scholarly journals Challenges and Recent Advances in Enzyme-Mediated Wastewater Remediation—A Review

Nanomaterials ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 3124
Author(s):  
Khadega A. Al-Maqdi ◽  
Nada Elmerhi ◽  
Khawlah Athamneh ◽  
Muhammad Bilal ◽  
Ahmed Alzamly ◽  
...  

Different classes of artificial pollutants, collectively called emerging pollutants, are detected in various water bodies, including lakes, rivers, and seas. Multiple studies have shown the devastating effects these emerging pollutants can have on human and aquatic life. The main reason for these emerging pollutants in the aquatic environment is their incomplete removal in the existing wastewater treatment plants (WWTPs). Several additional treatments that could potentially supplement existing WWTPs to eliminate these pollutants include a range of physicochemical and biological methods. The use of enzymes, specifically, oxidoreductases, are increasingly being studied for their ability to degrade different classes of organic compounds. These enzymes have been immobilized on different supports to promote their adoption as a cost-effective and recyclable remediation approach. Unfortunately, some of these techniques have shown a negative effect on the enzyme, including denaturation and loss of catalytic activity. This review focuses on the major challenges facing researchers working on the immobilization of peroxidases and the recent progress that has been made in this area. It focuses on four major areas: (1) stability of enzymes upon immobilization, enzyme engineering, and evolution; (2) recyclability and reusability, including immobilization on membranes and solid supports; (3) cost associated with enzyme-based remediation; and (4) scaling-up and bioreactors.

Water ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 181
Author(s):  
Ionela Cătălina Vasilachi ◽  
Dana Mihaela Asiminicesei ◽  
Daniela Ionela Fertu ◽  
Maria Gavrilescu

Emerging pollutants (EPs) are chemicals known to cause major impacts on the terrestrial, aquatic life and human health as a result of their chronic and acute toxicity. Although lots of studies on EPs behavior in the aquatic environment are currently available in literature, an urgent requirement exists to complete toxicological studies and develop and implement efficient and ecological methods for their removal. This paper raises some relevant problems related to water environment pollution with EPs, the risks they can generate for aquatic life and humans and opportunities to reduce the effects of pollution by EPs removal. Categories of emerging chemicals of concern in the environment, their sources, fate and impacts, with some examples are discussed. Organic UV filters are shortly presented as a relative new EPs category, with a focus on the need to develop extensive experimental studies on their environmental occurrence, fate and removal. Furthermore, sources for the aquatic environment resulting from discharging EPs directly into rivers from wastewater treatment plants are examined. The incidence of environmental and human health risks related to EPs is also considered. The removal of EPs from the environment as a solution to risk mitigation is addressed, with emphasis on several non-conventional processes involving biological removal of EPs. The paper provides a critical look at the current challenges posed by the presence of emerging pollutants in the aquatic environment, with critical comments and recommendations for further research to reduce the impact of EPs on water and human health and improve the performance of developed methods for their removal.


1994 ◽  
Vol 30 (4) ◽  
pp. 35-46 ◽  
Author(s):  
Franz-Bernd Frechen

Odorous emissions from wastewater treatment plants can cause serious annoyance in the vicinity. According to recently issued federal regulations. when designing new WWTPs or expanding existing ones, expert opinion has to be taken into account. Also problems arise with existing plants that have to be solved. It is necessary to understand the basics of odour and odour-related annoyance as well as the use of appropriate measurement technique in order to describe the problem correctly. Then problems can be detected and solved properly by using appropriate measures. There are many measures to be taken against odour emissions, depending upon the type of plant, process design, way of operation and others. If, however, these measures are not able to guarantee a sufficient emission level, then collection of waste air and subsequent deodorization must be chosen to solve the problem. Different technologies for deodorization are known today, and available data concerning these techniques at Germany's wastewater treatment planlts are shown later. Among the possible technologies developed in recent years biological methods are gaining more and more attention. as they are efficient. cost-effective and environment-friendly.


Nanomaterials ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 215
Author(s):  
Nina Finčur ◽  
Paula Sfîrloagă ◽  
Predrag Putnik ◽  
Vesna Despotović ◽  
Marina Lazarević ◽  
...  

Pharmaceuticals and pesticides are emerging contaminants problematic in the aquatic environment because of their adverse effects on aquatic life and humans. In order to remove them from water, photocatalysis is one of the most modern technologies to be used. First, newly synthesized photocatalysts were successfully prepared using a sol–gel method and characterized by different techniques (XRD, FTIR, UV/Vis, BET and SEM/EDX). The photocatalytic properties of TiO2, ZnO and MgO nanoparticles were examined according to their removal from water for two antibiotics (ciprofloxacin and ceftriaxone) and two herbicides (tembotrione and fluroxypyr) exposed to UV/simulated sunlight (SS). TiO2 proved to be the most efficient nanopowder under UV and SS. Addition of (NH4)2S2O8 led to the faster removal of both antibiotics and herbicide fluroxypyr. The main intermediates were separated and identified for the herbicides and antibiotic ciprofloxacin. Finally, the toxicity of each emerging pollutant mixture and formed intermediates was assessed on wheat germination and biomass production.


2021 ◽  
Vol 11 (2) ◽  
pp. 756
Author(s):  
Hippokratis Apostolidis ◽  
Georgia Papantoniou ◽  
Thrasyvoulos Tsiatsos

The presented paper examines the deployment of a cost-effective biofeedback system that provides anxiety awareness during online examination activities. Human anxiety is classified by evaluating biosignals related to skin conductance, skin temperature, and heart rate. The first aim of this study is to check the presented system performance. Thus, we test the convergent validity of the system regarding self-report measures of anxiety. Moreover, the system is validated against a commercial tool of anxiety detection. Fifteen (15) postgraduate students took part in the relevant psychometric test. The convergent validity of the system is found to be satisfactory. The second aim of this study is to identify the participant’s personality dimensions according to Technology Readiness Index (TRI) which affects their academic performance and their real-time anxiety, as provided by the biofeedback device, during academic examinations. Thirty-five (35) postgraduate students, who were taking examinations in the form of synchronous online tests in the classroom for one of their lessons, took part in this stage of the research. The examined relationships are presented via a path model showing mainly that insecurity causes academic performance to decline, which in turn has a significant negative effect with increasing anxiety.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Tarun Jairaj Narwani ◽  
Narayanaswamy Srinivasan ◽  
Sohini Chakraborti

AbstractComputational methods accelerate the drug repurposing pipelines that are a quicker and cost-effective alternative to discovering new molecules. However, there is a paucity of web servers to conduct fast, focussed, and customized investigations for identifying new uses of old drugs. We present the NOD web server, which has the mentioned characteristics. NOD uses a sensitive sequence-guided approach to identify close and distant homologs of a protein of interest. NOD then exploits this evolutionary information to suggest potential compounds from the DrugBank database that can be repurposed against the input protein. NOD also allows expansion of the chemical space of the potential candidates through similarity searches. We have validated the performance of NOD against available experimental and/or clinical reports. In 65.6% of the investigated cases in a control study, NOD is able to identify drugs more effectively than the searches made in DrugBank. NOD is freely-available at http://pauling.mbu.iisc.ac.in/NOD/NOD/.


NeoReviews ◽  
2021 ◽  
Vol 22 (12) ◽  
pp. e819-e836
Author(s):  
Amy G. Feldman ◽  
Ronald J. Sokol

Cholestatic jaundice is a common presenting feature of hepatobiliary and/or metabolic dysfunction in the newborn and young infant. Timely detection of cholestasis, followed by rapid step-wise evaluation to determine the etiology, is crucial to identify those causes that are amenable to medical or surgical intervention and to optimize outcomes for all infants. In the past 2 decades, genetic etiologies have been elucidated for many cholestatic diseases, and next-generation sequencing, whole-exome sequencing, and whole-genome sequencing now allow for relatively rapid and cost-effective diagnosis of conditions not previously identifiable via standard blood tests and/or liver biopsy. Advances have also been made in our understanding of risk factors for parenteral nutrition–associated cholestasis/liver disease. New lipid emulsion formulations, coupled with preventive measures to decrease central line–associated bloodstream infections, have resulted in lower rates of cholestasis and liver disease in infants and children receiving long-term parental nutrition. Unfortunately, little progress has been made in determining the exact cause of biliary atresia. The median age at the time of the hepatoportoenterostomy procedure is still greater than 60 days; consequently, biliary atresia remains the primary indication for pediatric liver transplantation. Several emerging therapies may reduce the bile acid load to the liver and improve outcomes in some neonatal cholestatic disorders. The goal of this article is to review the etiologies, diagnostic algorithms, and current and future management strategies for infants with cholestasis.


1970 ◽  
Vol 4 ◽  
pp. 115-119 ◽  
Author(s):  
Rajan P Paudel

Invasive species adversely affects the ecology and habitat of the species existing in a particular region. They are one of the top threats to the biodiversity of life on Earth. Mikania micrantha is spreading like a wildfire in Nepal whose effect on Rhino habitat is being studied in Chitwan National Park. Various mechanical, chemical and biological methods of control for Mikania are available. It's likely to be more cost effective to prevent the spread of invasive species in the first place than to tackle the biodiversity crisis once they have become established.DOI: http://dx.doi.org/10.3126/init.v4i0.5544The Initiation Vol.4 2011 115-119


2018 ◽  
Vol 78 (6) ◽  
pp. 1304-1311 ◽  
Author(s):  
I. Mishima ◽  
M. Hama ◽  
Y. Tabata ◽  
J. Nakajima

Abstract Small-scale wastewater treatment plants (SWTPs), called Johkasou, are widely used as decentralized and individual wastewater treatment systems in sparsely populated areas in Japan. Even in SWTPs, nutrients should be removed to control eutrophication. An iron electrolysis method is effective to remove phosphorus chemically in SWTPs. However, it is necessary to determine the precise conditions under which phosphorus can be effectively and stably removed in full scale SWTPs for a long period. Therefore, long-term phosphorus removal from SWTPs was investigated and optimum operational conditions for phosphorus removal by iron electrolysis were analyzed in this study. Efficient phosphorus removal can be achieved for a long time by adjusting the amount of iron against the actual population equivalent. The change of the recirculation ratio had no negative effect on overall phosphorus removal. Phosphorus release to the bulk phase was prevented by the accumulated iron, which was supplied by iron electrolysis, resulting in stable phosphorus removal. The effect of environmental load reduction due to phosphorus removal by iron electrolysis was greater than the cost of power consumption for iron electrolysis.


Energies ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 6025
Author(s):  
Marcin Dębowski ◽  
Magda Dudek ◽  
Marcin Zieliński ◽  
Anna Nowicka ◽  
Joanna Kazimierowicz

Hydrogen is an environmentally friendly biofuel which, if widely used, could reduce atmospheric carbon dioxide emissions. The main barrier to the widespread use of hydrogen for power generation is the lack of technologically feasible and—more importantly—cost-effective methods of production and storage. So far, hydrogen has been produced using thermochemical methods (such as gasification, pyrolysis or water electrolysis) and biological methods (most of which involve anaerobic digestion and photofermentation), with conventional fuels, waste or dedicated crop biomass used as a feedstock. Microalgae possess very high photosynthetic efficiency, can rapidly build biomass, and possess other beneficial properties, which is why they are considered to be one of the strongest contenders among biohydrogen production technologies. This review gives an account of present knowledge on microalgal hydrogen production and compares it with the other available biofuel production technologies.


2021 ◽  
pp. 218-245
Author(s):  
R. Jasrotia

The decreasing levels of consumable water on earth have been a serious issue and this issue makes the researchers and scientists develop new technologies for the purification of polluted water. Several reports have been carried on wastewater remediation by utilizing spinel ferrite-based nanoparticles and their composites. The spinel ferrites-based nanoparticles utilized for wastewater treatment was cost effective, chemically stable, easily retrieved and reusable. The present work addresses the various fabrication techniques for the preparation of spinel ferrite-based nanoparticles and their utilization for the removal of organic and inorganic pollutants through the adsorption paths.


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