. POM shows a good balance of mechanical and thermal properties. However, this polymer is obtained from petrochemical sources, and in some markets, environmentally friendly materials are important. Blending POM with PLA preserves the advantages of POM while ensuring the bio-based content of PLA. POM/PLA blends were prepared by an injection molding process with various injection speeds of 10, 50, 100, and 1000 mm/s to ensure high ductility. Mechanical property analysis showed that the PLA content and processing temperatures are highly effective in modifying the stiffness of POM/PLA blends. The effect of crystallization on POM/PLA blends was assessed by varying the annealing time. High-magnification scanning electron microscopy images revealed that the gaps between fibrillar regions represent the growth direction of the PLA phase before it was removed. This was evidence for the effect of PLA on the crystallization of POM. The crystal size and crystalline volume also affected the structural characteristics of POM/PLA blends.

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