An optimal magnetite immobilized Pseudomonas- putida 5-x cellsystem for Cu2+ removal from industrial waste effluent

2000 ◽  
Vol 41 (12) ◽  
pp. 241-248 ◽  
Author(s):  
L. Wang ◽  
H. Chua ◽  
P. K. Wong ◽  
W. H. Lo ◽  
P. H. F. Yu ◽  
...  
Keyword(s):  
Cell Surface ◽  
Pseudomonas Putida ◽  
Adsorption Capacity ◽  
Growth Phase ◽  
Industrial Waste ◽  
Early Death ◽  
Freundlich Isotherm ◽  
Cell System ◽  
Desorption Process ◽  
Industrial Waste Effluent

An optimal magnetite immobilized Pseudomonas putida 5-x cell system was developed to remove Cu2+ from industrial waste effluent. Cu2+ adsorption capacity of P. putida 5-x cultured in sulphate-limiting medium (SLM) was minimum in early log growth phase, and reached maximum in late stationary growth phase or early death phase. Pretreated cells by 0.6 N HCl could greatly enhance the adsorption capacity of biomass up to 85.6 mg/g and had no significant effect for the loss of P. putida 5-x cells during the pretreatment. In a semi-continuous biosorption system, the removal efficiency of Cu2+ from wastewater reached 96%, and recovery efficiency of Cu2+ was 95%, and the concentration in the recovery solution was 1.4 g/L using 0.6 N HCl as eluant. The mechanism of Cu2+ adsorption by this type of biomass was studied by using the technique of transmission electron microscopy (TEM). Degradation of a peptidoglycan layer on the cell surface was observed after acidic pretreatment, but no further degradation appeared after the adsorption-desorption cycle. TEM and X-ray analysis also showed that Cu2+ was mainly accumulated on the cell surface, so it was effectively desorpted by acidic treatment in the desorption process. The process of adsorption obeyed the Freundlich isotherm.

scholarly journals A Validated SPE-UPLC-DAD Method for Quantification of Parabens in Industrial Waste Effluent Water Samples by Using Activated Carbon Nanofiber Modified Filter Paper

2021 ◽  
Vol 33 (2) ◽  
pp. 350-358
Author(s):  
Eegala Bheema Shankar ◽  
Challa Gangu Naidu ◽  
CH. N.S. Sai Pavan Kumar ◽  
Kasturi Rajashekhar
Keyword(s):  
Activated Carbon ◽  
Filter Paper ◽  
Water Samples ◽  
Industrial Waste ◽  
Carbon Nanofiber ◽  
Solid Phase ◽  
Array Detector ◽  
Effluent Water ◽  
Desorption Process ◽  
Industrial Waste Effluent

The present work describes a sensitive, simple, cost-effective and fast analytical procedure to detect the parabens in industrial waste effluent water samples using novel activated carbon nanofiber (CNF) modified filter paper based solid phase extraction technique coupled with liquid chromatography with photodiode array detector (UPLC-PDA). The carbon nanofiber coated filter paper was used as an adsorbent and also characterized by field emission scanning electron microscope (FESEM) showed superior porous structure. Various factors effecting the adsorption and desorption process were studied. The optimum parameters which improve the efficiency are paper length 1 cm × 2 cm, adsorption time 15 min, eluent methanol, eluent volume 5 mL, sample pH 7, desorption time 2 min, 2% salt addition and 300 rpm stirring rate respectively. The parabens exhibited superior linearity ranging from 0.1-50 ng mL-1. The regression coefficient (R2) value ranging from 0.9981-0.9989. This method exhibited good sensitivity with the quantification limit (LOQ) between 0.5-0.75 ng mL-1 and detection limit (LOD) over the range of 0.1-0.25 ng mL-1. The precision was expressed from the RSDs values from 0.74-0.97 %. The spiked analytes revealed excellent recoveries in the range of 95.30-116.72 % with RSD less than 5.72 % for all the water samples also applied for real samples.

scholarly journals Preparation and Characterization of Cationized Cellulose for the Removal of Anionic Dyes

2001 ◽  
Vol 19 (3) ◽  
pp. 197-210 ◽  
Author(s):  
A. Hashem ◽  
Reda M. El-Shishtawy
Keyword(s):  
Adsorption Capacity ◽  
Freundlich Isotherm ◽  
Structural Features ◽  
Isotherm Models ◽  
Acid Orange 7 ◽  
Anionic Dyes ◽  
Adsorption Parameters ◽  
Direct Blue ◽  
Equilibrium Data

The factors influencing the cationization of microcrystalline cellulose with 3-chloro-2-hydroxypropyl triethylammonium chloride in the presence of NaOH were investigated. The course of the reaction was followed by estimating the nitrogen content of the cationized product while its structural features were confirmed by IR analysis. The ability of cationized cellulose to adsorb anionic dyes, viz. Acid Orange 7, Direct Blue 75 and Direct Violet 31, was investigated at 25°C and 50°C. The equilibrium data obtained were fitted by the Langmuir and Freundlich isotherm models, allowing the corresponding adsorption parameters to be determined. The results showed that the adsorption capacity was dependent on the adsorbent, temperature, the nature of the dye and (to some extent) on van der Waals and hydrogen bonding. Cationized cellulose exhibited a much better adsorption capacity towards anionic dyes than cellulose.

scholarly journals Adsorption Behavior of Inorganic and Organic Phosphate by Iron Manganese Plaques on Reed Roots in Wetlands

2018 ◽  
Vol 10 (12) ◽  
pp. 4578 ◽  
Author(s):  
Yingjie Zhu ◽  
Xiaoli Du ◽  
Can Gao ◽  
Zhenya Yu
Keyword(s):  
Adsorption Capacity ◽  
Fine Particles ◽  
Freundlich Isotherm ◽  
Organic Phosphate ◽  
Photoelectron Spectra ◽  
Phosphate Adsorption ◽  
Isotherm Models ◽  
Hydroxyl Groups ◽  
Iron Manganese ◽  
Inorganic And Organic

Inorganic and organic phosphate adsorption by iron–manganese (Fe–Mn) plaques extracted from reed roots was investigated. Scanning electron microscopy indicated the roots had rough surfaces and fine particles attached. X-ray photoelectron spectra indicated that Fe and Mn in the Fe–Mn plaques were mainly in the +III and +IV oxidation states, respectively. The contact time, initial phosphate concentration, and temperature effects on inorganic and organic phosphate adsorption were investigated by performing batch tests. Pseudo-second-order model described inorganic and organic phosphate adsorption, indicating the chemisorption was the dominant adsorption process. Langmuir and Freundlich isotherm models were fitted to the equilibrium data, and the Langmuir model fitted best. The maximum inorganic and organic phosphate adsorption capacities at 298 K were 7.69 and 3.66 mg/g, respectively. The inorganic and organic phosphate adsorption processes were spontaneous and exothermic. The inorganic phosphate adsorption capacity was higher than the organic phosphate adsorption capacity, and the presence of organic phosphate did not negatively affect adsorption at inorganic to organic phosphate molar ratios between 1:1 and 3:1. Fourier-transform infrared spectra before and after adsorption showed abundant functional groups on Fe–Mn plaques and that phosphate was probably adsorbed via replacement of hydroxyl groups and inner-sphere surface complexation.

Kinetics of lead ion biosorption from aqueous solution onto lyophilized Aspergillus niveus

2010 ◽  
Vol 5 (1) ◽  
Author(s):  
Hülya Karaca ◽  
Turgay Tay ◽  
Merih Kıvanç
Keyword(s):  
Adsorption Capacity ◽  
Correlation Coefficients ◽  
Freundlich Isotherm ◽  
Second Order ◽  
Lead Ions ◽  
Lead Ion ◽  
Maximum Adsorption Capacity ◽  
Order Kinetic ◽  
Aspergillus Niveus ◽  
Pseudo Second Order

The biosorption of lead ions (Pb2+) onto lyophilized fungus Aspergillus niveus was investigated in aqueous solutions in a batch system with respect to pH, contact time and initial concentration of the ions at 30 °C. The maximum adsorption capacity of lyophilized A. niveus was found to be 92.6 mg g−1 at pH 5.1 and the biosorption equilibrium was established about in 30 min. The adsorption capacity obtained is one of the highest value among those reported in the literature. The kinetic data were analyzed using the pseudo-first-order kinetic, pseudo-second-order kinetic, and intraparticle diffusion equations. Kinetic parameters, such as rate constants, equilibrium adsorption capacities, and related correlation coefficients for the kinetic models were calculated and discussed. It was found that the adsorption of lead ions onto lyophilized A. niveus biomass fit the pseudo-second-order kinetic model well. The Langmuir and Freundlich isotherm parameters for the lead ion adsorption were applied and the Langmuir model agreed better with the adsorption of lead ions onto lyophilized A. niveus.

scholarly journals Investigation of competitive adsorption and desorption of heavy metals from aqueous solution using raw rock: Characterization kinetic, isotherm, and thermodynamic

2021 ◽  
Vol 348 ◽  
pp. 01016
Author(s):  
Rajaa Bassam ◽  
Marouane El Alouani ◽  
Nabila Jarmouni ◽  
Jabrane Maissara ◽  
Mohammed El Mahi Chbihi ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Adsorption Process ◽  
Freundlich Isotherm ◽  
Langmuir Model ◽  
Second Order ◽  
Isotherm Models ◽  
Desorption Process ◽  
Pseudo Second Order ◽  
Rock Characterization ◽  
Metals Adsorption

Heavy metals are the most dangerous inorganic pollutants Due to their bioaccumulation and their nonbiodegradability, for this, several studies have focused on the recovery of these metals from water using different techniques. In this context, our study consists of evaluating an efficient and eco-friendly pathway of competitive recovery of heavy metals (Cd, Cr and As) from aqueous solutions by adsorption using raw rock. This adsorbent was characterized before and after the adsorption process by several techniques. The multi-metals adsorption process in the batch mode was undertaken to evaluate the effect of adsorbent mass, contact time, pH, Temperature, and initial heavy metals concentration. The kinetic data were analyzed using the pseudo-first-order, pseudo-second-order and intra-particle diffusion kinetic models. According to the modeling of the experimental results, the adsorption kinetics of heavy metals were adapted to the pseudo-second-order model. The adsorption isotherms were evaluated by the Langmuir and Freundlich isotherm models. The experimental isotherm data of heavy metals were better fitted with the Langmuir model rather than Freundlich isotherm models. The maximum experimental adsorption capacities (Qmax) predicted by the Langmuir model are 15.23 mg/g for Cd (II), 17.54 mg/g for Cr (VI) and 16.36 mg/g for As (III). The values of thermodynamic parameters revealed that the heavy metals adsorption was exothermic, favorable, and spontaneous in nature. The desorption process of heavy metals showed that this raw rock had excellent recycling capacity. Based on the results, these untreated clays can be used as inexpensive and environmentally friendly adsorbents to treat water contaminated by heavy metals.

scholarly journals Studi Kemampuan Adsorpsi Ion Logam Cr6+ oleh Tanah Vulkanik “Studi Kasus Wilayah Industri Penyamakan Kulit, Garut”

2020 ◽  
Vol 21 (1) ◽  
pp. 125-130
Author(s):  
Nyoman Sumawijaya ◽  
Asep Mulyono ◽  
Anna Fadliah Rusydi
Keyword(s):  
Adsorption Capacity ◽  
Waste Treatment ◽  
Liquid Waste ◽  
Freundlich Isotherm ◽  
Organic Content ◽  
Maximum Adsorption Capacity ◽  
Soil Media ◽  
Pass Through ◽  
Soil Organic Content ◽  
The Impact

ABSTRACTThe leather tanning industry in Sukaregang, Garut Regency, produces liquid waste containing Chromium and is discharged directly into the Ciwalen River without a waste treatment process. The content of Cr6+ as metal ions in the waste can also contaminating groundwater. The movement of Cr6+ will pass through the soil media before entering to the groundwater wells. The capability of the soil to adsorb the contaminant will reduce the impact on groundwater. The purpose of this study was to determine the ability of the soil in adsorbing and inhibiting the movement of Cr6+ into groundwater. The study was carried out at Sukaregang, Garut Regency and conducting adsorption experiments with a batch system. The analysis was carried out using the Langmuir and Freundlich isotherm model. The experimental results showed that Cr6+ adsorbed ranged from 38% to 57% of the initial concentration. The results from Langmuir Isotherm were: the distribution coefficient (Kads) was 0.45 L/mg and the maximum adsorption capacity (qm) was 2.44 mg/100g sorbent with R2 = 0.959 and Freundlich Isotherm was: qm was 2,86 mg/100g sorbent and Kads was 0,35 L/mg with R2 = 0,860. This large adsorption capacity is caused by soil texture and soil organic content. The soil in Sukaregang tanning industries has a high adsorption capacity towards Cr6+ contaminants.Keywords: adsorption, chromium, Cr6+, contaminant, volcanic soil, GarutABSTRAKIndustri penyamakan kulit di wilayah Sukaregang, Kabupaten Garut, menghasilkan limbah cair yang mengandung Kromium dan dibuang ke Sungai Ciwalen tanpa proses pengolahan limbah. Kandungan ion logam Cr6+ pada limbah dapat mencemari air tanah. Pergerakan ion logam Cr6+ akan melalui media tanah sebelum memasuki sumur-sumur penduduk. Beberapa jenis tanah mempunyai kemampuan untuk mengadsorpsi ion pencemar sehingga tidak semua limbah yang meresap ke dalam tanah mencemari air tanah. Tujuan dari penelitian ini adalah untuk mengetahui peranan tanah dalam menghambat pergerakan ion logam Cr6+ ke dalam air tanah. Penelitian dilaksanakan dengan pengambilan sampel tanah di daerah Sukaregang, Garut, dan melakukan percobaan adsorpsi dengan sistem batch. Sementara analisis dilakukan dengan menggunakan model isotherm Langmuir dan Freundlich. Hasil percobaan menunjukkan konsentrasi Cr6+ yang teradsorpsi berkisar 38 – 57 % dari konsentrasi awal. Kads sebesar 0,45 L/mg dan qm sebesar 2,44 mg/100g tanah dengan nilai R2 = 0,959 menggunakan isoterm Langmuir dan isoterm Freundlich memberikan nilai qm sebesar 2,86 mg/100 g sorbent dan Kads sebesar 0,35 L/mg dengan R2 = 0,860. Tingginya daya adsorpsi ini disebabkan oleh tekstur tanah dan kandungan bahan organik. Tanah di wilayah penelitian memiliki daya adsorpsi yang besar terhadap kontaminan Cr6+.Kata kunci: adsorpsi, kromium, Cr6+, kontaminan, tanah vulkanik, Garut

scholarly journals Adsorption of Mn2+ from Aqueous Solution Using Manganese Oxide-Coated Hollow Polymethylmethacrylate Microspheres (MHPM)

2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
Dhiraj Dutta ◽  
Jyoti Prasad Borah ◽  
Amrit Puzari
Keyword(s):  
Aqueous Solution ◽  
Manganese Oxide ◽  
Adsorption Capacity ◽  
High Surface ◽  
High Surface Area ◽  
Freundlich Isotherm ◽  
Ion Concentration ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Coated Sand

Results of investigation on adsorption of Mn2+ from aqueous solution by manganese oxide-coated hollow polymethylmethacrylate microspheres (MHPM) are reported here. This is the first report on Mn-coated hollow polymer as a substitute for widely used materials like green sand or MN-coated sand. Hollow polymethylmethacrylate (HPM) was prepared by using a literature procedure. Manganese oxide (MnO) was coated on the surface of HPM (MHPM) by using the electroless plating technique. The HPM and MHPM were characterized by using optical microscopy (OM), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and thermogravimetric analysis (TGA). Optical and scanning micrographs were used to monitor the surface properties of the coated layer which revealed the presence of MnO on the surface of HPM. TGA showed the presence of 4-5% of MnO in MHPM. Adsorption isotherm studies were carried out as a function of pH, initial ion concentration, and contact time, to determine the adsorption efficiency for removal of Mn2+ from contaminated water by the synthesized MHPM. The isotherm results showed that the maximum adsorption capacity of MnO-coated HPM to remove manganese contaminants from water is 8.373 mg/g. The obtained R 2 values of Langmuir isotherm and Freundlich isotherm models were 1 and 0.87, respectively. Therefore, R 2 magnitude confirmed that the Langmuir model is best suited for Mn2+ adsorption by a monolayer of MHPM adsorbent. The material developed shows higher adsorption capacity even at a higher concentration of solute ions, which is not usually observed with similar materials of this kind. Overall findings indicate that MHPM is a very potential lightweight adsorbent for removal of Mn2+ from the aqueous solution because of its low density and high surface area.

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