scholarly journals The Effect of Hydroxyl on the Super-Hydrophobicity of Dodecyl Methacrylate (LMA) Coated Fabrics Through Simple Dipping-Plasma Crosslinked Method

2020 ◽  
Author(s):  
Liyun Xu ◽  
Yu Zhang ◽  
Ying Guo ◽  
Ruiyun Zhang ◽  
Jianjun Shi ◽  
...  
Keyword(s):  
Thermoplastic Polyurethane ◽  
Hydrophobic Effect ◽  
Water Repellency ◽  
Surface Hydrophobicity ◽  
Binding Property ◽  
Interesting Phenomenon ◽  
Water Contact ◽  
Capacitively Coupled ◽  
Pet Fabric ◽  
Dodecyl Methacrylate

In order to obtain stable super-hydrophobicity, suitable hydrophobic treatment agent should be selected according to different materials. In this paper, cotton and poly (-ethylene terephthalate) (PET) fabric was respectively coated by dodecyl methacrylate (LMA) via argon combined capacitively coupled plasma (CCP), and the surface hydrophobicity and durability of treated cotton and polyester fabrics were also discussed. An interesting phenomenon was happened that LMA coated cotton fabric (Cotton-g-LMA) had better water repellency and mechanical durability than LMA coated PET fabric (PET-g-LMA), and LMA coated hydroxyl grafted PET fabrics (PET fabrics were successively coated with polyethylene glycol (PEG) and LMA, PET-g-PEG&LMA) had similar performance to those of cotton fabrics. The water contact angle (WCA) of Cotton-g-LMA, PET-g-LMA and PET-g-PEG&LMA was 156 °, 153 ° and 155 °, respectively, and after 45 washing cycles or 1000 rubbing cycles, the corresponding WCA was decreased to 145 °, 88 °, 134 °and 146 °, 127 °, 143 °, respectively. Also, thermoplastic polyurethane (TPU) and polyamides-6 (PA6) fabrics were all exhibited the same properties to PET fabric. Therefore, the grafting of hydroxyl can improve the hydrophobic effect of LMA coating and the binding property between LMA and fabrics effectively without changing the wearing comfort..

scholarly journals The Effect of Hydroxyl on the Superhydrophobicity of Dodecyl Methacrylate (LMA) Coated Fabrics through Simple Dipping-Plasma Crosslinked Method

Coatings ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1263
Author(s):  
Liyun Xu ◽  
Yu Zhang ◽  
Ying Guo ◽  
Ruiyun Zhang ◽  
Jianjun Shi ◽  
...  
Keyword(s):  
Thermoplastic Polyurethane ◽  
Hydrophobic Effect ◽  
Surface Hydrophobicity ◽  
Contact Angles ◽  
Binding Property ◽  
Interesting Phenomenon ◽  
Water Contact ◽  
Capacitively Coupled ◽  
Pet Fabric ◽  
Dodecyl Methacrylate

In order to obtain stable superhydrophobicity, suitable hydrophobic treatment agents should be selected according to different material properties. In this paper, cotton and poly(ethylene terephthalate) (PET) fabrics were respectively coated with dodecyl methacrylate (LMA) via argon combined capacitively coupled plasma (CCP), and the surface hydrophobicity and durability of the treated cotton and polyester fabrics are also discussed. An interesting phenomenon happened, whereby the LMA-coated cotton fabric (Cotton-g-LMA) had better water repelling and mechanical durability properties than LMA-coated PET fabric (PET-g-LMA), and LMA-coated hydroxyl-grafted PET fabrics (PET fabrics were successively coated with polyethylene glycol (PEG) and LMA, PET-g-PEG & LMA) had a similar performance to cotton fabrics. The water contact angles of Cotton-g-LMA, PET-g-LMA and PET-g-PEG & LMA were 156°, 153° and 155°, respectively, and after 45 washing cycles or 1000 rubbing cycles, the corresponding water contact angles decreased to 145°, 88°, 134° and 146°, 127° and 143°, respectively. Additionally, thermoplastic polyurethane (TPU) and polyamides-6 (PA6) fabrics all exhibited the same properties as the PET fabric. Therefore, the grafting of hydroxyl can improve the hydrophobic effect of LMA coating and the binding property between LMA and fabrics effectively, without changing the wearing comfort.

Breathable, Antistatic and Superhydrophobic PET/Lyocell Fabric

2015 ◽  
Vol 10 (3) ◽  
pp. 155892501501000 ◽  
Author(s):  
Seong Ok Kwon ◽  
Chung Hee Park ◽  
Jooyoun Kim
Keyword(s):  
Transmission Rate ◽  
Water Repellency ◽  
Air Permeability ◽  
Water Contact ◽  
Moisture Regain ◽  
Pet Fabric ◽  
Multi Scale ◽  
Static Water ◽  
Finish Agent ◽  
Blend Fabric

The objective of this study was to develop a breathable and antistatic superhydrophobic PET/lyocell fabric by simple finishing with polymeric fluorocarbon siloxane. To find an optimum concentration of the finish agent, four different concentrations of fluorocarbon finish agent were applied on three different types of fabrics; lyocell 100%, PET 100%, and PET/lyocell blend (50%/50%). Static water contact angle (WCA), shedding angle, and water repellency tests were measured to evaluate the wettability and hydrophobicity of treated fabrics. A PET/lyocell blend fabric treated with 40 g/L fluorocarbon finish agent exhibited superhydrophobic characteristics with WCA of 153.6° and shedding angle of 9.5° resulting from its lowed surface energy and multi-scale roughness. The effects of fluorocarbon finish on fabric moisture regain, electrostatic property, water vapor transmission rate (WVTR), and air permeability were evaluated as parameters for clothing comfort. PET/lyocell blend fabric treated with fluorocarbon exhibited significantly lower static electricity and higher moisture regain than the treated PET fabric. WVTR and air permeability were maintained after the finish. The blended fabric achieved noteworthy combination of antistatic and superhydrophobic properties. The functionality of finished PET and PET/lyocell fabrics, measured by WCA, shedding angle, and water repellency rate, was maintained until 10 washing cycles.

scholarly journals Stable super-hydrophobic and comfort PDMS-coated polyester fabric

e-Polymers ◽  
2021 ◽  
Vol 21 (1) ◽  
pp. 654-661
Author(s):  
Liyun Xu ◽  
Kaifang Xie ◽  
Yuegang Liu ◽  
Chengjiao Zhang
Keyword(s):  
Water Repellency ◽  
High Water ◽  
Polyester Fabric ◽  
Small Scale ◽  
Water Contact ◽  
Pdms Film ◽  
Practical Applications ◽  
Pet Fabric ◽  
Cost Efficient ◽  
Poly Ethylene

Abstract Super-hydrophobic fabrics have shown great potential during the last decade owing to their novel functions and enormous potential for diver’s applications. Surface textures and low surface energy coatings are the keys to high water repellency. However, the toxicity of nanomaterials, long perfluorinated side-chain polymers, and the fragile of micro/nano-texture lead to the super-hydrophobic surfaces are confined to small-scale uses. Thus, in this article, a stable polydimethylsiloxane (PDMS)-coated super-hydrophobic poly(ethylene terephthalate) (PET) fabric (PDMS-g-PET) is manufactured via dip-plasma crosslinking without changing the wearing comfort. Benefiting from the special wrinkled structure of PDMS film, the coating is durable enough against physical abrasion and repeated washing damage, which is suffered from 100 cycles of washing or 500 abrasion cycles, and the water contact angle is still above 150°. This study promotes the way for the development of environmentally friendly, safe, and cost-efficient for designing durable superhydrophobic coatings for various practical applications.

scholarly journals Binding Property Evaluation of Low Melting Point Filaments with Conventional Filaments in Weft-Knitted Fabrics

2018 ◽  
Vol 13 (2) ◽  
pp. 155892501801300
Author(s):  
Qiaoqiao Lin ◽  
Jiali Jiang ◽  
Shuangxi Xu ◽  
Yueping Chen ◽  
Yuanchao Hu ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Melting Point ◽  
Polyethylene Terephthalate ◽  
Treatment Temperature ◽  
Commercial Application ◽  
Binding Property ◽  
Binding Properties ◽  
Knitted Fabrics ◽  
Pet Fabric ◽  
Young’S Moduli

In this paper, low melting point polyamide (LMPA) filaments and low melting point polyethylene terephthalate (LMPET) filaments were blended with conventional filaments, including polyamide (PA), polyethylene terephthalate (PET) and polypropylene (PP), to prepare weft-knitted fabrics. The binding properties of low the melting point filaments in weft-knitted fabrics after heat treatment were investigated by testing mechanical properties and observing the morphology. The effect of heat treatment on the binding properties of the low melting point filaments is discussed. Tensile stress at small deformations and Young's moduli of all fabrics increased and then decreased with increasing heat treatment temperature or time. Thus, an optimal heat treatment process is obtained. LMPA/PA fabric shows better binding properties than LMPET/PET fabric. Both are better than other fabrics considered in this study. This could lead to commercial application of these fabrics.

scholarly journals Integration of Polypyrrole Electrode into Piezoelectric PVDF Energy Harvester with Improved Adhesion and Over-Oxidation Resistance

Polymers ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 1071
Author(s):  
Kyungha Baik ◽  
Sohyun Park ◽  
Changsang Yun ◽  
Chung Hee Park
Keyword(s):  
Energy Harvester ◽  
Chemical Vapor ◽  
Aluminum Foil ◽  
Surface Hydrophobicity ◽  
Alkaline Treatment ◽  
Electrode System ◽  
Pvdf Film ◽  
Smart Textiles ◽  
Water Contact ◽  
Hydrophobic Coating

Smart textiles for wearable devices require flexibility and a lightweight, so in this study, a soft polypyrrole (PPy) electrode system was integrated into a piezoelectric polyvinylidenefluoride (PVDF) energy harvester. The PVDF energy harvester integrated with a PPy electrode had the piezoelectric output voltage of 4.24–4.56 V, while the PVDF energy harvester with an additional aluminum-foil electrode exhibited 2.57 V. Alkaline treatment and chemical vapor deposition with n-dodecyltrimethoxysilane (DTMS) were employed to improve the adhesion between the PVDF and PPy and the resistance to over-oxidation in aqueous solutions. The PVDF film modified by an alkaline treatment could have the improved adhesion via the introduction of polar functional groups to its surface, which was confirmed by the ultrasonication. The surface hydrophobicity of the PPy electrode was enhanced by the DTMS coating, resulting in the improvement of the resistance to over-oxidation with a water contact angle of 111°. Even with the hydrophobic coating, the electrodes remained electroconductive and continued to transfer an electric charge, maintaining the piezoelectricity of the PVDF film. The developed electrode-integrated energy harvester is expected to be applied to smart textiles because it offers the advantages of efficient piezoelectric generation, flexibility, and durability.

scholarly journals A Non-electric and Affordable Surface Engineered Particle (SEP) based Point-of-Use (POU) Water Disinfection System

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Deepa Dixit ◽  
Virupakshi Soppina ◽  
Chinmay Ghoroi
Keyword(s):  
Developing Countries ◽  
Drinking Water ◽  
Low Income ◽  
Alkali Treatment ◽  
Health Hazard ◽  
Surface Hydrophobicity ◽  
Water Disinfection ◽  
Binding Property ◽  
Point Of Use ◽  
Gravity Driven

AbstractAccess to safe drinking water is still a distant dream to millions of people around the world. Especially, people from the low-income group in the developing countries remain deprived of this fundamental right and causes millions of death. There is an urgent need to develop affordable and easy to handle water filter which can provide desired drinking water quality without any electricity. In the present work, a simple and low-cost surface engineered particle (SEP) based filter is developed via alkali treatment of soda-lime-silica particle. The SEP based filter can be used as a portable, non-electric, gravity-driven Point-of-Use (POU) water disinfection system. The developed SEP-based filter is capable to arrest the 99.48% (~2 to 2.5 log10 reduction) of gram-negative bacteria Escherichia coli (E. coli OP50) on its surface from the water containing 3 × 108 cells/ml. No bacterial regrowth is observed in the purified water for 12 h. The performance of SEP bed filter is implicated to the nano-scale surface roughness, its distribution along with the surface charge and surface hydrophobicity which are favorable to attract and adhere the bacteria in the flowing water. The observation is consistent over multiple filtration cycles indicating the suitability of SEP based bed filter for POU water disinfection. The SEP surface with 0.05 mM Ag+ loading (SEP+) completely inactivated (>99.99999%) bacteria and protects any bacteria recontamination in the purified water for its long term usage. The strong and effective silver binding property of SEP surface enables very minimal silver loading and eliminates any health hazard due to low silver leaching (~50 ppb) which is well below the drinking water equivalent level (DWEL ≤ 100 ppb). In rural and urban slum areas of developing countries where no water purification system exists prior to consumption, the easy-to-implement and affordable SEP-based gravity-driven non-electric point-of-use water purifier (materials cost ~ 0.25 USD) can be used to protect millions of lives from water borne diseases.

scholarly journals Facile Fabrication of Recyclable, Superhydrophobic, and Oleophilic Sorbent from Waste Cigarette Filters for the Sequestration of Oil Pollutants from an Aqueous Environment

Processes ◽  
2018 ◽  
Vol 6 (9) ◽  
pp. 140 ◽  
Author(s):  
Augustine Ifelebuegu ◽  
Egetadobobari Lale ◽  
Fredrick Mbanaso ◽  
Stephen Theophilus
Keyword(s):  
Sorption Capacity ◽  
Chemical Vapour ◽  
Water Repellency ◽  
Environmental Damage ◽  
Aqueous Environment ◽  
Water Contact ◽  
Water Separation ◽  
Oil Sorption ◽  
Oil Water Separation ◽  
Surface Modified

The oil industry is plagued with regular incidences of spills into the environment, causing environmental damage to flora and fauna, especially in marine environments where spills easily travel long distances from their sources. This study was carried out to investigate a simple two-step process for the conversion of waste cigarette filters into a superhydrophobic and oleophilic sorbent for application in oil/water separation and spill clean-up. Ultrasonically cleaned filters were surface modified by chemical vapour deposition using methyltrichlorosilane. The results show that the functionalised waste filters achieved superhydrophobic properties with a water contact angle of 154 ± 3.5°, adsorbing 16 to 26 times their weights in various oils, which is a better oil sorption performance than those of commercially available non-woven polypropylene adsorbents. Also, the sorption capacity did not significantly deteriorate after 20 cycles of reuse, with up to 75% sorption capacity retained. The surface modified filters demonstrated excellent water repellency, oil sorption, and recyclability showing their potential application for full scale oil spill clean-up.

Measuring Surface Hydrophobicity as Compared to Measuring a Hydrophobic Effect on Adhesion Events

1995 ◽  
Vol 58 (9) ◽  
pp. 1034-1037 ◽  
Author(s):  
H. AL-MAKHLAFI ◽  
M. LAKAMRAJU ◽  
N. PODHIPLEUX ◽  
B. SINGLA ◽  
J. MCGUlRE
Keyword(s):  
Contact Angle ◽  
Bacteriophage T4 ◽  
Hydrophobic Effect ◽  
Surface Hydrophobicity ◽  
Antimicrobial Proteins ◽  
Hydrophilic Surfaces ◽  
Measuring Surface ◽  
Simple Contact ◽  
Contact Angle Analysis ◽  
Effect Of Surface

Simple contact-angle methods are commonly used to describe surface influences on phenomena including adsorption, adhesion, fouling, and cleaning, However, for the purpose of quantitatively relating surface hydrophobicity to such phenomena, contact-angle analysis may be insufficient. Here we show that even with model hydrophobic and hydrophilic surfaces, measurement of the effect of surface hydrophobicity on adsorption of the antimicrobial proteins nisin and bacteriophage T4 lysozyme yielded conflicting results, apparently because different mechanisms govern events at the interface, depending on surface hydrophobicity. This finding is explained in terms of the presence of two competing mechanisms for attractive associations at these surfaces: hydrophobic and attractive electrostatic associations.

scholarly journals Superhydrophobic Surface with Gamma Irradiation Resistance and Self-Cleaning Effect in Air and Oil

Coatings ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 106 ◽  
Author(s):  
Yan Zhang ◽  
Jing Zhang ◽  
Yujian Liu
Keyword(s):  
Superhydrophobic Surface ◽  
Water Repellency ◽  
Sio2 Nanoparticles ◽  
Superior Performance ◽  
Sliding Angle ◽  
Water Contact ◽  
Composite Surface ◽  
Static Water Contact Angle ◽  
Static Water ◽  
Dirt Removal

A superhydrophobic surface was synthesized by a combination of an epoxy/polymethylphenylsiloxane matrix and dual-scale morphology of silica (SiO2) nanoparticles. When the amount of SiO2 reached 30 wt.%, the as-prepared surface showed a high static water contact angle (WCA) of 154° and a low sliding angle (SA) of 5°, excellent water repellency, and dirt-removal effects both in air and oil (hexamethylene). Even after exposure to as high as a 12.30 Mrad dose of gamma-rays, the composite surface still maintained its superior performance.

scholarly journals Facile Fabrication of Magnetic, Durable and Superhydrophobic Cotton for Efficient Oil/Water Separation

Polymers ◽  
2019 ◽  
Vol 11 (3) ◽  
pp. 442 ◽  
Author(s):  
Mingguang Yu ◽  
Qing Wang ◽  
Wenxin Yang ◽  
Yonghang Xu ◽  
Min Zhang ◽  
...  
Keyword(s):  
Separation Efficiency ◽  
Water Repellency ◽  
Cotton Fabrics ◽  
Ammonia Solution ◽  
Hot Water ◽  
Water Contact ◽  
Water Separation ◽  
Efficient Strategy ◽  
Oil Water Separation ◽  
Oil Water

In this paper, we present a facile and efficient strategy for the fabrication of magnetic, durable, and superhydrophobic cotton for oil/water separation. The superhydrophobic cotton functionalized with Fe3O4 magnetic nanoparticles was prepared via the in situ coprecipitation of Fe2+/Fe3+ ions under ammonia solution on cotton fabrics using polyvinylpyrrolidone (PVP) as a coupling agent and hydrophobic treatment with tridecafluorooctyl triethoxysilane (FAS) in sequence. The as-prepared cotton demonstrated excellent superhydrophobicity with a water contact angle of 155.6° ± 1.2° and good magnetic responsiveness. Under the control of the external magnetic field, the cotton fabrics could be easily controlled to absorb the oil from water as oil absorbents, showing high oil/water separation efficiency, even in hot water. Moreover, the cotton demonstrated remarkable mechanical durable properties, being strongly friction-resistant against sandpaper and finger wipe, while maintaining its water repellency. This study developed a novel and efficient strategy for the construction of magnetic, durable, and superhydrophobic biomass-based adsorbent for oil/water separation, which can be easily scaled up for practical oil absorption.

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