scholarly journals Comparative study on mechanisms for improving mechanical properties and microstructure of cement paste modified by different types of nanomaterials

2021 ◽  
Vol 10 (1) ◽  
pp. 370-384
Author(s):  
Tao Meng ◽  
Kanjun Ying ◽  
Xiufen Yang ◽  
Yongpeng Hong
Keyword(s):  
Mechanical Properties ◽  
Cement Paste ◽  
Cement Hydration ◽  
Inhibitory Effect ◽  
Test Methods ◽  
Cement Clinker ◽  
Hydration Products ◽  
Nucleation Effect ◽  
Nano Graphene ◽  
Nano Titanium Dioxide

Abstract Filling and nucleation are the mechanisms of modifying cement paste with nanomaterials, as investigated by previous studies, and are difficult to reflect the different effects of nanomaterials, especially on the changes of cement clinker and hydration products in the cement hydration process. In this study, the mechanisms of modifying cement paste with nano-calcium carbonate (NC), nano-graphene oxide (NG), nano-silica (NS), and nano-titanium dioxide (NT) were investigated by determining the mechanical properties of cement paste treated with nanomaterials and analysing the changes in the cement clinker (tricalcium silicate and dicalcium silicate), hydration products (portlandite and ettringite), and microstructure through many micro-test methods. The results indicate that the incorporation of nanomaterials could improve the early strength of cement paste specimens due to more consumption of cement clinker. Meanwhile, different nanomaterials promote the formation of different hydration products at early ages. C–A–S–H gel, flower-like ettringite, and C–S–H seeds are widely distributed in the cement paste with the incorporation of NC, NG, and NS, respectively. NT exhibits insignificant nucleation effect and has inhibitory effect on portlandite precipitation. This study provides key insights into the mechanism of nanomaterials from the perspective of cement hydration, which may promote the further research and application of nanomaterials in the cement and concrete industries.

scholarly journals Effect of Delaminated MXene (Ti3C2) on the Performance of Cement Paste

2019 ◽  
Vol 2019 ◽  
pp. 1-8 ◽  
Author(s):  
Jianping Zhu ◽  
Genshen Li ◽  
Chunhua Feng ◽  
Libo Wang ◽  
Wenyan Zhang
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Cement Paste ◽  
Cement Hydration ◽  
Hydration Heat ◽  
Hydration Process ◽  
Cement Matrix ◽  
Cement Composites ◽  
Hydrated Cement ◽  
Hydration Products

Delaminated MXene was incorporated into cement to improve the properties of cement composites, and its effects on the hydration process, microstructures, and mechanical properties were investigated, respectively. The investigation results showed that delaminated MXene was well-dispersed in the cement matrix and significantly reinforced the compressive strength of cement, especially when the addition is 0.01 wt%. Meanwhile, the total hydration heat of cement hydration and the quantity of hydration products were increased with the addition of delaminated MXene. In addition, the formation of HD C-S-H gel was promoted, and the microstructure of hydrated cement became more compact.

scholarly journals Study of the mechanical-electrical-magnetic properties and the microstructure of three-layered cement-based absorbing boards

2020 ◽  
Vol 59 (1) ◽  
pp. 160-169
Author(s):  
Yafei Sun ◽  
Yueyue Peng ◽  
Tianshu Zhou ◽  
Hongwei Liu ◽  
Peiwei Gao
Keyword(s):  
Mechanical Properties ◽  
Magnetic Properties ◽  
Carbon Fiber ◽  
Carbon Black ◽  
Mechanical Strength ◽  
Cement Hydration ◽  
Hydration Products ◽  
Frequency Range ◽  
Cement Slurry ◽  
Nano Graphene

AbstractIn this paper, a three-layered cement-based wave-absorbing board is designed and prepared by mixing wave-absorbing fillers such as nano-Si3N4, multi-layer nano graphene platelets (NGPs), nano-Ni, carbon fiber (CF) and carbon black (CB) into cement slurry. The effect of the amount of wave-absorbing fillers on the mechanical properties, resistivity and wave-absorbing reflectivity of cement slurry is studies. The microstructure of NGPs, nano-Si3N4 and the wave-absorbing board are characterized by TEM and SEM. Research shows that low content of NGPs and other wave-absorbing fillers can significantly reduce the resistivity of cement slurry and improve its mechanical strength, and dense massive crystals are precipitated in the cement hydration products. The reflectivity test reveals that in the frequency range of 2~18 GHz, the minimum reflectivity of the three-layered cement-based wave absorbing board reaches −18.8 dB, and the maximum bandwidth less than −10 dB reaches 15.3 GHz. This study can serve as reference for the preparation of new three-layered cement-based wave absorbing boards.

scholarly journals Monitoring of Early and Late Age Hydration Products of Volcanic Ash Blended Cement Paste

Proceedings ◽  
2019 ◽  
Vol 34 (1) ◽  
pp. 9
Author(s):  
Joseph ◽  
Al-Bahar ◽  
Chakkamalayath ◽  
Al-Arbeed ◽  
Rasheed
Keyword(s):  
Portland Cement ◽  
Cement Paste ◽  
Volcanic Ash ◽  
Cement Hydration ◽  
Blended Cement ◽  
Sustainable Construction ◽  
Hydration Products ◽  
N2 Adsorption ◽  
Complete Replacement ◽  
Blended Cement Paste

One of the major concerns of concrete industries is to develop materials that consume less natural virgin resources and energy to make sustainable construction practices. Efforts have been made and even implemented to use the waste/by product materials such as fly ash, slag, silica fume, and natural pozzolana as a partial or complete replacement for Portland cement in concrete mixtures. The deterioration of concrete structures in the existing hot and cold climates of Gulf Cooperation Council countries, along with chloride and sulphate attack, demands the use of pozzolanic materials for concrete construction. Volcanic ash incorporated cement based concretes are known for its better performance in terms of strength and durability in harsh marine environments. Understanding the cement hydration process and characterizing the hydration products in microstructural level is a complex and interdependent process that allows one to design complex mix proportions to produce sustainable concrete materials. In this paper, the early and late age hydration behavior along with micro- and pore structure of cement paste samples prepared with locally available ordinary Portland cement (OPC) and volcanic ash (VA) obtained from Saudi Arabia was monitored using X-ray diffraction (XRD), scanning electron microscopy (SEM), thermogravimetric (TGA) and N2-Adsorption analysis. The hydration progress of cement paste samples with different combinations of OPC and VA (0%, 15%, 25%, and 35%) at a w/c ratio of 0.45 after 14, 28, and 90 days were discussed. The qualitative XRD and SEM of cement paste samples showed no new phases were formed during the course of hydration. The disappearance of portlandite with increase in VA content was due to both pozzolanic effect and dilution effect. This was further confirmed quantitatively by the TGA observations that the samples with VA contain less Ca(OH)2 compared to the control specimens. N2 adsorption experiments after 90 days of curing showed larger hysteresis as the VA content increases. The studies show that the incorporation of volcanic ash certainly contributes to the generation of C-S-H and hence the cement hydration progress, especially in the later ages through pozzolanic reactions. A 15–25 % volcanic ash blended cement paste samples showed compact and denser morphological features, which will be highly detrimental for the durability performances.

scholarly journals Characterization of Titanium Nanotube Reinforced Cementitious Composites: Mechanical Properties, Microstructure, and Hydration

Materials ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1617 ◽  
Author(s):  
Hyeonseok Jee ◽  
Jaeyeon Park ◽  
Erfan Zalnezhad ◽  
Keunhong Jeong ◽  
Seung Min Woo ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Cement Paste ◽  
Cementitious Materials ◽  
Cement Clinker ◽  
Early Age ◽  
Potential Candidate ◽  
Hydration Kinetics ◽  
Cement Pastes ◽  
Viable Solution ◽  
First Time

In recent years, nano-reinforcing technologies for cementitious materials have attracted considerable interest as a viable solution for compensating the poor cracking resistance of these materials. In this study, for the first time, titanium nanotubes (TNTs) were incorporated in cement pastes and their effect on the mechanical properties, microstructure, and early-age hydration kinetics was investigated. Experimental results showed that both compressive (~12%) and flexural strength (~23%) were enhanced with the addition of 0.5 wt.% of TNTs relative to plain cement paste at 28 days of curing. Moreover, it was found that, while TNTs accelerated the hydration kinetics of the pure cement clinker phase (C3S) in the early age of the reaction (within 24 h), there was no significant effect from adding TNTs on the hydration of ordinary Portland cement. TNTs appeared to compress the microstructure by filling the cement paste pore of sizes ranging from 10 to 100 nm. Furthermore, it could be clearly observed that the TNTs bridged the microcracks of cement paste. These results suggested that TNTs could be a great potential candidate since nano-reinforcing agents complement the shortcomings of cementitious materials.

scholarly journals Effect propylene glycol as a quality improvers for Portland and Portland-limestone cements

2019 ◽  
Vol 4 (1) ◽  
pp. 1-7
Author(s):  
Hashem FS ◽  
Eisa E Hekal ◽  
Abdel M Wahab
Keyword(s):  
Mechanical Properties ◽  
Propylene Glycol ◽  
Transition Zone ◽  
Cement Paste ◽  
Cement Hydration ◽  
Interfacial Transition Zone ◽  
Setting Times ◽  
Sand Particles

The performance of propylene glycol (PG) on the grindability, setting and hardening of Portland (OPC) and Portland-Limestone cements (PLC) was studied. Propylene glycol was added to OPC clinker with percentage ratios; 0, 0.03, 0.04 and 0.05 wt.% of the OPC clinker. PLC was made by replacing 5 and 10 wt. % of OPC with limestone. PG offers better grinding aid performance with higher Blaine areas. Besides, presence of PG shows higher water of consistency and lower initial and final setting times. The mechanical properties of mortar specimens made from OPC and PLC admixed with PG were improved especially in the first 7 days. This explained due to increase in the cement fineness which leads to an increase in the degree of cement hydration, as well as to improvement in the interfacial transition zone between the cement paste and sand particles, thus resulting in an enhancement in the strength. DTA and SEM results confirmed the improved properties achieved due to admixing OPC or PLC with PG.

The Preparation and Pozzolanic Activity of Metakaolin Admixtures

2013 ◽  
Vol 539 ◽  
pp. 230-234 ◽  
Author(s):  
Bao Min Wang ◽  
Yuan Zhang ◽  
Ming Li
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Cement Paste ◽  
Cement Mortar ◽  
Heat Treating ◽  
Ratio Method ◽  
Strength Ratio ◽  
Hydration Products ◽  
Burning Temperature ◽  
Optimum Proportion

The optimum burning temperature of kaolinite and the optimum proportion of metakaolin (MK) in cement paste were studied by the compressive strength ratio method. Metakaolin was obtained at different burning temperature of 700°C, 750°C, 800°C and 850°C for 4 hours, and mixed into cement with the incorporation of 0, 5wt.%, 10wt.%, 15wt.% and 20wt.%. At last, the mechanical properties were researched. The influence of different burning temperature on hydration products of metakaolin cement mortar were analyzed. The results show that the compressive strength ratio of metakaolin cement mortar and the metakaolin pozzolanicity reach the maximum when the metakaolin obtained by heat treating of 750°C, the optimum proportion of metakaolin in cement is 10%~15%.

Thermodynamic Interpretation of Carbonation Process of Portland Cement Hydration Products

2013 ◽  
Vol 753-755 ◽  
pp. 543-557
Author(s):  
Yan Jun Liu ◽  
Bo Tian Chen ◽  
Yong Chao Zheng
Keyword(s):  
Carbon Dioxide ◽  
Free Energy ◽  
Gibbs Free Energy ◽  
Cement Paste ◽  
Cement Hydration ◽  
Hardened Cement ◽  
Hydration Products ◽  
Hardened Cement Paste ◽  
Equilibrium Pressure ◽  
Carbonation Process

Cement hydration products carbonation is not only blamed for the carbonation-induced hardened cement paste or concrete cracking, also attributed to the pore water PH-value decrease, which causes the reinforcement corrosion under the existence of water and oxygen due to removal of oxide film passivating rebar surface, in hardened cement paste and concrete. Based on chemical thermodynamics, this paper presents the susceptibility of different cement hydration products to carbonation through calculating their Standard Gibbs Free Energy respectively, Gibbs free energy under temperature variation and the minimum equilibrium pressure of carbon dioxide triggering the carbonation process. The calculated results show that, under standard state (25°C, 100kpa), the minimum equilibrium pressure of carbon dioxide triggering carbonation process is significantly variable for different types of cement hydration products. For example, mono-sulfate sulfoferrite hydrates (3CaOFe2O3CaSO412H2O) is the most susceptible to carbonation, followed by mono-sulfate aluminate hydrates (3CaOAl2O3CaSO412H2O), while multi-sulfate sulfoaluminate hydrates (3CaOAl2O33CaSO432H2O) is the least vulnerable to carbonation, followed by silicate hydrates (5CaO6SiO25.5H2O). The findings in this paper are significant in understanding thermodynamic mechanism of cement hydrates carbonation and seeking the solution to prevent cement hydrates from carbonation-induced deterioration.

scholarly journals Effect of Ultrafine Additives on the Morphology of Cement Hydration Products

Crystals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1002
Author(s):  
Grigory Yakovlev ◽  
Rostislav Drochytka ◽  
Gintautas Skripkiunas ◽  
Larisa Urkhanova ◽  
Irina Polyanskikh ◽  
...  
Keyword(s):  
Silica Fume ◽  
Cement Paste ◽  
Cement Hydration ◽  
Chemical Reactivity ◽  
Xrd Analysis ◽  
Hardened Cement ◽  
Hydration Products ◽  
Hardened Cement Paste ◽  
X Ray ◽  
Strong Adhesion

The present research is focused on the investigation of the influence of ultrafine additives on the structure formation of hardened cement paste and the establishment of the mechanisms of the morphological transformations, which determine the properties of hydrated products. In the course of the research, the modification of ordinary Portland cement was performed by the suspension of multi-walled carbon nanotubes (MWCNTs), carbon black (CB) paste, and silica fume (SF). Scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) microanalysis, X-ray diffraction (XRD) analysis, thermal analysis, and Fourier-transform infrared (FTIR) spectroscopy were used to study cement hydration products. The morphology of hardened cement paste depends on the chemical reactivity of additives, their geometry, and their genesis. The action mechanism of the inert carbon-based additives and pozzolanic silica fume were considered. The cement hydration products formed in the process of modification by both types of ultrafine additives are described. In the case of the modification of cement paste by inert MWCNTs and CB paste, the formation of cement hydration products on their surface without strong adhesion was observed, whereas in the case of the addition of SF separately and together with MWCNTs, the strong adhesion of additives and cement hydration products was noted.

Microstructure and Mechanism of Concrete Using Inorganic Silicate Admixture

2013 ◽  
Vol 284-287 ◽  
pp. 1235-1241
Author(s):  
Si Yu Zou ◽  
Ran Huang ◽  
An Cheng ◽  
Wei Ting Lin ◽  
Jia Liang Chang
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Porous Structure ◽  
Cement Hydration ◽  
Microscopic Analysis ◽  
Positive Influence ◽  
Composition Analysis ◽  
Hydration Products ◽  
Chemical Composition Analysis ◽  
Porosity Measurements

The study evaluates the properties of concrete mixed with inorganic silicate admixture. The admixture was used in proportions of 3%, 5%, and 7% of the weight of the cement. We performed tests on compressive strength and elastic modulus to evaluate the mechanical properties of concrete. Results show that the addition of the inorganic silicate admixture has a positive influence on the mechanical properties of concrete, with the best results obtained with 3% admixture. MIP porosity measurements determined that the addition of inorganic silicate admixture increased the density of the porous structure. SEM microscopic analysis revealed many needle-like protrusions into the porous structure of concrete. XRF chemical composition analysis indicated that these structures comprised mainly Na2O and SiO2. Can with cement hydration products Ca(OH)2 bring in Chemical reaction. Inferred pore structure Within be C-S-H gel of needle-like protruding structure. it can improve the main cause of mechanical properties of concrete.

scholarly journals Physico-mechanical characterisation of construction materials based on agro-sourced particles: Hemp concrete

2020 ◽  
Vol 330 ◽  
pp. 01039
Author(s):  
Redouane Zerrouki ◽  
Amar Benazzouk ◽  
Suzanne Daher ◽  
Hassen Beji
Keyword(s):  
Mechanical Properties ◽  
Cement Hydration ◽  
Construction Materials ◽  
Inhibitory Effect ◽  
Partial Replacement ◽  
Test Results ◽  
Lightweight Construction ◽  
Mechanical Characterisation ◽  
Mechanical Strengths ◽  
Different Levels

The study reported in this paper was undertaken to investigate the feasibility of lightweight construction materials, based on vegetable particles. The developed material consists of reference mortar containing different levels of hemp particles as partial replacement of sand in mixture by volume at: 0% (MR), 50%, and 100%. The binder nature has been selected based on the results obtained of chemical compatibility evaluation that highlight the reduction in inhibitory effect exerted by particles on cement hydration. The objective of this work is to evaluate the physico-mechanical properties, through the examination of materials lightning, mechanical strengths (compressive/flexural), and the elasticity behavior of the material at different volume rates of hemp particles. The influence of the direction after casting the material, according to the parallel (//) and perpendicular (?) orientations, with respect to the direction of the stress has been examined. Test-results have shown that despite a significant reduction in mechanical properties, the material exhibits higher residual stress that highlight a ductile behaviour, compared to the reference material. Results also indicated that the perpendicular (?) casting direction leads to exhibit higher mechanical properties, compared to the parallel state.

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