scholarly journals Arsenic (III) Removal from Aqueous Water by Indigenous Iron Ore Adsorbent from Balochistan Province of Pakistan

2021 ◽  
Vol 40 (1) ◽  
pp. 16-30
Author(s):  
Zulfiqar Ali Bhatti
Keyword(s):  
Iron Ore ◽  
Arsenic Removal ◽  
Hydride Generation ◽  
Freundlich Isotherm ◽  
Adsorption Method ◽  
X Ray ◽  
Removal Of Arsenic ◽  
Optimized Conditions ◽  
Adsorption Intensity ◽  
Oval Shape

The work focuses on the removal of Arsenic-III (As(III)) from water sample by an indigenous iron ore from Balochistan by adsorption method. Three iron ore samples were analyzed by X-Ray Diffractometer (XRD) and a sample from Shikarap containing iron 36.2% was selected because it contained the highest amount of hematite. The batch study was conducted to examine the adsorption by iron ore and maximum adsorption was observed at pH 6, 1/2 g dose per 50 mL solution, contact time 2 hr and shaking speed 150 rpm. At the optimized conditions, the removal was 89% when monitored at 50μg L-1 initial concentration of arsenic. The arsenic removal was monitored by Atomic Absorption Spectrometer (AAS) using hydride generation. Dubinin - Radushkevich (D-R), Freundlich and Langmuir's isotherms were examined. The highest adsorption capacityof iron ore for As(III) removal was observed 13.67 μg g-1 by Langmuir model and Freundlich isotherm indicated good adsorption intensity with value n = 1.512. Thermodynamic parameters revealed that adsorption was exothermic and physisorption. The Scanning Electron Microscope (SEM) and Energy Dispersive X-Ray (EDX)techniques were applied to scan the surface morphology and the percentage elemental composition of samples respectively. SEM results demonstrated that Shikarap mineral grains are an oval shape and these were changed after the uptake of As(III). The EDX spectra of Shikarap mineral confirm the As(III) adsorption on particles as As 4.19%.

scholarly journals Arsenic Removal from Aqueous Solutions Using Carbon Embedded Silica and Zeolite: Column Adsorption Studies

2020 ◽  
pp. 42-53
Keyword(s):  
Aqueous Solutions ◽  
Rice Husk ◽  
Arsenic Removal ◽  
Freundlich Isotherm ◽  
Column Height ◽  
Isotherm Models ◽  
Tem Analysis ◽  
X Ray ◽  
Transmission Electron ◽  
Column Adsorption

Column adsorption of the As (III) & As (V) using rice husk mediated carbon embedded silica (CES) and zeolite (Z-RHA) has been proved promising technique rather than the other conventional methods. The present work investigates the adsorption capability of newly manufactured CES and Z-RHA to remove As (III) & As (V) from aqueous solutions. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Scanning electron microscope (SEM), Energy dispersive X-ray (EDX), and Transmission electron microscopy (TEM) analysis have been investigated for the characterization of synthesized materials. The effects of different parameters like initial concentrations, column diameter, column height, particle size distribution have been investigated. The maximum removal efficiency of CES adsorbents for As (III) is 98% and for As (V) is 85%, and of Z-RHA for As (III) is 95% and for As (V) is 92%. To describe the adsorption behavior the Langmuir and Freundlich isotherm models as well as to kinetics models like Adam-Bohart, Thomas, and Yoon Nelson model were applied. Finally, to dispose of the rice husk mediated adsorbents after arsenic treatment solidification has been done.

scholarly journals Arsenic Removal from Arsenopyrite-Bearing Iron Ore and Arsenic Recovery from Dust Ash by Roasting Method

Processes ◽  
2019 ◽  
Vol 7 (10) ◽  
pp. 754 ◽  
Author(s):  
Rijin Cheng ◽  
Hua Zhang ◽  
Hongwei Ni
Keyword(s):  
Inductively Coupled Plasma ◽  
Iron Ore ◽  
Arsenic Removal ◽  
Chemical Properties ◽  
Atomic Emission ◽  
Nitrogen Atmosphere ◽  
Emission Spectrometry ◽  
Plasma Atomic Emission Spectrometry ◽  
X Ray ◽  
Reducing Atmosphere

In most cases, arsenic is an unfavorable element in metallurgical processes. The mechanism of arsenic removal was investigated through roasting experiments performed on arsenopyrite-bearing iron ore. Thermodynamic calculation of arsenic recovery was carried out by FactSage 7.0 software (Thermfact/CRCT, Montreal, Canada; GTT-Technologies, Ahern, Germany). Moreover, the arsenic residues in dust ash were recovered by roasting dust ash in a reducing atmosphere. Furthermore, the corresponding chemical properties of the roasted ore and dust ash were determined by X-ray diffraction, inductively coupled plasma atomic emission spectrometry, and scanning electron microscopy, coupled with energy-dispersive X-ray spectroscopy. The experimental results revealed that the arsenic in arsenopyrite-bearing iron ore can be removed in the form of As2O3(g) in an air or nitrogen atmosphere by a roasting method. The efficiency of arsenic removal through roasting in air was found to be less than that in nitrogen atmosphere. The method of roasting in a reducing atmosphere is feasible for arsenic recovery from dust ash. When the carbon mass ratio in dust ash is 1.83%, the arsenic removal products is almost volatilized and recovered in the form of As2O3(g).

scholarly journals Removal of Arsenic (III) Present in Ground Water of Bangladesh with Polymer Supported Hydrated Fe(III) Oxides

2015 ◽  
Vol 63 (2) ◽  
pp. 85-89
Author(s):  
Mohammad Arifur Rahman ◽  
Evanta Kabir ◽  
AM Shafiqul Alam
Keyword(s):  
Efficient Method ◽  
Arsenic Removal ◽  
Specific Interaction ◽  
Contaminated Groundwater ◽  
Nacl Solution ◽  
Preferential Adsorption ◽  
Membrane Effect ◽  
Polymer Supported ◽  
Removal Of Arsenic ◽  
Optimized Conditions

In the present study, a technique to remove arsenic has been developed with a polymer-supported hydrated Fe(III) oxide (HFO) by using a strongly basic anionic exchanger IRA-420 as the host material and FeCl3-HCl-NaCl solution as the reaction environment. The optimized conditions were applied to a sample collected from Sonargaon, Dhaka. The removal efficiency of this method was more than 80%, which indicates that this method can be used as an efficient method for arsenic removal in Bangladesh. IRA-420-HFO exhibits more preferential adsorption of arsenic ions which is attributed to the Donnan membrane effect exerted by the host resin (IRA-420) as well as to the loaded HFO particles for specific interaction toward arsenic (III) ions. All the results indicated that HFO polymer derivative is an attractive adsorbent for efficient arsenic (III) removal from contaminated groundwater of Bangladesh.Dhaka Univ. J. Sci. 63(2):85-89, 2015 (July)

scholarly journals Specifically designed magnetic biochar from waste wood for arsenic removal

2021 ◽  
Vol 31 (1) ◽  
Author(s):  
Chih-Kuei Chen ◽  
Jia-Jia Chen ◽  
Nhat-Thien Nguyen ◽  
Thuy-Trang Le ◽  
Nguyen-Cong Nguyen ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Arsenic Removal ◽  
Physical Adsorption ◽  
Adsorption Method ◽  
Waste Wood ◽  
Processing Technologies ◽  
Magnetic Biochar ◽  
X Ray ◽  
Modified Biochar ◽  
Operation Conditions

AbstractArsenic is a carcinogenic substance, with many cases of poisoning related to arsenic pollution in groundwater. In Taiwan arsenic in groundwater caused the notorious Blackfoot disease. Methods for arsenic removal from water include precipitation, membrane processes, ion exchange, and adsorption, but these processing technologies suffer from high investment costs and complex operations. The traditional adsorption method cannot be used for arsenic removal due to its high operating costs, difficulties in recovery, and low adsorption capacity. To address these issues, this study designed an adsorption material based on biochar for arsenic removal with higher adsorption properties and easy recovery. Biochar sources are readily available from waste wood as a cheap and environmentally friendly material. The efficiency of As (III) removal is also promoted by FeCl3 and KMnO4. The objectives of this research are to obtain optimum operation conditions by assessing the effects of different iron and manganese contents, different doses, different pH and different initial concentration. The adsorption mechanism between As (III) and biochar was studied by adsorption isotherms and the kinetic model. X-ray diffraction, energy-dispersive X-ray spectroscopy and elemental analyzer analysis results show that modified biochar has major elements of Fe and Mn. There is greater magnetism, 40 emu g− 1, in the modified biochar. The maximum adsorption efficiency of 81% and 0.72 mg g− 1 capacity occurs when the ratio of Mn, Fe and C is 4:1:1. The adsorption capacity is high under higher pH with pristine biochar and 1FeC under lower pH with 1Fe2MnC. The reaction mechanism is divided into four pathways. The first pathway is the attachment of As (III) ions into the pore of biochar via physical adsorption. In the second pathway, biochar can connect with As (III) through hydrogen bonding from the function group -OH in the biochar and the As (III) itself. In the third pathway, they can contact each other by electron force when the biochar surface is filled with a positive charge. In the fourth pathway, the compounds of manganese have strong oxidizability to oxidize As (III) to As(V). The iron ions then act as a bridge connecting the biochar and the As (III), resulting in the formation of new complex compounds.

Experimental Study of Adsorption Treatment of the Arsenic-Containing Rural Drinking Groundwater

2013 ◽  
Vol 295-298 ◽  
pp. 1129-1134
Author(s):  
Jing Liu ◽  
Hua Yang ◽  
Yan Zuo ◽  
Zhi Min Ren ◽  
De Jun Bian
Keyword(s):  
Experimental Study ◽  
Drinking Water ◽  
Room Temperature ◽  
Arsenic Removal ◽  
Ph Value ◽  
Adsorption Method ◽  
Adsorption Time ◽  
Ph Values ◽  
Adsorption Treatment ◽  
Removal Of Arsenic

The arsenic-containing rural drinking groundwater was treated by adsorption method in the paper. It was studied that the varieties and dosages of adsorbents, pH value and adsorption time have an effect on removal of arsenic. The experimental results indicated that the rate of arsenic removal is able to reach 91.39% at room temperature and under the condition of neutral pH values, 2.0 g of zeolite as adsorbent and 1 h of adsorption time. The content of arsenic in the treated drinking groundwater can be up to the current national hygiene standards of rural drinking water (<0.05mg /L).

Arsenic removal by MF membrane with chemical sludge adsorption and NF membrane equipped with vibratory shear enhanced process

2003 ◽  
Vol 3 (5-6) ◽  
pp. 303-310 ◽  
Author(s):  
S.-H. Yi ◽  
S. Ahmed ◽  
Y. Watanabe ◽  
K. Watari
Keyword(s):  
Arsenic Removal ◽  
Membrane Surface ◽  
Membrane Process ◽  
Low Concentrations ◽  
Strong Shear ◽  
Low Levels ◽  
Removal Processes ◽  
Removal Of Arsenic ◽  
Concentration Polarization Layer ◽  
Chemical Sludge

Conventional arsenic removal processes have difficulty removing low concentrations of arsenic ion from water. Therefore, it is very hard to comply with stringent low levels of arsenic, such as below 10 μg/L. So, we have developed two arsenic removal processes which are able to comply with more stringent arsenic regulations. They are the MF membrane process combined with chemical sludge adsorption and NF membrane process equipped with the vibratory shear enhanced process (VSEP). In this paper, we examine the performance of these new processes for the removal of arsenic ion of a low concentration from water. We found that chemical sludge produced in the conventional rapid sand filtration plants can effectively remove As (V) ions of H2AsO4- and HAsO42- through anion exchange reaction. The removal efficiency of MF membrane process combined with chemical sludge adsorption increased to about 36%, compared to MF membrane alone. The strong shear force on the NF membrane surface produced by vibration on the VSEP causes the concentration polarization layer to thin through increased back transport velocity of particles. So, it can remove even dissolved constituents effectively. Therefore, As (V) ions such as H2AsO4- and HAsO42- can be removed. The concentration of As (V) ions decreased from 50 μg/L to below 10 μg/L and condensation factor in recirculating water increased up to 7 times by using NF membrane equipped with VSEP.

scholarly journals Release of toxic methylene blue from water by mesoporous silicalite-1: characterization, kinetics and isotherm studies

2021 ◽  
Vol 11 (7) ◽  
Author(s):  
Sabarish Radoor ◽  
Jasila Karayil ◽  
Aswathy Jayakumar ◽  
Jyotishkumar Parameswaranpillai ◽  
Suchart Siengchin
Keyword(s):  
Electron Microscopy ◽  
Contact Time ◽  
Dye Removal ◽  
Batch Adsorption ◽  
Aqueous Environment ◽  
Order Kinetic ◽  
Adsorption Method ◽  
X Ray ◽  
Ft Ir ◽  
Adsorption Desorption

AbstractIn the present work, we have developed a mesoporous silicalite-1 using CMC as a template for the removal of MB from aqueous solution. The synthesized silicalite-1 were characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), Energy-dispersive X-ray spectroscopy (EDAX) and N2 adsorption–desorption isotherm (BET). XRD and FT-IR analysis confirmed the formation of crystallinity and development of MFI structure in the mesoporous silicalite-1. The adsorption of MB dye on mesoporous silicalite-1 was conducted by batch adsorption method. The effect of various parameters such as adsorbent dosage, initial dye concentration, contact time and temperature on the dye uptake ability of silicalite-1 was investigated. The operating parameters for the maximum adsorption are silicalite-1 dosage (0.1 wt%), contact time (240 min), initial dye concentration (10 ppm) and temperature (30 ℃). The MB dye removal onto mesoporous silicalite-1 followed pseudo-second-order kinetic and Freundlich isotherm. The silicalite-1 exhibits 86% removal efficiency even after six adsorption–desorption cycle. Therefore, the developed mesoporous silicalite-1 is an effective eco-friendly adsorbent for MB dye removal from aqueous environment.

scholarly journals Evaluation of Fe-Mg Binary Oxide for As (III) Adsorption—Synthesis, Characterization and Kinetic Modelling

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 805
Author(s):  
Saif Ullah Khan ◽  
Rumman Zaidi ◽  
Feroz Shaik ◽  
Izharul Haq Farooqi ◽  
Ameer Azam ◽  
...  
Keyword(s):  
Arsenic Removal ◽  
Kinetic Modelling ◽  
Arsenic Concentration ◽  
Experimental Studies ◽  
Precipitation Method ◽  
Arsenic Adsorption ◽  
Adsorbent Dosage ◽  
X Ray ◽  
Co Precipitation ◽  
Contaminated Waters

Nanotechnology has received much attention in treating contaminated waters. In the present study, a facile co-precipitation method was employed to synthesize a novel iron and magnesium based binary metal oxide using a stoichiometrically fixed amount of FeNO3.9H2O and MgNO3.6H2O in a proportion of molar concentration 1:1 and was later evaluated in removing As (III) from contaminated waters. Characterization of the prepared nanomaterial was done using X-ray diffraction (XRD), scanning electron microscopy (SEM), Energy Dispersive X-Ray Analysis (EDAX) and ultraviolet–visible spectrophotometry (UV-VIS). Experimental studies on batch scale were carried out, examining the effect of varying initial concentrations of metal, adsorbent dosage, application time and initial pH on removal efficiency. Arsenic removal increased on increasing adsorbent dosage (0.1–1 g/L) but trend reversed on increasing initial arsenic concentration attaining qmax of 263.20 mg/g. Adsorption was quite efficient in pH range 4–8. Freundlich fitted better for adsorption isotherm along with following Pseudo-2nd order kinetics. The reusability and effect of co-existing ions on arsenic adsorption, namely SO42−, CO32− and PO43− were also explored with reusability in 1st and 2nd cycles attained adsorptive removal up to 77% and 64% respectively. The prepared nano-adsorbent showed promising results in terms of high arsenic uptake (qmax of 263.20 mg/g) along with facile and cost-effective synthesis. Thus, the co-precipitation technique used in this work is a simple one step procedure without any use of any precursor as compared to most of the other procedures used for synthesis.

scholarly journals Freeze–Thaw Resistance and Air-Void Analysis of Concrete with Recycled Glass–Pozzolan Using X-ray Micro-Tomography

Materials ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 154
Author(s):  
Marija Krstic ◽  
Julio F. Davalos ◽  
Emanuele Rossi ◽  
Stefan C. Figueiredo ◽  
Oguzhan Copuroglu
Keyword(s):  
Fly Ash ◽  
Pore Structure ◽  
The United States ◽  
Adsorption Method ◽  
X Ray ◽  
Freeze Thaw ◽  
Void System ◽  
Spatial Parameters ◽  
Micro Tomography ◽  
Air Void

Recent studies have shown promising potential for using Glass Pozzolan (GP) as an alternative supplementary cementitious material (SCM) due to the scarcity of fly ash and slag in the United States. However, comprehensive studies on the freeze–thaw (FT) resistance and air void system of mixtures containing GP are lacking. Therefore, this study aimed to evaluate GP’s effect on FT resistance and characterize mixtures with different GP contents, both macro- and microscopically. In this study, six concrete mixes were considered: Three mixes with 20%, 30% and 40% GP as cement replacements and two other comparable mixes with 30% fly ash and 40% slag, as well as a mix with 100% Ordinary Portland cement (OPC) as a reference. Concrete samples were prepared, cured and tested according to the ASTM standards for accelerated FT resistance for 1000 cycles and corresponding dynamic modulus of elasticity (Ed). All the samples showed minimal deterioration and scaling and high F/T resistance with a durability factor of over 90%. The relationships among FT resistance parameters, air-pressured method measurements of fresh concretes and air void analysis parameters of hardened concretes were examined in this study. X-ray micro-tomography (micro-CT scan) was used to evaluate micro-cracks development after 1000 freeze–thaw cycles and to determine spatial parameters of air voids in the concretes. Pore structure properties obtained from mercury intrusion porosimetry (MIP) and N2 adsorption method showed refined pore structure for higher cement replacement with GP, indicating more gel formation (C-S-H) which was verified by thermogravimetric analysis (TGA).

Preparation of xanthated bentonite and its removal behavior for Pb(II) ions

2010 ◽  
Vol 61 (5) ◽  
pp. 1235-1243 ◽  
Author(s):  
Y. F. He ◽  
F. R. Li ◽  
R. M. Wang ◽  
F. Y. Li ◽  
Y. Wang ◽  
...  
Keyword(s):  
Adsorption Mechanism ◽  
Removal Rate ◽  
Freundlich Isotherm ◽  
Particle Size Analysis ◽  
Lead Ions ◽  
Size Analysis ◽  
Optimum Conditions ◽  
X Ray Diffraction ◽  
X Ray ◽  
Ft Ir

Xanthate was successfully grafted onto bentonite by a relatively simple solution reaction. The obtained xanthated bentonite (XBent) was characterized by FT-IR spectrophotometer, thermogravimetric analysis (TG), particle size analysis, x-ray diffraction (XRD) and scanning electron microscopy (SEM). XBent acting as a type of environmentally friendly adsorbent was applied to remove lead ions from aqueous solutions. The optimum conditions were as follows: [Pb2 + ] = 500 mg L−1, [XBent] = 2 g L−1, pH = 5.0; oscillating 60 min under 200 rpm at 25°C. The removal rate of lead was up to 99.9%. It was found that the lead(II) ions—XBent adsorption isotherm model fitted well to the Freundlich isotherm. The adsorption mechanism was also investigated by SEM and XRD, which concluded that lead ions were complexed or chelated with XBent. XBent appears to have potential to be used later in water treatment as a type of inorganic polymer reagent.

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