scholarly journals Development of Photocatalytic Coatings by Thermal Hydrolysis of TiCl4 on Ceramic Roofing Tiles Made from Ferroalumina and Evaluation of De-Pollution Properties

Materials ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 620
Author(s):  
Angeliki Christogerou ◽  
Dimitra Koumpouri ◽  
George N. Angelopoulos
Keyword(s):  
Environmental Sustainability ◽  
Building Materials ◽  
Organic Pollutant ◽  
Indigo Carmine ◽  
Bauxite Residue ◽  
Thermal Hydrolysis ◽  
Atmospheric Conditions ◽  
Lower Efficiency ◽  
Negative Effect ◽  
Hydrolysis Of

The development of new, environmental friendly building materials with photocatalytic properties remain still on the top of the investigations both for academy and industry. The main drive is the increasing air pollution and the greenhouse gas emissions that have negative effect on public health and buildings. Ceramic roofing tiles functionalized with TiO2 can contribute on tackling these severe environmental problems by improving their properties. In this study, heavy clay ceramics manufactured from clay-body mixture and a Bayer process bauxite residue (ferroalumina) are used as substrates for the deposition of TiO2 coatings in order to produce self-cleaning ceramic surfaces. The process is based on the thermal hydrolysis of TiCl4 which takes place in a CVD reactor under atmospheric conditions. All coated samples were annealed at 600 °C and characterized in means of XRD, SEM/EDS and degradation ability of an organic pollutant. The formation of titania mixed phases (rutile and perovskite) shows positive results regarding the photocatalytic activity of the samples. The ones containing ferroalumina decomposed 100% the indigo carmine solution after 4 h, in comparison with the reference one which presented lower efficiency. Finally, this paper addresses technical feasible solutions for the production of photocatalytic active ceramics within the concept of circular economy and environmental sustainability.

scholarly journals Thermal Characterization of Recycled Materials for Building Insulation

Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3564
Author(s):  
Arnas Majumder ◽  
Laura Canale ◽  
Costantino Carlo Mastino ◽  
Antonio Pacitto ◽  
Andrea Frattolillo ◽  
...  
Keyword(s):  
Environmental Impact ◽  
Environmental Sustainability ◽  
Building Materials ◽  
Raw Materials ◽  
Natural Fibers ◽  
Thermal Characterization ◽  
Recycled Materials ◽  
Building Insulation ◽  
Operational Phase

The building sector is known to have a significant environmental impact, considering that it is the largest contributor to global greenhouse gas emissions of around 36% and is also responsible for about 40% of global energy consumption. Of this, about 50% takes place during the building operational phase, while around 10–20% is consumed in materials manufacturing, transport and building construction, maintenance, and demolition. Increasing the necessity of reducing the environmental impact of buildings has led to enhancing not only the thermal performances of building materials, but also the environmental sustainability of their production chains and waste prevention. As a consequence, novel thermo-insulating building materials or products have been developed by using both locally produced natural and waste/recycled materials that are able to provide good thermal performances while also having a lower environmental impact. In this context, the aim of this work is to provide a detailed analysis for the thermal characterization of recycled materials for building insulation. To this end, the thermal behavior of different materials representing industrial residual or wastes collected or recycled using Sardinian zero-km locally available raw materials was investigated, namely: (1) plasters with recycled materials; (2) plasters with natural fibers; and (3) building insulation materials with natural fibers. Results indicate that the investigated materials were able to improve not only the energy performances but also the environmental comfort in both new and in existing buildings. In particular, plasters and mortars with recycled materials and with natural fibers showed, respectively, values of thermal conductivity (at 20 °C) lower than 0.475 and 0.272 W/(m⋅K), while that of building materials with natural fibers was always lower than 0.162 W/(m⋅K) with lower values for compounds with recycled materials (0.107 W/(m⋅K)). Further developments are underway to analyze the mechanical properties of these materials.

scholarly journals The effect of drying temperature on the properties of gelatin from carps (Cyprinus carpio) skin

2019 ◽  
Vol 37 (No. 4) ◽  
pp. 246-251 ◽  
Author(s):  
Joanna Tkaczewska ◽  
Maciej Wielgosz ◽  
Piotr Kulawik ◽  
Marzena Zajac
Keyword(s):  
Cyprinus Carpio ◽  
Freeze Drying ◽  
Treatment Method ◽  
Thermal Hydrolysis ◽  
Gel Properties ◽  
Drying Temperature ◽  
Freeze Dried ◽  
Different Temperatures ◽  
Pre Treatment ◽  
Hydrolysis Of

The influence of drying temperature on the characteristics and gel properties of gelatine from Cyprinus carpio L. skin was studied. Gelatine was extracted from the carp skin using NaOH and ethanol pre-treatment method, extracted in water in 45°C and then dried in 4 different temperatures: 50, 70, 80°C and freeze-dried. The  electrophoresis and functional properties of gelatines were investigated. Freeze drying allowed to obtain a high gelling force, and all other methods did not give satisfactory results. The proteins in gelatines dried at higher temperatures separated by electrophoresis gave severely blurred bands. It may be explained by thermal hydrolysis of collagen fibrils. Freeze drying is the only effective method for drying this product, which can be used in industry.

scholarly journals An Alternative to Clay in Building Materials: Red Mud Sintering Using Fly Ash via Taguchi’s Methodology

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Suchita Rai ◽  
Dilip H. Lataye ◽  
M. J. Chaddha ◽  
R. S. Mishra ◽  
P. Mahendiran ◽  
...  
Keyword(s):  
Fly Ash ◽  
Construction Industry ◽  
Red Mud ◽  
Morphological Analysis ◽  
Building Materials ◽  
Sintering Temperature ◽  
Bauxite Residue ◽  
Significant Parameter ◽  
Alkaline Waste ◽  
Free Caustic Soda

“Red mud” or “bauxite residue” is a highly alkaline waste generated from alumina refinery with a pH of 10.5–12.5 which poses serious environmental problems. Neutralization or its treatment by sintering in presence of additives is one of the methods for overcoming the caustic problem as it fixes nearly all the leachable free caustic soda present in red mud. In the present study, feasibility of reducing the alkaline nature of red mud by sintering using fly ash as an additive via Taguchi methodology and its use for brick production, as an alternative to clay, is investigated. The analysis of variance (ANOVA) shows that sintering temperature is the most significant parameter in the process. A pH of 8.9 was obtained at 25–50% of red mud and 50–75% fly ash with water and temperature of . Alternatively 50% of red mud can be mixed with 50% of fly ash with water at temperature of to get a pH of about 8.4. The mechanism of this process has been explained with also emphasis on chemical, mineralogical, and morphological analysis of the sintered red mud. The results would be extremely useful in utilization of red mud in building and construction industry.

scholarly journals Low-temperature thermal hydrolysis of sludge prior to anaerobic digestion: principal component analysis (PCA) of experimental data

Data in Brief ◽  
2021 ◽  
pp. 107323
Author(s):  
Mohamed N.A. Meshref ◽  
Seyed Mohammad Mirsoleimani Azizi ◽  
Wafa Dastyar ◽  
Rasha Maal-Bared ◽  
Bipro Ranjan Dhar
Keyword(s):  
Experimental Data ◽  
Principal Component Analysis ◽  
Anaerobic Digestion ◽  
Low Temperature ◽  
Principal Component ◽  
Component Analysis ◽  
Thermal Hydrolysis ◽  
Hydrolysis Of

scholarly journals Effect of calcination temperature and calcination time on the kaolinite/tio2 composite for photocatalytic reduction of CO2

2012 ◽  
Vol 58 (4) ◽  
pp. 10-22 ◽  
Author(s):  
Martin Reli ◽  
Kamila Kočí ◽  
Vlastimil Matějka ◽  
Pavel Kovář ◽  
Lucie Obalová
Keyword(s):  
Crystallite Size ◽  
Physical Adsorption ◽  
Photocatalytic Reduction ◽  
Thermal Hydrolysis ◽  
Calcination Time ◽  
Different Temperatures ◽  
Higher Temperature ◽  
Titanyl Sulphate ◽  
Reduction Of Co2 ◽  
Hydrolysis Of

Abstract The kaolinite/TiO2 composite (60 wt% of TiO2) was prepared by thermal hydrolysis of a raw kaolin suspension in titanyl sulphate and calcined at different temperatures (600, 650 and 700°C) and for different times (1, 2 and 3 h). The obtained samples were characterized by XRPD, N2 physical adsorption and SEM, and tested for photocatalytic reduction of CO2. The different calcination conditions did not influence TiO2 phase composition, only slightly changed the specific surface area, and significantly affected crystallite size of kaolinite/TiO2 composite. A higher temperature and longer duration of calcination lead to higher crystallinity of the powder. The photocatalytic results showed that the crystallite size determined the efficiency of kaolinite/TiO2 photocatalysts.

Specificity in Thermal Hydrolysis of Triglycerides

1968 ◽  
Vol 33 (3) ◽  
pp. 305-307 ◽  
Author(s):  
C. BUZIASSY ◽  
W. W. NAWAR
Keyword(s):  
Thermal Hydrolysis ◽  
Hydrolysis Of

Thermal hydrolysis of waste activated sludge at Hengelo Wastewater Treatment Plant, The Netherlands

2014 ◽  
Vol 70 (1) ◽  
pp. 1-7 ◽  
Author(s):  
Mathijs Oosterhuis ◽  
Davy Ringoot ◽  
Alexander Hendriks ◽  
Paul Roeleveld
Keyword(s):  
Activated Sludge ◽  
Treatment Plant ◽  
Waste Activated Sludge ◽  
Treatment Technique ◽  
Thermal Hydrolysis ◽  
Sludge Treatment ◽  
Water Board ◽  
Anaerobic Biodegradability ◽  
Hydrolysis Process ◽  
Hydrolysis Of

The thermal hydrolysis process (THP) is a sludge treatment technique which affects anaerobic biodegradability, viscosity and dewaterability of waste activated sludge (WAS). In 2011 a THP-pilot plant was operated, connected to laboratory-scale digesters, at the water board Regge en Dinkel and in cooperation with Cambi A.S. and MWH Global. Thermal hydrolysis of WAS resulted in a 62% greater volatile solids (VS) reduction compared to non-hydrolysed sludge. Furthermore, the pilot digesters could be operated at a 2.3 times higher solids loading rate compared to conventional sludge digesters. By application of thermal sludge hydrolysis, the overall efficiency of the sludge treatment process can be improved.

scholarly journals Disclosure Integration of Lean Six Sigma Principles in Sustainable Supply Chain in Poultry Industry

2021 ◽  
Vol 4 (1) ◽  
pp. 300-312
Author(s):  
Ratna Yulia Kusumastuti ◽  
Heti Mulyati ◽  
Gendut Suprayitno
Keyword(s):  
Supply Chain ◽  
Environmental Sustainability ◽  
Six Sigma ◽  
Management System ◽  
Security Management ◽  
Lean Six Sigma ◽  
Poultry Industry ◽  
Supply Chain Security ◽  
Negative Effect ◽  
Positive Effect

The poultry industry has been in the spotlight for its enormous potential economic development. However, poultry industry is still not implementing the concept of sustainability properly. There are still many wastes that have not been managed properly and there are still many problems in the supply chain that require more systematic handling. Many studies have shown that the implementation of Lean Six Sigma (LSS) and sustainability has positive results on the company's bottom line performance. This research tried to integrate the application of LSS principles and sustainability along the supply chain in the poultry industry in Indonesia. Data were collected from 4 listed poultry firms in Indonesia. The research method used SEM PLS with SmartPLS software. The results showed that supply chain security management system disclosure as the principle of LSS had a positive effect on the collaboration of supply chain disclosure and collaboration of supply chain disclosure had a positive effect on sustainability. The results also showed that risk management disclosure had a negative effect on the collaboration of supply chain disclosure and economic sustainability had a negative effect on environmental sustainability, but social sustainability had a positive effect on environmental sustainability. Based on the results of this study, there is a need to improve supply chain security management system and supply chain collaboration in order to advance sustainable poultry industry.

scholarly journals Playing Global Monopoly in Cement: The Globalization of CEMEX

2021 ◽  
Vol 8 (1) ◽  
pp. 10
Author(s):  
Mark William Cawman ◽  
Patricia Fine-Skalnik
Keyword(s):  
International Business ◽  
Environmental Sustainability ◽  
Multinational Corporation ◽  
Building Materials ◽  
Significant Risk ◽  
Cultural Dimensions ◽  
Business Growth ◽  
Research Article ◽  
Political Implications

This research article is intended for use as a classroom case study with questions for discussion in International Business. This research analyzes CEMEX and their strategy for globalization. CEMEX is a Mexico founded building materials company that operates in more than fifty countries and maintains trade relationships in over one-hundred nations. In addition to CEMEX creating an international business, CEMEX embraces core values including ethics, integrity, and environmental sustainability. The literature review in this study, documents how CEMEX overcame cultural and political implications, and significant risk to become a significant multinational corporation. The topical focus and purpose of this research is to explore CEMEX critically as a specimen company representing cross-cultural and international business growth. The analysis includes the utilization of the Hofstede Cultural Dimensions framework and the PESTLEEG analysis.

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