The Effect of Ar+ Ion Implantation on the Impact-Abrasive Wear Property of Cu-Polyimide System

1988 ◽  
Vol 119 ◽  
Author(s):  
S. K. Koh ◽  
K. D. Pae
Keyword(s):  
Ion Implantation ◽  
Abrasive Wear ◽  
Optical Microscope ◽  
Wear Property ◽  
X Ray Diffraction ◽  
Wear Properties ◽  
X Ray ◽  
Cu Film ◽  
Pi System ◽  
The Impact

AbstractA thin Cu film(400 Å) was deposited on a smooth polyimide(PI) substrate. Ar+ ion implantation onto the Cu/PI film has been shown to mix Cu and PI and to modify the impact-abrasive wear property. Ar+ ions with energies of 200 keV, and dosage between 1015 to 4×1016 ions/cm2 were used. The surface analyses were carried out with RBS, X-ray and Optical Microscope. The wear properties of the Cu-PI system were determined by a newly constructed Impact-Abrasive Wear Tester. An X-ray diffraction study shows an increase in Cu( 111 )peak with Ar+ ion dosage. The wear property was found to be a function of ion energy, ion dosage, crystallinity of Cu, the amount of mixing of Cu and PI, and the damage of PI substrate due to ion implantation.

Influence of Carbon Content in Cobalt-Based Superalloys on Mechanical and Wear Properties

2004 ◽  
Vol 126 (2) ◽  
pp. 204-212 ◽  
Author(s):  
Rong Liu ◽  
Matthew X. Yao ◽  
Xijia Wu
Keyword(s):  
Mechanical Properties ◽  
Wear Resistance ◽  
Carbon Content ◽  
X Ray Diffraction ◽  
Wear Properties ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Pin On Disc ◽  
Rotating Bending ◽  
The Impact

Two cobalt-based superalloys containing 1.6% and 2% carbon respectively were studied, with the emphasis on the influence of the carbon content on their microstructures, wear resistance, and mechanical properties. Phase formation and transformation in the microstructures were analyzed using metallographic, X-ray diffraction, and differential scanning calorimetry techniques. Wear resistance, tensile and fatigue behaviors of the alloys were investigated on a pin-on-disc tribometer, MTS machine and rotating-bending machine, respectively. It is found that the wear resistance was increased significantly with the carbon content. The mechanical properties of the alloys are also influenced by the carbon content, but the impact is not so significant as on the wear resistance. It was observed that the carbon content increased the yielding strength and fatigue strength, but decreased the fracture stress and fracture strain.

scholarly journals Wear Characterization of Al/ B4C surface composite produced by TIG arc process

2018 ◽  
Vol 3 (2) ◽  
pp. 01-05
Author(s):  
N. Yuvaraj ◽  
Keyword(s):  
Optical Microscope ◽  
X Ray Diffraction ◽  
Wear Properties ◽  
Composite Surface ◽  
X Ray ◽  
Surface Composite ◽  
Surface Composites ◽  
Scanning Electron ◽  
Wear Characterization

Aluminum-based surface composites were fabricated by the TIG arc process. B4C micro and nanoparticles were filled separately on the grooves of the Aluminum substrate and modified the surfaces with different TIG arc speeds. The modified composite surface was characterized by optical microscope, Scanning Electron microscope, and X-ray diffraction. The microhardness and wear properties of the composite surface were evaluated. The results of this study revealed that the newly formed nanocomposite surface enhances the hardness and wear characteristics. The wear worn-out surfaces of the composite surface were analyzed through SEM studies in order to understand the wear mechanisms

scholarly journals Effects of Ti, Ni, and Dual Ti/Ni Plasma Immersion Ion Implantation on the Corrosion and Wear Properties of Magnesium Alloy

Coatings ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 313
Author(s):  
Jun Dai ◽  
Zheng Liu ◽  
Banglong Yu ◽  
Qingdong Ruan ◽  
Paul K. Chu
Keyword(s):  
Magnesium Alloy ◽  
Ion Implantation ◽  
Photoelectron Spectroscopy ◽  
Wear Test ◽  
Corrosion And Wear ◽  
X Ray Diffraction ◽  
Wear Properties ◽  
X Ray ◽  
Bonding Properties ◽  
Plasma Immersion Ion Implantation

Ti, Ni, and Ti/Ni plasma immersion ion implantation is carried out on the AM60 magnesium alloy with a 6 × 1016 ions/cm2 fluence and energy of 35 keV. The corrosion and wear properties of the ion-implanted samples are determined systematically by X-ray photoelectron spectroscopy, X-ray diffraction, scanning electron microscopy, electrochemical methods and wear tests. A Ni-rich layer composed of α-Mg, Ni2O3, and NiTi2 is formed on the surface after dual Ti/Ni ion implantation, and the ion implantation range is approximately 300 nm. The corrosion resistance of the Ni- and Ti/Ni-implanted AM60 samples is significantly reduced in the 3.5% NaCl solution. However, NiTi2 does not adhere well to the grinding ring during the wear test due to the bonding properties, and the sample implanted with both Ti and Ni shows the best wear resistance.

scholarly journals The impact of point defects in n-type GaN layers on thermal decomposition of InGaN/GaN QWs

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Mikolaj Grabowski ◽  
Ewa Grzanka ◽  
Szymon Grzanka ◽  
Artur Lachowski ◽  
Julita Smalc-Koziorowska ◽  
...  
Keyword(s):  
Quantum Wells ◽  
High Temperatures ◽  
Point Defects ◽  
X Ray Diffraction ◽  
Helium Ions ◽  
X Ray ◽  
Sapphire Substrates ◽  
Transmission Electron ◽  
The Impact ◽  
Ingan Quantum Wells

AbstractThe aim of this paper is to give an experimental evidence that point defects (most probably gallium vacancies) induce decomposition of InGaN quantum wells (QWs) at high temperatures. In the experiment performed, we implanted GaN:Si/sapphire substrates with helium ions in order to introduce a high density of point defects. Then, we grew InGaN QWs on such substrates at temperature of 730 °C, what caused elimination of most (but not all) of the implantation-induced point defects expanding the crystal lattice. The InGaN QWs were almost identical to those grown on unimplanted GaN substrates. In the next step of the experiment, we annealed samples grown on unimplanted and implanted GaN at temperatures of 900 °C, 920 °C and 940 °C for half an hour. The samples were examined using Photoluminescence, X-ray Diffraction and Transmission Electron Microscopy. We found out that the decomposition of InGaN QWs started at lower temperatures for the samples grown on the implanted GaN substrates what provides a strong experimental support that point defects play important role in InGaN decomposition at high temperatures.

Optical properties of anatase TiO2 films modified by N ion implantation

2012 ◽  
Vol 90 (1) ◽  
pp. 39-43 ◽  
Author(s):  
X. Xiang ◽  
D. Chang ◽  
Y. Jiang ◽  
C.M. Liu ◽  
X.T. Zu
Keyword(s):  
Thin Films ◽  
Ion Implantation ◽  
Photoelectron Spectroscopy ◽  
Radio Frequency Magnetron Sputtering ◽  
X Ray Diffraction ◽  
X Ray ◽  
Atomic Force ◽  
Light Region ◽  
Uv Visible ◽  
Substrate Temperatures

Anatase TiO2 thin films are deposited on K9 glass samples at different substrate temperatures by radio frequency magnetron sputtering. N ion implantation is performed in the as-deposited TiO2 thin films at ion fluences of 5 × 1016, 1 × 1017, and 5 × 1017 ions/cm2. X-ray diffraction, atomic force microscope, X-ray photoelectron spectroscopy (XPS), and UV–visible spectrophotometer are used to characterize the films. With increasing N ion fluences, the absorption edges of anatase TiO2 films shift to longer wavelengths and the absorbance increases in the visible light region. XPS results show that the red shift of TiO2 films is due to the formation of N–Ti–O compounds. As a result, photoactivity is enhanced with increasing N ion fluence.

The Microstructure and Electrical Property of Porous Cu Film on Soft PVDF Substrate

2012 ◽  
Vol 472-475 ◽  
pp. 1451-1454
Author(s):  
Xue Hui Wang ◽  
Wu Tang ◽  
Ji Jun Yang
Keyword(s):  
Electrical Properties ◽  
Film Surface ◽  
X Ray Diffraction ◽  
Si Substrate ◽  
X Ray ◽  
Cu Films ◽  
Cu Film ◽  
Diffraction Peaks ◽  
Sputtering Pressure ◽  
Effect Method

The porous Cu film was deposited on soft PVDF substrate by magnetron sputtering at different sputtering pressure. The microstructure and electrical properties of Cu films were investigated as a function of sputtering pressure by X-ray diffraction XRD and Hall effect method. The results show that the surface morphology of Cu film is porous, and the XRD revealed that there are Cu diffraction peaks with highly textured having a Cu-(220) or a mixture of Cu-(111) and Cu-(220) at sputtering pressure 0.5 Pa. The electrical properties are also severely influenced by sputtering pressure, the resistivity of the porous Cu film is much larger than that fabricated on Si substrate. Furthermore, the resistivity increases simultaneously with the increasing of Cu film surface aperture, but the resistivity of Cu film still decreases with the increasing grain size. It can be concluded that the crystal structure is still the most important factor for the porous Cu film resistivity.

Ionic conductivity in nanocrystalline Gd doped ceria

2008 ◽  
Vol 1122 ◽  
Author(s):  
Gianguido Baldinozzi ◽  
David Simeone ◽  
Dominique Gosset ◽  
Mickael Dollé ◽  
Georgette Petot-Ervas
Keyword(s):  
Grain Size ◽  
Ionic Conductivity ◽  
Sol Gel ◽  
Doped Ceria ◽  
Narrow Size Distribution ◽  
Conductivity Measurements ◽  
X Ray Diffraction ◽  
X Ray ◽  
Grain Sizes ◽  
The Impact

AbstractWe have synthesized Gd-doped ceria polycrystalline samples (5, 10, 15 %mol), having relative densities exceeding 95% and grain sizes between 30 and 160 nm after axial hot pressing (750 °C, 250 MPa). The samples were prepared by sintering nanopowders obtained by sol-gel chemistry methods having a very narrow size distribution centered at about 16 nm. SEM and X-ray diffraction were performed to characterize the sample microstructures and to assess their structures. We report ionic conductivity measurements using impedance spectroscopy. It is important to investigate the properties of these systems with sub-micrometric grains and as a function of their composition. Therefore, samples having micrometric and nanometric grain sizes (and different Gd content) were studied. Evidence of Gd segregation near the grain boundaries is given and the impact on the ionic conductivity, as a function of the grain size and Gd composition, is discussed and compared to microcrystalline samples.

scholarly journals Lanthanoid Complexes Supported by Retro-Claisen Condensation Products of β-Triketonates

2018 ◽  
Author(s):  
Laura Abad Galán ◽  
Alexandre N. Sobolev ◽  
Eli Zysman-Colman ◽  
Mark Ogden ◽  
Massimiliano Massi
Keyword(s):  
Chelating Ligands ◽  
X Ray Diffraction ◽  
Reaction Conditions ◽  
Claisen Condensation ◽  
X Ray ◽  
Condensation Products ◽  
Complexation Reactions ◽  
The Impact ◽  
Low Solubility

<i>β</i>-Triketonates have been recently used as chelating ligands for lanthanoid ions, presenting unique structures varying from polynuclear assemblies to polymers. In an effort to overcome low solubility of the complexes of tribenzoylmethane, four <i>β</i>-triketones with higher lipophilicity were synthesised. Complexation reactions were performed for each of these molecules using different alkaline bases in alcoholic media. X-ray diffraction studies suggested that the ligands were undergoing decomposition under the reaction conditions. This is proposed to be caused by <i>in situ</i>retro-Claisen condensation reactions, consistent with two examples that have been reported previously. The lability of the lanthanoid cations in the presence of a varying set of potential ligands gave rise to structures where one, two, or three of the molecules involved in the retro-Claisen condensationreaction were linked to the lanthanoid centres. These results, along with measurements of ligand decomposition in the presence of base alone, suggest that using solvents of lower polarity will mimimise the impact of the retro-Claisen condensation in these complexes. <br>

scholarly journals Influence of the Para-Substituent in Lanthanoid Complexes of Bistetrazole Substituted Calix[4]arenes

2019 ◽  
Author(s):  
Rene Z.H. Phe ◽  
Brian Skelton ◽  
Massimiliano Massi ◽  
Mark Ogden
Keyword(s):  
Structural Changes ◽  
Cluster Formation ◽  
Ammonium Cation ◽  
Ammonium Salts ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
Mononuclear Complexes ◽  
Scattering Measurements ◽  
The Impact

5,11,17,23-Tetra-tert-butyl-25,27-dihydroxy-26,28-bis(tetrazole-5-ylmethoxy)calix[4]arene has been reported to form remarkable Ln19 and Ln12 elongated clusters, upon addition of aqueous ammonium carboxylates. The impact of the <i>para</i> substituent on lanthanoid cluster formation has been studied by synthesising two new bis-tetrazole calixarenes, with <i>p</i>-H, and <i>p</i>-allyl substituents. Solution phase dynamic light scattering measurements of the reaction mixtures indicated that clusters are not formed with the <i>p</i>-H and <i>p</i>-allyl derivatives, in contrast with the behaviour of the <i>t-</i>butyl analogue. Lanthanoid complexes of the <i>p</i>-H and <i>p</i>-allyl calixarenes were characterised by single crystal X-ray diffraction, and were found to form mononuclear complexes, linked to form a one-dimensional coordination polymer for the <i>p</i>-allyl system. All of the complexes were isolated as ammonium salts, with ammonium cation included in the calixarene cavity in most cases. It is concluded that the nature of the <i>para</i> substituent has a profound impact on the lanthanoid cluster formation process, and derivatives with more subtle structural changes will be required to determine if additional lanthanoid “bottlebrush” clusters can be isolated.<br><br>

Sign in / Sign up

Export Citation Format

Share Document