scholarly journals Comparative Analysis of the Functional Properties of Films Based on Carrageenans, Chitosan, and Their Polyelectrolyte Complexes

Marine Drugs ◽  
2021 ◽  
Vol 19 (12) ◽  
pp. 704
Author(s):  
Aleksandra V. Volod’ko ◽  
Viktoriya N. Davydova ◽  
Valentina A. Petrova ◽  
Dmitry P. Romanov ◽  
Evgeniya A. Pimenova ◽  
...  
Keyword(s):  
Functional Properties ◽  
Layer Structure ◽  
Chitosan Film ◽  
Single Layer ◽  
Structural Features ◽  
Amorphous Structure ◽  
Layer By Layer ◽  
Cross Sectional ◽  
Polyelectrolyte Complexes ◽  
Chitosan Films

The influence of the structural features of carrageenan on the functional properties of the films was studied. The carrageenans and chitosan films, as well as three-layer films containing a polyelectrolyte complex (PEC) of the two, were prepared. The X-ray diffractograms of carrageenan films reflected its amorphous structure, whereas chitosan and three-layer films were characterized by strong reflection in the regions of 20° and 15° angles, respectively. The SEM of the cross-sectional morphology showed dense packing of the chitosan film, as well as the layer-by-layer structure of different densities for the PEC. Among the tested samples, κ/β-carrageenan and chitosan films showed the highest tensile strength and maximum elongation. Films containing the drug substance echinochrome were obtained. Mucoadhesive properties were assessed as the ability of the films to swell on the mucous tissue and their erosion after contact with the mucosa. All studied films exhibited mucoadhesive properties. All studied films exhibited mucoadhesive properties which depended on the carrageenans structure. Multilayer films are stronger than single-layer carrageenan films due to PEC formation. The resulting puncture strength of the obtained films was comparable to that of commercial samples described in the literature.

Microstructural characterization of CoPtCr/Cr thin film disks by cross-section TEM and elongated probe micro-diffraction

1991 ◽  
Vol 49 ◽  
pp. 762-763
Author(s):  
M.A. Parker ◽  
K.E. Johnson ◽  
C. Hwang ◽  
A. Bermea
Keyword(s):  
Magnetic Recording ◽  
Electron Probe ◽  
Microstructural Characterization ◽  
Crystallographic Structure ◽  
Recording Media ◽  
Layer By Layer ◽  
Cross Sectional ◽  
New Techniques ◽  
Polished Side

We have reported the dependence of the magnetic and recording properties of CoPtCr recording media on the thickness of the Cr underlayer. It was inferred from XRD data that grain-to-grain epitaxy of the Cr with the CoPtCr was responsible for the interaction observed between these layers. However, no cross-sectional TEM (XTEM) work was performed to confirm this inference. In this paper, we report the application of new techniques for preparing XTEM specimens from actual magnetic recording disks, and for layer-by-layer micro-diffraction with an electron probe elongated parallel to the surface of the deposited structure which elucidate the effect of the crystallographic structure of the Cr on that of the CoPtCr.XTEM specimens were prepared from magnetic recording disks by modifying a technique used to prepare semiconductor specimens. After 3mm disks were prepared per the standard XTEM procedure, these disks were then lapped using a tripod polishing device. A grid with a single 1mmx2mm hole was then glued with M-bond 610 to the polished side of the disk.

Observations on the Structure of Ta2O5

1972 ◽  
Vol 30 ◽  
pp. 540-541
Author(s):  
P. S. Kotval ◽  
C. J. Dewit
Keyword(s):  
Electron Microscope ◽  
Structural Features ◽  
Amorphous Structure ◽  
Polished Surface ◽  
Distilled Water ◽  
Anodic Films ◽  
Amorphous Films ◽  
Beam Heating ◽  
Diffraction Patterns ◽  
Hexagonal Arrays

The structure of Ta2O5 has been described in the literature in several different crystallographic forms with varying unit cell lattice parameters. Earlier studies on films of Ta2O5 produced by anodization of tantalum have revealed structural features which are not consistent with the parameters of “bulk” Ta2O5 crystalsFilms of Ta2O5 were prepared by anodizing a well-polished surface of pure tantalum sheet. The anodic films were floated off in distilled water, collected on grids, dried and directly examined in the electron microscope. In all cases the films were found to exhibit diffraction patterns representative of an amorphous structure. Using beam heating in the electron microscope, recrystallization of the amorphous films can be accomplished as shown in Fig. 1. As suggested by earlier work, the recrystallized regions exhibit diffraction patterns which consist of hexagonal arrays of main spots together with subsidiary rows of super lattice spots which develop as recrystallization progresses (Figs. 2a and b).

Płyty kołowe Hencky’ego–Bolle’a spoczywające na podłożu sprężystym Własowa

2020 ◽  
Vol 29 (4) ◽  
pp. 444-453
Author(s):  
Mykola Nagirniak
Keyword(s):  
Differential Equation ◽  
Circular Plate ◽  
Significant Influence ◽  
Single Layer ◽  
Medium Thickness ◽  
Cross Sectional ◽  
Equation Solution ◽  
Integral Characteristics ◽  
Two Parameter ◽  
Plate Deflection

The work presents the equations of the theory of symmetrical plates, resting on one-way, single-layer, two-parameter Vlasov’s subsoil. Two cases of differential equation solution of the plate deflection of thin and medium thickness on the ground substrate were analyzed depending on the size of the integral characteristics UÖD and 6ÖD. The example of loading the circular plate with a Pk load evenly distributed over the edge was considered and shows dimensionless graphs of deflection, bending torques and transverse forces in the plate and in the ground subsoil. The effect of the Poisson’s coefficient of the plate on deflection values and cross-sectional forces was investigated. The Poisson’s number has been shown to have a significant influence on deflection values and bending torque, however shown negligible effect on transverse forces values.

Effects of Varying Geometrical Parameters on Boiling From Microfabricated Enhanced Structures

2003 ◽  
Vol 125 (1) ◽  
pp. 103-109 ◽  
Author(s):  
C. Ramaswamy ◽  
Y. Joshi ◽  
W. Nakayama ◽  
W. B. Johnson
Keyword(s):  
Heat Dissipation ◽  
Layer Structure ◽  
Single Layer ◽  
Nucleate Boiling ◽  
Heat Fluxes ◽  
Working Fluid ◽  
Geometrical Parameters ◽  
Small Range ◽  
Two Phase ◽  
Wall Superheat

The current study involves two-phase cooling from enhanced structures whose dimensions have been changed systematically using microfabrication techniques. The aim is to optimize the dimensions to maximize the heat transfer. The enhanced structure used in this study consists of a stacked network of interconnecting channels making it highly porous. The effect of varying the pore size, pitch and height on the boiling performance was studied, with fluorocarbon FC-72 as the working fluid. While most of the previous studies on the mechanism of enhanced nucleate boiling have focused on a small range of wall superheats (0–4 K), the present study covers a wider range (as high as 30 K). A larger pore and smaller pitch resulted in higher heat dissipation at all heat fluxes. The effect of stacking multiple layers showed a proportional increase in heat dissipation (with additional layers) in a certain range of wall superheat values only. In the wall superheat range 8–13 K, no appreciable difference was observed between a single layer structure and a three layer structure. A fin effect combined with change in the boiling phenomenon within the sub-surface layers is proposed to explain this effect.

scholarly journals RLC-GNN: An Improved Deep Architecture for Spatial-Based Graph Neural Network with Application to Fraud Detection

2021 ◽  
Vol 11 (12) ◽  
pp. 5656
Author(s):  
Yufan Zeng ◽  
Jiashan Tang
Keyword(s):  
Numerical Experiments ◽  
State Of The Art ◽  
Single Layer ◽  
Fraud Detection ◽  
Layer By Layer ◽  
Residual Structure ◽  
Detection Algorithms ◽  
Deep Architecture ◽  
Graph Neural Networks ◽  
Node Embeddings

Graph neural networks (GNNs) have been very successful at solving fraud detection tasks. The GNN-based detection algorithms learn node embeddings by aggregating neighboring information. Recently, CAmouflage-REsistant GNN (CARE-GNN) is proposed, and this algorithm achieves state-of-the-art results on fraud detection tasks by dealing with relation camouflages and feature camouflages. However, stacking multiple layers in a traditional way defined by hop leads to a rapid performance drop. As the single-layer CARE-GNN cannot extract more information to fix the potential mistakes, the performance heavily relies on the only one layer. In order to avoid the case of single-layer learning, in this paper, we consider a multi-layer architecture which can form a complementary relationship with residual structure. We propose an improved algorithm named Residual Layered CARE-GNN (RLC-GNN). The new algorithm learns layer by layer progressively and corrects mistakes continuously. We choose three metrics—recall, AUC, and F1-score—to evaluate proposed algorithm. Numerical experiments are conducted. We obtain up to 5.66%, 7.72%, and 9.09% improvements in recall, AUC, and F1-score, respectively, on Yelp dataset. Moreover, we also obtain up to 3.66%, 4.27%, and 3.25% improvements in the same three metrics on the Amazon dataset.

scholarly journals Evolution of biobased and nanotechnology packaging – a review

2020 ◽  
Vol 35 (4) ◽  
pp. 491-515
Author(s):  
Tom Lindström ◽  
Folke Österberg
Keyword(s):  
Biodegradable Polymers ◽  
Food Packaging ◽  
Environmental Issues ◽  
Barrier Properties ◽  
Environmental Problems ◽  
Layer By Layer ◽  
Polyelectrolyte Complexes ◽  
Life Issues ◽  
Technological Developments ◽  
End Of Life Issues

AbstractThis review deals with the evolution of bio-based packaging and the emergence of various nanotechnologies for primary food packaging. The end-of life issues of packaging is discussed and particularly the environmental problems associated with microplastics in the marine environment, which serve as a vector for the assimilation of persistent organic pollutants in the oceans and are transported into the food chain via marine and wild life. The use of biodegradable polymers has been a primary route to alleviate these environmental problems, but for various reasons the market has not developed at a sufficient pace that would cope with the mentioned environmental issues. Currently, the biodegradable plastics only constitute a small fraction of the fossil-based plastic market. Fossil-based plastics are, however, indispensable for food safety and minimization of food waste, and are not only cheap, but has generally more suitable mechanical and barrier properties compared to biodegradable polymers. More recently, various nanotechnologies such as the use of nanoclays, nanocellulose, layer-by-layer technologies and polyelectrolyte complexes have emerged as viable technologies to make oxygen and water vapor barriers suitable for food packaging. These technological developments are highlighted as well as issues like biodegradation, recycling, legislation issues and safety and toxicity of these nanotechnologies.

scholarly journals The Simulation Design of Microwave Absorption Performance for the Multi-Layered Carbon-Based Nanocomposites Using Intelligent Optimization Algorithm

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1951
Author(s):  
Danfeng Zhang ◽  
Congai Han ◽  
Haiyan Zhang ◽  
Bi Zeng ◽  
Yun Zheng ◽  
...  
Keyword(s):  
Layer Structure ◽  
Optimal Solution ◽  
Single Layer ◽  
Simulation Design ◽  
Wide Bandwidth ◽  
Abc Algorithm ◽  
Bee Colony ◽  
Absorbing Material ◽  
Important Means ◽  
Carbon Based

The optimal design objectives of the microwave absorbing (MA) materials are high absorption, wide bandwidth, light weight and thin thickness. However, it is difficult for single-layer MA materials to meet all of these requirements. Constructing multi-layer structure absorbing coating is an important means to improve performance of MA materials. The carbon-based nanocomposites are excellent MA materials. In this paper, genetic algorithm (GA) and artificial bee colony algorithm (ABC) are used to optimize the design of multi-layer materials. We selected ten kinds of materials to construct the multi-layer absorbing material and optimize the performance. Two algorithms were applied to optimize the two-layer MA material with a total thickness of 3 mm, and it was found that the optimal bandwidth was 8.12 GHz and reflectivity was −53.4 dB. When three layers of MA material with the same thickness are optimized, the ultra-wide bandwidth was 10.6 GHz and ultra-high reflectivity was −84.86 dB. The bandwidth and reflectivity of the optimized material are better than the single-layer material without optimization. Comparing the GA and the ABC algorithm, the ABC algorithm can obtain the optimal solution in the shortest time and highest efficiency. At present, no such results have been reported.

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