scholarly journals Phenomenological Modelling of Non-Monotonous Shear Viscosity Functions

2004 ◽  
Vol 14 (2) ◽  
pp. 82-88 ◽  
Author(s):  
J. David ◽  
P. Filip
Keyword(s):  
Experimental Data ◽  
Shear Rate ◽  
Phenomenological Models ◽  
Shear Viscosity ◽  
Wide Class ◽  
Extreme Points ◽  
Rheological Behaviour ◽  
Viscosity Functions ◽  
Materials Used ◽  
The Individual

AbstractThe aim of this paper is to present a new phenomenological rheological model suitable for the description of a wide class of viscoelastic fluids. Classical phenomenological models predict the relation shear viscosity vs. shear rate (or shear stress) for shear-thinning (or thickening) materials exhibiting smooth monotonous passage from the first - upper (lower) - Newtonian plateau to the second - lower (upper) - one. However, present state of non-Newtonian materials used in practice (ranging from aqueous surfactant solutions, bituminous materials, associative polymers, polymer thickeners, lacquers and gels, to some special disperse systems, etc.) evokes the need to describe this - for many materials non-monotonous - relation in the corresponding way, i.e. through the sufficiently simple phenomenological model with a moderate number of parameters. A six-parameter model enabling description of not only monotonous but also non-monotonous course of shear viscosity function against shear rate (stress) is proposed including physical characterisation of the parameters. This model describes not only extreme points (maximum or minimum) but also a possible appearance of intermediate Newtonian plateau or its indication. The meaning and influence of the individual six parameters is documented on the experimental data published in the literature. There is a good agreement of the model proposed with many different experimental data representing different rheological behaviour. The applicability of this model for a wide class of viscoelastic materials is its principal advantage over the hitherto published phenomenological models.

Rheological Properties and Extrusion Performance Evaluation of Silica Filled Epoxidized Natural Rubber (ENR) Compounds as Compared to Natural Rubber/Butadiene Rubber (NR/BR) Compound

2016 ◽  
Vol 1133 ◽  
pp. 236-240
Author(s):  
Teku Zakwan Zaeimoedin ◽  
Mazlina Mustafa Kamal ◽  
Ahmad Kifli Che Aziz
Keyword(s):  
Performance Evaluation ◽  
Shear Rate ◽  
Natural Rubber ◽  
Rheological Properties ◽  
Shear Viscosity ◽  
Rheological Behaviour ◽  
Butadiene Rubber ◽  
Melt Mixing ◽  
Lower Shear ◽  
Internal Mixer

In tyre industries, rheological and processability properties of rubber and polymer are great of importance since there are alot extrusion processes involved in the tyre manufacturing other than calendaring and moulding processes. Uniformity and consistency in the flow behaviour and processability of rubber are essential in providing the solution to the rubber industries in order to improve productivity, products quality and energy conservation. In this works, effects of silane coupling agent on rheological behaviour and extrusion performance of silica filled ENR tread compounds were studied and compared to NR/BR tread compound. The compounds were prepared by melt mixing in tangential internal mixer, while the rheological properties of compounds were determined by Capillary Rheometer, Cure Rheometer and Mooney viscometer. The compound were further examined for its extrudability performance evaluation by extruded the rubber through 30mm cold feed extruder machine using ASTM Extrusion Die, ‘Garvey’ type. Results showed that, ENR/silica compounds exhibit higher shear viscosity curves as compared to NR/BR compound at low shear rate regime. However an opposite trend was observed towards high shear rate regime tested which ENR/silica compounds gave slightly lower shear viscosity curve compared to NR/BR compound. As for extrudability performance evaluation, NR/BR compound gave better extrusion characteristics and appearance as compared to ENR/silica compounds.

Study on the Rheological Behaviour of Sisal Fibre/HDPE Composites with Flame Retardant

2017 ◽  
Vol 737 ◽  
pp. 307-312
Author(s):  
Apaipan Rattanapan
Keyword(s):  
Shear Rate ◽  
Flame Retardant ◽  
Magnesium Hydroxide ◽  
Shear Viscosity ◽  
Flame Retardants ◽  
Rheological Behaviour ◽  
Elongation Rate ◽  
Ammonium Polyphosphate ◽  
Sisal Fibre ◽  
Elongation Viscosity

The rheological behaviour of sisal fibre/HDPE composites containing two types of flame retardants as magnesium hydroxide and ammonium polyphosphate was studied using a capillary rheometer. The mass ratio of HDPE to sisal fibre was set as 20 phr. Flame retardants were added at 10, 20 and 30 phr. Results showed that the composites exhibited pseudoplastic behaviour as the shear viscosity decreased with increasing shear rate. Shear stress and real shear viscosity increased with increasing flame retardant, with magnesium hydroxide giving higher values than ammonium polyphosphate. Therefore, magnesium hydroxide had a marked effect on the processing power, while ammonium polyphosphate did not greatly affect the shear viscosity of the composites. An increase in elongation rate reduced the elongation viscosity. The flame retardant contents had no significant effect on the elongation viscosity at high elongation rate. The materials showed increased extrudate swell with increasing apparent shear rate, but this significantly decreased with the addition of flame retardant. The power law index (n) for all composites was less than 1 and the flow consistency index K was higher for composites with flame retardant than those without. Moreover, magnesium hydroxide was more effective than ammonium polyphosphate causing an increase in the K value.

scholarly journals Processing the Vane Shear Flow Data from Couette Analogy

2008 ◽  
Vol 18 (3) ◽  
pp. 34037-1-34037-6 ◽  
Author(s):  
Patrice Estellé ◽  
Christophe Lanos ◽  
Arnaud Perrot ◽  
Sofiane Amziane
Keyword(s):  
Experimental Data ◽  
Shear Stress ◽  
Shear Rate ◽  
Shear Flow ◽  
Rotational Velocity ◽  
Rheological Behaviour ◽  
Bingham Fluid ◽  
Flow Data ◽  
Velocity Data ◽  
Torsional Flow

Abstract A new procedure is described to convert the vane torque and rotational velocity data into shear stress vs shear rate relationships. The basis of the procedure consists in considering locally the sheared material as a Bingham fluid and computing a characteristic shear rate from Couette analogy. The approach is first applied to experimental vane data of Newtonian fluid, then used to process vane experimental data of non-Newtonian and yield stress materials. Results, which are favourably compared with torsional flow, show that the approach correctly predicts the rheological behaviour of the materials investigated.

Study of potential curves by UHF type methods. CH4 molecule and its dissociation products

1986 ◽  
Vol 51 (4) ◽  
pp. 731-737
Author(s):  
Viliam Klimo ◽  
Jozef Tiňo
Keyword(s):  
Experimental Data ◽  
Quantum Chemistry ◽  
High Energy ◽  
Basis Set ◽  
Electronic Correlation ◽  
Exact Methods ◽  
Energy Parameters ◽  
Bond Functions ◽  
The Individual ◽  
Potential Curves

Geometry and energy parameters of the individual dissociation intermediate steps of CH4 molecule, parameters of the barrier to linearity and singlet-triplet separation of the CH2 molecule have been calculated by means of the UMP method in the minimum basis set augmented with the bond functions. The results agree well with experimental data except for the geometry of CH2(1A1) and relatively high energy values of CH(2II) and CH2(1A1) where the existence of two UHF solutions indicates a necessity of description of the electronic correlation by more exact methods of quantum chemistry.

scholarly journals Quantification of shear viscosity and wall slip velocity of highly concentrated suspensions with non-Newtonian matrices in pressure driven flows

2021 ◽  
Author(s):  
Patrick Wilms ◽  
Jan Wieringa ◽  
Theo Blijdenstein ◽  
Kees van Malssen ◽  
Reinhard Kohlus
Keyword(s):  
Shear Stress ◽  
Liquid Phase ◽  
Shear Rate ◽  
Shear Viscosity ◽  
Slip Velocity ◽  
Volume Fraction ◽  
Solid Volume Fraction ◽  
Wall Slip ◽  
Flow Index ◽  
Concentrated Suspensions

AbstractThe rheological characterization of concentrated suspensions is complicated by the heterogeneous nature of their flow. In this contribution, the shear viscosity and wall slip velocity are quantified for highly concentrated suspensions (solid volume fractions of 0.55–0.60, D4,3 ~ 5 µm). The shear viscosity was determined using a high-pressure capillary rheometer equipped with a 3D-printed die that has a grooved surface of the internal flow channel. The wall slip velocity was then calculated from the difference between the apparent shear rates through a rough and smooth die, at identical wall shear stress. The influence of liquid phase rheology on the wall slip velocity was investigated by using different thickeners, resulting in different degrees of shear rate dependency, i.e. the flow indices varied between 0.20 and 1.00. The wall slip velocity scaled with the flow index of the liquid phase at a solid volume fraction of 0.60 and showed increasingly large deviations with decreasing solid volume fraction. It is hypothesized that these deviations are related to shear-induced migration of solids and macromolecules due to the large shear stress and shear rate gradients.

A correlation to predict the performance characteristics of centrifugal pumps handling slurries

1997 ◽  
Vol 211 (2) ◽  
pp. 147-157 ◽  
Author(s):  
K A Kazim ◽  
B Maiti ◽  
P Chand
Keyword(s):  
Experimental Data ◽  
Particle Size ◽  
Suspended Solids ◽  
Reduction Factor ◽  
Performance Characteristics ◽  
Centrifugal Pumps ◽  
Pump Performance ◽  
New Correlation ◽  
Effect Of Particle Size ◽  
The Individual

Centrifugal pumps are being used increasingly for transportation of slurries through pipelines. To design a slurry handling system it is essential to have a knowledge of the effects of suspended solids on the pump performance. A new correlation to predict the head reduction factor for centrifugal pumps handling solids has been developed. This correlation takes into account the individual effect of particle size, particle size distribution, specific gravity and concentration of solids on the centrifugal pump performance characteristics. The range of validity of the correlation has been verified by experiment and by using experimental data available from the literature. The present correlation shows better agreement with the experimental data than existing correlations.

scholarly journals Analysis of Equation of State for Carbon Nanotubes

2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
Jeewan Chandra ◽  
Pooja Kapri Bhatt ◽  
Kuldeep Kholiya
Keyword(s):  
Experimental Data ◽  
Carbon Nanotubes ◽  
Thermal Expansion ◽  
Carbon Nanotube ◽  
Equation Of State ◽  
Compression Behavior ◽  
Nanotube Bundles ◽  
The Individual

Compression behavior of carbon nanotube bundles and individual carbon nanotubes within the bundle has been studied by using the Suzuki, Shanker, and usual Tait formulations. It is found that the Suzuki formulation is not capable of explaining the compression behavior of nanomaterials. Shanker formulation slightly improves the results obtained by the Suzuki formulation, but only usual Tait’s equation (UTE) of state gives results in agreement to the experimental data. The present study reveals that the product of bulk modules and the coefficient of volume thermal expansion remain constant for carbon nanotubes. It has also been found that the individual carbon nanotubes are less compressible than bundles of carbon nanotubes.

Forced Response Sensitivity of a Mistuned Rotor From an Embedded Compressor Stage

2015 ◽  
Author(s):  
Fanny M. Besem ◽  
Robert E. Kielb ◽  
Nicole L. Key
Keyword(s):  
Experimental Data ◽  
Forced Response ◽  
Symmetric System ◽  
Response Analysis ◽  
Cfd Simulations ◽  
Forcing Function ◽  
Wear And Tear ◽  
The Individual ◽  
The Impact ◽  
Interblade Phase Angle

The frequency mistuning that occurs due to manufacturing variations and wear and tear of the blades can have a significant effect on the flutter and forced response behavior of a blade row. Similarly, asymmetries in the aerodynamic or excitation forces can tremendously affect the blade responses. When conducting CFD simulations, all blades are assumed to be tuned (i.e. to have the same natural frequency) and the aerodynamic forces are assumed to be the same on each blade except for a shift in interblade phase angle. The blades are thus predicted to vibrate at the same amplitude. However, when the system is mistuned or when asymmetries are present, some blades can vibrate with a much higher amplitude than the tuned, symmetric system. In this research, we first conduct a deterministic forced response analysis of a mistuned rotor and compare the results to experimental data from a compressor rig. It is shown that tuned CFD results cannot be compared directly with experimental data because of the impact of frequency mistuning on forced response predictions. Moreover, the individual impact of frequency, aerodynamic, and forcing function perturbations on the predictions is assessed, leading to the conclusion that a mistuned system has to be studied probabilistically. Finally, all perturbations are combined and Monte-Carlo simulations are conducted to obtain the range of blade response amplitudes that a designer could expect.

scholarly journals Three-dimensional data-tracking simulations of sprinting using a direct collocation optimal control approach

PeerJ ◽  
2021 ◽  
Vol 9 ◽  
pp. e10975
Author(s):  
Nicos Haralabidis ◽  
Gil Serrancolí ◽  
Steffi Colyer ◽  
Ian Bezodis ◽  
Aki Salo ◽  
...  
Keyword(s):  
Experimental Data ◽  
Reaction Force ◽  
Three Dimensional ◽  
Contact Model ◽  
Model Parameters ◽  
Ground Contact ◽  
Control Approach ◽  
Average Percentage ◽  
Data Tracking ◽  
The Individual

Biomechanical simulation and modelling approaches have the possibility to make a meaningful impact within applied sports settings, such as sprinting. However, for this to be realised, such approaches must first undergo a thorough quantitative evaluation against experimental data. We developed a musculoskeletal modelling and simulation framework for sprinting, with the objective to evaluate its ability to reproduce experimental kinematics and kinetics data for different sprinting phases. This was achieved by performing a series of data-tracking calibration (individual and simultaneous) and validation simulations, that also featured the generation of dynamically consistent simulated outputs and the determination of foot-ground contact model parameters. The simulated values from the calibration simulations were found to be in close agreement with the corresponding experimental data, particularly for the kinematics (average root mean squared differences (RMSDs) less than 1.0° and 0.2 cm for the rotational and translational kinematics, respectively) and ground reaction force (highest average percentage RMSD of 8.1%). Minimal differences in tracking performance were observed when concurrently determining the foot-ground contact model parameters from each of the individual or simultaneous calibration simulations. The validation simulation yielded results that were comparable (RMSDs less than 1.0° and 0.3 cm for the rotational and translational kinematics, respectively) to those obtained from the calibration simulations. This study demonstrated the suitability of the proposed framework for performing future predictive simulations of sprinting, and gives confidence in its use to assess the cause-effect relationships of technique modification in relation to performance. Furthermore, this is the first study to provide dynamically consistent three-dimensional muscle-driven simulations of sprinting across different phases.

scholarly journals FEM Analysis of Various Multilayer Structures for CMOS Compatible Wearable Acousto-Optic Devices

Sensors ◽  
2021 ◽  
Vol 21 (23) ◽  
pp. 7863
Author(s):  
Mehwish Hanif ◽  
Varun Jeoti ◽  
Mohamad Radzi Ahmad ◽  
Muhammad Zubair Aslam ◽  
Saima Qureshi ◽  
...  
Keyword(s):  
Coupling Coefficient ◽  
Figure Of Merit ◽  
Electromechanical Coupling ◽  
Piezoelectric Materials ◽  
Fem Analysis ◽  
Film Structure ◽  
Multilayer Structures ◽  
Electromechanical Coupling Coefficient ◽  
Materials Used ◽  
The Individual

Lately, wearable applications featuring photonic on-chip sensors are on the rise. Among many ways of controlling and/or modulating, the acousto-optic technique is seen to be a popular technique. This paper undertakes the study of different multilayer structures that can be fabricated for realizing an acousto-optic device, the objective being to obtain a high acousto-optic figure of merit (AOFM). By varying the thicknesses of the layers of these materials, several properties are discussed. The study shows that the multilayer thin film structure-based devices can give a high value of electromechanical coupling coefficient (k2) and a high AOFM as compared to the bulk piezoelectric/optical materials. The study is conducted to find the optimal normalised thickness of the multilayer structures with a material possessing the best optical and piezoelectric properties for fabricating acousto-optic devices. Based on simulations and studies of SAW propagation characteristics such as the electromechanical coupling coefficient (k2) and phase velocity (v), the acousto-optic figure of merit is calculated. The maximum value of the acousto-optic figure of merit achieved is higher than the AOFM of all the individual materials used in these layer structures. The suggested SAW device has potential application in wearable and small footprint acousto-optic devices and gives better results than those made with bulk piezoelectric materials.

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