scholarly journals Content of fluorine in soils in the vicinity of aluminium plant in Podgorica

2002 ◽  
Vol 47 (1) ◽  
pp. 1-8
Author(s):  
Srdjan Blagojevic ◽  
Miodrag Jakovljevic ◽  
Mirjana Radulovic

The purpose of this paper was to determine whether soils, located in the vicinity of the aluminium plant in Podgorica, are polluted with fluorine. For this purpose 60 soil samples (26 of brown and 34 of alluvial soil) were collected from two depths (0 to 20 and 20 to 40 cm). Total and available fluorine were determined by potentiometric method, after necessary preparations of soil samples for the analysis. It was found that in almost all soil samples the content of total fluorine was above 300 mg/kg - maximum permissible value for the content of this element in agricultural soils. Highest values were found on locations southwards of the aluminium plant. However, the content of available fluorine (soluble in water) in the soil samples is very low (average value is 0.70 mg/kg) indicating that major part of deposited fluorine had transformed itself into insoluble compounds like CaF2.

2021 ◽  
Author(s):  
Poniman Poniman ◽  
Anik Hidayah ◽  
Sukarjo Sukarjo

Cadmium (Cd) is a heavy metal that is prohibited in food products. In the long term, consumption of food containing Cd can cause cancer (it is a direct carcinogen in humans). Poor management of the Serayu watershed has resulted in pollution of the surrounding land. Meanwhile, trust in management must be built within the framework of trade in the Industrial Era 4.0, which is developing continuously in world trade relations. This study aimed to obtain information on the distribution of Cd in agricultural soils in the middle of the Serayu watershed in March-August 2017. A total of 220 soil samples were taken using the GRID method, and the analysis of Cd concentration was determined by atomic absorption spectrofotometry (AAS). The results showed that Cd was detected in 142 soil samples in the range of 1.0-<1.5 mg kg−1 and detected in the range of 0.5-<1.0 mg kg−1 in 78 soil samples. The results were non-normally distributed with a clustered distribution pattern. The average value of the distribution of Cd in agricultural land in the middle of Serayu watershed was 1.21 mg kg−1, and the highest Cd concentration was 2.18 mg kg−1. The Cd concentration in the middle of the Serayu watershed is classified within the safe category because the concentration is still below the critical Cd threshold value of 3-8 mg kg−1. Keywords: agricultural land, cadmium, distribution, the middle of Serayu watershed


2020 ◽  
Vol 66 (5) ◽  
pp. 916-929
Author(s):  
Eligio Malusá ◽  
Małgorzata Tartanus ◽  
Witold Danelski ◽  
Artur Miszczak ◽  
Ewelina Szustakowska ◽  
...  

Abstract The analysis of 142 agricultural soil samples collected in organic farms across Poland with the intent to evaluate the level of DDT contamination resulted in more than 80% of the soils containing DDT. The ΣDDT (sum of all metabolites and isomers) concentration ranged between 0.005 and 0.383 mg/kg ΣDDT, with an average value of 0.064 mg/kg ΣDDT. However, the majority of plant samples collected from the crops growing on the sampled soils did not contain detectable DDT residues. The high DDT pollution levels detected in samples from four voivodeships (regions) among those monitored have been hypothesised to be linked to horticultural productions occurring to the sampled fields and typical of those regions, particularly in big-sized farms, during the period of DDT application, as well as the number of pesticides landfills present in these voivodeships. The elaboration of the o,p′-DDT/p,p′-DDT and DDT/(DDE + DDD) ratios to appraise the source or the period of contamination suggested that the contamination originated from past use of DDT rather than from impurities of more recent applications of other formulated substances. Such outcome thus suggests that the risk of contamination of organic products is likely derived from general environmental pollution levels rather than from the use of unauthorised substances in organic farming productions. Data from a trial with artificial contamination of soils indicated that using the DDT/(DDE + DDD) ratio in the presence of a low level of contamination could be less reliable than in highly contaminated soils.


2020 ◽  
Vol 4 (1) ◽  
pp. 14-28
Author(s):  
S. K. Gaikwad ◽  
N. D. Pathan ◽  
N. S. Bansode ◽  
S. P. Gaikwad ◽  
Y. P. Badhe ◽  
...  

To study the chemistry of major ion in groundwater from Vel (Velu) River basin, sixty (60) samples of dug wells and bore wells were collected and analyzed using standard techniques given by APHA. It shows order of dominance for cations, Na+ > Ca2+ > Mg2+ > K+ and in anionic concentration as HCO3- > Cl- > SO42- in groundwater. The pH of groundwater is slightly alkaline (range: pH 7.0 - 8.1), while average values of Electrical Conductivity (EC) is about 2641 µS/cm indicating high mineralization of groundwater. In general, the cationic concentration (Na+, K+, Ca2+ and Mg2+) of the groundwater increase in the downstream side (from Northwest to South east), suggesting geological control on the composition of groundwater while highest concentration is in lower part of the basin are generally associated with the high salinity. In the major anions, bicarbonate (HCO3-) is higher due to rock-water interaction. Average value of chloride is about of 235 mg/L due to discharge zones along with anthropogenic activities. The geochemical data plotted on Piper Trilinear Diagram is showing dominant hydro-chemical facies: Ca2++Mg2+, Na++ K+, Cl-+ SO42- -HCO3- found in 83.3 % samples indicating the alkaline earth exceeding the alkalis and the strong acids exceeds the weak acids. The pH, Total Hardness (TH) and Magnesium (Mg2+) of the samples show more proportion of samples falling above desirable limit. Otherwise the quality of groundwater is good for drinking. The irrigation indices like SAR, KR and SSP were considered to evaluate groundwater suitability for irrigation. Comparing with SAR parameter all samples are excellent to good for irrigation. In SSP, 33.3 % samples are within permissible, while 66.6% samples are doubtful for irrigation purpose. In KR almost all samples (excluding 04 samples in lower side of basin) are suitable for irrigation. So, variations in climate, geology with anthropogenic activities are modifying the groundwater geochemistry of Vel River Basin.


Minerals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 373
Author(s):  
Jonathan Suazo-Hernández ◽  
Erwin Klumpp ◽  
Nicolás Arancibia-Miranda ◽  
Patricia Poblete-Grant ◽  
Alejandra Jara ◽  
...  

Engineered nanoparticles (ENPs) present in consumer products are being released into the agricultural systems. There is little information about the direct effect of ENPs on phosphorus (P) availability, which is an essential nutrient for crop growthnaturally occurring in agricultural soils. The present study examined the effect of 1, 3, and 5% doses of Cu0 or Ag0 ENPs stabilized with L-ascorbic acid (suspension pH 2–3) on P ad- and desorption in an agricultural Andisol with total organic matter (T-OM) and with partial removal of organic matter (R-OM) by performing batch experiments. Our results showed that the adsorption kinetics data of H2PO4− on T-OM and R-OM soil samples with and without ENPs were adequately described by the pseudo-second-order (PSO) and Elovich models. The adsorption isotherm data of H2PO4− from T-OM and R-OM soil samples following ENPs addition were better fitted by the Langmuir model than the Freundlich model. When the Cu0 or Ag0 ENPs doses were increased, the pH value decreased and H2PO4− adsorption increased on T-OM and R-OM. The H2PO4− desorption (%) was lower with Cu0 ENPs than Ag0 ENPs. Overall, the incorporation of ENPs into Andisols generated an increase in P retention, which may affect agricultural crop production.


2009 ◽  
Vol 66 (3) ◽  
pp. 361-367 ◽  
Author(s):  
Gustavo Souza Valladares ◽  
Otávio Antônio de Camargo ◽  
José Ruy Porto de Carvalho ◽  
Alessandra Maria Cia Silva

Agricultural management with chemicals may contaminate the soil with heavy metals. The objective of this study was to apply Principal Component Analysis and geoprocessing techniques to identify the origin of the metals Cu, Fe, Mn, Zn, Ni, Pb, Cr and Cd as potential contaminants of agricultural soils. The study was developed in an area of vineyard cultivation in the State of São Paulo, Brazil. Soil samples were collected and GPS located under different uses and coverings. The metal concentrations in the soils were determined using the DTPA method. The Cu and Zn content was considered high in most of the samples, and was larger in the areas cultivated with vineyards that had been under the application of fungicides for several decades. The concentrations of Cu and Zn were correlated. The geoprocessing techniques and the Principal Component Analysis confirmed the enrichment of the soil with Cu and Zn because of the use and management of the vineyards with chemicals in the preceding decades.


2015 ◽  
Vol 39 (1) ◽  
pp. 31-39 ◽  
Author(s):  
Ivanildo Amorim de Oliveira ◽  
Milton César Costa Campos ◽  
José Marques Junior ◽  
Renato Eleotério de Aquino ◽  
Daniel de Bortoli Teixeira ◽  
...  

The lack of information concerning the variability of soil properties has been a major concern of researchers in the Amazon region. Thus, the aim of this study was to evaluate the spatial variability of soil chemical properties and determine minimal sampling density to characterize the variability of these properties in five environments located in the south of the State of Amazonas, Brazil. The five environments were archaeological dark earth (ADE), forest, pasture land, agroforestry operation, and sugarcane crop. Regular 70 × 70 m mesh grids were set up in these areas, with 64 sample points spaced at 10 m distance. Soil samples were collected at the 0.0-0.1 m depth. The chemical properties of pH in water, OM, P, K, Ca, Mg, H+Al, SB, CEC, and V were determined at these points. Data were analyzed by descriptive and geostatistical analyses. A large part of the data analyzed showed spatial dependence. Chemical properties were best fitted to the spherical model in almost all the environments evaluated, except for the sugarcane field with a better fit to the exponential model. ADE and sugarcane areas had greater heterogeneity of soil chemical properties, showing a greater range and higher sampling density; however, forest and agroforestry areas had less variability of chemical properties.


Author(s):  
C. E. Soteros ◽  
D. W. Sumners ◽  
S. G. Whittington

AbstractIn this paper we are concerned with questions about the knottedness of a closed curve of given length embedded in Z3. What is the probability that such a randomly chosen embedding is knotted? What is the probability that the embedding contains a particular knot? What is the expected complexity of the knot? To what extent can these questions also be answered for a graph of a given homeomorphism type?We use a pattern theorem due to Kesten 12 to prove that almost all embeddings in Z3 of a sufficiently long closed curve contain any given knot. We introduce the idea of a good measure of knot complexity. This is a function F which maps the set of equivalence classes of embeddings into 0, ). The F measure of the unknot is zero, and, generally speaking, the more complex the prime knot decomposition of a given knot type, the greater its F measure. We prove that the average value of F diverges to infinity as the length (n) of the embedding goes to infinity, at least linearly in n. One example of a good measure of knot complexity is crossing number.Finally we consider similar questions for embeddings of graphs. We show that for a fixed homeomorphism type, as the number of edges n goes to infinity, almost all embeddings are knotted if the homeomorphism type does not contain a cut edge. We prove a weaker result in the case that the homeomorphism type contains at least one cut edge and at least one cycle.


SOIL ◽  
2015 ◽  
Vol 1 (1) ◽  
pp. 23-33 ◽  
Author(s):  
S. Czarnecki ◽  
R.-A. Düring

Abstract. Essential and non-essential metals occur in soils as a result of weathering, industrial processes, fertilization, and atmospheric deposition. Badly adapted cultivation of agricultural soils (declining pH value, application of unsuitable fertilizers) can enhance the mobility of metals and thereby increase their concentrations in agricultural products. As the enrichment of metals in soils occurs over long time periods, monitoring of the long-term impact of fertilization is necessary to assess metal accumulation in agricultural soils. The main objective of this study was to test the effects of different mineral fertilizer variations on soil properties (pH, Corg, and cation exchange capacity (CEC)) and pseudo-total and mobile metal contents of soils after 14 years of fertilizer application and to determine residual effects of the fertilization 8 years after cessation of fertilizer treatment. Soil samples were taken from a field experiment which was carried out at four different locations (210, 260, 360, and 620 m above sea level) in Hesse, Germany. During the study, a significant decrease in soil pH and an evident increase in soil carbon content and cation exchange capacity with fertilization were determined. The CEC of the soils was closely related to their organic C contents. Moreover, pseudo- and mobile metal (Cd, Cu, Mn, Pb, Zn) contents in the soils increased due to application of 14 years of mineral fertilizer treatments (N, P, NP, and NPK) when compared to control plots. Eight years after termination of the fertilization in the soil samples taken from soil profiles of the fertilized plots (NPK) for monitoring the residual effects of the fertilizer application, a decrease of 82.6, 54.2, 48.5, 74.4, and 56.9% in pseudo-total Cd, Cu, Mn, Pb, and Zn contents, respectively, was determined.


2002 ◽  
Vol 11 (4) ◽  
pp. 285-300 ◽  
Author(s):  
V. MÄNTYLAHTI ◽  
P. LAAKSO

Increasing concentrations of arsenic and heavy metals in agricultural soils are becoming a growing problem in industrialized countries. These harmful elements represent the basis of a range of problems in the food chain, and are a potential hazard for animal and human health. It is therefore important to gauge their absolute and relative concentrations in soils that are used for crop production. In this study the arsenic and heavy metal concentrations in 274 mineral soil samples and 38 organogenic soil samples taken from South Savo province in 2000 were determined using the aqua regia extraction technique. The soil samples were collected from 23 farms.The elements analyzed were arsenic, cadmium, chromium, copper, mercury, nickel, lead and zinc. The median concentrations in the mineral soils were:As 2.90 mg kg –1, Cd 0.084 mg kg –1, Cr 17.0 mg kg –1, Cu 13.0 mg kg –1, Hg 0.060 mg kg –1, Ni 5.4 mg kg –1, Pb 7.7 mg kg –1, Zn 36.5 mg kg –1. The corresponding values in the organogenic soils were:As 2.80 mg kg –1, Cd 0.265 mg kg –1, Cr 15.0 mg kg –1, Cu 29.0 mg kg –1, Hg 0.200 mg kg –1, Ni 5.9 mg kg –1, Pb 11.0 mg kg –1, Zn 25.5 mg kg –1. The results indicated that cadmium and mercury concentrations in the mineral and organogenic soils differed. Some of the arsenic, cadmium and mercury concentrations exceeded the normative values but did not exceed limit values. Most of the agricultural fields in South Savo province contained only small amounts of arsenic and heavy metals and could be classified as “Clean Soil”. A draft for the target values of arsenic and heavy metal concentrations in “Clean Soil” is presented.;


2017 ◽  
Vol 2 (3) ◽  
pp. 12
Author(s):  
Maya Setiawardani ◽  
Tintin Suhaeni

Mastery of keyboarding being part urgent to communicate through the computer, and very important, especially students who study in the field of business. On the other side, individual performance also influenced by the work environment, and music is one form the environment that could effect keyboarding performance. A model that can describe this is the stimulus-responsible model of mehrabian-russell which explains that music can affect the performance of individual writing. Almost all of Indonesia has traditional music. Therefore, research is needed to identify the effects of traditional music to enrich the area of innovation in strategies and techniques of learning keyboarding skills. In this study conducted an experiment on two groups, the treatment groups(traditional music) and control group (without traditional) and questionnaire to strengthen the experimental results. In preliminary tests of typing, both groups had a mean AWPM identical or similar. Furthermore, tests carried one, where the treatment group listened to five kinds of music Java, Sunda, and Bali. The test result and the result of the questionnaire showed that (typing skills shown by the average value of AWPM) will increase significantly used of traditional music as the background. So, the genre of traditional music can be stimulant to improve average performance of AWPM. There are three traditional kinds of music that can improve student typing speed and accuracy significantly, a regional music cublek-cublek suweng, kebiar bali, and oleg tambuliningan, but cublek-cublek suweng is a genre of traditional music that has the best effect. Therefore, the process of learning courses keyboarding skills needs to use instrumental traditional music, especially instrumental music that has a fast and cheerfully tempo.


Sign in / Sign up

Export Citation Format

Share Document