scholarly journals Effect of Ni(NO3)2 Pretreatment on the Pyrolysis of Organsolv Lignin Derived from Corncob Residue

Processes ◽  
2020 ◽  
Vol 9 (1) ◽  
pp. 23
Author(s):  
Wenli Wang ◽  
Yichen Liu ◽  
Yue Wang ◽  
Longfei Liu ◽  
Changwei Hu

The thermal degradation of lignin for value-added fuels and chemicals is important for environment improvement and sustainable development. The impact of pretreatment and catalysis of Ni(NO3)2 on the pyrolysis behavior of organsolv lignin were studied in the present work. Samples were pyrolyzed at 500 ∘C with an upward fixed bed, and the characteristics of bio-oil were determined. After pretreatment by Ni(NO3)2, the yield of monophenols increased from 23.3 wt.% to 30.2 wt.% in “Ni-washed” and decreased slightly from 23.3 wt.% to 20.3 wt.% in “Ni-unwashed”. Meanwhile, the selective formation of vinyl-monophenols was promoted in “Ni-unwashed”, which indicated that the existence of nickel species promoted the dehydration of C-OH and breakage of C-C in pyrolysis. In comparison with “Water”, HHV of bio-oil derived from “Ni-unwashed” slightly increased from 27.94 mJ/kg to 28.46 mJ/kg, suggesting that the lowering of oxygen content in bio-oil is associated with improved quality. Furthermore, the content of H2 in gas products dramatically increased from 2.0% to 7.6% and 17.1%, respectively.

2021 ◽  
Vol 92 ◽  
pp. 06030
Author(s):  
Tomáš Ric ◽  
Daniela Šálková

Research background: The paper deals with the connections between international tourism and shopping, and therefore the purchase of clothing in relation to consumers. In the last few years, shopping has become one of the factors determining tourist’s decisions about choosing a travel destination. One-third of tourists have ever travelled just to buy clothes abroad. Such behaviour offers enormous economic potential for companies and the state economy. Shopping tourism is an integral part of globalization. Purpose of the article: The article’s aim is to characterize the elements of consumer behaviour in the framework of shopping tourism when buying clothing products. In addition to consumer preferences, the aim is to characterize the main types of clothing products that travellers are interested in and the impact of this consumer behaviour on the globalization. Methods: A questionnaire is compiled on the basis of stated hypotheses. The results will be evaluated using appropriate statistical methods such as the Kruskal-Wallis test, Spearman’s correlation coefficient and categorical principal components analysis. Findings & Value added: Research has shown that the first group of preferred garments consists of local products at a higher price level produced in low quantity. The second type of product is low-cost garments produced at a high cost under conditions that do not correspond to the principles of sustainable development. The clothing industry impact on global sustainable development is largely negative. In this regard, we can talk about the negative impact of globalization. This is no different from tourism.


Equilibrium ◽  
2019 ◽  
Vol 14 (2) ◽  
pp. 317-339 ◽  
Author(s):  
Inna Semenenko ◽  
Ruslan Halhash ◽  
Kseniia Sieriebriak

Research background: Sustainable development is the agenda for many countries including Ukraine, which adopted it at the national level and promoted through its regions. As the country is constantly struggling with the results of the military conflict and the impact of the occupation of its part by separatists, which led to economic decrease and emergence of numerous social and environmental issues, the transition of Ukraine to sustainable development path becomes especially important. At the same time, there is no official methodology adopted by the Ukrainian government, how to assess sustainable development of its regions. Availability of objective assessments would contribute to development of the relevant policy recommendations. Purpose of the article: The purpose of the article is to assess sustainable development of the regions in Ukraine and to show the dynamics of performance of the regions before and after the beginning of the military conflict in the East of Ukraine. Methods: We suggest the methodology of calculation of the integral index of sustainable development of the regions in Ukraine. This methodology takes into account the three pillars of sustainable development concept (economic, social and environmental) and uses the data available for all Ukrainian regions from the official statistics source. In order to determine the position of individual regions in the development of the Ukrainian economy and to identify certain groups of regions according to their level of sustainable development, we apply the method of statistical grouping. Findings & Value added: The conducted analyses showed the dynamics of indicators of sustainable development of the Ukrainian regions, the performance of the regions and their affiliation to the corresponding attributive groups. The situation and interrelation of the regions in Ukraine totally changed after the beginning of the military conflict in the East of Ukraine. The Luhansk and Donetsk regions, which are directly affected by the military conflict, became the outsiders among other regions in Ukraine, though before the conflict the values of sustainable development indicators had been above the average values in Ukraine. The leaders among the regions also changed, and the difference between the leaders and the following groups became significant. The results of the analyses allowed to visualize the dynamics of sustainable development of the regions in Ukraine and define the key directions for future development.


Energies ◽  
2020 ◽  
Vol 13 (8) ◽  
pp. 1970 ◽  
Author(s):  
Jayanto Kumar Sarkar ◽  
Qingyue Wang

In the present study, a series of laboratory experiments were conducted to examine the impact of pyrolysis temperature on the outcome yields of waste coconut shells in a fixed bed reactor under varying conditions of pyrolysis temperature, from 400 to 800 °C. The temperature was increased at a stable heating rate of about 10 °C/min, while keeping the sweeping gas (Ar) flow rate constant at about 100 mL/min. The bio-oil was described by Fourier transform infrared spectroscopy (FTIR) investigations and demonstrated to be an exceptionally oxygenated complex mixture. The resulting bio-chars were characterized by elemental analysis and scanning electron microscopy (SEM). The output of bio-char was diminished pointedly, from 33.6% to 28.6%, when the pyrolysis temperature ranged from 400 to 600 °C, respectively. In addition, the bio-chars were carbonized with the expansion of the pyrolysis temperature. Moreover, the remaining bio-char carbons were improved under a stable structure. Experimental results showed that the highest bio-oil yield was acquired at 600 °C, at about 48.7%. The production of gas increased from 15.4 to 18.3 wt.% as the temperature increased from 400 to 800 °C. Additionally, it was observed that temperature played a vital role on the product yield, as well as having a vital effect on the characteristics of waste coconut shell slow-pyrolysis.


2014 ◽  
Vol 554 ◽  
pp. 266-270 ◽  
Author(s):  
Farid Nasir Ani ◽  
Arshad Adam Salema ◽  
Ismail Hasan

Pyrolysis is one of the effective ways to convert biomass into energy and value added products. Till date, no comparative study has been done on the characteristic of bio-oils of oil palm shell (OPS) and empty fruit bunch (EFB) from various fast pyrolysis techniques. This includes fluidized bed, fixed bed, rotating cone, microwave and others. Thus, the main objective of this paper was to analyze the characteristics of OPS and EFB bio-oils obtained from these processing techniques. Temperature was found to be the key parameter for the quality of bio-oils. Besides the various pyrolysis techniques, the lignocellulosic constituents of oil palm biomass also influence the chemical composition of the bio-oils. Overall, chemical analysis of OPS and EFB bio-oil through GC-MS has shown variation in the amount of phenol and its derivatives.


Materials ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1609 ◽  
Author(s):  
Yong Cui ◽  
Wenliang Wang ◽  
Jianmin Chang

This study investigated and compared the product characteristics of pyrolysis lignin under different catalytic effects resulting from various calcium salts. The pyrolysis of lignin was conducted in a fixed-bed reactor with calcium salt additives, which included CaCl2, Ca(OH)2, and Ca(HCOO)2. The compositions of gas and bio-oil were detected using gas chromatography/mass spectrometry (GC/MS). The characterizations of chars were examined using Brunauer–Emmett–Teller (BET) surface area and scanning electron microscopy (SEM). The results indicate that all three types of calcium salts helped to promote bio-oil yield and inhibit gas and char from forming. Regarding the composition of gas products, calcium salt additives increased the concentrations of H2 and CH4 while decreasing the concentration of CO. In addition, calcium salt additives facilitated the formation of phenol and alkyl-phenols in bio-oil, but reduced the yields of guaiacol and vanillin, in the order CaCl2 < Ca(OH)2 < Ca(HCOO)2. Furthermore, when compared with the addition of CaCl2, the chars prepared by the addition of Ca(OH)2 and Ca(HCOO)2 had relatively higher BET surface areas. In conclusion, Ca(HCOO)2 had the greatest positive influence in regard to the product quality of lignin pyrolysis whilst also elevating the yield of value-added chemicals in bio-oils.


Author(s):  
Денис Вікторович Прозоров ◽  
Олена Сергіївна Юрченко

Intensification of globalization processes and dynamic conditions of enterprises, increased demands of investors, stakeholders and other stakeholders necessitate the formation of analytical information about the effectiveness of economic, social and environmental activities and creating value for the future. The purpose of the article is disclosure of methodical basis of the comprehensive analysis of sustainable development of the enterprises based on integrated reporting The subject of the research is a set of theoretical, methodological and practical aspects of analytical support of integrated reporting of enterprises. Methods used in the research: general scientific and special methods of the research: dialectical method of knowing the essence of analytical support of integrated ability; integrated approach, methods of concretization, abstraction - the basis of disclosure of models analysis of indicators of integrated reporting; induction and deduction (knowledge of the features of the analysis of the effectiveness of social and environmental activities); analogies - for the formation of analytical tools. The main hypothesis of research is suggestion that a comprehensive analysis of sustainable development of enterprises should be aimed at generating information to assess the effectiveness of activities in the triune dimension (economic, social and environmental) in order to meet the informational needs of various stakeholders. The statement of basic materials. The basis for the development of conceptual and methodological basis of a comprehensive analysis of sustainable development of enterprises is the concept of capital, value and sustainable development, expansion of the subject area and system of indicators that characterize effectiveness and allow to assess sustainable development. In order to improve the information and organizational structure of analysis of integrated reporting, new approaches to the analysis of analytical procedures are proposed on the basis of an orderly system of indicators that determine the effectiveness of economic, social and environmental activities. The suitability of the proposed system of indicators is demonstrated on the basis of assessments of the analysis of the current state of efficiency of social activities of agricultural enterprises. Practical significance of the research is the possibility of application of provided scientific and methodological recommendations for improving the methodological approach to a comprehensive analysis of sustainable development of enterprises, which provides a system of indicators by three blocks of analysis the effectiveness of economic, social and environmental activities. Conclusions of research. The proposed approach to a comprehensive analysis of sustainable development of enterprises, in contrast to existing ones, differs in an orderly system of indicators in terms of analyzing the effectiveness of social activities and assessing the impact of key social factors on value added which will provide complete, reliable information about sustainable development of enterprises


2021 ◽  
Vol 129 ◽  
pp. 07006
Author(s):  
Viera Sukalova

Research background: Human resources today are well the most important and valuable resource of a company, and therefore it is very important that the company constantly deals with the field of working conditions. Working conditions represent a convex set of conditions, factors and other elements affecting the worker who performs the assigned work tasks for the employer and significantly affect his productivity, well-being, health and loyalty to the employer. Currently, the field of working conditions has been hit hard by the Covid 19 pandemic. The company's goal in the field of working conditions should be to create the best possible working conditions that will provide employees with a suitable and quality working environment, damage to health at work and benefits to increase their comfort. Purpose of the article: The aim of our article is to analyse the legal aspects of labour protection and working conditions in EU and Slovakia and to document on the Case study current problems of work management and also the impact of Covid 19 on employees’ working conditions. Methods: Analysis, Synthesis, Case study, Questionnaire We analyzed the current legislation of the EU and Slovakia in the field of occupational safety and working conditions, and on the example of a case study and the use of a questionnaire survey, we identified problems in this area. Findings & Value added: Identification of current problem areas in the management of working conditions and design of a system solution for sustainable development.


2021 ◽  
Vol 7 (2) ◽  
pp. 37-49
Author(s):  
Olena Vasyl’yeva

The aim of the article is to assess the impact of various factors (forms of capital) on the formation of gross value added and gross output of the agricultural sector of Ukraine’s economy under sustainable development using the modified Cobb-Douglas production function. Methods. The theoretical and methodological basis of the study consisted of the papers on economic growth, sustainable development and forecasting by scientists in classical and modern economics. A monographic method was used to cover the scientists’ views on the research issue. The parameters of the production function describing how variables (physical and human capital, pollutant emissions) act on gross value added and gross output of the agricultural sector of Ukraine were estimated on the basis of the modified Cobb-Douglas production function. Statistics for agriculture covering the period 2008-2018 were used for the assessment. The correlation and regression analysis was used to determine and verify the parameters of the production function. Equations of balance and construction of isoquants were used to foresight the optimal combinations of factors of the production function. Results. Using the Cobb-Douglas production function, econometric analysis with eco-socio-economic factors has shown that economic growth in agriculture is associated with improved quantitative and qualitative characteristics of labour potential, growing capital investment and reducing pollutant emissions. Estimation of the elasticity coefficients of the constructed Cobb-Douglas function (the sum exceeds 1) justifies that the economic development of agriculture mainly contains the features of a large-scale economy: modern level of science and technology provides advantageous expanding production to increase output. Practical significance. The constructed models allow to forecast assessment of the development of the agricultural sector’s components and can be used to develop the basic directions of the state agricultural policy to manage the formation and use of resource potential. Value/originality. Modelling how the resource factors act on output using the method of construction and calculation of parameters of the production function allows to predict the sustainable development of agricultural production under quantitative and qualitative changes in the use of labour and capital, as well as environmental factors. Further research ensures obtaining a dynamic multi-factor model of sustainable development of the agricultural sector and determining the main mechanisms of influence on the levers of economic growth.


Buildings ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 73
Author(s):  
Ioannis Vardopoulos ◽  
Christos Stamopoulos ◽  
Georgios Chatzithanasis ◽  
Christos Michalakelis ◽  
Panagiota Giannouli ◽  
...  

This article, as part of the ‘SUMcity’ research program, aims to give a comprehensive account of the regeneration that occurred in Athens by the adaptive reuse of the old FIX Brewery to house the new Hellenic National Museum of Contemporary Art (EMST). Adaptive reuse is an urban sustainability development evolving process, used to manage assets and resources efficiently, resulting in economic development, increased local attraction, and revitalized community engagement. Other than that, modern societies experience the dynamic stream of social media and smart city initiatives, amid a long-discussed and complex cultural heritage preservation backdrop. Notwithstanding the value added to the city, the interaction of sustainable development with adaptive reuse projects, culture, tourism, social media use, and smart city initiatives, along with the impact of this intangible relationship, has yet to be set in a more tangible form. Methodologically, a newly developed conceptual framework is used in order to re-define the (cor)relations among the existent concepts of sustainable development, smart city and cultural heritage. Subsequently, a primary questionnaire-based research is conducted on Instagram users’ geotagging the Hellenic National Museum of Contemporary Art (EMST), analyzing their views in an attempt to demonstrate the arising local potential and sustainability.


2021 ◽  
Vol 1 (93) ◽  
pp. 20-45
Author(s):  
Оksana Garkushenko ◽  

Such a timely phenomenon in the modern world as digitalization can become a tool for achieving sustainable development goals. But it is new, and its benefits and threats are not well understood. This problem can be partially solved by creating economic and mathematical models for assessing the impact of digitalization on sustainable development. Nonetheless, most of the existing models in this field are devoted to defining the impact of digitalization on the economic aspects of countries' activities, and environmental ones are either ignored or presented approximately, with significant abstraction. Despite this, the objective of the paper is to develop and implement an economic and mathematical model, which in a generalized form can be used for different countries of the world, subject to its certain adaptation and detailing of national indicators. This approach allows to take into account the difference in the social and economic situation of countries and levels of their digitalization, which makes it possible to draw more valid conclusions based on the results of estimations. The proposed model is built on the basis of the system dynamics method, which takes into account the path-dependence, and is implemented on the example of Ukraine. With its help, two computational experiments were carried out: an inertial one (a forecast for 5 years, provided that all the current patterns of digitalization of the country's economy are preserved) and a scenario, in which patterns of investing in digital capital in Ukraine change (to the patterns of European countries – Spain and Hungary), while maintaining the rest conditions unchanged. Using this model, it was defined that digital equipment and technologies as part of the environmental capital of the Ukrainian industry, as well as non-digital equipment and technologies, have an extremely small impact on reducing energy consumption and do not contribute to a significant reduction in the air pollution. Provided that the current situation persists (the inertial scenario), emissions of pollutants into the air in 2024 may even grow by 0.8% compared to 2019. During the experiment on investment patterns’ replacement in Ukraine with the patterns of Hungary and Spain, it was found that despite the change in the nature and (in the case of Hungary) the direction of investments in digital equipment and technologies, which significantly affected their amount (both in manufacturing and environmental capital), while the rest conditions for the functioning of industry remain unchanged, the indicators of value added, energy consumption, employees’ sickness rate and air pollution level stay practically the same as before such a replacement. Therefore, the "blind" copying of the digitalization practices of other countries, while maintaining unchanged other conditions, without taking into account the peculiarities of the national institutional environment, the degree of development of science and technology, is inappropriate, since it does not lead to an improvement in the situation in Ukraine. The general conclusion is that digitalization by itself is not able to reverse the current unfavorable trends in development of Ukraine for the better. It is necessary to achieve fundamental changes in the growth of the real sector of the economy on an innovative basis, in the amount and structure of investments, in the propensity of economic entities to invest, which is now at a low level, and also to form an integral industrial-digital ecosystem, similar to European ones, but taking into account the heterogeneity of European economies and their experience, as well as the characteristics of the current state and dynamics of development of the technical, technological and institutional environment of Ukraine.


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