scholarly journals Ammonium Release and Adsorption Characters of Polyurethane–Biochar Crosslinked Material as an Additive Filler in Stormwater Treatment

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1557
Author(s):  
Yuan Wang ◽  
Yike Meng ◽  
Chuanyue Wang ◽  
Bao Wang
Keyword(s):  
High Water ◽  
Exchange Capacity ◽  
Deionized Water ◽  
Raw Material ◽  
Ammonium Concentration ◽  
Stormwater Treatment ◽  
Sand Column ◽  
Isothermal Adsorption ◽  
Leading Role ◽  
Ammonium Adsorption

The additive fillers in bioretention facilities play a leading role in stormwater treatment to purify polluted runoff. At present, many traditional materials could not meet the requirements at the same time, including low ammonium leaching quantities, high water storage volume and strong ammonium adsorption. This study investigated a polymer material, polyurethane–biochar crosslinked material (PCB), to evaluate the feasibility of using it as an additive filler in stormwater treatment compared with its raw material hardwood biochar (HB), and two traditional fillers. Successive leaching and ammonium isothermal adsorption experiments were conducted in deionized water and artificial stormwater. PCB leached 4.98–5.31 μmol/g NH4-N, less than the leaching quantities of compost, the traditional filler. After polyurethane modification, ammonium adsorption of PCB was improved: at a typical ammonium concentration of 2 mg/L in stormwater, PCB could adsorb 43.6 mg/kg ammonium versus 34.6 mg/kg for HB. With the addition of PCB in sand column, the ammonium adsorption improved from 31.34 to 84.72%. To improve the performance of bioretention facilities, PCB is recommended to be added into filter layers in stormwater treatment, taking advantage of its high cation exchange capacity and spongy internal structure to minimize overland flooding and enhance removal of ammonium from stormwater.

Flame Photometry Characterization Procedure for Sodium Content in Brazilian Bentonites for Nanotechnology Applications

2019 ◽  
Vol 12 (2) ◽  
pp. 122-129
Author(s):  
Hellen S. Santos ◽  
Karine L. Buarque da Silva ◽  
Ariel E. Zanini ◽  
Danilo S. Coelho ◽  
Marcelo Embiruçu ◽  
...  
Keyword(s):  
Control Process ◽  
Sodium Concentration ◽  
High Water ◽  
Sodium Content ◽  
Industrial Applications ◽  
Exchange Capacity ◽  
Sodium Cation ◽  
Flame Photometry ◽  
Logarithmic Scale ◽  
Average Value

Background: Brazilian bentonites have a low sodium concentration in their interlayer structure. This is a problem with most of the industrial applications that demand the characteristics of sodium bentonites. Objective: As a solution for this limitation, sodium carbonate is added to in natura clays, promoting ion exchange between other interlayer cations with sodium. Methods: A process was used based on the principle of Stokes’ Law (BR Patent 10 2013 016298). For this, we used four glass columns in series, in which a high water flow was considered to obtain purified clays. It was proposed as a simple, fast and economical method for sodium determination that was developed and applied in bentonites by flame photometry. The equipment calibration was performed with a NaCl standard solution in concentrations between 80 and 110 ppm. The bentonites in the suspension were separated by means of centrifugation, being thus analyzed by a flame photometer. Results: The samples were prepared according to the manufacturer’s specifications to contain detectable amounts of sodium by means of flame photometry. A resulting linear relationship between the average value readings versus sodium standard content solution (both in ppm) was obtained by the logarithmic scale, as expected. Conclusion: The procedure allowed to define a method that could be used in the sodification control process, thus making it possible to differentiate the sodium cation content in terms of the value of cation exchange capacity (CEC) from bentonite. X-ray analysis of in natura and the sodified clays showed nanostructural differences related to interlayer distance.

scholarly journals Phosphorus Release and Adsorption Properties of Polyurethane–Biochar Crosslinked Material as a Filter Additive in Bioretention Systems

Polymers ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 283
Author(s):  
Yike Meng ◽  
Yuan Wang ◽  
Chuanyue Wang
Keyword(s):  
Removal Rate ◽  
Phosphorus Release ◽  
Phosphate Adsorption ◽  
Stormwater Treatment ◽  
Isothermal Adsorption ◽  
Phosphorus Pollution ◽  
Adsorption Capacities ◽  
Saturated Water Content ◽  
Phosphate Treatment ◽  
Potential Use

Bioretention systems are frequently employed in stormwater treatment to reduce phosphorus pollution and prevent eutrophication. To enhance their efficiency, filter additives are required but the currently used traditional materials cannot meet the primary requirements of excellent hydraulic properties as well as outstanding release and adsorption capacities at the same time. In this research, a polyurethane-biochar crosslinked material was produced by mixing the hardwood biochar (HB) with polyurethane to improve the performance of traditional filter additives. Through basic parameter tests, the saturated water content of polyurethane-biochar crosslinked material (PCB) was doubled and the permeability coefficient of PCB increased by two orders of magnitude. Due to the polyurethane, the leaching speed of phosphorus slowed down in the batching experiments and fewer metal cations leached. Moreover, PCB could adsorb 93–206 mg/kg PO43− at a typical PO43− concentration in stormwater runoff, 1.32–1.58 times more than HB, during isothermal adsorption experiments. In the simulating column experiments, weaker hydropower reduced the PO43− leaching quantities of PCB and had a stable removal rate of 93.84% in phosphate treatment. This study demonstrates the potential use of PCB as a filter additive in a bioretention system to achieve hydraulic goals and improve phosphate adsorption capacities.

scholarly journals Ecological and physiological peculiarities of bryophytes on a post-technogenic salinized territory

2019 ◽  
Vol 27 (4) ◽  
pp. 342-348
Author(s):  
O. V. Lobachevska ◽  
N. Y. Kyyak ◽  
I. V. Rabyk
Keyword(s):  
Reproductive Strategy ◽  
Abiotic Factors ◽  
Experimental Studies ◽  
Liquid Waste ◽  
Total Content ◽  
Exchange Capacity ◽  
Salicornia Europaea ◽  
Leading Role ◽  
Bryum Argenteum ◽  
Storage Area

Taxonomic, biomorphological and ecological structures of bryophytes, their reproductive strategy and the main mechanisms of tolerance in the conditions of salinization were investigated. Bryophytes are the pioneers that have colonized the territory of a tailing storage that holds liquid waste from potassium-magnesium concentrate production of the Mining and Chemical Enterprise "Polymineral". Due to excess salts, the soil solution in the shore area of the tailing pond acquires high osmotic pressure. Three experimental plots which differed significantly in the level of the substrate salinity were laid at the distance of 3, 6 and 9 m from the reservoir for experimental studies. Water extracts of the substrates from the test sites showed the highest concentrations for sulfates – 10.4–64.6 mg Eq/100 g of soil and chlorides – 7.6–43.3 mg Eq/100 g of soil. It was established that the investigated areas of the tailing storage territory differed in the biochemical activity of the substrate, which was evaluated by its redox potential. On the areas of the uncovered substrate it was the lowest – 230 mV, which indicates anaerobiosis in conditions of very high salinization and moisture. Higher ROP values were determined at the sites of bryophyte cover distribution – 295–330 mV. The aim of the study was to determine the features of taxonomic, biomorphological and ecological structures of bryophytes, their reproductive strategy and to establish the main mechanisms of adaptation to the conditions of salinization on the tailing storage territory. 24 species and 3 varieties of bryophytes, belonging to 12 families and 16 genera were found on the shore of the tailing storage pond. The results of biomorphological and ecological analysis of bryophytes indicate the uneven conditions of the habitats and their considerable ecological plasticity. Among the bryophytes, mesophytes, xeromesophytes and meso-eutrophs, eutrophs with a life-form of low dense and loose turf dominated. In salinization conditions, dioicous acrocarpous mosses prevailed, the fertile turf of which, depending on the influence of abiotic factors, differed significantly in the number of sexual shoots, their ratio and productivity. Bulbils were found only on the tips of Bryum argenteum shoots. Along with Salicornia europaea L., a euhalophyte, the leading role in the initial stage of overgrowth of the tailing storage area most often belonged to Didymodon rigidulus, Bryum argenteum, Funaria hygrometrica and Barbula unguiculata. The process of formation of bryophyte cover occurred along a gradient of decrease in salt concentration at the experimental sites. Adaptation of bryophytes to substrate salinity is due to a change in metabolic processes, which is manifested in an increase of the total content of carbohydrates and an increase of the cation exchange capacity of moss cell walls, which is the primary barrier that reduces the toxic effect of ions under salt stress.

scholarly journals PREPARATION, CHARACTERIZATION OF BIOCHAR FOR A SUSTAINABLE SOIL HEALTH

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Rekha A. ◽  
Vidhya A.
Keyword(s):  
Soil Health ◽  
Physicochemical Characteristic ◽  
High Water ◽  
Exchange Capacity ◽  
Climatic Conditions ◽  
Water Retention Capacity ◽  
Retention Capacity ◽  
Bet Analysis ◽  
Thermochemical Processes

Recent research suggests that biochar is a promising approach to minimize soil contamination caused by heavy metals and organic pollutants. It is also involved in the amendment of soil by altering the nutrients, pH and other factors. Through intensive literature review, this paper was aimed to better understand the selection of feedstock processes, preparation, and characterization of biochar. Wide variety of feedstock used for the biochar production based on the cost effectiveness, ease availability and they are ecofriendly to the environment. Among the thermochemical processes, pyrolysis is the promising techniques followed for the production of BC. The stabilization efficacy was mainly determined by cation exchange capacity, pH, and ash content of the biochar. The physicochemical characteristic of the biochar is analyzed using various methods such as SEM, FTIR, TGA and BET analysis. The surface area plays a major role in the metal sorption. The quality characteristics of biochar as a soil amendment varied greatly with the feedstock materials and the pyrolysis conditions. Biochar plays a great role in increasing the pH which helps the acidic soil region and its high-water retention capacity enhance the moisture level in the soil which enhances the microbial communities and its activity. Biochar becomes stabilized in the soil by interacting with soil particles. The inherent characteristics of the biochar as dictated by feedstock and pyrolysis conditions, interact with climatic conditions such as precipitation and temperature to influence how long biochar carbon remains stored in the soil. Due to its carbon sequestration in the soil, it helps in increasing the fertility of the soil and also enhances the crop yield.

scholarly journals THE CHANGE OF SANDY SOIL PROPERTIES AFTER ADDING CHARCOAL PRODUCED FROM A TRADITIONAL KILN IN THE MEKONG DELTA, VIET NAM

2021 ◽  
Vol 1 (42) ◽  
pp. 109-115
Author(s):  
Binh Phan Khanh Huynh ◽  
Tho Van Nguyen ◽  
Vien My Tran
Keyword(s):  
Soil Properties ◽  
Bulk Density ◽  
Sandy Soil ◽  
Organic Matter Content ◽  
Mekong Delta ◽  
Exchange Capacity ◽  
Matter Content ◽  
Raw Material ◽  
Control Treatment ◽  
Viet Nam

This study aimed to use charcoal derived from the bamboo and melaleuca produced by traditional kiln applied to sandy soil growing mustard green (Brassica juncea L.). The charcoals were applied at three ratio (1%,2%, and 3%, which correspond to 10, 20, and 30 g charcoal/kg soil in pots) and the control treatment without charcoal. Soil properties were investigated including bulk density, pH, electrical conductivity (EC), cation exchange capacity (CEC), organic matter content, total nitrogen, and total phosphorous. The results showed that bulk density decreased in charcoal-treated soils. pH and EC were in the suitable range for plants.Nutrients and CEC of the soil in the charcoal treatment were significantly higher compared with the control (CEC increase 6.8% to 16%; TC increase 80% to 115%; TN increase 37.5 to 75%). Green mustard growing on charcoalamended soil had greater height (higher 3% to 21%), bigger leaves, and higher yield (increase18% to 81%) than those of plants groomed in the control treatment. This study showed the potential of using charcoal as supplying nutrient to the poor soil. Moreover, the abundant of raw material and easy to produce, it is suitable for applying in the Mekong Delta, Viet Nam, and other countries with similar conditions and infrastructure. 

scholarly journals Hydrothermal Transformation of Natural Zeolite from Ende-NTT and Its Application as Adsorbent of Cationic Dye

2018 ◽  
Vol 16 (2) ◽  
pp. 138 ◽  
Author(s):  
Yulius Dala Ngapa ◽  
Sri Sugiarti ◽  
Zaenal Abidin
Keyword(s):  
Adsorption Capacity ◽  
Hydrothermal Method ◽  
Natural Zeolite ◽  
Hydrothermal Process ◽  
Exchange Capacity ◽  
Synthetic Zeolite ◽  
Crystal Formation ◽  
Isothermal Adsorption ◽  
Hydrothermal Transformation ◽  
Equilibrium Process

A synthetic zeolite was produced from natural zeolite from Ende-Nusa Tenggara Timur (NTT) by hydrothermal method. This study aims to produce synthetic zeolite from Ende natural zeolite to remove cation dye through the adsorption process. Temperature of crystal formation (ageing) was performed at 60 °C for 6 h and hydrothermal process was at 100 °C for 24 h. The natural zeolite produced synthetic NaP1 and synthetic Faujasite. Based on the research results, the synthesis of zeolite by the hydrothermal method can enhance the adsorption capacity and Cation Exchange Capacity (CEC). The adsorption capacity in the natural zeolites of type ZG, ZL and ZC before the hydrothermal process were 17.289, 17.276, and 16.483 mg/g, respectively, and after hydrothermal they increased to 37.398, 37.369 and 37.362 mg/g, respectively. In addition, the CEC increased from 84.154, 81.042, and 77.474 cmol/kg, respectively, to 244.063, 216.354, and 211.432 cmol/kg, respectively. The Langmuir model most closely matched the isothermal adsorption equilibrium process.

scholarly journals Mineralogical and physico-chemical characterizations of clay from Keur Saër (Senegal)

Clay Minerals ◽  
2012 ◽  
Vol 47 (4) ◽  
pp. 499-511 ◽  
Author(s):  
A. Mbaye ◽  
C. A. K. Diop ◽  
B. Rhouta ◽  
J. M. Brendle ◽  
F. Senocq ◽  
...  
Keyword(s):  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Clay Fraction ◽  
Exchange Capacity ◽  
Raw Material ◽  
Basic Knowledge ◽  
Mineral Mixture ◽  
Fine Clay ◽  
Main Component ◽  
Adsorption Desorption

AbstractThere is interest in exploiting and developing natural resources, particularly deposits of natural clays. Senegal has several clay mineral deposits for which chemical and mineralogical compositions have been little studied. Some of these natural materials are nowadays used in pottery and ceramics. To extend applications, a better basic knowledge is required and, for this objective, the raw clay and separated <2 μm clay fraction from Keur Saër (Senegal) were subjected to chemical and mineralogical studies. Several techniques including X-ray diffraction (XRD), thermal analysis (TG-DTA), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), N2 adsorption-desorption isotherms, cation exchange capacity (CEC) measurements and solid state nuclear magnetic resonance (NMR) have been used to characterize the material. It was found that the raw clay and the separated clay fraction consist of a mineral mixture in which kaolinite is the main component. 29Si and 27Al MAS-NMR spectra show the presence of silicon atoms linked to three other silicon atoms via an oxygen atom and six coordinated Al atoms. Significant increases in the specific surface area and cation exchange capacity were observed on purification, reaching a maximum of about 73.2 m2g–1 and 9.5 meq/100 g for the separated fine clay fraction while the values for the raw material were around 28.9 m2g–1 and 7.3 meq/100 g.

scholarly journals Effect of Heavy Metal Ions on Steroid Estrogen Removal and Transport in SAT Using DLLME as a Detection Method of Steroid Estrogen

Water ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 589
Author(s):  
Ge Zhang ◽  
Yuesuo Yang ◽  
Ying Lu ◽  
Yu Chen ◽  
Wenbo Li ◽  
...  
Keyword(s):  
High Performance ◽  
Endocrine Disrupting Chemicals ◽  
Breakthrough Curves ◽  
Soil Aquifer Treatment ◽  
Mixed Solution ◽  
Fluorescence Detector ◽  
Sand Column ◽  
Isothermal Adsorption ◽  
Scheme Design ◽  
Steroid Estrogen

Environmental endocrine-disrupting chemicals have become a global environmental problem, and the distribution, transport, and fate of estrogens in soil and water environments closely relate to human and ecological health as well as to the remediation scheme design. A new micro-extraction technique termed dispersive liquid–liquid micro-extraction (DLLME) combined with high-performance liquid chromatography with fluorescence detector (HPLC-FLD) was developed for the determination of the concentration of steroid estrogens in water samples. The detection limits of HPLC-FLD and DLLME-HPLC/FLD were 0.68–1.73 μg L−1 and 7.16–69.22 ng L−1, respectively. Based on this method, the isothermal adsorption of 17β-E2 on sand and a breakthrough experiment of 17β-E2 and Cu2+ in a soil aquifer treatment (SAT) system were studied. The 17β-E2 adsorption capacity of sand in 17β-E2 solution was detected to be larger than that in a mixed solution of 17β-E2 and Cu(NO3)2 solution, and the breakthrough curves of 17β-E2 and Cu2+ in the mixed solution shifted forward in sand column experiments. Both suggested that the competitive adsorption of 17β-E2 and Cu2+ in the mixed solution might occur on the surface of the sand. In the process of the removal of 17β-E2 in wastewater by SAT, the existence of Cu2+ slightly inhibited the adsorption of 17β-E2 and accelerated the breakthrough of 17β-E2. These results ought to be a warning for SAT application for 17β-E2 removal in water where heavy metals coexist.

scholarly journals Physicochemical properties of bean pod (Phaseolus vulgaris) flour and its potential as a raw material for the food industry

2020 ◽  
Vol 73 (2) ◽  
pp. 9179-9187
Author(s):  
Marcela Martínez-Castaño ◽  
Diana Paola Mejía Díaz ◽  
José Contreras-Calderón ◽  
Cecilia Gallardo Cabrera
Keyword(s):  
Antioxidant Capacity ◽  
Dietary Fiber ◽  
Food Industry ◽  
Structural Characteristics ◽  
High Water ◽  
Raw Material ◽  
Vacuum Drying ◽  
Drying Methods ◽  
The Sustainable Development ◽  
Functional Studies

The sustainable development of agro-industry requires the efficient use of all raw matters, which implies physicochemical and functional studies of by-products for finding their potential usage in industrial processes. The objective of the present study was to assess some physicochemical and functional properties of fIour obtained from the bean pod. Two types of drying methods were tested: convection and vacuum. The fIours tended to yellow color according to b* parameter values (convection drying: 17.54; vacuum drying: 18.35), with a slight red hue. They also showed high water-holding (convection drying: 8.30 g g-1; vacuum drying: 7.56 g g-1) and oil holding capacity (convection drying: 2.53 g g-1; vacuum drying: 2.56 g g-1), polyphenols content (convection drying: 26.62 mg GAE g-1 DW; vacuum drying: 3.77 mg GAE g-1 DW) and antioxidant capacity (convection drying: 33.42 µmol Trolox g-1; vacuum drying: 5.27 µmol Trolox g-1). The results were similar for the two types of drying methods, except for the antioxidant capacity. Since convection drying is more economical and available than vacuum drying, only the fIour obtained by convection method was analyzed on compositional and structural characteristics. This fIour showed to be a good source of dietary fiber (66.93%), being the insoluble fiber the predominant fraction (59.97%). Moreover, a high content of ash (6.65%) and low lipid content (0.58%) were also found. The IR spectrum showed signs corroborating the presence of dietary fiber, which also was evidenced morphologically. Overall, the results obtained indicated that the bean pod fIour obtained by convection drying has potential use as a raw material for the food industry.

Sugarcane Biochar for Agricultural Use Produced in Different Conditions of Pyrolysis

2019 ◽  
pp. 1-8
Author(s):  
Juliany Barbosa de Pinho ◽  
Aloisio Bianchini ◽  
Pedro Silvério Xavier Pereira ◽  
Letycia Cunha Nunes ◽  
Rodrigo Fernandes Daros ◽  
...  
Keyword(s):  
Chemical Properties ◽  
Exchange Capacity ◽  
Raw Material ◽  
Physical And Chemical Properties ◽  
Oxidizing Atmosphere ◽  
Different Temperatures ◽  
Agricultural Use ◽  
Physical And Chemical ◽  
And Chemical Properties

From the pyrolysis process, biochar is a carbon rich and recalcitrant organic material with potential for long term carbon sequestration because of its aromatic structure. However, the physical and chemical properties of the biochar vary due to the diversity of raw material and the conditions of production. The present study aimed to evaluate the biochar from the sugarcane bagasse at different temperatures and under two conditions of pyrolysis. The biochar was produced at two final temperatures 200°C (1 hour); 250°C (1h) and 250°C (2h), with pyrolysis of an oxidizing and non-oxidizing atmosphere for both. PH, cation exchange capacity (CTC), carbon content (C), Nitrogen (N), hydrogen (H), H:C, C:N and ash ratios were evaluated. The contents of C, H, N and the atomic ratios H:C and C:N were higher in Biochar produced in a non-oxidizing atmosphere (BNO). However, the content of ash, pH and CTC were higher in Biochar produced in oxidizing atmospheres (BO). One can conclude the direct influence of the pyrolysis condition.

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