scholarly journals Preparation of Magnetically Driven Nickel Phosphide Nanowires and Their Electrochemical Properties

2021 ◽  
Vol 12 (1) ◽  
pp. 49
Author(s):  
Hye-Won Kim ◽  
Heon-Cheol Shin
Keyword(s):  
Aspect Ratio ◽  
Surface Area ◽  
Phosphorus Content ◽  
Nickel Phosphide ◽  
Phase Synthesis ◽  
Reaction Surface ◽  
Surface Areas ◽  
Low Phosphorus ◽  
Degradation Degree ◽  
First Time

In this study, nickel phosphide nanowires with various structures and compositions were fabricated for the first time via magnetically-assisted liquid phase synthesis. The curvature and aspect ratio of the nanowires largely depended on the strength of the magnetic field applied during synthesis. Their phosphorus content together with the morphology were significantly modified according to the pH and reducing agent concentration. Nanowires with different structures and phosphorus contents were preliminarily tested for their capabilities to serve in general electrochemical applications. The degree of reaction (i.e., amount of reaction charge) increased with increases in the reaction area and phosphorus content of the nanowires. The rate characteristics of the reaction showed a peculiar increasing trend for a small reaction surface area and low phosphorus content. A change in the ohmic overpotential according to the nanowire curvature (aspect ratio) and porosity was suggested to be the reason for this unusual trend. Electrodes with high phosphorus contents or high reaction surface areas rapidly deteriorated during repetitive redox reactions. Based on the results for the degradation degree, the effect of the reaction surface area dominated that of the phosphorus content in the deterioration of the nickel phosphide nanowires.

Mesoporous tantalum oxide photocatalysts for Schrauzer-type conversion of dinitrogen to ammonia

2005 ◽  
Vol 83 (4) ◽  
pp. 308-314 ◽  
Author(s):  
Chaoyang Yue ◽  
Michel L Trudeau ◽  
David Antonelli
Keyword(s):  
Surface Area ◽  
Tantalum Oxide ◽  
Catalytic Efficiency ◽  
Mesoporous Structure ◽  
Turnover Rates ◽  
Type Conversion ◽  
Electron Hole ◽  
Surface Areas ◽  
Before And After ◽  
First Time

Mesoporous tantalum oxide, Fe3+-doped mesoporous tantalum oxide, and bis(toluene) titanium reduced mesoporous tantalum oxide were used for the first time as Schrauzer-type photocatalysts for the conversion of dinitrogen to ammonia. The materials were characterized by XRD, TEM, XPS, and nitrogen absorption before and after catalytic runs. The results showed low to moderate activities depending on the composition. In contrast to previously studied Ti catalysts, Fe doping and heat pretreatment were not prerequisites for photocatalytic activity, but did improve the turnover rates by up to a factor of two. The optimal Fe loading for the tantalum oxides was found to be 1 wt% and the optimal heating condition at 300 °C for 3 h. Increased surface area and heat treatment were also found to improve activities. Contrary to our expectations, reduction of the mesostructure with bis(toluene) titanium had little effect on the catalytic activity. In spite of the dramatically higher surface areas of the mesoporous tantalum oxides as compared with bulk titanias used previously in this process, the overall catalytic activities were still less than those obtained in the Schrauzer system. This suggests that the increase in diffusion and surface area offered by the mesoporous structure is offset by the smaller crystalline domain sizes in the walls of the structure, leading to poor electron-hole separation and a reduction in catalytic efficiency. Key words: mesoporous, Schrauzer, ammonia, photocatalysis, tantalum oxide.

scholarly journals Accelerated room-temperature crystallization of ultrahigh-surface-area porous anatase titania by storing photogenerated electrons

2017 ◽  
Vol 53 (10) ◽  
pp. 1619-1621 ◽  
Author(s):  
Juan Su ◽  
Xiaoxin Zou ◽  
Binghan Li ◽  
Hui Chen ◽  
Xinhao Li ◽  
...  
Keyword(s):  
Reaction Time ◽  
Surface Area ◽  
Room Temperature ◽  
Surface Areas ◽  
Photogenerated Electrons ◽  
Anatase Titania ◽  
First Time ◽  
Temperature Crystallization

A technology for storing photogenerated electrons is for the first time applied for significantly accelerating the crystallization of amorphous TiO2 at room temperature (reducing the reaction time from 80 to 2 days). The resulting porous anatase titania exhibits ultrahigh surface areas up to 736 m2 g−1.

Anaerobic degradation of organic materials - significance of the substrate surface area

2003 ◽  
Vol 47 (12) ◽  
pp. 231-238 ◽  
Author(s):  
L.M. Palmowski ◽  
J.A. Müller
Keyword(s):  
Particle Size ◽  
Specific Surface ◽  
Surface Area ◽  
Anaerobic Degradation ◽  
Degradation Rate ◽  
Organic Materials ◽  
Sample Surface ◽  
Hydrolysis Rate ◽  
Surface Areas ◽  
Degradation Degree

In anaerobic degradation of substrates containing mainly particulate organic matter, solids hydrolysis is rate-limiting. In these investigations, the particle size of various substrates was reduced by comminution to support hydrolysis. Two positive effects of comminution were observed. For substrates with high fibre content, which are particularly resistant to biodegradation, a significant improvement of the degradation degree was observed as a result of comminution. Secondly, for all substrates tested, and particularly for those rich in fibres, the degradation rate of comminuted samples was significantly higher. The first reason for both effects is an increase of the sample surface area. Several methods for measuring the specific surface area of organic materials, including particle size analysis, Nitrogen-adsorption and enzyme adsorption, were used and compared for the purpose of this study, where the surface area accessible to microbial enzymes is critical. The significance of the surface area in anaerobic degradation of particulate substrates was investigated through a kinetic model where the hydrolysis rate was based on the sample surface area. Good agreements were obtained between model and experiments carried out with samples of various specific surface areas. These results reinforced the significance of the sample surface area in anaerobic degradation processes. However, other effects of comminution responsible for the increased degradation degree and degradation rate were identified and discussed. These include: the increase of dissolved compounds due to cell rupture, exposition of surface areas previously inaccessible for microbial degradation, and alteration of the sample structure such as the lignin-cellulose arrangements.

Cell morphology, volume, and surface area determinations from multilevel contouring within HVEM micrographs of serial sections and whole-cell mounts

1987 ◽  
Vol 45 ◽  
pp. 588-589
Author(s):  
M. Marko ◽  
A. Leith ◽  
D. Parsons
Keyword(s):  
Surface Area ◽  
Electron Micrographs ◽  
Cell Morphology ◽  
Individual Variation ◽  
Serial Section ◽  
Stereo Pair ◽  
Complex Structures ◽  
Serial Sections ◽  
Surface Areas ◽  
Computer Based

The use of serial sections and computer-based 3-D reconstruction techniques affords an opportunity not only to visualize the shape and distribution of the structures being studied, but also to determine their volumes and surface areas. Up until now, this has been done using serial ultrathin sections.The serial-section approach differs from the stereo logical methods of Weibel in that it is based on the Information from a set of single, complete cells (or organelles) rather than on a random 2-dimensional sampling of a population of cells. Because of this, it can more easily provide absolute values of volume and surface area, especially for highly-complex structures. It also allows study of individual variation among the cells, and study of structures which occur only infrequently.We have developed a system for 3-D reconstruction of objects from stereo-pair electron micrographs of thick specimens.

Inter Layer Dielectric Defect Induced High Contact Resistance

2010 ◽  
Author(s):  
Re-Long Chiu ◽  
Jason Higgins ◽  
Toby Kinder ◽  
Juha Tyni ◽  
Sharon Ying ◽  
...  
Keyword(s):  
Contact Resistance ◽  
Failure Analysis ◽  
Failure Mode ◽  
Phosphorus Content ◽  
Moisture Absorption ◽  
Thermal Processes ◽  
Analysis Methods ◽  
Low Phosphorus

Abstract High contact resistance can be caused by moisture absorption in low phosphorus content BPTEOS. Moisture diffused through the TiN glue layer is absorbed by the BPTEOS during subsequent thermal processes resulting in increased contact resistance. This failure mode was studied by combining different failure analysis methods and was confirmed by duplication on experimental wafers.

scholarly journals Tuning the hierarchical pore structure of graphene oxide through dual thermal activation for high-performance supercapacitor

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jeongpil Kim ◽  
Jeong-Hyun Eum ◽  
Junhyeok Kang ◽  
Ohchan Kwon ◽  
Hansung Kim ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Pore Structure ◽  
Specific Capacitance ◽  
Surface Area ◽  
Thermal Annealing ◽  
High Performance ◽  
Annealing Process ◽  
Supercapacitor Electrode ◽  
Simple Method ◽  
Surface Areas

AbstractHerein, we introduce a simple method to prepare hierarchical graphene with a tunable pore structure by activating graphene oxide (GO) with a two-step thermal annealing process. First, GO was treated at 600 °C by rapid thermal annealing in air, followed by subsequent thermal annealing in N2. The prepared graphene powder comprised abundant slit nanopores and micropores, showing a large specific surface area of 653.2 m2/g with a microporous surface area of 367.2 m2/g under optimized conditions. The pore structure was easily tunable by controlling the oxidation degree of GO and by the second annealing process. When the graphene powder was used as the supercapacitor electrode, a specific capacitance of 372.1 F/g was achieved at 0.5 A/g in 1 M H2SO4 electrolyte, which is a significantly enhanced value compared to that obtained using activated carbon and commercial reduced GO. The performance of the supercapacitor was highly stable, showing 103.8% retention of specific capacitance after 10,000 cycles at 10 A/g. The influence of pore structure on the supercapacitor performance was systematically investigated by varying the ratio of micro- and external surface areas of graphene.

Accelerating ion diffusion with unique three-dimensionally interconnected nanopores for self-membrane high-performance pseudocapacitors

Nanoscale ◽  
2017 ◽  
Vol 9 (46) ◽  
pp. 18311-18317 ◽  
Author(s):  
Yuan Gao ◽  
Yuanjing Lin ◽  
Zehua Peng ◽  
Qingfeng Zhou ◽  
Zhiyong Fan
Keyword(s):  
Aspect Ratio ◽  
Surface Area ◽  
Structural Stability ◽  
High Aspect Ratio ◽  
High Performance ◽  
Three Dimensional ◽  
Rate Capability ◽  
Large Surface Area ◽  
Nanoporous Structure ◽  
Ion Diffusion

Three-dimensional interconnected nanoporous structure (3-D INPOS) possesses high aspect ratio, large surface area, as well as good structural stability. Profiting from its unique interconnected architecture, the 3-D INPOS pseudocapacitor achieves a largely enhanced capacitance and rate capability.

The new face of large dams in the 21st century

2021 ◽  
Author(s):  
Atal Ahmadzai
Keyword(s):  
Surface Area ◽  
Aquatic Ecosystems ◽  
Energy Demand ◽  
Environmental Aspects ◽  
Water Insecurity ◽  
Surface Areas ◽  
Large Dams ◽  
Physical Attributes ◽  
Under Construction ◽  
Ecological Disturbances

Alerted by increasing water insecurity and energy demand, countries, mainly in the Global South, are building dams of unprecedented magnitude. Hundreds of large dams (≥ 100 metres) have been constructed since 2000, with hundreds more under construction. Analyses of the physical attributes of these dams present a concerning image. While they create expansive reservoirs with large surface areas, they have inefficient surface area-to-volume ratios ('S2VR'). Their unprecedented size and the reservoirs’ expansive surface area, indicate severe environmental costs, mainly through ecological disturbances to the (riverine) aquatic ecosystems; and greenhouse gas emissions (GHG). Other ecological costs due to the larger S2VR include a high evaporation rate and compromised biodiversity of a wider area, both up- and downstream. The safety and environmental aspects of these large dams should be robustly scrutinised.

Functionalization and Tip-open of Carbon Nanotubes for High-Performance Symmetric Supercapacitor

2021 ◽  
Author(s):  
Yaxiong Zhang ◽  
Erqing Xie
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Aspect Ratio ◽  
Specific Surface ◽  
Surface Area ◽  
Chemical Stability ◽  
High Aspect Ratio ◽  
High Performance ◽  
Large Specific Surface Area ◽  
Symmetric Supercapacitor

Carbon nanotubes (CNTs) have been widely studied as supercapacitor electrodes because of their excellent conductivity, high aspect ratio, excellent mechanical properties, chemical stability, and large specific surface area. However, the...

scholarly journals The Effects of Methane Storage Capacity Using Upgraded Activated Carbon by KOH

2018 ◽  
Vol 8 (9) ◽  
pp. 1596 ◽  
Author(s):  
Jung Park ◽  
Gi Lee ◽  
Sang Hwang ◽  
Ji Kim ◽  
Bum Hong ◽  
...  
Keyword(s):  
Surface Area ◽  
Storage Capacity ◽  
Activated Carbons ◽  
Chemical Activation ◽  
High Surface ◽  
Heat Of Adsorption ◽  
Low Grade ◽  
Surface Areas ◽  
Ch4 Adsorption ◽  
Ch4 Storage

In this study, a feasible experiment on adsorbed natural gas (ANG) was performed using activated carbons (ACs) with high surface areas. Upgraded ACs were prepared using chemical activation with potassium hydroxide, and were then applied as adsorbents for methane (CH4) storage. This study had three principal objectives: (i) upgrade ACs with high surface areas; (ii) evaluate the factors regulating CH4 adsorption capacity; and (iii) assess discharge conditions for the delivery of CH4. The results showed that upgraded ACs with surface areas of 3052 m2/g had the highest CH4 storage capacity (0.32 g-CH4/g-ACs at 3.5 MPa), which was over two times higher than the surface area and storage capacity of low-grade ACs (surface area = 1152 m2/g, 0.10 g-CH4/g-ACs). Among the factors such as surface area, packing density, and heat of adsorption in the ANG system, the heat of adsorption played an important role in controlling CH4 adsorption. The released heat also affected the CH4 storage and enhanced available applications. During the discharge of gas from the ANG system, the residual amount of CH4 increased as the temperature decreased. The amount of delivered gas was confirmed using different evacuation flow rates at 0.4 MPa, and the highest efficiency of delivery was 98% at 0.1 L/min. The results of this research strongly suggested that the heat of adsorption should be controlled by both recharging and discharging processes to prevent rapid temperature change in the adsorbent bed.

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