scholarly journals Development of Bioinspired Functional Chitosan/Cellulose Nanofiber 3D Hydrogel Constructs by 3D Printing for Application in the Engineering of Mechanically Demanding Tissues

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1663
Author(s):  
Arnaud Kamdem Tamo ◽  
Ingo Doench ◽  
Lukas Walter ◽  
Alexandra Montembault ◽  
Guillaume Sudre ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Composite Structures ◽  
Soft Tissues ◽  
Mechanical Performance ◽  
Cellulose Nanofibers ◽  
High Water Content ◽  
Natural Polymers ◽  
Mechanical Reinforcement ◽  
3D Printed

Soft tissues are commonly fiber-reinforced hydrogel composite structures, distinguishable from hard tissues by their low mineral and high water content. In this work, we proposed the development of 3D printed hydrogel constructs of the biopolymers chitosan (CHI) and cellulose nanofibers (CNFs), both without any chemical modification, which processing did not incorporate any chemical crosslinking. The unique mechanical properties of native cellulose nanofibers offer new strategies for the design of environmentally friendly high mechanical performance composites. In the here proposed 3D printed bioinspired CNF-filled CHI hydrogel biomaterials, the chitosan serves as a biocompatible matrix promoting cell growth with balanced hydrophilic properties, while the CNFs provide mechanical reinforcement to the CHI-based hydrogel. By means of extrusion-based printing (EBB), the design and development of 3D functional hydrogel scaffolds was achieved by using low concentrations of chitosan (2.0–3.0% (w/v)) and cellulose nanofibers (0.2–0.4% (w/v)). CHI/CNF printed hydrogels with good mechanical performance (Young’s modulus 3.0 MPa, stress at break 1.5 MPa, and strain at break 75%), anisotropic microstructure and suitable biological response, were achieved. The CHI/CNF composition and processing parameters were optimized in terms of 3D printability, resolution, and quality of the constructs (microstructure and mechanical properties), resulting in good cell viability. This work allows expanding the library of the so far used biopolymer compositions for 3D printing of mechanically performant hydrogel constructs, purely based in the natural polymers chitosan and cellulose, offering new perspectives in the engineering of mechanically demanding hydrogel tissues like intervertebral disc (IVD), cartilage, meniscus, among others.

scholarly journals The Mechanical Properties of Fiber Metal Laminates Based on 3D Printed Composites

Materials ◽  
2020 ◽  
Vol 13 (22) ◽  
pp. 5264
Author(s):  
Bharat Yelamanchi ◽  
Eric MacDonald ◽  
Nancy G. Gonzalez-Canche ◽  
Jose G. Carrillo ◽  
Pedro Cortes
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
High Velocity ◽  
Mechanical Performance ◽  
High Velocity Impact ◽  
Low Velocity ◽  
Fiber Metal Laminates ◽  
Velocity Impact ◽  
3D Printed ◽  
Fiber Metal

The production and mechanical properties of fiber metal laminates (FMLs) based on 3D printed composites have been investigated in this study. FMLs are structures constituting an alternating arrangement of metal and composite materials that are used in the aerospace sector due to their unique mechanical performance. 3D printing technology in FMLs could allow the production of structures with customized configuration and performance. A series of continuous carbon fiber reinforced composites were printed on a Markforged system and placed between layers of aluminum alloy to manufacture a novel breed of FMLs in this study. These laminates were subjected to tensile, low velocity and high velocity impact tests. The results show that the tensile strength of the FMLs falls between the strength of their constituent materials, while the low and high velocity impact performance of the FMLs is superior to those observed for the plain aluminum and the composite material. This mechanism is related to the energy absorption process displayed by the plastic deformation, and interfacial delamination within the laminates. The present work expects to provide an initial research platform for considering 3D printing in the manufacturing process of hybrid laminates.

Magnetic Field-Assisted 3D Printing of Limpet Teeth Inspired Polymer Matrix Composite With Compression Reinforcement

2021 ◽  
Vol 144 (4) ◽  
Author(s):  
Dylan Joralmon ◽  
Evangeline Amonoo ◽  
Yizhen Zhu ◽  
Xiangjia Li
Keyword(s):  
Magnetic Field ◽  
3D Printing ◽  
Polymer Matrix ◽  
Mechanical Performance ◽  
Polymer Matrix Composites ◽  
Cost Effective ◽  
Industrial Applications ◽  
Mechanical Reinforcement ◽  
3D Printed ◽  
Geometric Morphology

Abstract Lightweight and cost-effective polymer matrix composites (PMCs) with extraordinary mechanical performance will be a key to the next generation of diverse industrial applications, such as aerospace, electric automobile, and biomedical devices. Limpet teeth made of mineral-polymer composites have been proved as nature’s strongest material due to the unique hierarchical architectures of mineral fiber alignment. Here, we present an approach to build limpet teeth inspired structural materials with precise control of geometric morphologies of microstructures by magnetic field-assisted 3D printing (MF-3DP). α-Iron (III) oxide-hydroxide nanoparticles (α-FeOOHs) are aligned by the magnetic field during 3D printing and aligned α-FeOOHs (aFeOOHs) bundles are further grown to aligned goethite-based bundles (aGBs) by rapid thermal treatment after printing. The mechanical reinforcement of aGBs in PMCs can be modulated by adjusting the geometric morphology and alignment of α-FeOOHs encapsulated inside the 3D printed PMCs. In order to identify the mechanical enhancement mechanism, physics-based modeling, simulation, and tests were conducted, and the results further guided the design of bioinspired goethite-based PMCs. The correlation of the geometric morphology of self-assembled α-FeOOHs, curing characteristics of α-FeOOHs/polymer composite, and process parameters were identified to establish the optimal design of goethite-based PMCs. The 3D printed PMCs with aGBs show promising mechanical reinforcement compared with PMCs without aGBs. This study opens intriguing perspectives for designing high strength 3D printed PMCs on the basis of bioinspired architectures with customized configurations.

Magnetic Field Assisted 3D Printing of Limpet Teeth Inspired Polymer Matrix Composite With Compression Reinforcement

2021 ◽  
Author(s):  
Dylan Joralmon ◽  
Evangeline Amonoo ◽  
Yizhen Zhu ◽  
Xiangjia Li
Keyword(s):  
Magnetic Field ◽  
3D Printing ◽  
Polymer Matrix ◽  
Mechanical Performance ◽  
Polymer Matrix Composites ◽  
Cost Effective ◽  
Industrial Applications ◽  
Mechanical Reinforcement ◽  
3D Printed ◽  
Geometric Morphology

Abstract Lightweight and cost-effective polymer matrix composites (PMCs) with extraordinary mechanical performance will be a key to the next generation of diverse industrial applications such as aerospace, electric automobile, and biomedical devices. Limpet teeth made of mineral-polymer composites have been proved as nature’s strongest material due to the unique hierarchical architectures of mineral fiber alignment. Here, we present an approach to build limpet teeth inspired structural materials with precise control of geometric morphologies of microstructures by magnetic field-assisted 3D printing (MF-3DP). α-Iron (III) oxide-hydroxide nanoparticles (α-FeOOHs) are aligned by the magnetic field during 3D printing and aligned α-FeOOHs bundles are further grown to aligned goethite-based bundles (aGBs) by rapid thermal treatment after printing. The mechanical reinforcement of goethite-based fillers in PMCs can be modulated by adjusting the geometric morphology and alignment of mineral particles encapsulated inside the 3D printed PMCs. In order to identify the mechanical enhancement mechanism, physics-based modeling, simulation, and tests were conducted and the results further guided the design of bioinspired goethite-based PMCs. The correlation of the geometric morphology of self-assembled α-FeOOHs, curing characteristics of α-FeOOHs/polymer composite, and process parameters were identified to establish the optimal design of goethite-based PMCs. The 3D-printed PMCs with aGBs show promising mechanical reinforcement. This study opens intriguing perspectives for designing high strength 3D printed PMCs on the basis of bioinspired architectures with customized configurations.

Mechanical Performance Analysis of ULTEM 9085 in a Heated, Irradiated Environment

2018 ◽  
Author(s):  
Matthew B. Ng ◽  
Sean N. Brennan
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Mechanical Performance ◽  
Cost Effective ◽  
Radiation Environment ◽  
Inspection System ◽  
Control Group ◽  
Inspection Systems ◽  
3D Printed ◽  
Cost Efficient

This paper investigates the thermal and radiation performance of 3D-printed ULTEM materials following ASTM standard D638. ULTEM is a thermoplastic in the polyetherimide (PEI) family that is regularly used as a high-grade material for 3D printing. This material has similar properties to polyether ether ketone (PEEK), which is another thermoplastic that has strong mechanical properties at elevated temperature conditions. While PEEK has stronger mechanical properties, ULTEM is significantly more cost efficient to acquire and process via 3D printing. Also, most 3D printers are unable to utilize PEEK because of the significantly higher temperature requirements this material imposes on a 3D printer. This work is motivated by the need to rapidly deploy robotic inspection systems within a nuclear canister environment, which exposes the material to temperatures up to 170°C (340°F), and radiation levels of 270 Gy/hr (27 krad/hr), which are significantly beyond that of conventional 3D-printed parts. The design analysis was performed via an experiment consisting of three treatment groups of dogbone ULTEM test pieces. After tensile testing all of the pieces, the material properties were compared to those of the control group. These results allow manufacturers to select a more cost-effective material to build parts to operate in such a harsh high-temperature, high-radiation environment, which could include applications in both space systems and nuclear inspection robotics. Specifically, the results were used to guide the development of a robust robotic inspection system for the Nuclear Energy University Program (NEUP) by replacing complex parts with easily-fabricated 3D-printed ULTEM pieces.

scholarly journals Effect of Length of Cellulose Nanofibers on Mechanical Reinforcement of Polyvinyl Alcohol

Polymers ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 128
Author(s):  
Mengxia Wang ◽  
Xiaran Miao ◽  
Hui Li ◽  
Chunhai Chen
Keyword(s):  
Mechanical Properties ◽  
Polyvinyl Alcohol ◽  
High Performance ◽  
Mechanical Performance ◽  
Cellulose Nanofibers ◽  
Composite Films ◽  
Nanocomposite Films ◽  
Mechanical Reinforcement ◽  
Research Attention ◽  
Casting Technique

Cellulose nanofibers (CNF), representing the nano-structured cellulose, have attained an extensive research attention due to their sustainability, biodegradability, nanoscale dimensions, large surface area, unique optical and mechanical performance, etc. Different lengths of CNF can lead to different extents of entanglements or network-like structures through van der Waals forces. In this study, a series of polyvinyl alcohol (PVA) composite films, reinforced with CNF of different lengths, were fabricated via conventional solvent casting technique. CNF were extracted from jute fibers by tuning the dosage of sodium hypochlorite during the TEMPO-mediated oxidation. The mechanical properties and thermal behavior were observed to be significantly improved, while the optical transparency decreased slightly (Tr. > 75%). Interestingly, the PVA/CNF20 nanocomposite films exhibited higher tensile strength of 34.22 MPa at 2 wt% filler loading than the PVA/CNF10 (32.55 MPa) while displayed higher elastic modulus of 482.75 MPa than the PVA/CNF20 films (405.80 MPa). Overall, the findings reported in this study provide a novel, simple and inexpensive approach for preparing the high-performance polymer nanocomposites with tunable mechanical properties, reinforced with an abundant and renewable material.

scholarly journals Functional Bionanocomposite Fibers of Chitosan Filled with Cellulose Nanofibers Obtained by Gel Spinning

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1563
Author(s):  
Sofia Marquez-Bravo ◽  
Ingo Doench ◽  
Pamela Molina ◽  
Flor Estefany Bentley ◽  
Arnaud Kamdem Tamo ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Mechanical Performance ◽  
Cellulose Nanofibers ◽  
Microstructural Characterization ◽  
Fiber Formation ◽  
Fiber Direction ◽  
Composite Fibers ◽  
X Ray Diffraction ◽  
Gel Spinning ◽  
X Ray

Extremely high mechanical performance spun bionanocomposite fibers of chitosan (CHI), and cellulose nanofibers (CNFs) were successfully achieved by gel spinning of CHI aqueous viscous formulations filled with CNFs. The microstructural characterization of the fibers by X-ray diffraction revealed the crystallization of the CHI polymer chains into anhydrous chitosan allomorph. The spinning process combining acidic–basic–neutralization–stretching–drying steps allowed obtaining CHI/CNF composite fibers of high crystallinity, with enhanced effect at incorporating the CNFs. Chitosan crystallization seems to be promoted by the presence of cellulose nanofibers, serving as nucleation sites for the growing of CHI crystals. Moreover, the preferential orientation of both CNFs and CHI crystals along the spun fiber direction was revealed in the two-dimensional X-ray diffraction patterns. By increasing the CNF amount up to the optimum concentration of 0.4 wt % in the viscous CHI/CNF collodion, Young’s modulus of the spun fibers significantly increased up to 8 GPa. Similarly, the stress at break and the yield stress drastically increased from 115 to 163 MPa, and from 67 to 119 MPa, respectively, by adding only 0.4 wt % of CNFs into a collodion solution containing 4 wt % of chitosan. The toughness of the CHI-based fibers thereby increased from 5 to 9 MJ.m−3. For higher CNFs contents like 0.5 wt %, the high mechanical performance of the CHI/CNF composite fibers was still observed, but with a slight worsening of the mechanical parameters, which may be related to a minor disruption of the CHI matrix hydrogel network constituting the collodion and gel fiber, as precursor state for the dry fiber formation. Finally, the rheological behavior observed for the different CHI/CNF viscous collodions and the obtained structural, thermal and mechanical properties results revealed an optimum matrix/filler compatibility and interface when adding 0.4 wt % of nanofibrillated cellulose (CNF) into 4 wt % CHI formulations, yielding functional bionanocomposite fibers of outstanding mechanical properties.

scholarly journals Three-Dimensional Printing of Hydroxyapatite Composites for Biomedical Application

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 353
Author(s):  
Yanting Han ◽  
Qianqian Wei ◽  
Pengbo Chang ◽  
Kehui Hu ◽  
Oseweuba Valentine Okoro ◽  
...  
Keyword(s):  
Tissue Engineering ◽  
3D Printing ◽  
Biomedical Application ◽  
Three Dimensional ◽  
Antibacterial Properties ◽  
Natural Polymers ◽  
Three Dimensional Printing ◽  
3D Printed ◽  
Dental Applications ◽  
Hard Tissue Engineering

Hydroxyapatite (HA) and HA-based nanocomposites have been recognized as ideal biomaterials in hard tissue engineering because of their compositional similarity to bioapatite. However, the traditional HA-based nanocomposites fabrication techniques still limit the utilization of HA in bone, cartilage, dental, applications, and other fields. In recent years, three-dimensional (3D) printing has been shown to provide a fast, precise, controllable, and scalable fabrication approach for the synthesis of HA-based scaffolds. This review therefore explores available 3D printing technologies for the preparation of porous HA-based nanocomposites. In the present review, different 3D printed HA-based scaffolds composited with natural polymers and/or synthetic polymers are discussed. Furthermore, the desired properties of HA-based composites via 3D printing such as porosity, mechanical properties, biodegradability, and antibacterial properties are extensively explored. Lastly, the applications and the next generation of HA-based nanocomposites for tissue engineering are discussed.

Mechanical Properties of 3D-Printed Wood-Plastic Composites

2018 ◽  
Vol 777 ◽  
pp. 499-507 ◽  
Author(s):  
Ossi Martikka ◽  
Timo Kärki ◽  
Qing Ling Wu
Keyword(s):  
Mechanical Properties ◽  
Composite Materials ◽  
3D Printing ◽  
Impact Strength ◽  
Polylactic Acid ◽  
Wood Plastic Composite ◽  
Wood Plastic Composites ◽  
Plastic Composite ◽  
Plastic Composites ◽  
3D Printed

3D printing has rapidly become popular in both industry and private use. Especially fused deposition modeling has increased its popularity due to its relatively low cost. The purpose of this study is to increase knowledge in the mechanical properties of parts made of wood-plastic composite materials by using 3D printing. The tensile properties and impact strength of two 3D-printed commercial wood-plastic composite materials are studied and compared to those made of pure polylactic acid. Relative to weight –mechanical properties and the effect of the amount of fill on the properties are also determined. The results indicate that parts made of wood-plastic composites have notably lower tensile strength and impact strength that those made of pure polylactic acid. The mechanical properties can be considered sufficient for low-stress applications, such as visualization of prototypes and models or decorative items.

scholarly journals Effect of temperature on the mechanical properties of 3D-printed PLA tensile specimens

2018 ◽  
Vol 24 (8) ◽  
pp. 1337-1346 ◽  
Author(s):  
Marzio Grasso ◽  
Lyes Azzouz ◽  
Paula Ruiz-Hincapie ◽  
Mauro Zarrelli ◽  
Guogang Ren
Keyword(s):  
Mechanical Properties ◽  
3D Printing ◽  
Mechanical Test ◽  
Optical Microscope ◽  
Middle Part ◽  
Gauge Length ◽  
Effect Of Temperature ◽  
Content Type ◽  
Relevant Effect ◽  
3D Printed

Purpose Recent advancements of 3D printing technology have brought forward the interest for this technique in many engineering fields. This study aims to focus on mechanical properties of the polylactic acid (PLA) feeding material under different thermal conditions for a typical fusion deposition of 3D printer system. Design/methodology/approach Specimens were tested under static loading within the range 20ºC to 60ºC considering different infill orientations. The combined effect of temperature and filament orientation is investigated in terms of constitutive material parameters and final failure mechanisms. The difference between feeding system before and post-3D printing was also assessed by mechanical test on feeding filament to verify the thermal profile during the deposition phase. Findings The results in terms of Young’s modulus, ultimate tensile strength (UTS), strain at failure (εf) and stress at failure (σf) are presented and discussed to study the influence of process settings over the final deposited material. Fracture surfaces have been investigated using an optical microscope to link the phenomenological interpretation of the failure with the micro-mechanical behaviour. Experimental results show a strong correlation between stiffness and strength with the infill orientation and the temperature values. Moreover, a relevant effect is related to deformed geometry of the filament approaching glass transition region of the polymer according to the deposition orientation. Research limitations/implications The developed method can be applied to optimise the stiffness and strength of any 3D-printed composite according to the infill orientation. Practical implications To avoid the failure of specimens outside the gauge length, a previously proposed modification to the geometry was adopted. The geometry has a parabolic profile with a curvature of 1,000 mm tangent to the middle part of the specimen. Originality/value Several authors have reported the stiffness and strength of 3D-printed parts under static and ambient temperature for different build parameters. However, there is a lack of literature on the combination of the latter with the temperature effects on the mechanical properties which this paper covers.

A physical investigation of dimensional and mechanical characteristics of 3D printed nut and bolt for industrial applications

2022 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Ramesh Chand ◽  
Vishal S. Sharma ◽  
Rajeev Trehan ◽  
Munish Kumar Gupta
Keyword(s):  
Mechanical Properties ◽  
Shear Strength ◽  
3D Printing ◽  
Surface Properties ◽  
3D Printer ◽  
Content Type ◽  
Safety Issues ◽  
Machine Failure ◽  
Sharp Edges ◽  
3D Printed

Purpose A nut bolt joint is a primary device that connects mechanical components. The vibrations cause bolted joints to self-loosen. Created by motors and engines, leading to machine failure, and there may be severe safety issues. All the safety issues and self-loosen are directly and indirectly the functions of the accuracy and precision of the fabricated nut and bolt. Recent advancements in three-dimensional (3D) printing technologies now allow for the production of intricate components. These may be used technologies such as 3D printed bolts to create fasteners. This paper aims to investigate dimensional precision, surface properties, mechanical properties and scanning electron microscope (SEM) of the component fabricated using a multi-jet 3D printer. Design/methodology/approach Multi-jet-based 3D printed nut-bolt is evaluated in this paper. More specifically, liquid polymer-based nut-bolt is fabricated in sections 1, 2 and 3 of the base plate. Five nuts and bolts are fabricated in these three sections. Findings Dimensional inquiry (bolt dimension, general dimensions’ density and surface roughness) and mechanical testing (shear strength of nut and bolt) were carried out throughout the study. According to the ISO 2768 requirements for the General Tolerances Grade, the nut and bolt’s dimensional examination (variation in bolt dimension, general dimensions) is within the tolerance grades. As a result, the multi-jet 3D printing (MJP)-based 3D printer described above may be used for commercial production. In terms of mechanical qualities, when the component placement moves from Sections 1 to 3, the density of the manufactured part decreases by 0.292% (percent) and the shear strength of the nut and bolt decreases by 30%. According to the SEM examination, the density of the River markings, sharp edges, holes and sharp edges increased from Sections 1 to 3, which supports the findings mentioned above. Originality/value Hence, this work enlightens the aspects causing time lag during the 3D printing in MJP. It causes variation in the dimensional deviation, surface properties and mechanical properties of the fabricated part, which needs to be explored.

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