scholarly journals Discrimination of Heavy Metal Sources in the Sefidrud Delta Coastal Lagoons, Caspian Sea, N Iran: A Statistical Approach

2021 ◽  
Author(s):  
Behrouz Rafiei ◽  
Fatemeh Ahmadi-Ghomi ◽  
Asghar Seif ◽  
Ali Shakibaazad ◽  
Sonia Shamshiri ◽  
...  
Keyword(s):  
Caspian Sea ◽  
Coastal Lagoons ◽  
Sediment Cores ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Anthropogenic Sources ◽  
The Caspian Sea ◽  
Test Technique ◽  
Significant Difference ◽  
Accumulation Index

Abstract Amirkola (more than 500 years in age), Kiashahr and Zibakenar (a few decades in age) lagoons are located on the Sefidrud Delta, the southern coast of the Caspian Sea. Evaluating the pollution degree caused by heavy metals (including Cu, Cr, Co, Ni, Pb, Zn and V), 106 sediment samples and three sediment cores were taken from studied lagoons. Three indices, including geo-accumulation index (Igeo), contamination factor (CF), and pollution load index (PLI), were employed to determine the contamination degree in the lagoons. Based on contamination indices, the Kiashahr and Zibakenar lagoons show significant to moderate contamination with Co, Cu, Pb, Zn and V. Nonparametric statistical analysis (Two-step cluster analysis, analysis of variance, and T-test technique) was used to discriminate the pollution sources. Statistical methods indicated the unique interpretation of contaminants sources. There is a significant difference in metal concentrations between Amirkola and two younger lagoons. Despite the same geogenic origin of sediments in the Sefidrud Delta and lagoons deposits, Co, Zn, and Pb show anthropogenic sources in the newly-formed Kiashahr and Zibakenar lagoons.

scholarly journals GEOCHEMISTRY AND ENVIRONMENTAL ASSESSMENT OF HEAVY METALS IN SURFACE SOIL IN AL-HAWIJA, SOUTHWEST KIRKUK

2020 ◽  
Vol 53 (2E) ◽  
pp. 36-61
Author(s):  
Ahmed Al-Obeidi
Keyword(s):  
Heavy Metals ◽  
Soil Pollution ◽  
Ecological Risk ◽  
Inductively Coupled Plasma ◽  
Surface Soil ◽  
Risk Index ◽  
Size Fraction ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Anthropogenic Sources

Soil pollution adversely affects the safety and health of the human being. The main objective of the study is to determine the concentrations of heavy metals (As, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb and Zn) in surface soil in Al-Hawija, southwestern Kirkuk. Twenty-one samples were collected and analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) to measure the content of heavy metals and assess the soil pollution by using the contamination factor, degree of contamination, geoaccumulation index, pollution load index and ecological risk index (RI). The results indicate that there is high pollution by lead, chromium and copper (78.8, 87.4 and 53.8 mg/kg) respectively, in industrial areas due to anthropogenic sources with the presence of significant ecological risk (Er) of the lead (116) in site S7, due to its high concentrations, while size fraction analysis indicated that all heavy metals are concentrated in the fine parts as a result of adsorption processes by clay minerals.

scholarly journals Seasonal Variation of Metallic Contamination of Water and Sediments in Navigation Canal and Industrial Zone South Port Said, Egypt

2018 ◽  
pp. 1-12
Author(s):  
Nabil, A. E. Azzaz ◽  
Mokhtar, S. Beheary ◽  
Mohamed, N. Raslan ◽  
Hazem T. Abd El Hamid
Keyword(s):  
Heavy Metals ◽  
Risk Index ◽  
Winter Season ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Industrial Zone ◽  
Sediment Samples ◽  
Accumulation Index ◽  
Port Said ◽  
Mean Concentration

In the present study, water and sediment samples were collected from Navigation Canal and from Industrial Zone South Port Said to assess heavy metals contamination. It was shown that, the highest mean concentration of heavy metals in water samples was observed in summer, and the lowest mean was observed in winter. It has been made evident that the industrialization in Industrial Zone South Port Said was responsible for the present deteriorating conditions. However, it was shown that, the highest mean concentration of heavy metals in sediment samples was observed in winter, and the lowest mean was observed in summer. Pollution status was evaluated using some indices: geo-accumulation index (Igeo), contamination factor (CF), pollution load index (PLI) and ecological risk index (RI). Based on Igeo, all metal values were unpolluted. On the basis of the values of CF, sediments are high in winter and low in summer. Metals concentrations were in the following order: Ni > Fe > Mn > Pb > Cu > Zn > Co > Cd. According to CF classification, Ni contamination was considerable. RI of winter season can be classified as moderate pollution. No pollution was classified for PLI in all seasons. The decrease in PLI and RI values were indicated dilution and dispersion of metal content with increasing distance from source areas. It is suggested that PLI can give an indication about the trend spatially and temporarily. In addition, it also provides significant data and advice to the policy and decision makers on the contamination degree of the area.

scholarly journals <i>Lingulodinium machaerophorum</i> expansion over the last centuries in the Caspian Sea reflects global warming

2012 ◽  
Vol 9 (11) ◽  
pp. 16663-16704
Author(s):  
S. A. G. Leroy ◽  
H. A. K. Lahijani ◽  
J.-L. Reyss ◽  
F. Chalié ◽  
S. Haghani ◽  
...  
Keyword(s):  
Sea Level ◽  
Caspian Sea ◽  
Global Climate ◽  
Sediment Cores ◽  
Sea Surface ◽  
Sea Level Changes ◽  
The Caspian Sea ◽  
Sea Level Fluctuations ◽  
Marine Surface ◽  
A Minor

Abstract. We analysed dinoflagellate cyst assemblages in four short sediment cores, two of them dated by radionuclides, taken in the south basin of the Caspian Sea. The interpretation of the four sequences is supported by a collection of 27 lagoonal or marine surface sediment samples. A sharp increase in the biomass of the dinocyst occurs after 1967, especially owing to Lingulodinium machaerophorum. Considering nine other cores covering parts or the whole of Holocene, this species started to develop in the Caspian Sea only during the last three millennia. By analysing instrumental data and collating existing reconstructions of sea level changes over the last few millennia, we show that the main forcing of the increase of L. machaerophorum percentages and of the recent dinocyst abundance is global climate change, especially sea surface temperature increase. Sea level fluctuations likely have a minor impact. We argue that the Caspian Sea has entered the Anthropocene.

scholarly journals Study of the Effective Factors on Shelf Currents in the Southern Caspian Sea

2019 ◽  
Vol 1 (1) ◽  
Author(s):  
Maryam ShieaAli
Keyword(s):  
Caspian Sea ◽  
Low Frequency ◽  
Coastal Current ◽  
Surface Currents ◽  
Measured Temperature ◽  
The Caspian Sea ◽  
The West ◽  
Southwestern Part ◽  
Significant Difference ◽  
Weak Winds

The current and wind records and the physical parameter structures such as temperature and salinity in the southwestern part of the Caspian Sea adjacent to Anzali Port were investigated from November 2004 up to the end of January 2005. Results show that, despite the existence of relatively weak winds along the coast in the area, the measurements indicate strong long shore currents. However, when heavy wind tension is observed in the area, then strong currents are also present, which - from the perspective of direction – also have good coordination with the wind. The direction of dominated currents was parallel to the coast from the west to the east. In most cases, the flow rate was identical from the surface to the seabed, and in this condition - because the values of the measured temperature points were almost identical-barotropic currents were present. However, in the autumn at some region, a significant difference was observed between the surface currents and subsurface currents due to temperature differences that affected the density and caused the creation of barclinic currents. Due to the high velocity of currents compared to wind velocity, and the intense slope of the coast and low-frequency movements in the area, we can hypothesize the existence of motions such as Kelvin waves and conclude that the effect of the wind compared to the other factors of the coastal current in the area was weaker.

scholarly journals Accumulation and toxicological risk assessment of Cd, As, Pb, Hg, and Cu from topsoils of school playgrounds at Obio-Akpor LGA Rivers State Nigeria

2017 ◽  
Vol 5 (1) ◽  
pp. 38 ◽  
Author(s):  
Okereke Chioma ◽  
Agomuo Emmanuel ◽  
Amadi Peter
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Hazard Quotient ◽  
Hazard Index ◽  
Contamination Factor ◽  
Enrichment Factors ◽  
Pollution Load Index ◽  
Anthropogenic Sources ◽  
Adverse Health Effects ◽  
School Playgrounds

The adverse health effects associated with heavy metal pollution have become a subject of topical discussion. Using standard methods, this study evaluated the accumulation and toxicological risks of heavy metal deposition on top soils of school playgrounds in Obio-Akpor LGA. Results obtained from the top soils, sampled from 10 different schools showed that the concentration of heavy metals assessed, followed the trend; Hg<As<Cd<Pb<Cu. Marginal differences between the test and control samples were observed for the geoaccumulation index of the heavy metals except for copper. For the contamination factor, FCUA had the least results for cadmium (0.31) but highest in arsenic (0.016) while OPS, UDPS and RBPS recorded the highest contamination factor for lead, mercury, and copper respectively. The results for the pollution load index and degree of contamination of the test sites showed that the sites were unpolluted and had low contamination status, while the enrichment factors showed the deposition of only cadmium to be of a natural origin, and the rest of the heavy metals resulted from anthropogenic sources. The trend from the hazard quotient was Pb>Hg>Cu>Cd>As while the highest (0.0213) and least (0.0162) total hazard index value occurred at RBPS and MOM respectively. These values obtained for this study indicate that the school playground's soils are still within the recommended heavy metal content safe levels.

scholarly journals Assessment of the metal pollution in surface sediments of coastal Tasaul Lake (Romania)

2020 ◽  
Vol 192 (12) ◽  
Author(s):  
Dan Vasiliu ◽  
Andra Bucse ◽  
Naliana Lupascu ◽  
Bogdan Ispas ◽  
Catalin Gheablau ◽  
...  
Keyword(s):  
Metal Contamination ◽  
Surface Sediments ◽  
Heavy Metal Contamination ◽  
Contamination Factor ◽  
Distribution Patterns ◽  
Agricultural Runoff ◽  
Pollution Load Index ◽  
Anthropogenic Sources ◽  
Pollution Indices ◽  
Metal Concentrations

AbstractForty-three surface sediment samples were collected in September 2019 from Tasaul Lake (Black Sea coast, Romania) to examine the metal distribution patterns, assess the level of metal contamination, and identify the pollutant sources. The determined mean metal concentrations were as follows: Al 49,772 mg/kg, Zn 84.40 mg/kg, Cr 83.70 mg/kg, V 76.45 mg/kg, Ni 42.53 mg/kg, Cu 34.27 mg/kg, Pb 26.30 mg/kg, As 12.49 mg/kg, and Hg 0.06 mg/kg. The metals in the surface sediments of Tasaul Lake displayed moderate spatial variation, with higher metal concentrations mainly occurring in the south and southeast (As, Pb, and Hg), southwest (Cu and Zn), and west of the lake (Cr, Ni, and V). Heavy metal contamination in sediments is assessed using pollution indices such as enrichment factor, contamination factor, and pollution load index. The highest CFs and EFs were determined for As (moderate to high pollution), followed by Pb (low to moderate pollution). The Cu, Zn, and Hg pollution indices showed values corresponding to low pollution levels, while Ni, Cr, and V presented the lowest indices, suggesting unpolluted sediments. Multivariate statistical analyses were performed to identify the origin of the analyzed heavy metals. Cr was predominantly sourced from lithogenic components, Ni and V originated from both natural and anthropogenic sources, and As, Cu, Zn, Pb, and Hg showed mainly anthropogenic sources such as agricultural runoff, domestic and industrial wastewater discharges, and quarrying activities.

scholarly journals Major and Trace Elements in Moldavian Orchard Soil and Fruits: Assessment of Anthropogenic Contamination

2020 ◽  
Vol 17 (19) ◽  
pp. 7112 ◽  
Author(s):  
Inga Zinicovscaia ◽  
Rodica Sturza ◽  
Octavian Duliu ◽  
Dmitrii Grozdov ◽  
Svetlana Gundorina ◽  
...  
Keyword(s):  
Contamination Factor ◽  
Major And Trace Elements ◽  
Fruit Production ◽  
Pollution Load Index ◽  
Anthropogenic Contamination ◽  
Transfer Factors ◽  
Mass Fractions ◽  
Accumulation Index ◽  
The Republic ◽  
Almost All

The correct assessment of the presence of potentially contaminating elements in soil, as well as in fruits cultivated and harvested from the same places has major importance for both the environment and human health. To address this task, in the case of the Republic of Moldova where the fruit production has a significant contribution to the gross domestic product, the mass fractions of 37 elements (Na, Mg, Al, Ca, Si, K, Mn, Fe, Sc, Ti, V, Cr, Co, Ni, Zn, As, Br, Rb, Sr, Zr, Mo, Cd, Sb, Cs, Ba, La, Ce, Nd, Sm, Eu, Tb, Yb, Hf, Ta, W, Th, and U) were determined by instrumental neutron activation analysis in soil collected from four Moldavian orchards. In the case of three types of fruits, grapes, apples, and plums, all of them collected from the same places, only 22 elements (Na, Mg, Cl, K, Ca, Sc, Mn, Fe, Co, Ni, Cu, Zn, As, Br, Rb, Sr, Sb, Cs, Ba, La, Th, and U) were detected. The enrichment factor, contamination factor, geo-accumulation index, as well as pollution load index were calculated to assess the soil contamination. At the same time, the metal uptake from the soil into fruits was estimated by means of transfer factors. Soil samples showed for almost all elements mass fractions closer to the upper continental crust with the exception of a slightly increased content of As, Br, and Sb, but without overpassing the officially defined alarm thresholds. In the case of fruits, the hazard quotients for all elements with the exception of Sb in fruits collected in two orchards were below unity. A subsequent discriminant analysis allowed grouping all fruits according to their type and provenance.

scholarly journals Analysis of Heavy Metals in Surface Sediments from Agh Gel Wetland, Iran

2016 ◽  
Vol 10 (3) ◽  
pp. 41-46
Author(s):  
Soheil Sobhanardakani ◽  
◽  
Mehrnaz Ghoochian ◽  
Keyword(s):  
Heavy Metals ◽  
Surface Sediments ◽  
Contamination Factor ◽  
Dry Weight ◽  
Pollution Load Index ◽  
Pollution Load ◽  
Chemical Pollutants ◽  
Accumulation Index ◽  
The Mean ◽  
Geo Accumulation Index

Background: Soil and sediment serve as major reservoir for contaminants as they possess ability to bind various chemicals together. In this study the concentrations of heavy metals Cd, Cr and Cu were analyzed in surface sediments of Agh Gel Wetland in west of Iran. Methods: The sediment samples were taken from 10 stations. The samples were subjected to bulk digestion and chemical partitioning and Cd, Cr and Cu concentrations of the sediments were determined by ICP-OES. Geo-accumulation index (I-geo), Contamination factor (CF) and Pollution load index (PLI) were used to evaluate the magnitude of contaminants in the sediment profile. Results: The mean sediment concentrations (mg kg-1 dry weight) ranged within 0.20-0.29 (Cd), 58-71 (Cr) and 23-36 (Cu). According to the I-geo values, the sediments' qualities are classified as unpolluted to moderately polluted category. According to the CF values, the sediments' qualities are classified as low to moderate contamination. Furthermore, the PLI values indicated that there were no metal pollution exists for all sampling stations. Conclusion: The Agh Gel Wetland is potential to be threatened by chemical pollutants such as agricultural effluent. So to preserve the environment of the Agh Gel Wetland from deterioration, periodically monitoring of the water and sediment qualities is recommended.

scholarly journals Study of potential availability of heavy metals to phytoremediation to use of ash from biomass combustion

2018 ◽  
Keyword(s):  
Heavy Metals ◽  
Risk Index ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Biomass Combustion ◽  
Multivariate Statistical ◽  
New Class ◽  
Accumulation Index ◽  
Potential Availability ◽  
Test Soil

<p>Ashes, formed as a result of combustion of biomass are a new class of by-products of combustion and due to the large variety of these materials their chemical composition has not been fully determined. Their use is limited, despite the fact that their production has increased. This work presents the results of studies on the possibility of limiting the potential availability of Cu, Mn, Pb and Zn for plants by use of an inorganic stabilizer - ash from biomass combustion. In this study the usefulness of ash from biomass for binding mobile fractions of heavy metals (Cu, Mn, Pb and Zn) was evaluated. The investigations were executed using three extraction tests with the use of the following extraction solutions: 1 M HNO3 – acid soluble forms (As), 0.05 M EDTA – bioavailable forms (Bio), 2.5% CH3COOH – exchangeable forms (Ex). The values of the following parameters: Mobility Index (MI), Contamination Factor (CF), Pollution Load Index (PLI), Geo – accumulation Index (Igeo) and Ecological Risk Index (RI) were defined and determined for their suitability as a test soil stabilizer. Furthermore, a multivariate statistical analysis was carried out. It was found, that a phytoremediation process using investigated ash from biomass combustion can be applied to soil contaminated by heavy metals.</p>

scholarly journals Assessment of Heavy Metal Pollution of Water, Sediments and Algae in River Benue at Jimeta-Yola, Adamawa State, Nigeria

2019 ◽  
Vol 1 ◽  
pp. 186-195
Author(s):  
A A Tyovenda ◽  
S I Ikpughul ◽  
T Sombo
Keyword(s):  
Heavy Metal ◽  
Enrichment Factor ◽  
Metal Pollution ◽  
Heavy Metal Pollution ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Pollution Load ◽  
Accumulation Index ◽  
Geo Accumulation Index ◽  
Geo Accumulation

Heavy metal pollution of water, sediments and Algae in the upper region of River Benue at Jimeta-Yola, Adamawa state, Nigeria was assessed. The concentrations of the heavy metals (Pb, Hg, Ni, Cu, Cr, Zn, Mn, Fe) in the samples were analyzed using Atomic Adsorption Spectrometer. Pollution parameters such as enrichment factor, contamination factor, pollution load index and geo-accumulation index were evaluated. The result of heavy metal analysis showed that, the concentration (ppm) of the metals in water samples ranged as follows: Pb(0.25-0.50), Hg(0.00-2.00), Ni(0.10-0.31), Cu(0.03-0.13), Cr(0.00-1.33), Zn(0.01-0.04), Mn(0.03-0.06) and Fe(105.15-118.75) respectively. This result when compared with the EPA maximum permissible limits for drinking water showed that, all the metals except Cu and Zn had values above the permissible limits. The evaluation of enrichment factor revealed that, Hg showed extremely high enrichment while Pb showed significant enrichment for Algae, water and sediment samples. The contamination factor showed low contamination for all metals except Hg which showed considerable contamination for sediments, water and Algae samples. The pollution load index for sediments, water and Algae indicated no pollution. The geo-accumulation index of the metals in sediments, water and Algae indicates no or minimal pollution. The samples were enriched with Hg and Pb. These metals are capable of causing various types of cancer, brain and kidney damage among other ailments.

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