Breathable, Antistatic and Superhydrophobic PET/Lyocell Fabric

2015 ◽  
Vol 10 (3) ◽  
pp. 155892501501000 ◽  
Author(s):  
Seong Ok Kwon ◽  
Chung Hee Park ◽  
Jooyoun Kim

The objective of this study was to develop a breathable and antistatic superhydrophobic PET/lyocell fabric by simple finishing with polymeric fluorocarbon siloxane. To find an optimum concentration of the finish agent, four different concentrations of fluorocarbon finish agent were applied on three different types of fabrics; lyocell 100%, PET 100%, and PET/lyocell blend (50%/50%). Static water contact angle (WCA), shedding angle, and water repellency tests were measured to evaluate the wettability and hydrophobicity of treated fabrics. A PET/lyocell blend fabric treated with 40 g/L fluorocarbon finish agent exhibited superhydrophobic characteristics with WCA of 153.6° and shedding angle of 9.5° resulting from its lowed surface energy and multi-scale roughness. The effects of fluorocarbon finish on fabric moisture regain, electrostatic property, water vapor transmission rate (WVTR), and air permeability were evaluated as parameters for clothing comfort. PET/lyocell blend fabric treated with fluorocarbon exhibited significantly lower static electricity and higher moisture regain than the treated PET fabric. WVTR and air permeability were maintained after the finish. The blended fabric achieved noteworthy combination of antistatic and superhydrophobic properties. The functionality of finished PET and PET/lyocell fabrics, measured by WCA, shedding angle, and water repellency rate, was maintained until 10 washing cycles.

Coatings ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 106 ◽  
Author(s):  
Yan Zhang ◽  
Jing Zhang ◽  
Yujian Liu

A superhydrophobic surface was synthesized by a combination of an epoxy/polymethylphenylsiloxane matrix and dual-scale morphology of silica (SiO2) nanoparticles. When the amount of SiO2 reached 30 wt.%, the as-prepared surface showed a high static water contact angle (WCA) of 154° and a low sliding angle (SA) of 5°, excellent water repellency, and dirt-removal effects both in air and oil (hexamethylene). Even after exposure to as high as a 12.30 Mrad dose of gamma-rays, the composite surface still maintained its superior performance.


2016 ◽  
Vol 87 (12) ◽  
pp. 1481-1493 ◽  
Author(s):  
Yadie Yang ◽  
Hong Hu

In this study, a three-layered composite structure based on spacer fabric was designed for absorbent wound dressings. The fabrication and selection of spacer fabrics were discussed in Part I. In this part, two selected spacer fabrics were further modified by covering a polyurethane or a polystyrene electrospun nanofibrous membrane onto their outer layer surface to form the final spacer fabric-based dressing products. In order to confirm the performance of these new spacer fabric-based dressings, the comparisons were conducted with three types of commercial wound dressings. The comparison indicators included the water contact angle, wettability, absorbency, air permeability and water vapor transmission rate. The results showed that in addition to very good water vapor and air permeability, the developed spacer fabric-based dressings had better absorbing properties than commercial foam dressings. Furthermore, their wettability was also good for application as wound dressings. The study has paved a new way to produce advanced wound dressings using three-dimensional textile structures.


Author(s):  
Liyun Xu ◽  
Yu Zhang ◽  
Ying Guo ◽  
Ruiyun Zhang ◽  
Jianjun Shi ◽  
...  

In order to obtain stable super-hydrophobicity, suitable hydrophobic treatment agent should be selected according to different materials. In this paper, cotton and poly (-ethylene terephthalate) (PET) fabric was respectively coated by dodecyl methacrylate (LMA) via argon combined capacitively coupled plasma (CCP), and the surface hydrophobicity and durability of treated cotton and polyester fabrics were also discussed. An interesting phenomenon was happened that LMA coated cotton fabric (Cotton-g-LMA) had better water repellency and mechanical durability than LMA coated PET fabric (PET-g-LMA), and LMA coated hydroxyl grafted PET fabrics (PET fabrics were successively coated with polyethylene glycol (PEG) and LMA, PET-g-PEG&LMA) had similar performance to those of cotton fabrics. The water contact angle (WCA) of Cotton-g-LMA, PET-g-LMA and PET-g-PEG&LMA was 156 °, 153 ° and 155 °, respectively, and after 45 washing cycles or 1000 rubbing cycles, the corresponding WCA was decreased to 145 °, 88 °, 134 °and 146 °, 127 °, 143 °, respectively. Also, thermoplastic polyurethane (TPU) and polyamides-6 (PA6) fabrics were all exhibited the same properties to PET fabric. Therefore, the grafting of hydroxyl can improve the hydrophobic effect of LMA coating and the binding property between LMA and fabrics effectively without changing the wearing comfort..


e-Polymers ◽  
2021 ◽  
Vol 21 (1) ◽  
pp. 654-661
Author(s):  
Liyun Xu ◽  
Kaifang Xie ◽  
Yuegang Liu ◽  
Chengjiao Zhang

Abstract Super-hydrophobic fabrics have shown great potential during the last decade owing to their novel functions and enormous potential for diver’s applications. Surface textures and low surface energy coatings are the keys to high water repellency. However, the toxicity of nanomaterials, long perfluorinated side-chain polymers, and the fragile of micro/nano-texture lead to the super-hydrophobic surfaces are confined to small-scale uses. Thus, in this article, a stable polydimethylsiloxane (PDMS)-coated super-hydrophobic poly(ethylene terephthalate) (PET) fabric (PDMS-g-PET) is manufactured via dip-plasma crosslinking without changing the wearing comfort. Benefiting from the special wrinkled structure of PDMS film, the coating is durable enough against physical abrasion and repeated washing damage, which is suffered from 100 cycles of washing or 500 abrasion cycles, and the water contact angle is still above 150°. This study promotes the way for the development of environmentally friendly, safe, and cost-efficient for designing durable superhydrophobic coatings for various practical applications.


2014 ◽  
Vol 936 ◽  
pp. 1077-1081 ◽  
Author(s):  
Wei Wei Zhang ◽  
Li Ying Qian ◽  
Hui Ning Xiao

Both water repellency and water vapour barrier properties were endowed at paper surface by coating with beeswax-chitosan latex. It was found that the water vapour transmission rate of coated paper decreased as the drying temperature increased. However, water contact angle was not affected with it. Although the surface morphology deformed at high drying temperature, the roughness values maintained at micro-scale. Further analysis indicated that the water vapour barrier property of coated paper was influenced by the density of the coating layer.


Coatings ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1263
Author(s):  
Liyun Xu ◽  
Yu Zhang ◽  
Ying Guo ◽  
Ruiyun Zhang ◽  
Jianjun Shi ◽  
...  

In order to obtain stable superhydrophobicity, suitable hydrophobic treatment agents should be selected according to different material properties. In this paper, cotton and poly(ethylene terephthalate) (PET) fabrics were respectively coated with dodecyl methacrylate (LMA) via argon combined capacitively coupled plasma (CCP), and the surface hydrophobicity and durability of the treated cotton and polyester fabrics are also discussed. An interesting phenomenon happened, whereby the LMA-coated cotton fabric (Cotton-g-LMA) had better water repelling and mechanical durability properties than LMA-coated PET fabric (PET-g-LMA), and LMA-coated hydroxyl-grafted PET fabrics (PET fabrics were successively coated with polyethylene glycol (PEG) and LMA, PET-g-PEG & LMA) had a similar performance to cotton fabrics. The water contact angles of Cotton-g-LMA, PET-g-LMA and PET-g-PEG & LMA were 156°, 153° and 155°, respectively, and after 45 washing cycles or 1000 rubbing cycles, the corresponding water contact angles decreased to 145°, 88°, 134° and 146°, 127° and 143°, respectively. Additionally, thermoplastic polyurethane (TPU) and polyamides-6 (PA6) fabrics all exhibited the same properties as the PET fabric. Therefore, the grafting of hydroxyl can improve the hydrophobic effect of LMA coating and the binding property between LMA and fabrics effectively, without changing the wearing comfort.


Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1595
Author(s):  
Asif Javed ◽  
Peter Rättö ◽  
Lars Järnström ◽  
Henrik Ullsten

One severe weakness of most biopolymers, in terms of their use as packaging materials, is their relatively high solubility in water. The addition of kraft lignin to starch coating formulations has been shown to reduce the water solubility of starch in dry coatings. However, lignin may also migrate into aqueous solutions. For this paper, kraft lignin isolated using the LignoBoost process was used in order to examine the effect of pH level on the solubility of lignin with and without ammonium zirconium carbonate (AZC). Machine-glazed (MG) paper was coated in a pilot coating machine, with the moving substrate at high speed, and laboratory-coated samples were used as a reference when measuring defects (number of pinholes). Kraft lignin became soluble in water at lower pH levels when starch was added to the solution, due to the interactions between starch and lignin. This made it possible to lower the pH of the coating solutions, resulting in increased water stability of the dry samples; that is, the migration of lignin to the model liquids decreased when the pH of the coating solutions was reduced. No significant difference was observed in the water vapor transmission rate (WVTR) between high and low pH for the pilot-coated samples. The addition of AZC to the formulation reduced the migration of lignin from the coatings to the model liquids and led to an increase in the water contact angle, but also increased the number of pinholes in the pilot-coated samples.


2021 ◽  
Vol 16 ◽  
pp. 155892502110295
Author(s):  
Abdus Shahid ◽  
Solaiman Miah ◽  
Abdur Rahim

Jute bags are widely used to carry food grains and other materials that may be prone to quality deterioration due to thermal fluctuation. Thermal and moisture properties play a significant role in the packaging materials in the form of a container. This study deals with the effect of microencapsulated phase change material (MPCM) with hydrophobic binder on thermal and moisture management properties of jute fabric. Jute fabric was treated with MPCM by pad-dry-cure method. The treated sample was characterized by thermogravimetric analysis (TGA), differential scanning colorimeter (DSC), scanning electron microscope (SEM), moisture management tester (MMT), and air permeability tester. The results revealed that MPCM treated jute fabric shows greater thermal stability and heat absorption ability of 10.58 J/g while changing from solid to liquid phase. The SEM image ensures even distribution of MPCMs on fabric surface and surface roughness was also observed using image processing software. The air permeability was found to decrease whereas the water repellency enhanced in the developed sample.


MRS Advances ◽  
2017 ◽  
Vol 2 (49) ◽  
pp. 2689-2694
Author(s):  
Karla A. Gaspar-Ovalle ◽  
Juan V. Cauich-Rodriguez ◽  
Armando Encinas

ABSTRACTNanofibrous mats of poly ε-caprolactone (PCL) were fabricated by electrospinning. The nanofiber structures were investigated and characterized by scanning electron microscope, differential scanning calorimetry, thermogravimetric analysis, dynamic mechanical analysis, static water-contact-angle analysis and mechanical properties. The results showed that the nanofibrous PCL is an ideal biopolymer for cell adhesion, owing to its biocompatibility, biodegradability, structural stability and mechanical properties. Differential scanning calorimetry results showed that the fibrous structure of PCL does not alter its crystallinity. Studies of the mechanical properties, wettability and degradability showed that the structure of the electrospun PCL improved the tensile modulus, tensile strength, wettability and biodegradability of the nanotemplates. To evaluate the nanofibrous structure of PCL on cell adhesion, osteoblasts cells were seeded on these templates. The results showed that both adhesion and proliferation of the cells is viable on these electrospun PCL membranes. Thus electrospinning is a relatively inexpensive and scalable manufacturing technique for submicron to nanometer diameter fibers, which can be of interest in the commodity industry.


2021 ◽  
Author(s):  
Abdullah M. Al-Enizi ◽  
Asma A. Alothman ◽  
Mohd Ubaidullah ◽  
Ayman Nafady

Abstract Although pyrovatex has been widely utilized as commercial flame-retardant material, the discharge of poisonous formaldehyde is still a major concern. On the other side, fluorine-based materials have been successfully used to impart superhydrophobic textile surfaces, but they are highly expensive and extremely toxic. Based on these challenging concerns, we report a simple one-step method for the production of flame-retardant and water-repellent coating onto an electroconductive cotton-nickel (Cot-Ni) blend fabric. Firstly, the electroconductive cotton was prepared by weaving nickel strip twisted around cotton core yarns, which were then weaved with pure cotton yarns to introduce Cot-Ni blend fabric. Secondly a composite comprising ammonium polyphosphate (APP) and room-temperature vulcanized silicone rubber (RTV) was applied onto the electroconductive cotton fabrics via one-step pad-dry-cure technique. Results showed that the flame-retardant effect of cotton was enhanced due to the high binding of RTV with both APP and cotton fibers. Thus, different concentrations of APP were implemented in the composite to establish that only 100 g/L of APP with RTV presented an improved fire-retardancy. The surface of Cot-Ni fabric displayed different hierarchical morphologies relying on the concentration of APP. Moreover, RTV further enhanced the superhydrphobic nature of cotton surface. Importantly, the superhydrophobic activity was characterized by static water contact angle of the coated Cot-Ni blend. The CIE Lab colorimetric measurements of the coated Cot-Ni blend were also explored. The comfort characteristics of the coated Cot-Ni blend were assessed by measuring their air permeability and stiffness. Ultimately, these multifunctional cotton-nickel (Cot-Ni)/RTV-APP treated fabrics could be suitable for diverse applications, including firefighters’ wear, car seat mats, and grain storage containers.


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