Effect of ligand substitution in [Fe(H-trz)2(trz)]BF4 spin crossover nanoparticles
2015 ◽
Vol 3
(1)
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pp. 66-72
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Keyword(s):
Spin crossover iron(II) 1,2,4-triazole-based coordination compounds in the form of nanoparticles were prepared using a reverse microemulsion technique. Ligand substitution approach was applied to decrease the spin crossover temperature towards room temperature in the well-known [Fe(Htrz)2(trz)]BF4 complex. The compositions of the particles were determined by elemental analysis and thermogravimetry. The morphology was monitored by transition electron microscopy (TEM). The effect associated with the ligand substitution was investigated by optical and magnetic measurements. Transition temperature has been reduced by 33 K comparing the unsubstituted sample to that with 5 % substitution.
2010 ◽
Vol 667-669
◽
pp. 737-741
2005 ◽
Vol 3
(3-4)
◽
pp. 271-288
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2011 ◽
Vol 471-472
◽
pp. 542-547
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2004 ◽
Vol 34
(1)
◽
pp. 175-186
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Keyword(s):
2011 ◽
Vol 217-218
◽
pp. 368-371
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2021 ◽
Vol 2125
(1)
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pp. 012052
2009 ◽
Vol 60-61
◽
pp. 16-21
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