scholarly journals Review on Fabrication of Structurally Colored Fibers by Electrospinning

Fibers ◽  
2018 ◽  
Vol 6 (4) ◽  
pp. 70 ◽  
Author(s):  
Jiali Yu ◽  
Chi-Wai Kan

Structural color derived from the physical interactions of photons, with the specific chromatic mechanism differing from that of dyes and pigments, has brought considerable attention by the conducive virtue of being dye-free and fadeless. This has recently become a research hot-spot. Assemblies of colloidal nanoparticles enable the manufacture of periodic photonic nanostructures. In our review, the mechanism of nanoparticle assemblies into structurally colored structures by the electrospinning method was briefly introduced, followed by a comparatively comprehensive review summarizing the research related to photonic crystals with periodically aligned nanostructures constructed by the assembly of colloidal nanoparticles, and the concrete studies concerning the fabrication of well-aligned electrospun nanofibers incorporating with colloidal nanoparticles based on the investigation of relevant factors such as the sizes of colloidal nanoparticles, the weight ratio between colloidal nanoparticles, and the polymer matrix. Electrospinning is expected to be a deserving technique for the fabrication of structurally colored nanofibers while the colloidal nanoparticles can be well confined into aligned arrangement inside nanofibres during the electrospinning process after the achievement of resolving remaining challenges.

Materials ◽  
2020 ◽  
Vol 13 (10) ◽  
pp. 2407 ◽  
Author(s):  
Alexa-Maria Croitoru ◽  
Denisa Ficai ◽  
Anton Ficai ◽  
Natalia Mihailescu ◽  
Ecaterina Andronescu ◽  
...  

The interest in wound healing characteristics of bioactive constituents and therapeutic agents, especially natural compounds, is increasing because of their therapeutic properties, cost-effectiveness, and few adverse effects. Lately, nanocarriers as a drug delivery system have been actively investigated and applied in medical and therapeutic applications. In recent decades, researchers have investigated the incorporation of natural or synthetic substances into novel bioactive electrospun nanofibrous architectures produced by the electrospinning method for skin substitutes. Therefore, the development of nanotechnology in the area of dressings that could provide higher performance and a synergistic effect for wound healing is needed. Natural compounds with antimicrobial, antibacterial, and anti-inflammatory activity in combination with nanostructured fibers represent a future approach due to the increased wound healing process and regeneration of the lost tissue. This paper presents different approaches in producing electrospun nanofibers, highlighting the electrospinning process used in fabricating innovative wound dressings that are able to release natural and/or synthetic substances in a controlled way, thus enhancing the healing process.


2012 ◽  
Vol 463-464 ◽  
pp. 734-738 ◽  
Author(s):  
Tongsai Jamnongkan ◽  
Amnuay Wattanakornsiri ◽  
P. Pungboon Pansila ◽  
Claudio Migliaresi ◽  
Supranee Kaewpirom

Series of poly (vinyl alcohol)/chitosan (PVA/CS) electrospun nanofibers with different weight ratio of PVA and CS were fabricated by electrospinning method. The surface morphology, diameter, and structure of electrospun nanofibers were investigated by scanning electron microscopy (SEM). As a result of PVA and CS composition measurements, the electrospun nanofibers morphologies were mainly affected by weight ratio of the polymer solution. When increasing the chitosan content in the blend solution, the electrospun nanofibers could hardly form. This result indicates that the electrospun nanofiber formation is enhanced by chitosan content.


2013 ◽  
Vol 651 ◽  
pp. 87-90 ◽  
Author(s):  
Xiu Lian Wang ◽  
Liu Xue Zhang

In this study, composite nanofibers of polyaniline doped with dodecylbenzene sulfonic acid (PANI-DBSA) and polyurethane (PU) were prepared via an electrospinning process. The morphology, diameter, and structure of the electrospun nanofibers were investigated. SEM images showed that the morphology and diameter of the nanofibers were mainly affected by the weight ratio of the blend. The average diameter of the nanofibers was 370–1620 nm. The diameter gradually decreased with increasing PANI-DBSA content in the blend, and more beads were obtained in the composite.


TAPPI Journal ◽  
2019 ◽  
Vol 18 (6) ◽  
pp. 381-389 ◽  
Author(s):  
ZAHRA ASHRAFI ◽  
SAEEDEH MAZINANI ◽  
ALI AKBAR GHAREHAGHAJI ◽  
LUCIAN LUCIA

The design and synthesis of natural and synthetic polymer blends have received recent and wide attention. These new biomaterials exhibit progress in properties required in the field of medicine and healthcare. Herein, the aim of present study is to fabricate starch (ST)/polyacrylic acid (PAA) electrospun nanofibrous mat with a smooth and uniform morphology, lowest fiber diameter (below 100 nm) and the highest possible starch content. Starch itself is poor in process-ability, and its electrospinning could be quite a challenging process. To address this, we carried out the response surface methodology (RSM) technique for modelling the electrospinning process. In order to have ST/PAA nanofibers with the finest possible diameter, optimized processing parameters (applied voltage, nozzle‐collector distance and feed rate) obtained from RSM technique were applied. ST/PAA electrospun nanofibers with an average diameter of 74±13 nm were successfully achieved via the electrospinning method for the first time. The structure, preparation and properties of the nanofibrous structure were discussed. Results indicated that drug loaded ST/PAA blend nanofibrous structure has a great potential to be used in controlled drug release systems.


Molecules ◽  
2021 ◽  
Vol 26 (16) ◽  
pp. 4753
Author(s):  
Jorge Iván Castro ◽  
Manuel N. Chaur ◽  
Carlos Humberto Valencia Llano ◽  
Mayra Eliana Valencia Zapata ◽  
José Herminsul Mina Hernandez ◽  
...  

In recent decades, the number of patients requiring biocompatible and resistant implants that differ from conventional alternatives dramatically increased. Among the most promising are the nanocomposites of biopolymers and nanomaterials, which pretend to combine the biocompatibility of biopolymers with the resistance of nanomaterials. However, few studies have focused on the in vivo study of the biocompatibility of these materials. The electrospinning process is a technique that produces continuous fibers through the action of an electric field imposed on a polymer solution. However, to date, there are no reports of chitosan (CS) and polyvinyl alcohol (PVA) electrospinning with carbon nano-onions (CNO) for in vivo implantations, which could generate a resistant and biocompatible material. In this work, we describe the synthesis by the electrospinning method of four different nanofibrous membranes of chitosan (CS)/(PVA)/oxidized carbon nano-onions (ox-CNO) and the subdermal implantations after 90 days in Wistar rats. The results of the morphology studies demonstrated that the electrospun nanofibers were continuous with narrow diameters (between 102.1 nm ± 12.9 nm and 147.8 nm ± 29.4 nm). The CS amount added was critical for the diameters used and the successful electrospinning procedure, while the ox-CNO amount did not affect the process. The crystallinity index was increased with the ox-CNO introduction (from 0.85% to 12.5%), demonstrating the reinforcing effect of the nanomaterial. Thermal degradation analysis also exhibited reinforcement effects according to the DSC and TGA analysis, with the higher ox-CNO content. The biocompatibility of the nanofibers was comparable with the porcine collagen, as evidenced by the subdermal implantations in biological models. In summary, all the nanofibers were reabsorbed without a severe immune response, indicating the usefulness of the electrospun nanocomposites in biomedical applications.


Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 992
Author(s):  
Suchitha Devadas ◽  
Saja M. Nabat Al-Ajrash ◽  
Donald A. Klosterman ◽  
Kenya M. Crosson ◽  
Garry S. Crosson ◽  
...  

Lignin macromolecules are potential precursor materials for producing electrospun nanofibers for composite applications. However, little is known about the effect of lignin type and blend ratios with synthetic polymers. This study analyzed blends of poly(acrylonitrile-co-methyl acrylate) (PAN-MA) with two types of commercially available lignin, low sulfonate (LSL) and alkali, kraft lignin (AL), in DMF solvent. The electrospinning and polymer blend solution conditions were optimized to produce thermally stable, smooth lignin-based nanofibers with total polymer content of up to 20 wt % in solution and a 50/50 blend weight ratio. Microscopy studies revealed that AL blends possess good solubility, miscibility, and dispersibility compared to LSL blends. Despite the lignin content or type, rheological studies demonstrated that PAN-MA concentration in solution dictated the blend’s viscosity. Smooth electrospun nanofibers were fabricated using AL depending upon the total polymer content and blend ratio. AL’s addition to PAN-MA did not affect the glass transition or degradation temperatures of the nanofibers compared to neat PAN-MA. We confirmed the presence of each lignin type within PAN-MA nanofibers through infrared spectroscopy. PAN-MA/AL nanofibers possessed similar morphological and thermal properties as PAN-MA; thus, these lignin-based nanofibers can replace PAN in future applications, including production of carbon fibers and supercapacitors.


2020 ◽  
Vol 9 (1) ◽  
pp. 9-19
Author(s):  
Ida Sriyanti ◽  
Meily P Agustini ◽  
Jaidan Jauhari ◽  
Sukemi Sukemi ◽  
Zainuddin Nawawi

The purposes of this research were to investigate the synthesized Nylon-6 nanofibers using electrospinning technique and their characteristics. The method used in this study was an experimental method with a quantitative approach. Nylon-6 nanofibers have been produced using the electrospinning method. This fiber was made with different concentrations, i.e. 20% w/w (FN1), 25% w/w (FN2), and 30% w/w (FN3). The SEM results show that the morphology of all nylon-6 nanofibers) forms perfect fibers without bead fiber. Increasing fiber concentration from 20% w/w to 30% w/w results in bigger morphology and fiber diameter. The dimensions of the FN1, FN2, and FN3 fibers are 1890 nm, 2350 nm, and 2420 nm, respectively. The results of FTIR analysis showed that the increase in the concentration of nylon-6 (b) and the electrospinning process caused a peak shift in the amide II group (CH2 bond), the carbonyl group and the CH2 stretching of the amide III group from small wave numbers to larger ones. The results of XRD characterization showed that the electrospinning process affected the changes in the XRD pattern of nylon-6 nanofiber (FN1, FN2, and FN3) in the state of semi crystal. Nylon-6 nanofibers can be used for applications in medicine, air filters, and electrode for capacitors


Polymers ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2421 ◽  
Author(s):  
Shixiong Kang ◽  
Shicong Hou ◽  
Xunwei Chen ◽  
Deng-Guang Yu ◽  
Lin Wang ◽  
...  

Although electrospun nanofibers are expanding their potential commercial applications in various fields, the issue of energy savings, which are important for cost reduction and technological feasibility, has received little attention to date. In this study, a concentric spinneret with a solid Teflon-core rod was developed to implement an energy-saving electrospinning process. Ketoprofen and polyvinylpyrrolidone (PVP) were used as a model of a poorly water-soluble drug and a filament-forming matrix, respectively, to obtain nanofibrous films via traditional tube-based electrospinning and the proposed solid rod-based electrospinning method. The functional performances of the films were compared through in vitro drug dissolution experiments and ex vivo sublingual drug permeation tests. Results demonstrated that both types of nanofibrous films do not significantly differ in terms of medical applications. However, the new process required only 53.9% of the energy consumed by the traditional method. This achievement was realized by the introduction of several engineering improvements based on applied surface modifications, such as a less energy dispersive air-epoxy resin surface of the spinneret, a free liquid guiding without backward capillary force of the Teflon-core rod, and a smaller fluid–Teflon adhesive force. Other non-conductive materials could be explored to develop new spinnerets offering good engineering control and energy savings to obtain low-cost electrospun polymeric nanofibers.


RSC Advances ◽  
2017 ◽  
Vol 7 (46) ◽  
pp. 28951-28964 ◽  
Author(s):  
Nooshin Nikmaram ◽  
Shahin Roohinejad ◽  
Sara Hashemi ◽  
Mohamed Koubaa ◽  
Francisco J. Barba ◽  
...  

Encapsulation of bioactive materials and drugs using the emulsion electrospinning method.


2011 ◽  
Vol 332-334 ◽  
pp. 317-320 ◽  
Author(s):  
Hui Qin Zhang

In this study, composite nanofibers of polyaniline doped with dodecylbenzene sulfonic acid (PANI-DBSA) and Poly(lactic acid) (PLA) were prepared via an electrospinning process. The surface morphology, thermal properties and crystal structure of PLA/PANI-DBSA nanofibers are characterized using Fourier transform infrared spectroscopy (FT-IR), wide-angle x-ray diffraction (WAXD) and scanning electron microscopy (SEM). SEM images showed that the morphology and diameter of the nanofibers were affected by the weight ratio of blend solution.


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