scholarly journals Rheological Characterization of Carbopol® Dispersions in Water and in Water/Glycerol Solutions

Fluids ◽  
2019 ◽  
Vol 4 (1) ◽  
pp. 3 ◽  
Author(s):  
Priscilla R. Varges ◽  
Camila M. Costa ◽  
Bruno S. Fonseca ◽  
Mônica F. Naccache ◽  
Paulo De Souza Mendes

The influence of the solvent type on the rheological properties of Carbopol ® NF 980 dispersions in water and in water/glycerol solutions is investigated. The material formulation, preparation procedure, common experimental challenges and artifact sources are all addressed. Transient and steady-state experiments were performed. For both solvent types, a clearly thixotropic behavior occurs slightly above the yield stress, where the avalanche effect is observed. For larger stresses, thixotropy is always negligible. Among other findings, it is observed that, for a given Carbopol concentration, the dispersion in the more viscous solvent possesses a lower yield stress and moduli, a larger power-law index, and a longer time to reach steady state.

2016 ◽  
Vol 44 (3) ◽  
pp. 174-190 ◽  
Author(s):  
Mario A. Garcia ◽  
Michael Kaliske ◽  
Jin Wang ◽  
Grama Bhashyam

ABSTRACT Rolling contact is an important aspect in tire design, and reliable numerical simulations are required in order to improve the tire layout, performance, and safety. This includes the consideration of as many significant characteristics of the materials as possible. An example is found in the nonlinear and inelastic properties of the rubber compounds. For numerical simulations of tires, steady state rolling is an efficient alternative to standard transient analyses, and this work makes use of an Arbitrary Lagrangian Eulerian (ALE) formulation for the computation of the inertia contribution. Since the reference configuration is neither attached to the material nor fixed in space, handling history variables of inelastic materials becomes a complex task. A standard viscoelastic material approach is implemented. In the inelastic steady state rolling case, one location in the cross-section depends on all material locations on its circumferential ring. A consistent linearization is formulated taking into account the contribution of all finite elements connected in the hoop direction. As an outcome of this approach, the number of nonzero values in the general stiffness matrix increases, producing a more populated matrix that has to be solved. This implementation is done in the commercial finite element code ANSYS. Numerical results confirm the reliability and capabilities of the linearization for the steady state viscoelastic material formulation. A discussion on the results obtained, important remarks, and an outlook on further research conclude this work.


Author(s):  
M. A. Hassan ◽  
Manabendra Pathak ◽  
Mohd. Kaleem Khan

The temperature and concentration play an important role on rheological parameters of the gel. In this work, an experimental investigation of thermorheological properties of aqueous gel Carbopol Ultrez 20 for various concentrations and temperatures has been presented. Both controlled stress ramps and controlled stress oscillatory sweeps were performed for obtaining the rheological data to find out the effect of temperature and concentration. The hysteresis or thixotropic seemed to have negligible effect. Yield stress, consistency factor, and power law index were found to vary with temperature as well as concentration. With gel concentration, the elastic effect was found to increase whereas viscous dissipation effect was found to decrease. Further, the change in elastic properties was insignificant with temperature in higher frequency range of oscillatory stress sweeps.


2018 ◽  
Vol 20 (30) ◽  
pp. 20247-20256 ◽  
Author(s):  
A. V. Anupama ◽  
V. B. Khopkar ◽  
V. Kumaran ◽  
B. Sahoo

The magneto-rheological behaviour of fluids containing soft-ferrimagnetic Fe3O4 micro-octahedrons (M = magnetization, τY = dynamic yield-stress and H = applied-magnetic-field).


2021 ◽  
Vol 11 (23) ◽  
pp. 11141
Author(s):  
Tae-Woong Kong ◽  
Hyun-Min Yang ◽  
Han-Seung Lee ◽  
Chang-Bok Yoon

High fluidity concrete exhibits an excellent self-compacting property. However, the application of typical high-fluidity concrete is limited in the normal strength range (18~35 MPa) due to the large amount of binder. Therefore, it is important to solve these problems by adding a viscosity modifying agent (VMA) with a superplasticizer (PCE), which helps to improve the fluidity of the concrete. In addition, the rheology and stability of the concrete with VMA can be improved by preventing bleeding and segregation issues. Current studies focused on the physical phenomena of concrete such as the fluidity, rheological properties, and compressive strength of normal-strength, high-fluidity concrete (NSHFC) with different types of a polycarboxylate-based superplasticizer (NPCE). The obtained results suggested that the combinations of all-in-one polycarboxylate-based superplasticizers (NPCE) did not cause any cohesion or sedimentation even stored for a long time. The combination of three types of VMA showed the best fluidity (initial slump flow of 595~630 mm) without any segregation and bleeding, and the compressive strength at 28 days was also found to be the highest: 34–37 MPa. From these results, the combination of PCE (2.0%) + HPMC (0.3%) + WG (0.1%) + ST (0.1%) showed an 18% higher plastic viscosity and -4.4% lower yield stress than Plain.


1987 ◽  
Vol 63 (1) ◽  
pp. 552-554
Author(s):  
M. I. Alymov ◽  
E. N. Pirogov ◽  
L. L. Artyukhina ◽  
O. V. Komarov
Keyword(s):  

2019 ◽  
Vol 196 ◽  
pp. 00011 ◽  
Author(s):  
Yaroslav Ignatenko ◽  
Andrey Gavrilov ◽  
Oleg Bocharov ◽  
Roland May

The current study is devoted to simulating cuttings transport by drilling fluid through a horizontal section of borehole with an annular cross section. Drill pipe rotates in fixed eccentric position. Steady-state flow is considered. Cuttings are rigid spheres with equal diameters. The carrying fluid is drilling mud with Herschel-Bulkley rheology. Suspension rheology depends on local shear rate and particles concentration. Continuous mixture model with algebraic equation for particles slipping velocity is used. Two hydrodynamic regimes are considered: axial flow without drill pipe rotation and with drill pipe rotation. In the case of axial flow was shown that increasing of power index n and consistency factor k increases pressure gradient and decreases cuttings concentration. Increasing of yield stress leads to increasing of pressure gradient and cuttings concentration. Cuttings concentration achieves constant value for high yield stress and not depends on it. Rotation of the drill pipe significantly changes the flow structure: pressure loss occurs and particles concentration decreases in the cross section. Two basic regimes of rotational flow are observed: domination of primary vortex around drill pipe and domination secondary vorticity structures. Transition between regimes leads to significant changes of flow integral parameters.


Author(s):  
Dayane Izidoro ◽  
Maria-Rita Sierakowski ◽  
Nina Waszczynskyj ◽  
Charles W. I. Haminiuk ◽  
Agnes de Paula Scheer

The effects of ingredients on the sensory evaluation and rheological behavior of two brands of mayonnaise were examined in this work. Mayonnaise samples were examined by Analytical Descriptive Test and Ranking Test of Preference. The rheological parameters were determined at 25°C using a concentric cylinder Brookfield rheometer with a spindle SC4-34. The results showed that standard mayonnaise as opposed to low-fat mayonnaise gained higher grades for most sensory attributes. All samples were found to exhibit non-Newtonian pseudoplastic behavior described by Herschel–Bulkley model. A decrease in the yield stress, viscosity and shear stress with the decrease in oil content was observed in all products, which confirm that the rheological characterization is capable of distinguishing rather well between mayonnaises made with different formulation.


Author(s):  
Christopher M. Boggs ◽  
Fernando D. Goncalves ◽  
Mehdi Ahmadian

Magnetorheological (MR) fluids are often characterized by their field-dependent yield stress. Upon the activation of a magnetic field, the fluid has the ability to change from a fluid state to a semi-solid state in milliseconds. The field-dependent yield stress and the fluid’s fast response time make MR fluid an attractive technology for many applications. One such application that has gained considerable attention is in MR fluid dampers. The real-time control possibilities make MR dampers attractive alternatives to conventional viscous dampers. In comparing passive dampers with MR dampers, an equivalent viscous damping coefficient is often found from the energy dissipated by the MR damper with a fixed current applied to the damper. In contrast, this study investigates energy dissipation of the MR damper under a semi-active hybrid control policy. Hybrid control is a linear combination of skyhook and groundhook control. This study investigates the system energy under steady-state conditions at three frequencies, and how the system energy varies with varying contributions from skyhook and groundhook. A quarter-car rig was used to evaluate the dynamics of the hybrid suspension using an MR damper. Previous studies have shown that hybrid control can offer advantages to both the sprung and unsprung masses; however the relationship between energy dissipation and performance is not clear. In this study, we compare control policy performance to several energy-based measures. Results indicate that there is a strong correlation between sprung mass RMS acceleration and unsprung mass RMS acceleration to several of the energy-based measures.


Materials ◽  
2019 ◽  
Vol 12 (21) ◽  
pp. 3574 ◽  
Author(s):  
Yiolanda Damianou ◽  
Pandelitsa Panaseti ◽  
Georgios C. Georgiou

The steady-state Couette flow of a yield-stress material obeying the Bingham-plastic constitutive equation is analyzed assuming that slip occurs when the wall shear stress exceeds a threshold value, the slip (or sliding) yield stress. The case of Navier slip (zero slip yield stress) is studied first in order to facilitate the analysis and the discussion of the results. The different flow regimes that arise depending on the relative values of the yield stress and the slip yield stress are identified and the various critical angular velocities defining those regimes are determined. Analytical solutions for all the regimes are presented and the implications for this important rheometric flow are discussed.


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