scholarly journals Using Fly Ash Wastes for the Development of New Building Materials with Improved Compressive Strength

Materials ◽  
2022 ◽  
Vol 15 (2) ◽  
pp. 644
Author(s):  
Maria Harja ◽  
Carmen Teodosiu ◽  
Dorina Nicolina Isopescu ◽  
Osman Gencel ◽  
Doina Lutic ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Building Materials ◽  
Simple Procedure ◽  
Xrd Analysis ◽  
Partial Hydrolysis ◽  
Alkali Activation ◽  
Activation Process ◽  
Solid Ratio ◽  
Powder Xrd Analysis

Fly ash wastes (silica, aluminum and iron-rich materials) could be smartly valorized by their incorporation in concrete formulation, partly replacing the cement. The necessary binding properties can be accomplished by a simple procedure: an alkali activation process, involving partial hydrolysis, followed by gel formation and polycondensation. The correlations between the experimental fly ash processing conditions, particle characteristics (size and morphology) and the compressive strength values of the concrete prepared using this material were investigated by performing a parametric optimization study to deduce the optimal processing set of conditions. The alkali activation procedure included the variation of the NaOH solutions concentration (8–12 M), temperature values (25–65 °C) and the liquid/solid ratio (1–3). The activation led to important modifications of the crystallography of the samples (shown by powder XRD analysis), their morphologies (seen by SEM), particle size distribution and Blaine surface values. The values of the compressive strength of concrete prepared using fly ash derivatives were between 16.8–22.6 MPa. Thus, the processed fly ash qualifies as a proper potential building material, solving disposal-associated problems, as well as saving significant amounts of cement consumed in concrete formulation.

Alkali-Activated Fly Ash Foams – Synthesis, Chemo-Physical Properties and Microstructure Modeling

2014 ◽  
Vol 92 ◽  
pp. 14-19 ◽  
Author(s):  
Petr Hlaváček ◽  
Vit Šmilauer ◽  
František Škvára
Keyword(s):  
Thermal Conductivity ◽  
Compressive Strength ◽  
Fly Ash ◽  
Thermal Capacity ◽  
Alkali Activation ◽  
Activation Process ◽  
Strain Diagram ◽  
Element Analysis ◽  
Aluminium Powder ◽  
One Year

Inorganic foams offer several unique properties such as low thermal conductivity, fire resistance, or UV stability. Inorganic foam specimens were synthesized from fly ash and aluminium powder through an alkali-activation process. Depending on mix proportions, bulk densities ranged between 400 and 800 kg/m3. Thermal treatment at 80°C for 12 hours accelerated curing process. Compressive strength was found in the range 4.5-9.0 MPa, flexural strength 0.6-1.7 MPa, Young's modulus 0.6-1.1 GPa, thermal conductivity 0.14-0.16 W/m/K and thermal capacity around 1100 J/kg/K. Exposing the foams to temperature 800°C led to a small decrease of compressive strength while exposure to 1100°C sintered the foam to higher strength of 13 MPa. Volumetric shrinkage 20% occurred at 1100°C without further disintegration. Residual compressive strength was determined after exposure to NaCl, HCl, Na2SO4, MgSO4, H2SO4. The highest reduction to 20% occured in both acids with pH=2 after one year of exposition. Digitized microstructures entered finite element analysis to validate a stress-strain diagram.

scholarly journals Alkali-Activated Metakaolin and Fly Ash as Unfired Ceramic Bonding Systems

Minerals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 197
Author(s):  
Jozef Vlček ◽  
Michaela Topinková ◽  
Miroslava Klárová ◽  
Petra Maierová ◽  
Hana Ovčačíková ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Fly Ash ◽  
Water Glass ◽  
Raw Materials ◽  
Alkali Activation ◽  
Activation Process ◽  
Laboratory Conditions ◽  
Naoh Solution ◽  
Bonding Systems

Metakaolin (MK) prepared by the calcination of kaolin at 550 °C and fly ash (FA) from the combustion of black coal in a granulating boiler were used to prepare unfired ceramic bonding systems via the alkali activation process. A long-term stability of the mechanical properties of the prepared samples similar to the unfired ceramic systems was observed. The optimal metakaolin and fly ash ratio, the type of the activator (NaOH or water glass) and its concentration were evaluated after the hydration in: a) laboratory conditions; b) hydration box; and c) under the hydrothermal activation. Raw materials and the samples prepared by alkali activation process were characterized by XRD, XRF, TG/DTA, and FTIR methods. The mechanical properties of the prepared samples were tested using a compressive strength test after 2, 28 and 56 days of hydration. The compressive strengths of 16 and 24 MPa after 28 days of hydration were reached for FA samples activated with water glass. The alkali activation of MK was successful in the NaOH solution of the molar concentration above 5 M. The compressive strength values of metakaolin, activated hydrothermally and hydrated at laboratory conditions, reached 11.2 and 5.5 MPa, respectively, for 5 M activator of NaOH.

scholarly journals Novel Analytical Method for Mix Design and Performance Prediction of High Calcium Fly Ash Geopolymer Concrete

Polymers ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 900
Author(s):  
Chamila Gunasekara ◽  
Peter Atzarakis ◽  
Weena Lokuge ◽  
David W. Law ◽  
Sujeeva Setunge
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Gradient Algorithm ◽  
Geopolymer Concrete ◽  
Statistical Regression ◽  
Solid Ratio ◽  
Marquardt Algorithm ◽  
High Calcium ◽  
High Calcium Fly Ash ◽  
Matlab Programming

Despite extensive in-depth research into high calcium fly ash geopolymer concretes and a number of proposed methods to calculate the mix proportions, no universally applicable method to determine the mix proportions has been developed. This paper uses an artificial neural network (ANN) machine learning toolbox in a MATLAB programming environment together with a Bayesian regularization algorithm, the Levenberg-Marquardt algorithm and a scaled conjugate gradient algorithm to attain a specified target compressive strength at 28 days. The relationship between the four key parameters, namely water/solid ratio, alkaline activator/binder ratio, Na2SiO3/NaOH ratio and NaOH molarity, and the compressive strength of geopolymer concrete is determined. The geopolymer concrete mix proportions based on the ANN algorithm model and contour plots developed were experimentally validated. Thus, the proposed method can be used to determine mix designs for high calcium fly ash geopolymer concrete in the range 25–45 MPa at 28 days. In addition, the design equations developed using the statistical regression model provide an insight to predict tensile strength and elastic modulus for a given compressive strength.

An Investigation of Usability of Brown Coal Fly Ash for Building Materials

2013 ◽  
Vol 438-439 ◽  
pp. 30-35 ◽  
Author(s):  
Nirdosha Gamage ◽  
Sujeeva Setunge ◽  
Kasuni Liyanage
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Brown Coal ◽  
Water Contamination ◽  
Building Materials ◽  
Coal Fly Ash ◽  
Sustainable Building ◽  
Laboratory Investigations ◽  
Cold Pressed ◽  
Initial Results

The Victoria State of Australia has the second largest reserves of brown coal on earth, representing approximately 20% of the worlds reserves, and at current use, could supply Victoria with its energy for over 500 years. Its combustion, annually, yields up to 1.3 million tonnes of fly ash, which is largely use for land-fills. Disposal of fly ash in open dumps cause massive environmental problems such as ground water contamination that may create various health problems. This study focuses on the usability of brown coal fly ash to develop a sustainable building material. A series of laboratory investigations was conducted using brown coal fly ash combined with cement and aggregate to prepare cold pressed samples aiming to test their properties. Initial results indicate that compressive strength satisfies minimum standard compressive strength required for bricks or mortar.

scholarly journals USE OF ZEOLITE IS ACTIVATED AS SUBSTITUTION OF CEMENT FOR PRICE AND COST

2018 ◽  
Vol 1 (1) ◽  
Author(s):  
Ahmad Nurfiki Alwi ◽  
Arif Rahman Setiaji ◽  
Abdurrohim Kurnia Agung ◽  
Abdul Halim
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Hypothesis Testing ◽  
Building Materials ◽  
Production Costs ◽  
Light Weight ◽  
Residential Community ◽  
High Production ◽  
The Cost ◽  
Cement Compounds

The number of economic needs is one of the fundamental aspects to support the survival of every individual in an area.  If seen in general, the cost of building the building and residential community still use building materials and installation costs are relatively higher.  With the advancement of technology has found a lightweight brick that has better strength, lighter, faster installation and environmentally friendly, so many people began to switch to using lightweight bricks.  For now the price of lightweight brick is still expensive, but this deficiency is covered with the speed of mounting and light weight so overall lightweight brick usage on certain patterns is very profitable.  The use of cement on lightweight bricks leads to high production costs.  With the above problems we have a breakthrough to replace the cement by using zeozolites containing silica compounds that resemble one of the cement compounds.  In this research, cement replacement with Zeolite is 20%, 40% and 60%.  Before use Zeolite was first activated using Fly Ash ratio of 65% Zeolite: 35% Fly Ash and 50% Zeolite: 50% Fly Ash, also activated using Ca (OH) 2 ratio 65% Zeolite: 35% Ca (OH) 2  And 50% Zeolite: 50% Ca (OH) 2.  Thus, there are 15 compositions including the control composition, each composition will be made up of 10 specimens.  Hypothesis testing using two way anova, tested is the effect of cement change treatment with Zeolite and comparison of Zeolite composition with Fly Ash and Ca (OH) 2 to compressive strength, absorption and cost. Keywords: Zeolite, Cement, compressive strength, Cost

scholarly journals Thermal, Physico-Chemical, and Mechanical Behaviour of Mass Concrete with Hybrid Blends of Bentonite and Fly Ash

Materials ◽  
2018 ◽  
Vol 12 (1) ◽  
pp. 60 ◽  
Author(s):  
Muhammad Ahad ◽  
Muhammad Ashraf ◽  
Rabinder Kumar ◽  
Mukhtar Ullah
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Thermal Stresses ◽  
Thermo Gravimetric Analysis ◽  
Xrd Analysis ◽  
Pozzolanic Reaction ◽  
Pulse Velocity ◽  
Mass Concrete ◽  
Gravimetric Analysis ◽  
Physico Chemical

Mass concrete has been commonly known for its thermal stresses which arise due to the entrapment of hydration temperature susceptible to thermal cracking. The utilization of mineral additives is a promising and widely adopted technique to mitigate such effects. This paper presents the thermal, physico-chemical, mechanical, and morphological behaviour of mass concrete with blends of bentonite (BT) and fly ash (FA). Apart from the rise in temperature due to hydration, the compressive strength, ultrasonic pulse velocity (UPV), differential thermal analysis (DTA), thermo-gravimetric analysis (TGA), X-ray diffraction (XRD) analysis, and microstructure were studied. The results of this study revealed that the substitution of BT and FA significantly improved the compressive strength and development rate of UPV in the mass concrete samples. The FA concrete (FC) specimen presented the lowest temperature during the peak hours compared to all other concrete mixes studied in this research. Bentonite concrete (BC) was also found to be more effective in controlling the escalation of temperature in mass concrete. Scan electron microscopy (SEM) micrographs presented partially reacted FA particles in a mix. XRD and DTA analysis indicated that the concentration of calcium hydroxide (CH) declined by substituting FA and BT, specifically in ternary blends, which was due to the dilution effect and consumption of CH through the pozzolanic reaction.

scholarly journals Effect of nano CaCO3 on durability of concrete

2020 ◽  
Vol 165 ◽  
pp. 03029
Author(s):  
Jiangong Yang
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Test Data ◽  
Building Materials ◽  
Strength Test ◽  
Practical Application ◽  
Compressive Strength Test ◽  
Different Content ◽  
Durability Of Concrete

Through comparatively analyzing the impermeability and compressive strength test data of nano CaCO3 concrete with different content, this paper puts forward the method of optimizing the durability of nano CaCO3 concrete, and studies the influence of the content of fly ash on the durability of nano CaCO3 concrete on this basis, so as to provide a reference for improving the durability of concrete, so as to improve the recycling and reusing efficiency of building materials, and accelerate the practical application of nano CaCO3 concrete in engineering.

The Impact of Fly Ash after SNCR Treated with Tannin-Based Products on AAC Production

2019 ◽  
Vol 296 ◽  
pp. 173-179 ◽  
Author(s):  
Matěj Lédl ◽  
Lucie Galvánková ◽  
Rostislav Drochytka
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Bulk Density ◽  
Catalytic Reduction ◽  
Xrd Analysis ◽  
Gaseous Ammonia ◽  
X Ray Diffraction ◽  
Consistency Test ◽  
Effect Of Treatment ◽  
The Impact

This paper is focused on the effect of treatment of fly ash after selective non-catalytic reduction (SNCR) with tannin on autoclaved aerated concrete (AAC) production in order to reduce or stop ammonia leakage from the fresh mixture due to its alkalinity. A pure form of tannin and a tannin-based product „Farmatan“ were used as a treatment in dosage ranging from 0,5 g – 3 g of agent per 1 kg of fly ash. Efficient dosage was determined at 2 wt.% of fly ash by the speed of an indicator change due to gaseous ammonia diluted in water. The rheological properties of fresh mixtures were observed by consistency test in Viskomat showing that Farmatan causes delay of hydration. The results of bulk density and compressive strength testing revealed that Farmatan causes an increase of bulk density and at higher amount decreases the compressive strength because of thermal crack formation due to combined effect of delayed hydration and thixotropy. Using x-ray diffraction (XRD) analysis there were no differences in phase composition observed.

Investigation on Thermal Stability of Geopolymer Based Zeolite in Fire Case Study

2020 ◽  
Vol 1009 ◽  
pp. 31-36
Author(s):  
Kanokwan Kanyalert ◽  
Prinya Chindaprasirt ◽  
Duangkanok Tanangteerapong
Keyword(s):  
Weight Loss ◽  
Compressive Strength ◽  
High Temperature ◽  
Fly Ash ◽  
Alkali Activation ◽  
Different Types ◽  
Temperature Exposure ◽  
In Fire ◽  
Thermal Stability Of

This work aims to reveal the effects of zeolite on properties of fly ash based geopolymer under high temperature at 300 °C, 600 °C and 900 °C. The specimens were prepared by alkali activation of fly ash, which was partially replaced by two different types of zeolite at 10%, 20% and 30% by weight. The specimens were analyzed for the maximum compressive strength, weight loss percentage, XRD and SEM. The results highlighted that the percentage of weight loss increased with the ratio of zeolite replacement. The compressive strength of geopolymer with synthetic zeolite and natural zeolite at 7, 28, 60 days were similar. The high-temperature exposure resulted in the reduction in compressive strength in all proportions. At the same temperature, compressive strength of all specimens were not significantly different.

scholarly journals Fly Ash-Based Geopolymer Building Materials for Green and Sustainable Development

Materials ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 5699
Author(s):  
Rosicky Methode Kalombe ◽  
Victor Tunde Ojumu ◽  
Chuks Paul Eze ◽  
Sammy Mwasaha Nyale ◽  
John Kevern ◽  
...  
Keyword(s):  
Sustainable Development ◽  
Compressive Strength ◽  
Fly Ash ◽  
Environmental Impact ◽  
Co2 Emissions ◽  
Building Materials ◽  
Curing Conditions ◽  
High Alkalinity ◽  
Series Of Experiments ◽  
Minimal Environmental Impact

This study reports on formulations and conditions for producing fly ash-based geopolymers with a view to showing that the compressive strength required for construction applications can be obtained without the addition of aggregates, sand, and/or cement. It was shown in a series of experiments constituting at least 73% fly ash that a compressive strength of up to 90 MPa can be obtained depending on the curing conditions. While high alkalinity resulted in stronger materials, the results showed about 40% savings in CO2 emissions without using sand and cement. Such materials are suited for construction applications with minimal environmental impact.

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