Soil pH Effect on the Distribution of Heavy Metals Among Soil Fractions

2000 ◽  
pp. 107-119 ◽  
Author(s):  
C Tsadilas
Keyword(s):  
Heavy Metals ◽  
Soil Ph ◽  
Ph Effect ◽  
Soil Fractions

scholarly journals Fractionation of Heavy Metals in Multi-Contaminated Soil Treated with Biochar Using the Sequential Extraction Procedure

Biomolecules ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 448
Author(s):  
Mahrous Awad ◽  
Zhongzhen Liu ◽  
Milan Skalicky ◽  
Eldessoky S. Dessoky ◽  
Marian Brestic ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Organic Matter ◽  
Soil Organic Matter ◽  
Soil Ph ◽  
Contaminated Soil ◽  
Contaminated Soils ◽  
Extraction Procedure ◽  
Sequential Fractionation ◽  
Relationship Of ◽  
The Relationship

Heavy metals (HMs) toxicity represents a global problem depending on the soil environment’s geochemical forms. Biochar addition safely reduces HMs mobile forms, thus, reducing their toxicity to plants. While several studies have shown that biochar could significantly stabilize HMs in contaminated soils, the study of the relationship of soil properties to potential mechanisms still needs further clarification; hence the importance of assessing a naturally contaminated soil amended, in this case with Paulownia biochar (PB) and Bamboo biochar (BB) to fractionate Pb, Cd, Zn, and Cu using short sequential fractionation plans. The relationship of soil pH and organic matter and its effect on the redistribution of these metals were estimated. The results indicated that the acid-soluble metals decreased while the fraction bound to organic matter increased compared to untreated pots. The increase in the organic matter metal-bound was mostly at the expense of the decrease in the acid extractable and Fe/Mn bound ones. The highest application of PB increased the organically bound fraction of Pb, Cd, Zn, and Cu (62, 61, 34, and 61%, respectively), while the BB increased them (61, 49, 42, and 22%, respectively) over the control. Meanwhile, Fe/Mn oxides bound represents the large portion associated with zinc and copper. Concerning soil organic matter (SOM) and soil pH, as potential tools to reduce the risk of the target metals, a significant positive correlation was observed with acid-soluble extractable metal, while a negative correlation was obtained with organic matter-bound metal. The principal component analysis (PCA) shows that the total variance represents 89.7% for the TCPL-extractable and HMs forms and their relation to pH and SOM, which confirms the positive effect of the pH and SOM under PB and BB treatments on reducing the risk of the studied metals. The mobility and bioavailability of these metals and their geochemical forms widely varied according to pH, soil organic matter, biochar types, and application rates. As an environmentally friendly and economical material, biochar emphasizes its importance as a tool that makes the soil more suitable for safe cultivation in the short term and its long-term sustainability. This study proves that it reduces the mobility of HMs, their environmental risks and contributes to food safety. It also confirms that performing more controlled experiments, such as a pot, is a disciplined and effective way to assess the suitability of different types of biochar as soil modifications to restore HMs contaminated soil via controlling the mobilization of these minerals.

scholarly journals Adsorption of Heavy Metals on Soil Collected from Lixisol of Typical Karst Areas in the Presence of CaCO3 and Soil Clay and Their Competition Behavior

2020 ◽  
Vol 12 (18) ◽  
pp. 7315
Author(s):  
Guandi He ◽  
Zhenming Zhang ◽  
Xianliang Wu ◽  
Mingyang Cui ◽  
Jiachun Zhang ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Soil Sample ◽  
Soil Ph ◽  
Clay Content ◽  
Guizhou Province ◽  
Metal Exposure ◽  
Risk Area ◽  
High Risk Area ◽  
Ph Values ◽  
Pseudo Second Order

The content of heavy metals in the soil in Guizhou Province, which is a high-risk area for heavy metal exposure, is significantly higher than that in other areas in China. Therefore, the objective of this study was to evaluate the ability of CaCO3 and clay to accumulate heavy metals in topsoil sample collected from Lixisol using the method of indoor simulation. The results showed that the contents of Cu, Zn, Cd, Cr, Pb, Hg and As in the soil sample were 10.8 mg/kg, 125 mg/kg, 0.489 mg/kg, 23.5 mg/kg, 22.7 mg/kg, 58.3 mg/kg and 45.4 mg/kg, respectively. The soil pH values increased with the CaCO3 concentration in the soil, and the fluctuation of the soil pH values was weak after the CaCO3 concentrations reached 100 g/kg. The adsorption capacity of lime soil increased by approximately 10 mg/kg on average, and the desorption capacity decreased by approximately 300 mg/kg on average. The desorption of all heavy metals in this study did not change with increasing clay content. Pseudo-second-order kinetics were more suitable for describing the adsorption kinetics of heavy metals on the soil material, as evidenced by the higher R2 value. The Freundlich model can better describe the adsorption process of As on lime soil. The process of As, Cr, Cd and Hg adsorption on the soil sample was spontaneous and entropy-driven. Additionally, the process of Cu and Pb adsorption on the soil materials was spontaneous and enthalpy-driven. Generally, the adsorption and desorption of heavy metals in polluted soil increased and decreased, respectively, with increasing CaCO3 content. The effect of calcium carbonate on the accumulation of heavy metals in soil was greater than that of clay. In summary, CaCO3 and pH values in soil can be appropriately added in several areas polluted by heavy metals to enhance the crop yield and reduce the adsorption of heavy metals in soils.

scholarly journals Soil mite communities (Acari: Mesostigmata, Oribatida) as bioindicators for environmental conditions from polluted soils

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Minodora Manu ◽  
Viorica Honciuc ◽  
Aurora Neagoe ◽  
Raluca Ioana Băncilă ◽  
Virgil Iordache ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Soil Ph ◽  
Abiotic Factors ◽  
Mite Species ◽  
Point Of View ◽  
Vegetation Coverage ◽  
Tailing Pond ◽  
Soil Humidity ◽  
Biotic Factor ◽  
Mite Communities

AbstractAn anthropic ecosystem from Romania was investigated from acarological, vegetation and chemical point of view. The community structures of two groups of mites were studied (Acari: Mesostigmata, Oribatida) from a tailing pond, using transect method, in correlation with concentrations of heavy metals (As, Cu, Pb, Ni, Mn and Zn), with abiotic factors (altitude, aspect, soil temperature, soil humidity, soil pH) and biotic factor (vegetation coverage). Taking into account the mite communities, in total, 30 mite species were identified, with 1009 individuals and 18 immatures (10 species with 59 individuals, 5 immatures of Mesostigmata and 20 species with 950 individuals, 13 immatures of Oribatida). The investigated habitats from the tailing pond were grouped in five transects, with different degree of pollution, based on total metal loads. Taking into account of the connection between mites communities, abiotic factors and heavy metals, each transect were characterized through specific relationship. Using multivariate statistical analysis, we revealed that the occurrence of some Oribatida species was strongly correlated with vegetation coverage, soil pH and soil humidity, though concentrations of Cu, As, Mn, Ni and Zn also had an influence. Pb and Zn concentrations were shown to influence the occurrence of Mesostigmata mites. The heterogeneity of mites species richness at 2 m2 scale was correlated with a metric related to the heterogeneity of heavy metals at the same scale.

The pH effect on the detection of heavy metals in wastewater by laser-induced breakdown spectroscopy coupled with a phase transformation method

2020 ◽  
Vol 35 (1) ◽  
pp. 198-203 ◽  
Author(s):  
Shixiang Ma ◽  
Yun Tang ◽  
Yuyang Ma ◽  
Daming Dong ◽  
Lianbo Guo ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Phase Transformation ◽  
Industrial Wastewater ◽  
Ph Effect ◽  
Transformation Method ◽  
Metal Particles ◽  
Laser Induced Breakdown Spectroscopy ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown

Heavy metal particles in water are mainly derived from acidic industrial wastewater. The pH effect on the detection of toxic metals in wastewater by LIBS-PT method was investigated.

Using Regional Characteristic Amendments to Modify Heavy Metal Contaminated Soil of Guangxi, South China

2014 ◽  
Vol 675-677 ◽  
pp. 654-657
Author(s):  
Qiu Jun Li ◽  
Rui Jie Zhang ◽  
Ying Hui Wang ◽  
Da Rong Li
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Organic Matter ◽  
Soil Ph ◽  
South China ◽  
Contaminated Soil ◽  
Red Mud ◽  
Great Influence ◽  
Regional Characteristic ◽  
Coconut Husk

In this study we compared the efficiency of four kinds of amendments (silkworm excrement, coconut husk, red mud, sepiolite) and their mixtures to immobilize the heavy metals present in a contaminated acidic soil (Pb:420 mg ·kg−1; Zn :334 mg· kg−1) and to influence several enzymatic activities. The results showed that, silkworm excrement, coconut husk and their mixtures, which had high pH and/or high content of organic matter, reduced exchangeable Pb in the soil by 18% to 46%, and reduced available Zn by 24% to 35%, which was more efficacious than single sepiolite. The complex of silkworm excrement and red mud had a great influence on soil pH, while coconut husk increased the content of organic matter in soil significantly.

scholarly journals THE ROLE OF PH IN HEAVY METAL CONTAMINATION OF URBAN SOIL

2014 ◽  
Vol 22 (4) ◽  
pp. 311-318 ◽  
Author(s):  
Asta KAZLAUSKAITĖ-JADZEVIČĖ ◽  
Jonas VOLUNGEVIČIUS ◽  
Virginija GREGORAUSKIENĖ ◽  
Saulius MARCINKONIS
Keyword(s):  
Heavy Metals ◽  
Soil Ph ◽  
Urban Soil ◽  
Heavy Metal Contamination ◽  
Agricultural Soils ◽  
Chemical Elements ◽  
Chemical Reactivity ◽  
Atomic Emission ◽  
Parent Material ◽  
Ph Level

The aim of this study to assess interdependence between urban soil pH and its accumulation of heavy metals. The article meant to be a contribution to a better knowledge of peculiarities and diagnostics of urban soil and its anthropogenic transformation. The hypothesis assumes that relationship between urban soil pH and its accumulation of heavy metals may be determined by the origin and age of parent material as well as the nature and degree of the anthropogenic impact. The spatial variability of topsoil pH level was performed in 100 points in eldership of Šnipiškės of the city Vilnius. Laboratory analysis was based on ISO 10390:2005. Samples were collected from 20 cm topsoil layer in the same sampling points where have been analysed concentrations of topsoil chemical elements using optical atomic emission spectrophotometry. The contamination of urban soils exhibits somewhat different compared to agricultural soils. In contradiction to earlier studies in Lithuanian agricultural soils where strong correlation between soil pH and Cr, Cd, Pb, Ni, Cu and Zd found, the conducted analysis shows a statistically reliable, but very weak (<0.3) correlation between the soil pH and concentration of contaminants. The proof to this correlation is provided by an existing relationship between pH and the concentration of copper (r = 0.20), mercury (r = 0.15), strontium (r = –0.12) and the overall contamination index (r = 0.12). The applied statistical analysis, however, failed to reveal the nature of interdependence between the soil pH and its contamination with studied heavy metals there concentration of contaminant chemical elements depends on the pH range of the soil and, conversely, the chemical reactivity of the soil changes affect on the concentration of studied chemical elements.

scholarly journals Binding of Industrial Deposits of Heavy Metals and Arsenic in the Soil by 3-Aminopropyltrimethoxysilane

2014 ◽  
Vol 16 (2) ◽  
pp. 12-15 ◽  
Author(s):  
Piotr Grzesiak ◽  
Joanna Łukaszyk ◽  
Grzegorz Schroeder ◽  
Joanna Kurczewska
Keyword(s):  
Heavy Metals ◽  
Soil Ph ◽  
Soil Stabilization ◽  
Industrial Area ◽  
Copper Smelter ◽  
Total Binding ◽  
Stabilization Technique ◽  
Heavy Metals And Arsenic ◽  
Research Studies

Abstract The results of the research studies concerning binding of heavy metals and arsenic (HM+As), occurring in soils affected by emissions from Głogów Copper Smelter and Refinery, by silane nanomaterial have been described. The content of heavy metals and arsenic was determined by AAS and the effectiveness of heavy metals and arsenic binding by 3-Aminopropyltrimethoxysilane was examined. The total leaching level of impurities in those fractions was 73.26% Cu, 74.7% – Pb, 79.5% Zn, 65.81% – Cd and 55.55% As. The studies demonstrated that the total binding of heavy metals and arsenic with nanomaterial in all fractions was about as follows: 20.5% Cu, 9.5% Pb, 7.1% Zn, 25.3% Cd and 10.89% As. The results presented how the safety of food can be cultivated around industrial area, as the currently used soil stabilization technique of HM by soil pH does not guarantee their stable blocking in a sorptive complex.

scholarly journals Fractionation, Characterization and Speciation of Lead in the Industrially Polluted Soils of Tejgaon Area of Bangladesh and Lead Pollution of Associated Plants and Water

1970 ◽  
Vol 46 (3) ◽  
pp. 277-290
Author(s):  
MN Mondol ◽  
AS Chamon ◽  
B Faiz ◽  
MH Rahman ◽  
SF Elahi
Keyword(s):  
Organic Matter ◽  
Soil Ph ◽  
Rainy Season ◽  
Organic Matter Content ◽  
Industrial Area ◽  
Dry Season ◽  
Water Soluble ◽  
City Centre ◽  
Soil Fractions ◽  
Tolerable Level

The Tejgaon industrial area is located within the Dhaka Municipality area and about 5 km north of the city centre. At Tejgaon soil pH was around neutrality (mean 6.73) although the minimum value was 5.3 and the maximum 7.6. High buffering capacity resulting from high soil organic matter content (4.87-11.55%) probably influenced soil pH to a neutral value. Electrical conductivity (EC) (25-551 μS), organic matter (OM) (4.87-11.55%) and nitrogen (N) contents were also influenced by the industrial wastes and effluents of the factories. The average Pb concentrations (mg/kg) in different soil fractions were 7.80, 21.85, 56.15 and 130.29 and 11.42, 20.27, 40.33 and 95.08 in water-soluble, NH4OAc extractable, DTPA ( Dietheline-Triamine-Penta-Acetic acid) extractable and total fractions during dry (January) and rainy seasons (September) respectively. Comparing 1st (rainy season) and 2nd (dry season) sampling data, Pb concentrations in different soil fractions were higher in the 2nd sampling data. Concentration of total Pb in soils during 1st sampling were found above the natural background level with few exceptions. Only 4% of total Pb (=20 mg kg-1) samples were in the normal range during wet season. Lead concentration in the group of tolerable level was 58% (>20-<=100 mg kg-1) and 38% (>=100 mg kg-1) were found in the group of in excess of tolerable level during 1st sampling. On the other hand 62.5% (>=100 mg kg-1) were found in the group of in excess of tolerable level (0.01 mg kg-1 Pb) during dry season. In case of water samples, total Pb concentration in the rainy season, all samples were found in the group of in excess of tolerable level during 1st sampling. Plant samples were found to contain untolerable total Pb (>20 mg kg-1) during rainy and dry seasons, respectively. Key words: Speciation; Tejgaon soil; Industrial area; Lead. DOI: http://dx.doi.org/10.3329/bjsir.v46i3.9032 BJSIR 2011; 46(3): 277-290

scholarly journals HEAVY METALS POLLUTION OF WHEAT FIELDS (SOIL AND LEAVES) SAMPLED FROM BASRAH AND MAYSAN PROVINCES

2020 ◽  
Vol 17 (35) ◽  
pp. 315-326
Author(s):  
Qusai Hattab MADHI ◽  
Mohammed Hamza ABASS ◽  
Abdulnabi Abdul Ameer MATROOD
Keyword(s):  
Heavy Metals ◽  
Soil Ph ◽  
Negative Correlation ◽  
Agricultural Soils ◽  
Significant Negative Correlation ◽  
Soil Characteristics ◽  
Lead Content ◽  
Significant Difference ◽  
Heavy Metals Pollution ◽  
Wheat Leaves

This study was conducted to estimate the level of some heavy metals, mainly Lead (Pb), cadmium (Cd), chromium (Cr) and cobalt (Co) in the soil and wheat leaves of some wheat fields in Basra and Maysan province; the sampling areas were Al-Qurna, Al-Madinah, Al-Amara, Kumit, Ali Al-Sharqi, and Ali Al-Gharbi. It was performed the analysis using the Flame Atomic Spectrophotometer. The results indicated an increase in the concentrations of above mentioned these heavy metals in all examined areas; the levels in agricultural soils were found to be exceeding the internationally permissible limits according to EU-2000 standards, the highest levels of pollution were observed at Al- Qurna site with significant differences than other sites for both available and total HMs concentrations in soils. Indicating that the arrangement of the metals according to their available concentrations in the analyzed soil was as follows: lead (21.32 )˃ cobalt (14.63) ˃ chromium (11.06) ˃ cadmium (1.15) as mg/Kg of soil. Additionally, results showed that the highest lead content in the wheat leaves was examined in the Qurna fields (0.175 mg/kg), followed by Amara with a concentration of 0.136 mg/kg. The lowest concentration of lead was observed in wheat leaves in the Kumit fields (0.007 mg/kg). In terms of Cd concentration in wheat leaves, the highest level was observed in Al-Qurna, with a significant difference from other fields, reaching 0.009 mg/kg. The lowest concentration of this HM was recorded in Ali Al-Gharbi, which reached 0.002 mg/kg. The results of the correlation between the available concentration of heavy metals elements and soil characteristics revealed a significant correlation between the soil pH and lead, cadmium, and chromium available concentrations, whereas no correlation with cobalt and a significant correlation between soil EC and lead was observed and a highly significant negative correlation with the cobalt. Results proved the high levels of pollution in all examined areas in Basra and Maysan provinces.

scholarly journals Influence of wood ash recycling on chemical and biological condition of forest Arenosols

2006 ◽  
Vol 52 (Special Issue) ◽  
pp. S79-S86 ◽  
Author(s):  
R. Ozolincius ◽  
K. Armolaitis ◽  
A. Raguotis ◽  
I. Varnagiryte ◽  
J. Zenkovaite
Keyword(s):  
Heavy Metals ◽  
Forest Management ◽  
Soil Ph ◽  
Forest Floor ◽  
Sustainable Forest Management ◽  
Wood Ash ◽  
Nitrogen Fertilizers ◽  
Biological Condition ◽  
Set Up ◽  
And Control

The investigations were conducted in the frame of EU Research project Wood for Energy – a Contribution to the Development of Sustainable Forest Management (2001–2005). The integrated wood ash experiment was set up in a 38-year-old Scots pine (Pinus sylvestris L.) stand on Arenosols in SW part of Lithuania. Raw (not hardened) wood ash and nitrogen fertilizers were applied in 6 variants: 1.25 t ash/ha; 2.5 t ash/ha; 5.0 t ash/ha; 180 kg N/ha; 2.5 t ash + 180 kg N/ha and control (no treatment). The changes of soil pH, the content of some nutrients, heavy metals in Arenosols and soil solution, the abundance of ammonifiers, nitrifiers and denitrifiers in forest floor and mineral topsoil after the application of wood ash are presented and discussed in this paper.

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