Thermorheological Characterization of Elastoviscoplastic Carbopol Ultrez 20 Gel

Author(s):  
M. A. Hassan ◽  
Manabendra Pathak ◽  
Mohd. Kaleem Khan

The temperature and concentration play an important role on rheological parameters of the gel. In this work, an experimental investigation of thermorheological properties of aqueous gel Carbopol Ultrez 20 for various concentrations and temperatures has been presented. Both controlled stress ramps and controlled stress oscillatory sweeps were performed for obtaining the rheological data to find out the effect of temperature and concentration. The hysteresis or thixotropic seemed to have negligible effect. Yield stress, consistency factor, and power law index were found to vary with temperature as well as concentration. With gel concentration, the elastic effect was found to increase whereas viscous dissipation effect was found to decrease. Further, the change in elastic properties was insignificant with temperature in higher frequency range of oscillatory stress sweeps.

Author(s):  
Se-Ra Hong ◽  
Dong-Soo Sun ◽  
Whachun Yoo ◽  
Byoungseung Yoo

Gum-based food thickeners are widely used to care for patients with dysphagia in Korea. In this study, the flow properties of commercially available gum-based food thickeners marketed in Korea were determined as a function of temperature. The flow properties of thickeners were determined based on the rheological parameters of the power law and Casson models. Changes in shear stress with the rate of shear (1-100 s-1) at different temperatures (5, 20, 35, and 50 oC) were independent of the type of thickener. All thickeners had high shear-thinning behavior (n=0.08-0.18) with yield stress at the different temperatures tested. In general, apparent viscosity (na,50) values progressively decreased with an increase in temperature. In addition, the consistency index (K) and Casson yield stress (σoc) values did not change much upon an increase in temperature from 5 to 35 oC, except for sample B. In the temperature range of 5-50 oC, the thickeners followed an Arrhenius temperature relationship with a high determination coefficient (R2=0.93-0.97): activation energies (Ea) for the flow of thickeners were in the range of 2.44 - 10.7 kJ/mol. Rheological parameters demonstrated considerable differences in flow behavior between the different gum-based food thickeners, indicating that their flow properties are related to the type of thickener and the flow properties of gum.


2011 ◽  
Vol 324 ◽  
pp. 277-281 ◽  
Author(s):  
Pierre Campistron ◽  
Julien Carlier ◽  
Nadine Saad ◽  
Jamin Gao ◽  
Malika Toubal ◽  
...  

The main goal of this work is to develop an ultrasonic high frequency method for characterization of thin layers. The development of high frequency acoustic transducers for longitudinal waves and shear waves on silicon has enabeled the characterization of thin films deposited on this substrate. Three types of transducers have been achieved : (i) single crystal LiNbOSubscript text3 Y+163° for shear waves generation, and (ii) Y+36° for longitudinal waves, bonded and thinned on silicon substrate to achieve ultrasonic transducers in the frequency range 300-600 MHz ; (iii) thin films ZnO transducers were realized due to sputtering technologies working in the frequency range 1 GHz- 2.5 GHz. Using an inversion method and a network analyser which provide the scattering S11 parameter of the transducer versus the frequency we deduce the elastic properties of films deposited on the wafer surface. Thanks to these transducers the acoustic properties of thin films such as SU-8 based nanocomposites (doped with TiO2 , SrTiO3 or W nanoparticles) will be presented. In order to achieve mechanical impedance matching between silicon and water we control the mass of the embedded particles which provide a way to adjust the elastic properties of the characterized material. In another application an Indium metallic layer have been characterized in the high frequency range. We also use this method to characterize dielectric permittivity of the ZnO transducers.


2016 ◽  
Vol 139 (2) ◽  
Author(s):  
Sergio L. D. Kfuri ◽  
Edson J. Soares ◽  
Roney L. Thompson ◽  
Renato N. Siqueira

Industrial processes with non-Newtonian fluids are common in many segments such as petroleum, cosmetic, and food industries. Slurries, emulsions, and gas–liquid dispersions are some examples with industrial relevance. When a fluid flows in a pipe system, pressure losses are always present. For Newtonian fluids, a quite reasonable understanding of this phenomenon was already achieved and is available in the literature. The same cannot be stated for non-Newtonian fluids owing to their complex characteristics, such as pseudoplasticity, viscoplasticity, elasticity, and thixotropy. The understanding of the influence of these characteristics on flow behavior is very important in order to design efficient pipeline systems. The design of such systems requires the estimation of the pressure drop due to friction effects. However, there are few works regarding friction losses for non-Newtonian fluids in pipeline systems, making this task a difficult one. In this study, two classes of fluids are investigated and compared with the Newtonian results. The first category of fluids are the ones that exhibits pseudoplastic behavior and can be modeled as a power-law fluid, and the second category are the ones that possesses a yield stress and can be modeled as a Bingham fluid. Polyflow was used to compute the friction losses in both abrupt contractions and expansions laminar flow conditions. It shows that for the expansion cases, the aspect ratio affects more the local friction coefficients than for the contraction cases. The influence of the power index n on local friction losses is similar for both cases, abrupt contractions and abrupt expansions. At low Reynolds numbers, dilatant fluids present the lowest values of the friction coefficient, K, independent of geometry. At high Reynolds numbers, a reversal of the curves occurs, and the dilatant fluid presents larger values of K coefficient. For the cases investigated, there is also a Reynolds number in which all the curves exhibit the same value of K for any value of the power-law index. The effect of τy′ shows a different behavior between contractions and expansions. In the case of contractions, the material with the highest dimensionless yield stress has the highest K value. In the case of the expansions, the behavior is the opposite, i.e., the higher the yield stress, the lower is the values of the K coefficient. Equations for each accessory as a function of the rheological parameters of the fluid and the Reynolds number of the flow are also proposed. The data were adjusted according to two main equations: the two Ks method proposed by Hooper (1981, “The Two-K Method Predicts Head Losses in Pipe Fittings,” Chem. Eng., 81, pp. 96–100.) is used for all the contractions cases, and the equation proposed by Oliveira et al. (1997, “A General Correlation for the Local Coefficient in Newtonian Axisymmetric Sudden Expansions,” Int. J. Heat Fluid Flow, 19(6), pp. 655–660.) is used for all the expansions cases. The equations found were compared with the numerical results and showed satisfactory precision and thus can be used for engineering applications.


Author(s):  
Hossam M. Metwally ◽  
Raj M. Manglik

The enhanced heat transfer in laminar viscoplastic, shear thinning, Herschel-Bulkley fluid flows in sinusoidal corrugated-plate channels is investigated. With uniform-temperature plate walls, periodically developed flows are considered for a wide range of flow rates (10 ≤ Reg ≤ 700) and pseudoplastic flow behavior indices (n = 0.54, 0.8, and 1.0; the latter representing a Bingham plastic). The effects of fluid yield stress are simulated for the case where τy = 1.59 N/m2, representing a 0.5% xantham gum aqueous solution. Typical velocity and temperature distributions, along with extended results for isothermal friction factor ƒ and Colburn factor j are presented. The effect of the yield stress is found to be most dominant at low Reg regardless of the power law index n, and the recirculation or swirl in the wall trough regions is weaker than in the cases of Newtonian and power-law liquids. At higher Reg, the performance of the Herschel-Bulkley fluid asymptotically approaches that of the non-yield-stress power-law fluid. At low Reg, the yield stress increases ƒ by an order of magnitude and j is enhanced because of the higher wall gradients imposed by the plug-like flow field. The relative heat transfer enhancement, represented by the ratio (j/ƒ), and the role of the fluid yield stress and shear-thinning (or pseudoplastic) behaviors are also discussed.


2005 ◽  
Vol 73 (2) ◽  
pp. 291-299 ◽  
Author(s):  
E. Mitsoulis ◽  
S. Sofou

The lubrication approximation theory (LAT) is used to provide numerical results for calendering a sheet from an infinite reservoir. The Herschel–Bulkley model of viscoplasticity is employed, which reduces with appropriate modifications to the Bingham, power-law, and Newtonian models. A dimensionless slip coefficient is introduced to account for the case of slip at the roll surfaces. The results give the final sheet thickness as a function of the dimensionless power-law index (in the case of pseudoplasticity), the Bingham number or the dimensionless yield stress calculated at the nip (in the case of viscoplasticity), and the dimensionless slip coefficient in both cases. Integrated quantities of engineering interest are also calculated. These include the maximum pressure, the roll-separating force, and the power input to the rolls. Decreasing the power-law index or increasing the dimensionless yield stress lead to excess sheet thickness over the thickness at the nip. All engineering quantities calculated in dimensionless form increase substantially with the departure from the Newtonian values. The presence of slip decreases pressure and the engineering quantities and increases the domain in all cases.


Open Physics ◽  
2011 ◽  
Vol 9 (5) ◽  
Author(s):  
Kuppalapalle Vajravelu ◽  
Sreedharamalle Sreenadh ◽  
Palluru Devaki ◽  
Kerehalli Prasad

AbstractThe constitution of blood demands a yield stress fluid model, and among the available yield stress fluid models for blood flow, the Herschel-Bulkley model is preferred (because Bingham, Power-law and Newtonian models are its special cases). The Herschel-Bulkley fluid model has two parameters, namely the yield stress and the power law index. The expressions for velocity, plug flow velocity, wall shear stress, and the flux flow rate are derived. The flux is determined as a function of inlet, outlet and external pressures, yield stress, and the elastic property of the tube. Further when the power-law index n = 1 and the yield stress τ 0 → 0, our results agree well with those of Rubinow and Keller [J. Theor. Biol. 35, 299 (1972)]. Furthermore, it is observed that, the yield stress and the elastic parameters (t 1 and t 2) have strong effects on the flux of the non-Newtonian fluid flow in the elastic tube. The results obtained for the flow characteristics reveal many interesting behaviors that warrant further study on the non-Newtonian fluid flow phenomena, especially the shear-thinning phenomena. Shear thinning reduces the wall shear stress.


2012 ◽  
Vol 32 (2) ◽  
pp. 381-385 ◽  
Author(s):  
Ana Lúcia Gabas ◽  
Renato Alexandre Ferreira Cabral ◽  
Carlos Augusto Fernandes de Oliveira ◽  
Javier Telis-Romero

The rheological behavior and density of goat milk was studied as a function of solids concentration (10.5 to 50.0%) and temperature (273 to 331 k). Newtonian behavior was observed for values of total solids (TS) between 10.5 and 22.0% and temperatures from 276 to 331 k changing to pseudoplastic behavior without yield stress for TS from 25.0 to 39.4% at the same range of temperature. Goat milk with TS between 44.3 to 50.0% and temperatures of 273 to 296 k showed yield stress in addition to pseudoplastic behavior. At 303 to 331 k the power law model was observed again, without yield stress. The density of goat milk ranged from 991.7 to 1232.4 kg.m-3.


Polymers ◽  
2019 ◽  
Vol 11 (2) ◽  
pp. 335 ◽  
Author(s):  
Chao-Tsai Huang ◽  
Ling-Jue Chen ◽  
Tse-Yu Chien

Compression molding is a lightweight technology that allows to preserve fiber length and retain better mechanical properties compared to injection molding. In compression molding development, a suitable material such as glass fiber mat thermoplastics (GMT) is often used. However, because of the complicated micro-structure of the fibers and the fiber–resin matrix interactions, it is still quite challenging to understand the mechanism of compression molding and it is very difficult to obtain a uniformly compressed GMT product. In this study, we propose a method to measure the rheological properties of GMT through a compression system. Specifically, we utilized a compression molding system to record the relation between the loading force and the displacement. This quantitative information was used to estimate the power-law index and viscoelastic parameters and predict viscosity. Moreover, the estimated viscoelastic parameters of GMT were implemented into Moldex3D to evaluate the flow behavior under compression. The results showed that the trend of the loading force variation was consistent in numerical simulation and experiments. However, at the final stage of compression molding, the experimental loading force was much higher than that estimated by simulation. To find out the mechanism causing this deviation, a series of studies were performed. Through TGA measurement, we found that the fiber content of the center portion of the compressed part increased from 63% to 85% during compression. This was expected, as a result of the fiber–polymer matrix separation effect. This fiber–polymer matrix separation effect influenced the power-law index and rheological parameters of GMT, making them fluctuate. Specifically, the power-law index changed from 1.0 to 0.62. These internal changes of the rheological properties further induced a much higher loading force in the real experimental GMT system. We further verified the rheological properties variation using pure polyamide (PA) and found that since there is no fiber–polymer matrix interactions the power-law index and curve-fitting rheological parameters were almost constant. The mechanism causing the deviation was therefore validated.


2012 ◽  
Vol 32 (2) ◽  
pp. 333-341
Author(s):  
Maria E. M. Duarte ◽  
Deyzi S. Gouveia ◽  
Mario E. R. M. C. Mata ◽  
Alexandre J. de M. Queiroz

In this study the rheological behavior in different temperatures (0; 6; 18 e 24 ºC) and physicochemical parameters of integral annona (Annona squamosa) pulp and the annona pulp with milk in different percentages pulp/milk (75g of annona pulp/25g of milk, 50g of annona pulp/50g of milk, 25g of annona pulp/75g of milk) have been availed, in order to verify the effect of temperature and pulp concentration in the rheological behavior of these beverages. To obtain the rheological parameters a concentric cylinder rheometer has been used and the rheograms were analyzed using the Ostwald-de-Wael (power Law) and Herschel-Bulkley models. The physicochemical parameters (sugars, pH, ash, acidity and soluble solids) were determined in order to establish correlations with the rheological behavior. Finally, the best results had been obtained using the Herschel-Bulkley model; the low values for the behavior index (n <1) obtained confirm the pseudoplastic behavior of all samples.


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