scholarly journals Photocatalytic Microporous Membrane against the Increasing Problem of Water Emerging Pollutants

Materials ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1649 ◽  
Author(s):  
Pedro M. Martins ◽  
Joana M. Ribeiro ◽  
Sara Teixeira ◽  
Dmitri. Y. Petrovykh ◽  
Gianaurelio Cuniberti ◽  
...  
Keyword(s):  
Tio2 Nanoparticles ◽  
Polymer Nanocomposites ◽  
Cost Effective ◽  
Emerging Pollutants ◽  
Polymeric Membranes ◽  
Microporous Membrane ◽  
Solvent Casting ◽  
Photocatalytic Efficiency ◽  
Polyvinylidene Difluoride ◽  
X Ray

Emerging pollutants are an essential class of recalcitrant contaminants that are not eliminated from water after conventional treatment. Here, a photocatalytic microporous membrane based on polyvinylidene difluoride-co-trifluoroethylene (PVDF−TrFE) with immobilised TiO2 nanoparticles, prepared by solvent casting, was tested against representative emerging pollutants. The structure and composition of these polymeric membranes were characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy, Fourier-transform infrared spectroscopy, porosimetry, and contact angle goniometry. The nanocomposites exhibited a porous structure with a uniform distribution of TiO2 nanoparticles. The addition of TiO2 did not change the structure of the polymeric matrix; however, it increased the wettability of the nanocomposite. The nanocomposites degraded 99% of methylene blue (MB), 95% of ciprofloxacin (CIP), and 48% of ibuprofen (IBP). The microporous nanocomposite exhibited no photocatalytic efficiency loss after four use cycles, corresponding to 20 h of UV irradiation. The reusability of this system confirms the promising nature of polymer nanocomposites as the basis for cost-effective and scalable treatments of emerging pollutants.

scholarly journals Photocatalytic activity of Pr-modified TiO2 for the degradation of bisphenol A

2021 ◽  
Vol 3 (2) ◽  
Author(s):  
Denise S. Cordeiro ◽  
Fernando L. Cassio ◽  
Larissa Ciccotti ◽  
Thiago L. R. Hewer ◽  
Paola Corio ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Bisphenol A ◽  
Pore Diameter ◽  
Sol Gel ◽  
Bandgap Energy ◽  
Photocatalytic Efficiency ◽  
Average Pore ◽  
X Ray ◽  
Vis Spectroscopy ◽  
Adsorption Desorption

AbstractPraseodymium doped TiO2 nanoparticles were successfully prepared by the sol–gel method and characterized by X-ray powder diffraction, N2 adsorption–desorption isotherm, and UV–vis spectroscopy. The effects of the dopant on the crystallite size, specific surface area, average pore diameter, pore volume, and bandgap energy were investigated. The photocatalytic activity of the catalysts was evaluated by bisphenol A degradation and mineralization, which is a representative endocrine disruptor. Furthermore, under visible light irradiation the Pr-modified TiO2 photocatalysts exhibited higher photocatalytic efficiency than unmodified TiO2. When praseodymium was loaded (1.0–5.0%) onto the surface of TiO2, the rates of degradation and mineralization were increased 3–5 times.

scholarly journals Synthesis and Characterization of Clay Polymer Nanocomposites of P(4VP-co-AAm) and Their Application for the Removal of Atrazine

Polymers ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 721 ◽  
Author(s):  
Jorge A. Ramírez-Gómez ◽  
Javier Illescas ◽  
María del Carmen Díaz-Nava ◽  
Claudia Muro-Urista ◽  
Sonia Martínez-Gallegos ◽  
...  
Keyword(s):  
Polymer Nanocomposites ◽  
Nanocomposite Materials ◽  
Synthesis And Characterization ◽  
Cross Linking ◽  
X Ray Diffraction ◽  
Numerous Species ◽  
X Ray ◽  
Different Types ◽  
Synthesized Materials

Atrazine (ATZ) is an herbicide which is applied to the soil, and its mechanism of action involves the inhibition of photosynthesis. One of its main functions is to control the appearance of weeds in crops, primarily in corn, sorghum, sugar cane, and wheat; however, it is very toxic for numerous species, including humans. Therefore, this work deals with the adsorption of ATZ from aqueous solutions using nanocomposite materials, synthesized with two different types of organo-modified clays. Those were obtained by the free radical polymerization of 4-vinylpyridine (4VP) and acrylamide (AAm) in different stoichiometric ratios, using tetrabutylphosphonium persulfate (TBPPS) as a radical initiator and N,N′-methylenebisacrylamide (BIS) as cross-linking agent. The structural, morphological, and textural characteristics of clays, copolymers, and nanocomposites were determined through different analytical and instrumental techniques, i.e., X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and thermogravimetric analysis (TGA). Adsorption kinetics experiments of ATZ were determined with the modified and synthesized materials, and the effect of the ratio between 4VP and AAm moieties on the removal capacities of the obtained nanocomposites was evaluated. Finally, from these sets of experiments, it was demonstrated that the synthesized nanocomposites with higher molar fractions of 4VP obtained the highest removal percentages of ATZ.

Cost-effective masks for deep x-ray lithography

2003 ◽  
Author(s):  
Heinz-Ulrich Scheunemann ◽  
Bernd Loechel ◽  
Linke Jian ◽  
Daniel Schondelmaier ◽  
Yohannes M. Desta ◽  
...  
Keyword(s):  
Cost Effective ◽  
X Ray

scholarly journals X-Ray Absorption Spectroscopy of TiO2 Nanoparticles in Water Using a Holey Membrane-Based Flow Cell

2017 ◽  
Vol 4 (23) ◽  
pp. 1700755 ◽  
Author(s):  
Tristan Petit ◽  
Jian Ren ◽  
Sneha Choudhury ◽  
Ronny Golnak ◽  
Sreeju S. N. Lalithambika ◽  
...  
Keyword(s):  
Tio2 Nanoparticles ◽  
Absorption Spectroscopy ◽  
Flow Cell ◽  
X Ray ◽  
X Ray Absorption

Timely and cost effective determination of dose-width product for panoramic x-ray systems

2013 ◽  
Vol 29 (5) ◽  
pp. 574
Author(s):  
Ronan Spring ◽  
Mike Sheehy ◽  
Tom Carty
Keyword(s):  
Cost Effective ◽  
X Ray

Silver mirror reaction metallized chromatography paper for supercapacitor application

2021 ◽  
Author(s):  
I-Hsuan Chen ◽  
Jung-Hsien Chang ◽  
Ren-Jie Xie ◽  
Chia-Hui Tseng ◽  
Sheng-Rong Hsieh ◽  
...  
Keyword(s):  
Flexible Electronics ◽  
Photoelectron Spectroscopy ◽  
Cost Effective ◽  
Water Contact ◽  
X Ray ◽  
Supercapacitor Application ◽  
Resource Limited ◽  
Vis Spectroscopy ◽  
Silver Mirror ◽  
Silver Mirror Reaction

Abstract In this study, the easy-to-operate silver mirror reaction (SMR) was used for metallizing chromatography paper. The SMR-metallized paper was characterized by water contact angle measurements, a surface profiler, X-ray photoelectron spectroscopy, UV-vis spectroscopy, X-ray diffraction, and electrical resistance measurement. The characterization results show that Ag was successfully synthesized on cellulose fibers and was electrically conductive after cyclic bending. Moreover, this SMR-metallized paper was used as electrodes for fabricating a supercapacitor. This SMR-metallized paper could be used for realizing cost-effective flexible electronics applied in on-site biochemical sensing in resource-limited settings.

Use of anti-solvent to enhance thermoelectric response of hybrid-halide perovskite thin films

2022 ◽  
Author(s):  
Shrikant SAINI ◽  
Izuki Matsumoto ◽  
Sakura Kishishita ◽  
Ajay Kumar Baranwal ◽  
Tomohide Yabuki ◽  
...  
Keyword(s):  
Thin Films ◽  
Electrical Conductivity ◽  
Photoelectron Spectroscopy ◽  
High Performance ◽  
Cost Effective ◽  
Performance Tuning ◽  
Charge Carrier Density ◽  
X Ray ◽  
Thermoelectric Energy Harvesting ◽  
Halide Perovskite

Abstract Hybrid halide perovskite has been recently focused on thermoelectric energy harvesting due to the cost-effective fabrication approach and ultra-low thermal conductivity. To achieve high performance, tuning of electrical conductivity is a key parameter that is influenced by grain boundary scattering and charge carrier density. The fabrication process allows tuning these parameters. We report the use of anti-solvent to enhance the thermoelectric performance of lead-free hybrid halide perovskite, CH3NH3SnI3, thin films. Thin films with anti-solvent show higher connectivity in grains and higher Sn+4 oxidation states which results in enhancing the value of electrical conductivity. Thin films were prepared by a cost-effective wet process. Structural and chemical characterizations were performed using x-ray diffraction, scanning electron microscope, and x-ray photoelectron spectroscopy. The value of electrical conductivity and the Seebeck coefficient were measured near room temperature. The high value of power factor (1.55 µW/m.K2 at 320 K) was achieved for thin films treated with anti-solvent.

A COST EFFECTIVE X-RAY DETECTOR FOR PLASMA FOCUS DIAGNOSTICS

2000 ◽  
Vol 14 (15) ◽  
pp. 563-570 ◽  
Author(s):  
M. ZAKAULLAH ◽  
IJAZ AKHTAR ◽  
S. F. MEHMOOD ◽  
A. WAHEED ◽  
G. MURTAZA
Keyword(s):  
Ultraviolet Radiation ◽  
Plasma Focus ◽  
Vacuum Ultraviolet ◽  
Cost Effective ◽  
Low Energy ◽  
Radiation Environment ◽  
Anode Surface ◽  
Current Sheath ◽  
X Ray ◽  
Axially Moving

A time-resolved rugged X-ray detector (XRD) which may be used in intense radiation environment is developed. The detector is used to study the X-ray emission from a low-energy (2.3 kJ) Mather-type plasma focus energized by a 32 μF single capacitor, using hydrogen and argon (3:2) mixture as gas filling. In the detector, the electron emitter is made of nickel and aluminum. The sensitivity of the detector with nickel cathode is found to be very low. No signal could be recorded by masking the detector with even the 2 μm thick Al foil. When Al cathode is used in the XRD, the sensitivity of the detector increases abruptly. To stop the optical/ultraviolet radiation from approaching the active area, it is masked with 6 μm Al filter. It is found that an XRD with nickel cathode is not useful for X-ray detection in a low-energy plasma focus. However, due to its excellent response to vacuum ultraviolet radiation (≤600 Å), it may find application in the study of the axial rundown of current sheath, and its velocity. The X-ray emission from focus plasma is the highest at 0.5 mbar. With increase in pressure, the emission is dropped. At filling pressures of 2.0–2.5 mbar, the X-ray emission increases again. High X-ray emission at 0.5 mbar is due to interaction of energetic electrons in the current sheath with the anode surface, whereas moderately high emission at 2.0–2.5 mbar is caused by an axially moving shockwave.

scholarly journals Effect of Film Formation Method and Annealing on Crystallinity of Poly(L-Lactic Acid) Films

2011 ◽  
Author(s):  
Shan-Ting Hsu ◽  
Y. Lawrence Yao
Keyword(s):  
Drug Delivery ◽  
Lactic Acid ◽  
Film Formation ◽  
Solvent Casting ◽  
Crystalline Morphology ◽  
X Ray Diffraction ◽  
X Ray ◽  
Lamellar Structures ◽  
Coating Methods ◽  
Formation Method

Poly(L-lactic acid) (PLLA) has been shown to have potential medical usage such as in drug delivery because it can degrade into bioabsorbable products in physiological environments, and its degradation is affected by crystallinity. In this paper, the effect of film formation method and annealing on the crystallinity of PLLA are investigated. The films are made through solvent casting and spin coating methods, and subsequent annealing is conducted. The resulting crystalline morphology, structure, conformation, and intermolecular interaction are examined using optical microscopy, X-ray diffraction, and Fourier transform infrared spectroscopy. It is observed that solvent casting produces category 1 spherulites while annealed spin coated films leads to spherulites of category 2. Distinct lamellar structures and intermolecular interactions in the two kinds of films have been shown. The results enable better understanding of the crystallinity in PLLA, which is essential for its drug delivery application.

Sign in / Sign up

Export Citation Format

Share Document