Persistent Electronic Conduction in 12CaO7Al2O3 Thin Films Produced by Ar Ion Implantation: Selective Kick-Out Effect Leads to Electride Thin Films
Keyword(s):
ABSTRACTA new method to convert 12CaO7Al2O3 (C12A7) thin films to electronic conductor by hot Ar+ ion implantation has been developed and its mechanism is discussed. It was found that hot Ar+ ion implantation extruded free O2- ions in C12A7 films by kick-out effects at fluences higher than 1×1017 cm−2, which left electrons in the cages embedded in C12A7 crystal and produced high concentration F+-like centers (∼1.4×1021 cm−3). The resulting films show coloration and persistent electronic conduction with conductivities up to ∼1 Scm−1. On the other hand, fluences less than 1×1017 cm−2 kept the films transparent and insulating.
1914 ◽
Vol 90
(619)
◽
pp. 349-355
Keyword(s):
2018 ◽
Vol 2
(2)
◽
pp. 159
Keyword(s):
Keyword(s):
Keyword(s):
Keyword(s):
2006 ◽
Vol 20
(25n27)
◽
pp. 4667-4672
◽
Keyword(s):
Keyword(s):