scholarly journals Preparation and Performance Test of the Super-Hydrophobic Polyurethane Coating Based on Waste Cooking Oil

Coatings ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 861 ◽  
Author(s):  
Yingmo Cheng ◽  
Dejun Miao ◽  
Lingxiao Kong ◽  
Jiachen Jiang ◽  
Zhenxing Guo
Keyword(s):  
Thermal Conductivity ◽  
Contact Angle ◽  
Performance Test ◽  
Waste Cooking Oil ◽  
Raw Material ◽  
Polyurethane Coating ◽  
Sliding Angle ◽  
Cooking Oil ◽  
Sic Particles ◽  
Polyurethane Prepolymer

In order to solve the problem of dust accumulation on the fin surface of a mine air cooler, a method of preparing super-hydrophobic polyurethane (SPU) coating based on waste cooking oil (WCO) was proposed. Firstly, the polyurethane prepolymer was synthesized with WCO as a raw material, and then the polyurethane prepolymer was modified with amino-terminated polydimethylsiloxane (ATP) to obtain SPU emulsion. The chemical structure and thermal stability of SPU were characterized by infrared spectrum and thermogravimetric analysis. A series of nanocomposites were prepared by combining modified silicon carbide (APT-SiC) particles and SPU emulsions. According to the parameters of pull-off strength, contact angle, sliding angle and thermal conductivity, the filler ratio of nanocomposites was optimized. The test results show that when the content of APT-SiC particles is 20 wt %, super-hydrophobic polyurethane coating can be obtained. The coating has good pull- off strength and thermal conductivity, and the contact angle and sliding angle are 161° and 3°, respectively. In addition, the practical application of the super-hydrophobic polyurethane coating was tested by related experiments. The experimental results show that the coating has good self-cleaning, wear resistance and anti-corrosion performance, can meet the requirements of air coolers in special environments, and has great application prospects.

scholarly journals Innovative applications of waste cooking oil as raw material

2019 ◽  
Vol 102 (2) ◽  
pp. 153-160 ◽  
Author(s):  
Alberto Mannu ◽  
Monica Ferro ◽  
Maria Enrica Di Pietro ◽  
Andrea Mele
Keyword(s):  
Hazardous Waste ◽  
Industrial Application ◽  
Waste Cooking Oil ◽  
Review Article ◽  
Raw Material ◽  
Cooking Oil ◽  
Waste Cooking Oils ◽  
Cooking Oils ◽  
Recycled Waste

The consideration towards waste cooking oils is changing from hazardous waste to valuable raw material for industrial application. During the last 5 years, some innovative processes based on the employment of recycled waste cooking oil have appeared in the literature. In this review article, the most recent and innovative applications of recycled waste cooking oil are reported and discussed. These include the production of bioplasticizers, the application of chemicals derived from waste cooking oils as energy vectors and the use of waste cooking oils as a solvent for pollutant agents.

scholarly journals The Utilization of Waste Cooking Oil (WCO) as A Mixture of Polyol Sourcein. The Production of Polyurethane Using Toluene Diisocyanate

2019 ◽  
Vol 35 (1) ◽  
pp. 221-227
Author(s):  
Maulida Lubis ◽  
Mara Bangun Harahap ◽  
Iriany Iriany ◽  
Muhammad Hendra S. Ginting ◽  
Iqbal Navissyah Lazuardi ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Impact Strength ◽  
Waste Cooking Oil ◽  
Raw Material ◽  
Toluene Diisocyanate ◽  
Elongation At Break ◽  
Cooking Oil ◽  
A Value ◽  
Stirring Time

Cooking oil waste that has been disposed could contamine the environment. However, if it is processed well, it can potentially become a raw material of polyurethane. The aim of this study was to determine the best polyurethane on the tensile strength, impact strength, elongation at break, water absorption, characterization of Fourier Transform Infra-Red (FTIR) and the characterization of Scanning Electron Microscopy (SEM). The variables used in this study were ambient process temperature with 440 rpm stirring speed, 1-minute stirring time, the ratio of polyoland WCO was 7:3 (% w/w), and the ratio of Toluene Diisocyanate (TDI) and WCO was 1:1; 1:2; 1:3; 1:4 (% w/w). The results obtained from the analysis of the best tensile strength against the polyurethane synthetic was in the 1:1 ratio of mixed variations between oil and TDI with a value of 0.403 MPa. The best impact strength was in the ratio of mixed variations between oil and TDI with 1:4 (% w/w) with a value of 600.975 J/m2. The best elongation at break against polyurethane foam synthetic was in the 1:3 ratio of mixture variations of oil and TDI with a value of 4.506%.

scholarly journals Evolution of Waste Cooking Oil Collection in an Area with Long-Standing Waste Management Problems

2020 ◽  
Vol 12 (20) ◽  
pp. 8578
Author(s):  
Giovanni De Feo ◽  
Aurelio Di Domenico ◽  
Carmen Ferrara ◽  
Salvatore Abate ◽  
Libero Sesti Osseo
Keyword(s):  
Waste Management ◽  
Waste Cooking Oil ◽  
Raw Material ◽  
Economic Damage ◽  
Private Company ◽  
Campania Region ◽  
Awareness Campaigns ◽  
Cooking Oil ◽  
Management Problems ◽  
Collection Program

Waste cooking oil (WCO) can be a useful secondary raw material, if properly managed. On the contrary, uncontrolled disposal generates negative environmental impacts as well as economic loss. Therefore, improving WCO recovery rate, with the cooperation of citizens and effective collection programs, is fundamental. The aim of the study was to investigate the reason for the low recovery of WCO in those areas suffering serious waste management problems such as the Campania region in Southern Italy. For this purpose, the case of a WCO collection program adopted in Angri, a town of around 34,000 people with a high population density, was studied. In 2015, the collection program was managed by a social cooperative, while, in 2016, after the change of the local government, the collection of WCO was entrusted to a private company. In 2015, the households’ participation in the collection program was surveyed through a structured questionnaire. The results revealed that the collection of WCO was practiced by 53% of the respondents. Among those not collecting WCO, 76% of the sample wrongly disposed of WCO in their home (kitchen or toilet). Misinformation was the main reason why they did not adhere to the collection program. Therefore, it was suggested to support information and environmental education campaigns to promote environmental awareness of citizens. Unfortunately, the change of management, together with serious problems in the collection of municipal waste in the whole region, due to the continuous closures of the mechanical and biological plants, produced a sharp decline in the collection from 7730 kg in 2015 to an average of 3800 kg for the period 2016–2019, with a loss of more than 15,000 kg of WCO wrongly disposed with consequent environmental and economic damage. Therefore, information and awareness campaigns are important but the form of entrusting the collection service is equally important, especially in areas with long-standing waste management problems.

scholarly journals KRITERIA RUMAH MAKAN SUPPLIER MINYAK JELANTAH DALAM RANGKA PERENCANAAN BAHAN BAKU BIODIESEL

2019 ◽  
Vol 1 (1) ◽  
pp. 27-33
Author(s):  
D.U.M. Susilo ◽  
Th. Candra Wasis A.S. ◽  
Zakwan .
Keyword(s):  
Raw Materials ◽  
Waste Cooking Oil ◽  
Raw Material ◽  
Biodiesel Production ◽  
Analytic Hierarchy ◽  
Cooking Oil ◽  
Used Cooking Oil ◽  
A Value ◽  
Many Sources ◽  
The City

The using of biodiesel as an environmentally friendly fuel has received attention from consumers to producers. So, a lot of research was done on the potential raw material to become biodiesel. One of the raw materials for biodiesel was waste cooking oil. Pontianak City have many sources including waste cooking oil from restaurants. Therefore restaurants in the city of Pontianak might be used as suppliers of waste cooking oil in biodiesel production. This study aims to determine the priority of criteria and sub-criteria for restaurants as suppliers and determine good restaurants as suppliers of used cooking in Pontianak City . Purposive technique sampling using a sample of 61 house dining, interviewed to obtain alternative data suppliers. Expert survey questionnaire contains priority weighting of criteria and supplier criteria, analyzed using AHP ( Analytic Hierarchy Process ). Grouping of restaurants based on alternative supplier values ​​is used to determine good restaurants to be suppliers. The priority criteria for restaurants as consecutive suppliers are experience (0.289), quality (0.279), capacity (0.231), service (0.148) and price (0.053). Sub-criteria priority of restaurants as suppliers in a row is the time span of used cooking oil sold(0.161), length of time used cooking oil (0.155), income (0.129), type of cooking oil (0.107), type of fried food products (0.092), volume of cooking oil (0.090), frying volume (0.085), transaction convenience (0.082), subject to used cooking oil (0.056), used cooking oil price (0.030) and ease of payment (0.013). A value of ≥ 0.325 is a dining value that shows a very better priority as a supplier. The number of restaurants as suppliers is 8 % of the population of restaurants in the city of Pontianak..

scholarly journals PENGARUH MASSA KATALIS DAN WAKTU REAKSI PADA PEMBUATAN BIODIESEL DARI LIMBAH MINYAK JELANTAH DENGAN MENGGUNAKAN KATALIS HETEROGEN K2O DARI LIMBAH KULIT KAKAO

2017 ◽  
Vol 6 (2) ◽  
pp. 24-29
Author(s):  
Jefry R Turnip ◽  
Trio F. L. Tarigan ◽  
Mersi Suriani Sinaga
Keyword(s):  
Reaction Time ◽  
Corn Oil ◽  
Waste Cooking Oil ◽  
Raw Material ◽  
National Standard ◽  
Solid Catalyst ◽  
Waste Oil ◽  
Cooking Oil ◽  
High Level ◽  
Cooking Oils

Waste cooking oil is a waste oil that comes from many types of cooking oils such as corn oil, vegetable oil, ect. The purpose of this research is to waste cooking oil as a raw material to form biodiesel with K2O as the solid catalyst from cocoa pod ash (CPA) which is calcined on temperature 650 oC within 4 hours. This oil contains a high level of Free Fatty Acid (FFA) that is 3.13%. Therefore, pretreatment should be done by using activated carbon (1% w/w) to reduce levels of FFA. The research will be observed the effect of reaction time and the mass of catalyst. The characteristics of biodiesel is analyzed according to the levels of methyl ester in biodiesel, density, and viscosity based on the Indonesian National Standard (SNI). The best conditions of biodiesel are obtained with the amount of catalyst is 6% (w/w) that is calcined at 650 °C, reaction time 180 minutes, ratio mol of alcohol : oil is 12: 1, and 65 oC reaction of temperature, resulting the purity and yield of biodiesel is 99,8% and 92,68%. The results of this research indicates that the use of waste cooking as a raw material is suitable in the manufacture of biodiesel.

scholarly journals Modification of CaO Catalyst with Impregnation Method Using KoH in Biodiesel Synthesis from Waste Cooking Oil

2019 ◽  
Vol 19 (2) ◽  
pp. 62
Author(s):  
Syarifuddin Oko ◽  
Andri Kurniawan
Keyword(s):  
Surface Area ◽  
Catalyst Activity ◽  
Waste Cooking Oil ◽  
Raw Material ◽  
Impregnation Method ◽  
Wet Impregnation ◽  
Cooking Oil ◽  
Eds Analysis ◽  
Biodiesel Synthesis ◽  
Egg Shells

Chicken eggshells can be used as raw material in the manufacture of CaO catalysts. Increased CaO catalyst activity can be done by the impregnation method. The purpose of this study was to determine the effect of %K on the wet impregnation of CaO catalyst using KOH and to find out the impregnation catalyst (CaO / K2O) on the biodiesel yield. Prepared chicken egg shells were calcined at 900oC for 3 hours. Then the CaO obtained was impregnated using KOH with a variation of % K (5%, 7%, 9% and 12% (w / w)) while heated at 85oC. The impregnation product was calcined at 600oC for 5 hours. The impregnation catalyst (CaO K2O) was applied to the biodiesel synthesis through a transesterification reaction with a mole ratio of 1:12 waste cooking oil: methanol, the amount of catalyst was 1.5% at a reaction temperature of 70°C for 2.5 hours. Based on the results of SEM-EDS analysis, the highest K2O at 7% K was 21.99%), while the highest CaO content was at 9% K by 81.53%. For the highest surface area analysis at 7% K with a surface area of 71.22 m2 / g, alkalinity was 2.59 mmol / g. The best biodiesel was obtained with a yield of 87.17%, kinematic viscosity of 2.89 cSt, water content of 0.032%, density of 0.819 g/ml, methyl ester level of 99.39%.

scholarly journals Esterification of Waste Cooking Oil Using Ultrasonic: Kinetic Study

2019 ◽  
Vol 20 (2) ◽  
pp. 57-68
Author(s):  
Egi Agustian ◽  
Jessica Jessica ◽  
Pudji Untoro ◽  
Anny Sulaswatty
Keyword(s):  
Phosphoric Acid ◽  
Conventional Method ◽  
Acid Catalyst ◽  
Waste Cooking Oil ◽  
Reaction Rate Constant ◽  
Order Reaction ◽  
Second Order ◽  
Raw Material ◽  
Irreversible Reaction ◽  
Cooking Oil

Waste cooking oil (WCO) have a great potential as an alternative raw material for producing biodiesel. The literatures kinetic of the esterification of WCO in the presence of phosphoric acid catalyst with ultrasonic assisted are rare and most literatures used conventional method. This study aims to determine the optimum condition and the parameters of first and second order kinetics of the WCO esterification which was assisted by ultrasonic bath. Variables that used in this study are methanol/oil mole ratio, acid catalyst concentration and reaction temperature. The highest conversion was 42.08% with methanol/oil mole ratio of 15:1, a catalyst (phosphoric acid) concentration of 9% wt and temperature of 50oC within 90 minutes. The reaction time was reduced to 3 times (minute) compare to conventional method and fatty acid reduced 42%. Kinetic parameters were calculated with assumption that the esterification was the irreversible reaction. The reaction rate constant increasing with temperature. The value of activation energy for esterification of WCO is 42.94 kJ/mol for first order reaction and 35.30 kJ/mol for second order reaction.

Influence of Coconut Biodiesel and Waste Cooking Oil Blended Fuels on Engine Performance and Emission Characteristics

2012 ◽  
Author(s):  
A. M. Liaquat ◽  
H. H. Masjuki ◽  
M. A. Kalam ◽  
M. M. K. Bhuiya ◽  
M. Varman
Keyword(s):  
Diesel Fuel ◽  
Diesel Engines ◽  
Alternative Fuels ◽  
Performance Test ◽  
Engine Performance ◽  
Waste Cooking Oil ◽  
Attractive Alternative ◽  
Waste Products ◽  
Performance And Emission ◽  
Cooking Oil

Due to diminishing petroleum reserves and the environmental consequences of exhaust gases from petroleum fuelled engines, alternative fuels are becoming increasingly important for diesel engines. The processed form of vegetable oil (Biodiesel) and waste products (waste cooking oil) offer attractive alternative fuels for compression ignition engines. In this study experimental work has been carried out to investigate engine performance parameters and emissions characteristics for direct injection diesel engine using coconut biodiesel and waste cooking oil blends without any engine modifications. A total of three fuel samples, such as DF (100% low-sulfur diesel fuel), CB10 (10% coconut biodiesel and 90% DF), and C5W5 (5% CB + 5% waste cooking oil and 90% DF) respectively are used. Engine performance test was performed at 100% load keeping throttle 100% wide open with variable speeds of 1500 to 2400 rpm at an interval of 100 rpm. Whereas, emission tests were carried out at 2300 rpm at 100% and 80% throttle position. As the results of investigations, there has been a decrease in torque and brake power, where increase in specific fuel consumption has been observed for blend fuels over the entire speed range as compared to diesel fuel. In case of engine exhaust gas emissions, lower HC, CO, CO2 emissions and higher NOx emissions, were found for fuel blends compared to diesel fuel. However, sound level for both blend fuels was lower as compared to diesel fuel. It can be concluded that CB10 and C5W5 can be used in diesel engines without any engine modifications and have beneficial effects both in terms of emission reductions and alternative petroleum diesel fuel. However, C5W5 produced better results compared to CB10.

scholarly journals Bio-aviation fuel via catalytic hydrocracking of waste cooking oils

2020 ◽  
Vol 44 (1) ◽  
Author(s):  
R. El-Araby ◽  
E. Abdelkader ◽  
G. El Diwani ◽  
S. I. Hawash
Keyword(s):  
Catalytic Cracking ◽  
Freezing Point ◽  
Batch Reactor ◽  
Waste Cooking Oil ◽  
Jet Fuel ◽  
Raw Material ◽  
Aviation Fuel ◽  
Reaction Conditions ◽  
Oil Companies ◽  
Cooking Oil

Abstract Background Biomass fuels (bio-jet fuel) have recently attracted considerable attention as alternatives to conventional jet fuel. They have become the focus of aircraft manufacturers, engines, oil companies, governments and researchers alike. This study is concerned with the production of biojet fuel using waste cooking oil (WCO). Batch reactor is used for running the experimental study. The catalytic cracking products are investigated by GC mass spectra. Final products from different reaction conditions are subjected to fractional distillation. The (Bio kerosene) fraction was compared with the conventional jet A-1 and showed that it met the basic jet fuel specifications. Optimum reaction conditions are obtained at (450 °C), pressure of (120 bars), catalyst dose (2.5% w/v), reaction time (60 min) and hydrogen pressure 4 atmosphere. The aim of this study is to produce bio aviation fuel according to specifications and with a low freezing point from waste cooking oil in one step using a laboratory prepared catalyst and with a low percentage of hydrogen to complete the process of cracking and deoxygenation in one reactor, which is naturally reflected positively on the price of the final product of bio aviation fuel. Results The results indicated that the product obtained from WCO shows promising potential bio aviation fuels, having a low freezing point (− 55 °C) and that all bio kerosene’s specifications obtained at these conditions follow the international standard specifications of aviation turbine fuel. Conclusion Biojet fuel obtained from WCO has fairly acceptable physico-chemical properties compared to those of petroleum-based fuel. Adjustment of the hydro catalytic cracking reaction conditions was used to control quantities and characteristics of produced bio aviation fuel. Taking into consideration the economic evaluation WCO is preferable as raw material for bio aviation fuel production due to its low cost and its contribution in environmental pollution abatement. Blend of 5% bio aviation with jet A-1 (by volume) can be used in the engine without any modifications and a successful test of blended aviation fuel with 10% bio aviation has been achieved on Jet-Cat 80/120 engine.

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