scholarly journals A New Fe-C Porous Filter Material From Dredged Sediment: Preparation, Characterization, And Its Application

2021 ◽  
Author(s):  
Shuyi Chu ◽  
Qian Qu ◽  
Keke Pan ◽  
Yunjie Xu ◽  
Jibo Xiao
Keyword(s):  
Iron Powder ◽  
Average Pore Size ◽  
Filter Material ◽  
Raw Material ◽  
Bet Surface Area ◽  
Technological Condition ◽  
Component Ratio ◽  
Dredged Sediment ◽  
X Ray ◽  
Porous Filter

Abstract A new Fe-C porous filter material was prepared with dredged sediment of river as raw material. The orthogonal test L9(34) and component ratio experiment of raw material were conducted to investigate the optimum technological condition. Further, the filter obtained was characterized by Brunauer-Emmett-Teller (BET), scanning electron microscopy (SEM), energy dispersive X-ray spectroscope (EDS), and X-ray diffraction (XRD). Results showed that the optimal technological condition was sludge: straw: starch: iron powder: foam: iron powder 74.5∶10∶7.5∶3∶5, preheating temperature 280 ℃, preheating 15 min, sintering temperature 1080 ℃, and sintering 11 min. The BET surface area of the filter was 3.32 m2 g− 1, and average pore size was 10.05 nm. Phase composition mainly included SiO2, Fe3O4, Fe2O3 and muscovite (KAl2(Si3Al)O10(OH)2). Average effluent concentrations of total phosphorus (TP), total organic carbon (TOC), and total nitrogen (TN) of the biofilter system filled with the filter obtained were decreased to 0.08, 3.43, and 3.76 mg L− 1, separately, at hydraulic retention time 4 h. Thus, the filter prepared with dredged sediment of rive as raw material is an alternative material for polluted river water purification.

Copper Coated Iron Powder Prepared by Chemical Reduction Process

2011 ◽  
Vol 275 ◽  
pp. 161-164
Author(s):  
Xiao Yun Zhu ◽  
Zhong Cheng Guo
Keyword(s):  
Iron Powder ◽  
Chemical Reduction ◽  
Reduction Process ◽  
Raw Material ◽  
Solution Temperature ◽  
X Ray Diffraction ◽  
Powder Surface ◽  
X Ray ◽  
Reduced Iron Powder ◽  
Plating Solution

Using reduced iron powder as raw material, Copper coated iron powder(CCIP) is prepared by electroless alkaline-based plating. We discuss the impacts of reductant concentration, plating solution temperature and main salt concentration on the properties of CCIP. Surface morphology and composition are studied by using scanning electron microscopy and X-ray diffraction. The results show that after coating, the iron powder surface is rougher and the copper layer is uniform in its simple metallic form without any oxide states.

Experimental Study on Coal Chemical Looping Combustion Using CuFe2O4 as Oxygen Carrier

2013 ◽  
Vol 805-806 ◽  
pp. 1387-1390
Author(s):  
Lei Wang ◽  
Wu Qin ◽  
Ling Nan Wu ◽  
Xue Qing Hu ◽  
Ming Zhong Gao ◽  
...  
Keyword(s):  
Carbon Dioxide Capture ◽  
Oxygen Carrier ◽  
Raw Material ◽  
Bet Surface Area ◽  
Chemical Looping Combustion ◽  
Chemical Looping ◽  
Sem Images ◽  
X Ray ◽  
Thermogravimetric Analyzer ◽  
The Cost

Chemical-looping combustion (CLC) has been proposed as an efficient and clean technology that could contribute to achieve carbon dioxide capture with negligible cost. The technology uses a metal oxide as oxygen carrier that indirectly transfer oxygen from air to fuels to oxidize the fuels. CuFe2O4 was prepared as a novel oxygen carrier to decrease the cost of raw material and increase the reactivity of iron-based oxygen carrier. The structure of the prepared oxygen carrier was characterized by scanning electron microscope (SEM) and an X-ray diffractometer (XRD). The reaction of CuFe2O4 with coal was tested in a thermogravimetric analyzer (TGA). Results showed that the pyrolysis of coal under CO2 was more complete than that under N2, and the final conversion of CuFe2O4 during CLC of coal reached 66.6%. SEM images and BET surface area of the fresh and the used oxygen carrier show little agglomeration during the process.

scholarly journals Ferromagnetic activated carbon from cassava (Manihot dulcis) peels activated by iron(III) chloride: Synthesis and characterization

BioResources ◽  
2020 ◽  
Vol 15 (2) ◽  
pp. 2133-2146
Author(s):  
Gervais Kounou Ndongo ◽  
Ndi Julius Nsami ◽  
Ketcha Joseph Mbadcam
Keyword(s):  
Activated Carbon ◽  
Surface Area ◽  
Total Pore Volume ◽  
Volatile Matter ◽  
Proximate Analysis ◽  
Sem Analysis ◽  
Raw Material ◽  
Bet Surface Area ◽  
X Ray ◽  
Cassava Peel

Ferromagnetic activated carbon (FAC) was prepared through impregnation of cassava peel with FeCl3 (3.75%) solution and pyrolyzed at 800 °C. Samples were characterized using iodine number, methylene blue number, X-ray fluorescence, Fourier transformation infrared, X-ray diffraction (XRD), scanning electron microscopy (SEM) coupled to energy dispersive X-ray spectroscopy, elemental analysis and N2 adsorption for surface area determination. The proximate analysis of cassava peel showed that the moisture content, fixed carbon, ash content, and the volatile matter were 3.52%, 82.97%, 4.97%, and 8.54%, respectively. The prepared FAC had a BET surface area of 405.9 m2/g, pore size of 2.03 nm and total pore volume of 0.11 cm3/g. The SEM analysis showed the presence of both micro and mesopores on the FAC sample. The XRD pattern of FAC showed the presence of characteristic peaks of magnetite–maghemite, confirming that the prepared material is ferromagnetic. According to the experimental results, the cassava peels are considered as appropriate raw material for FAC preparation.

Comparison of Dolomite Clay and Cullet Addition on Physical and Mechanical Properties of Clay Bricks

2018 ◽  
Vol 766 ◽  
pp. 241-245
Author(s):  
Rattaphon Kantajan ◽  
Soravich Mulinta
Keyword(s):  
Compressive Strength ◽  
Water Absorption ◽  
Raw Materials ◽  
Physical And Mechanical Properties ◽  
Raw Material ◽  
Component Ratio ◽  
Clay Brick ◽  
Red Clay ◽  
X Ray ◽  
Clay Bricks

The purpose of this study was to study and characterize the properties of physical – mechanical for clay bricks. The raw materials used in the study are from local sources. They are Sri Khum red clay, dolomite and cullet. The component ratio of clay brick as an addition Sri Khum red clay 50–90 %, foaming agent (dolomite and cullet) 10–50%. The characterization of raw material was analyzed by particle analyzer, X-ray fluorescence (XRF) and X-ray diffraction (XRD). The shrinkage, water absorption and compressive strength of clay brick were tested. The results showed that the properties of clay bricks after firing at temperature at 900°C were studied. The Sri Khum red clay 80% and cullet 20% had a shrinkage of 6.95%, water absorption of 20.4% and compressive strength of 182 kg/cm2. The physical – mechanical of clay brick achieved the requirements of Thai industrial standard (TIS 77-2545).

scholarly journals Hydrochloric Acid Modification and Lead Removal Studies on Naturally Occurring Zeolites from Nevada, New Mexico, and Arizona

Processes ◽  
2021 ◽  
Vol 9 (7) ◽  
pp. 1238
Author(s):  
Garven M. Huntley ◽  
Rudy L. Luck ◽  
Michael E. Mullins ◽  
Nick K. Newberry
Keyword(s):  
New Mexico ◽  
Surface Area ◽  
Bet Surface Area ◽  
Lead Removal ◽  
X Ray Diffraction ◽  
Sem Images ◽  
X Ray ◽  
Naturally Occurring ◽  
27Al Mas Nmr ◽  
Modified Zeolites

Four naturally occurring zeolites were examined to verify their assignments as chabazites AZLB-Ca and AZLB-Na (Bowie, Arizona) and clinoptilolites NM-Ca (Winston, New Mexico) and NV-Na (Ash Meadows, Nevada). Based on powder X-ray diffraction, NM-Ca was discovered to be mostly quartz with some clinoptilolite residues. Treatment with concentrated HCl (12.1 M) acid resulted in AZLB-Ca and AZLB-Na, the chabazite-like species, becoming amorphous, as confirmed by powder X-ray diffraction. In contrast, NM-Ca and NV-Na, which are clinoptilolite-like species, withstood boiling in concentrated HCl acid. This treatment removes calcium, magnesium, sodium, potassium, aluminum, and iron atoms or ions from the framework while leaving the silicon framework intact as confirmed via X-ray fluorescence and diffraction. SEM images on calcined and HCl treated NV-Na were obtained. BET surface area analysis confirmed an increase in surface area for the two zeolites after treatment, NM-Ca 20.0(1) to 111(4) m2/g and NV-Na 19.0(4) to 158(7) m2/g. 29Si and 27Al MAS NMR were performed on the natural and treated NV-Na zeolite, and the data for the natural NV-Na zeolite suggested a Si:Al ratio of 4.33 similar to that determined by X-Ray fluorescence of 4.55. Removal of lead ions from solution decreased from the native NM-Ca, 0.27(14), NV-Na, 1.50(17) meq/g compared to the modified zeolites, 30 min HCl treated NM-Ca 0.06(9) and NV-Na, 0.41(23) meq/g, and also decreased upon K+ ion pretreatment in the HCl modified zeolites.

scholarly journals Fly Ash Coated with Magnetic Materials: Improved Adsorbent for Cu (II) Removal from Wastewater

Materials ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 63
Author(s):  
Maria Harja ◽  
Gabriela Buema ◽  
Nicoleta Lupu ◽  
Horia Chiriac ◽  
Dumitru Daniel Herea ◽  
...  
Keyword(s):  
Fly Ash ◽  
Adsorption Capacity ◽  
Copper Ions ◽  
Synthetic Wastewater ◽  
Bet Surface Area ◽  
Isotherm Models ◽  
Batch Adsorption ◽  
Maximum Adsorption Capacity ◽  
Copper Adsorption ◽  
X Ray

Fly ash/magnetite material was used for the adsorption of copper ions from synthetic wastewater. The obtained material was characterized by scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDAX), X-ray diffractometer (XRD), Fourier transform infrared spectroscopy (FTIR), Brunauer–Emmett–Teller (BET) surface area, and vibrating sample magnetometer (VSM). Batch adsorption experiments were employed in order to investigate the effects of adsorbent dose, initial Cu (II) concentration and contact time over adsorption efficiency. The experimental isotherms were modeled using Langmuir (four types of its linearization), Freundlich, Temkin, and Harkins–Jura isotherm models. The fits of the results are estimated according to the Langmuir isotherm, with a maximum adsorption capacity of 17.39 mg/g. The pseudo-second-order model was able to describe kinetic results. The data obtained throughout the study prove that this novel material represents a potential low-cost adsorbent for copper adsorption with improved adsorption capacity and magnetic separation capability compared with raw fly ash.

scholarly journals Study on Adsorption Properties of Modified Corn Cob Activated Carbon for Mercury Ion

Energies ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4483
Author(s):  
Yuyingnan Liu ◽  
Xinrui Xu ◽  
Bin Qu ◽  
Xiaofeng Liu ◽  
Weiming Yi ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Photoelectron Spectroscopy ◽  
Adsorption Process ◽  
Physical Adsorption ◽  
Raw Material ◽  
Order Kinetic ◽  
Mercury Ions ◽  
Corn Cob ◽  
Adsorption Time ◽  
X Ray

In this study, corn cob was used as raw material and modified methods employing KOH and KMnO4 were used to prepare activated carbon with high adsorption capacity for mercury ions. Experiments on the effects of different influencing factors on the adsorption of mercury ions were undertaken. The results showed that when modified with KOH, the optimal adsorption time was 120 min, the optimum pH was 4; when modified with KMnO4, the optimal adsorption time was 60 min, the optimal pH was 3, and the optimal amount of adsorbent and the initial concentration were both 0.40 g/L and 100 mg/L under both modified conditions. The adsorption process conforms to the pseudo-second-order kinetic model and Langmuir model. Scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and Zeta potential characterization results showed that the adsorption process is mainly physical adsorption, surface complexation and ion exchange.

scholarly journals Cotton stalk-derived hydrothermal carbon for methylene blue dye removal: investigation of the raw material plant tissues

2021 ◽  
Vol 8 (1) ◽  
Author(s):  
Libo Zhang ◽  
Junyan Tan ◽  
Gangying Xing ◽  
Xintong Dou ◽  
Xuqiang Guo
Keyword(s):  
Methylene Blue ◽  
Functional Materials ◽  
Raw Material ◽  
Plant Tissues ◽  
Chemical Compositions ◽  
Waste Biomass ◽  
Cotton Stalk ◽  
Acid Base ◽  
X Ray ◽  
Bet Analysis

AbstractConversion of the abundant agricultural residual cotton stalk (CS) into useful chemicals or functional materials could alleviate the fossil fuels caused energy shortages and environmental crises. Although some advances have been achieved, less attention has been paid to the plant tissues effect. In this study, the plant tissue of CS was changed by part degradation of some components (hemicelluloses and lignin, for example) with the aid of acid/base (or both). The pretreated CS was transformed into hydrochar by hydrothermal carbonization (HTC) method. Morphological and chemical compositions of CS hydrochar were analyzed by various techniques, including elemental analysis, Fourier transform infrared (FTIR), BET analysis, X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). Methylene blue (MB) removal of prepared CS hydrochar was used to evaluate CS hydrochar pollutions adsorption capacity. Results reveal acid/base (or both) pretreatment is beneficial for CS raw material to prepare high-quality CS hydrochar. The effects of some parameters, such as initial MB concentration, temperature, pH value and recyclability on the adsorption of MB onto both acid and base-pretreated CS hydrochar (CS-H2SO4 + NaOH-HTC) were studied. The present work exhibits the importance of agricultural waste biomass material plant tissues on its derived materials, which will have a positive effect on the direct utilization of waste biomass.

scholarly journals Geochemistry and Mineralogy of Ice-Dammed Lake Sediments of the Lębork Deposit

2021 ◽  
Author(s):  
Radosław Rogoziński ◽  
Alina Maciejewska
Keyword(s):  
Chemical Composition ◽  
Lake Sediments ◽  
Inductively Coupled Plasma ◽  
Mineralogical Composition ◽  
Raw Material ◽  
Element Analysis ◽  
X Ray ◽  
Dominant Component ◽  
Clay Deposits ◽  
Dammed Lake

AbstractVarved clay deposits from ice-dammed lakes are a particularly important and broadly applied raw material used for the production of high-quality ceramics (red bricks, roof tiles, etc.), but the mineralogy and geochemistry of these sediments are not fully understood. The aim of the present study was to determine the chemical and mineralogical composition of ice-dammed lake sediments of the Lębork deposit. Major-element analysis of the compositions of selected samples from the ice-dammed lake clays was performed by X-ray fluorescence (XRF) and trace elements were determined by inductively coupled plasma-mass spectrometry. The mineralogical composition of clay samples was determined by X-ray diffraction (XRD). Analyses of the chemical composition of the ice-dammed lake clays of the Lębork deposit showed that the dominant component was SiO2 with a mean content of 56.13 wt.%; the second most abundant component was Al2O3, with a mean content for the entire deposit of 11.61 wt.%. Analysis by ICP-MS indicated the presence of rare earth elements (REE), e.g. cerium, neodymium, lanthanum, and praseodymium; their mean contents are: 56.9, 27.0, 26.3, and 7.3 ppm, respectively. Mineralogical analysis of the varved clays identified quartz, muscovite, calcite, and clay minerals – illite, kaolinite, and montmorillonite. The material filling the Lębork basin is characterized by small lateral and vertical variability in chemical composition. The results of the present study may be of considerable importance in determining the parent igneous, metamorphic, and sedimentary rocks, the weathering products of which supplied material to the ice-dammed lake, as well as in determining the mechanisms and character of the sedimentation process itself.

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