scholarly journals Estimating Pollutant Residence Time and NO3 Concentrations in the Yucatan Karst Aquifer; Considerations for an Integrated Karst Aquifer Vulnerability Methodology

Water ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 1431 ◽  
Author(s):  
Carolina Martínez-Salvador ◽  
Miguel Moreno-Gómez ◽  
Rudolf Liedl
Keyword(s):  
Drinking Water ◽  
Residence Time ◽  
Transport Model ◽  
Karst Aquifer ◽  
Groundwater Vulnerability ◽  
Sole Source ◽  
Aquifer Vulnerability ◽  
Untreated Wastewater ◽  
The North ◽  
Set Up

Karst aquifers are a major source of drinking water with intrinsic features that increase the pollution risk from anthropogenic and natural impacts. In Yucatan, Mexico, groundwater is the sole source of drinking water, also acting as receptor of untreated wastewater due to the low regional coverage of sewer systems. To protect karst groundwater, vulnerability methodologies are widely used. Worldwide, multiple karst vulnerability schemes have been developed and tested; however, none of these consider pollutant residence time or pollutant concentration as core parameters to estimate vulnerability. This work aims to define important considerations regarding the behavior of nitrates (NO3) in a real scenario, to be included in a new integrated vulnerability method. This work has two main objectives: to set up a groundwater model to depict as close as possible the groundwater behavior of the Yucatan karst system, and to introduce a transport model to estimate the behavior of a pollution plume. Model outcomes suggest that pollutants have a short residence time, reaching the coast in the north after 3 years. Well fields are also affected by pollution at variable NO3 concentrations. Results can be further discretized to establish a base and to include these parameters as part of a new integrated groundwater vulnerability approach.

scholarly journals First Application of the Integrated Karst Aquifer Vulnerability (IKAV) method. Potential and Actual vulnerability in Yucatan, Mexico

2021 ◽  
Author(s):  
Miguel Moreno-Gómez ◽  
Carolina Martínez-Salvador ◽  
Rudolf Lied ◽  
Catalin Stefan ◽  
Julia Pacheco
Keyword(s):  
Transport Model ◽  
Karst Aquifer ◽  
Theoretical Models ◽  
Groundwater Vulnerability ◽  
Aquifer Vulnerability ◽  
Environmental Damage ◽  
Integrated Method ◽  
Support Tools ◽  
Vulnerability Maps ◽  
Water Resources Protection

Abstract. Groundwater vulnerability maps are important decision support tools for water resources protection against pollution and helpful to minimize environmental damage. However, these tools carry a high subjectivity along the multiple steps taken for the development of such maps. Additionally, the theoretical models on which they are based do not consider important parameters such as pollutant concentration or pollutant residence time in a given section of the aquifer, solely focusing the analysis on a theoretical travel time from a release point towards a target. In this work, an integrated methodology for the evaluation of potential (intrinsic) and actual vulnerability is presented. This integrated method, named IKAV, was developed after the analysis of several study cases and the application of multiple intrinsic groundwater vulnerability methods in a selected study area. Also, a solute transport model served as the basis to define additional parameters for vulnerability analysis for areas severely affected by anthropogenic practices. A defined workflow and several criteria for parameters and attributes selection, rating and weighting assignment, and vulnerability classification are presented. The first application of the IKAV method was carried out in the Yucatan karst, demonstrating to be a reliable method for vulnerability estimation. Results demonstrated the scope of the IKAV method to highlight important regional conditions, minimizing the subjectivity, and expanding the analysis of vulnerability.

The Italian way to prevent groundwater contamination risk

2007 ◽  
Vol 2 (3) ◽  
Author(s):  
M. V. Civita ◽  
M. De Maio ◽  
A. Fiorucci
Keyword(s):  
Groundwater Contamination ◽  
Groundwater Vulnerability ◽  
Aquifer Vulnerability ◽  
National Council ◽  
National Guidelines ◽  
National Agency ◽  
Point Count ◽  
Italian Law ◽  
Special Project ◽  
Set Up

In the early 1980's the Italian scientific community, together with a number of institutional decision-makers, realized how urgent it was to protect natural and environmental resources. They agreed that an adequate level of scientifically organized knowledge allows the accurate planning and development of environmental systems through management and direction of the actual development process, without hindering it. Since the special project was first set up in 1984, as part of the GNDCI-CNR (National Group for the Defence against Hydrogeologic Disasters, of the Italian National Council of Research) scientific context, it has been the cardinal point of Research Line 4 “Assessment of Aquifer Vulnerability”. The problem of groundwater contamination was examined in this project for the very first time in Italy in an organic and extensive manner as a key for forecasting and prevention purposes. The Italian approaches to assessing and mapping groundwater vulnerability to contamination are essentially based on two main methodologies:- The GNDCI Basic Method a HCS (Hazard Contamination Source) type approach that can be used for any type of Italian hydrogeologic situation, even where there is a limited amount of data. A unified legend and symbols are also defined for each hydrogeologic level.- The SINTACS [Soggiacenza (depth to groundwater); Infiltrazione (effective infiltration); Non saturo (unsaturated zone attenuation capacity); Tipologia della copertura (soil/overburden attenuation capacity); Acquifero (saturated zone characteristics); Conducibilità (hydraulic conductivity); Superficie topografica (Slope)] method, a PCSM (Point Count System Model) developed for use prevalently in areas with good data base coverage. The methodological approaches described in this paper now make up the Italian standard which has been set in the recent very important Italian Law (152/99) and which has now been ratified in the national guidelines produced by ANPA, the Italian National Agency for Environment Protection. In this paper the structure of the Research Line, the progress obtained by the 21 Research units (over 100 researchers) in 20 years of activity, the results gained etc. are briefly highlighted.

Application of a GIS-based DRASTIC model and groundwater quality index method for evaluation of groundwater vulnerability: a case study, Sefid-Dasht

2015 ◽  
Vol 15 (4) ◽  
pp. 784-792 ◽  
Author(s):  
Nastaran Khodabakhshi ◽  
Gholamreza Asadollahfardi ◽  
Nima Heidarzadeh
Keyword(s):  
Groundwater Quality ◽  
Quality Index ◽  
Major Ions ◽  
Groundwater Vulnerability ◽  
Vulnerability Index ◽  
Aquifer Vulnerability ◽  
Index Method ◽  
Drastic Model ◽  
Groundwater Quality Index ◽  
The North

Pollution control and removal of pollutants from groundwater are a challenging and expensive task. The aims of this paper are to determine the aquifer vulnerability of Sefid-Dasht, in Chaharmahal and Bakhtiari province, Iran, using the DRASTIC model. In addition, the groundwater quality index (GQI) technique was applied to assess the groundwater quality and study the spatial variability of major ion concentrations using a geographic information system (GIS). The vulnerability index ranged from 65 to 132, classified into two classes: low and moderate vulnerability. In the southern part of the aquifer, the vulnerability was moderate. Furthermore, the results indicate that the magnitude of the GQI index varies from 92% to 95%. This means the water has a suitable quality. However, from the north to the south and southwest of the aquifer, the water quality has been deteriorating, and the highest concentration of major ions was found in the southwest of the Sefid-Dasht aquifer. A comparison of the vulnerability maps with the GQI index map indicated a poor relation between them. In the DRASTIC method, movement of groundwater is not considered and may be the reason for such inconsistency. However, the movement of groundwater can transport contaminants.

scholarly journals GIS-based DRASTIC and composite DRASTIC indices for assessing groundwater vulnerability in the Baghin aquifer, Kerman, Iran

2020 ◽  
Vol 20 (8) ◽  
pp. 2351-2363
Author(s):  
Mohammad Malakootian ◽  
Majid Nozari
Keyword(s):  
Hydraulic Conductivity ◽  
Vadose Zone ◽  
Groundwater Vulnerability ◽  
Aquifer Vulnerability ◽  
Factors Affecting ◽  
North West ◽  
The North ◽  
Soil Media ◽  
Sensibility Analysis ◽  
The Impact

Abstract. The present study estimates the Kerman–Baghin aquifer vulnerability using DRASTIC and composite DRASTIC (CDRASTIC) indices with the aid of geographic information system (GIS) techniques. Factors affecting the transfer of contamination, including water table depth, soil media, aquifer media, the impact of the vadose zone, topography, hydraulic conductivity, and land use, were used to calculate the DRASTIC and CDRASTIC indices. A sensitivity test was also performed to determine the sensitivity of the parameters. Results showed that the topographic layer displays a gentle slope in the aquifer. Most of the aquifer was covered with irrigated field crops and grassland with a moderate vegetation cover. In addition, the aquifer vulnerability maps indicated very similar results, identifying the north-west parts of the aquifer as areas with high to very high vulnerability. The map removal sensibility analysis (MRSA) revealed the impact of the vadose zone (in the DRASTIC index) and hydraulic conductivity (in the CDRASTIC index) as the most important parameters in vulnerability evaluation. In both indices, the single-parameter sensibility analysis (SPSA) demonstrated net recharge as the most effective factor in vulnerability estimation. According to the results, parts of the studied aquifer have a high vulnerability and require protective measures.

scholarly journals First Steps into an Integrated Karst Aquifer Vulnerability Approach (IKAV). Intrinsic Groundwater Vulnerability Analysis of the Yucatan Karst, Mexico

Water ◽  
2019 ◽  
Vol 11 (8) ◽  
pp. 1610 ◽  
Author(s):  
Moreno-Gómez ◽  
Martínez-Salvador ◽  
Moulahoum ◽  
Liedl ◽  
Stefan ◽  
...  
Keyword(s):  
Karst Aquifer ◽  
Groundwater Vulnerability ◽  
Integrated Approach ◽  
Vulnerability Analysis ◽  
Aquifer Vulnerability ◽  
Regional Characteristics ◽  
Protection Strategies ◽  
Vulnerability Maps ◽  
Overlap Analysis ◽  
Very High

Karst groundwater vulnerability maps are important tools for the development of groundwater management and protection strategies. However, current methodologies do not always match regional characteristics and parameter adaptations are necessary. In addition, other important processes such as dilution and aquifer residence time are not included in vulnerability analysis for the complications of evaluating two or more criteria simultaneously. The integrated karst aquifer vulnerability approach (IKAV) project aims to develop an integrated approach to include these parameters and estimate global change implications in current and future scenarios. As a first step, intrinsic vulnerability methodologies are studied in order to highlight important parameters and the congruence with regional characteristics of the Yucatan karst. Results demonstrate agreement between methods for the evaluation of high and very high vulnerabilities and their relation with fissures and dolines. Moderate vulnerabilities are assigned to more than 50% of the area. However, moderate vulnerabilities, assigned to the coastal area and the Southern hill, are highly questionable. Intrinsic features affecting moderate classes vary according to the method. Parameter sensitivity analysis and overlap analysis demonstrate the influence of depth to the unsaturated zone, soils, precipitation, and slope on moderate values. Therefore, such parameters must be re-evaluated and discretized according to the characteristics of the study area to match Yucatan regional characteristics.

The Rotterdam Initiative in Reducing Waste Discharges at Source

1991 ◽  
Vol 24 (10) ◽  
pp. 171-177
Author(s):  
T. Vellinga ◽  
J. P. J. Nijssen
Keyword(s):  
Public Relations ◽  
Action Plan ◽  
Detailed Balance ◽  
River Rhine ◽  
The North ◽  
Complementary Role ◽  
Action Programme ◽  
The North Sea ◽  
Set Up

Much of the material dredged from the port of Rotterdam is contaminated to such a degree that it must be placed in specially constructed sites. The aim of Rotterdam is to ensure that the dredged material will once again be clean. This will entail the thorough cleansing of the sources of the contamination of the sediment in the harbours and in the River Rhine. The Rotterdam Rhine Research Project (RRP) is one of the means to achieve this based on: technical research, legal research, public relations and dialogues with dischargers. The programme for five selected heavy metals is almost complete. For many heavy metal discharge points between Rotterdam and Rheinfelden, a specially devised independent load assessment has been carried out four times. Balance studies were used to determine the relative contributions of the point discharges to the total. Currently the results are being used in an attempt to negotiate agreements with a selected number of the major dischargers. At present, more detailed balance studies are being set up and exploratory measurements carried out for organic micropollutants. It may be concluded that the research is progressing successfully and methods and techniques developed seem satisfactory and broadly applicable. The Rhine Action Programme encompasses an international effort to improve the quality of the Rhine water. Although the RRP plays a modest complementary role to the Rhine Action Plan, there is no doubt of the value of this Rotterdam initiative. The mode of work followed in the RRP contains elements that can be of use in combatting the contamination of the North Sea by rivers other than the Rhine.

scholarly journals Influence of the North Atlantic oscillation on the atmospheric levels of benzo[a]pyrene over Europe

2021 ◽  
Author(s):  
Pedro Jiménez-Guerrero ◽  
Nuno Ratola
Keyword(s):  
Spatial Pattern ◽  
North Atlantic Oscillation ◽  
North Atlantic ◽  
Transport Model ◽  
Regional Scale ◽  
The South ◽  
Climatic Fluctuations ◽  
The North ◽  
The North Atlantic ◽  
The North Atlantic Oscillation

AbstractThe atmospheric concentration of persistent organic pollutants (and of polycyclic aromatic hydrocarbons, PAHs, in particular) is closely related to climate change and climatic fluctuations, which are likely to influence contaminant’s transport pathways and transfer processes. Predicting how climate variability alters PAHs concentrations in the atmosphere still poses an exceptional challenge. In this sense, the main objective of this contribution is to assess the relationship between the North Atlantic Oscillation (NAO) index and the mean concentration of benzo[a]pyrene (BaP, the most studied PAH congener) in a domain covering Europe, with an emphasis on the effect of regional-scale processes. A numerical simulation for a present climate period of 30 years was performed using a regional chemistry transport model with a 25 km spatial resolution (horizontal), higher than those commonly applied. The results show an important seasonal behaviour, with a remarkable spatial pattern of difference between the north and the south of the domain. In winter, higher BaP ground levels are found during the NAO+ phase for the Mediterranean basin, while the spatial pattern of this feature (higher BaP levels during NAO+ phases) moves northwards in summer. These results show deviations up to and sometimes over 100% in the BaP mean concentrations, but statistically significant signals (p<0.1) of lower changes (20–40% variations in the signal) are found for the north of the domain in winter and for the south in summer.

scholarly journals Comparison of Hydrocarbon-Degrading Consortia from Surface and Deep Waters of the Eastern Mediterranean Sea: Characterization and Degradation Potential

Energies ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 2246
Author(s):  
Georgia Charalampous ◽  
Efsevia Fragkou ◽  
Konstantinos A. Kormas ◽  
Alexandre B. De Menezes ◽  
Paraskevi N. Polymenakou ◽  
...  
Keyword(s):  
Mediterranean Sea ◽  
Oil Spills ◽  
Eastern Mediterranean ◽  
Sole Source ◽  
Eastern Mediterranean Sea ◽  
Deep Waters ◽  
Degradation Rates ◽  
Polycyclic Aromatic ◽  
Set Up

The diversity and degradation capacity of hydrocarbon-degrading consortia from surface and deep waters of the Eastern Mediterranean Sea were studied in time-series experiments. Microcosms were set up in ONR7a medium at in situ temperatures of 25 °C and 14 °C for the Surface and Deep consortia, respectively, and crude oil as the sole source of carbon. The Deep consortium was additionally investigated at 25 °C to allow the direct comparison of the degradation rates to the Surface consortium. In total, ~50% of the alkanes and ~15% of the polycyclic aromatic hydrocarbons were degraded in all treatments by Day 24. Approximately ~95% of the total biodegradation by the Deep consortium took place within 6 days regardless of temperature, whereas comparable levels of degradation were reached on Day 12 by the Surface consortium. Both consortia were dominated by well-known hydrocarbon-degrading taxa. Temperature played a significant role in shaping the Deep consortia communities with Pseudomonas and Pseudoalteromonas dominating at 25 °C and Alcanivorax at 14 °C. Overall, the Deep consortium showed a higher efficiency for hydrocarbon degradation within the first week following contamination, which is critical in the case of oil spills, and thus merits further investigation for its exploitation in bioremediation technologies tailored to the Eastern Mediterranean Sea.

Excavations at Fishbourne, 1963. Third Interim Report

1964 ◽  
Vol 44 (1) ◽  
pp. 1-8
Keyword(s):  
Interim Report ◽  
The West ◽  
Civic Society ◽  
North West ◽  
The Third ◽  
North East ◽  
The North ◽  
The Future ◽  
Set Up

Early in 1963 much of the land occupied by the Roman building at Fishbourne was purchased by Mr. I. D. Margary, M.A., F.S.A., and was given to the Sussex Archaeological Trust. The Fishbourne Committee of the trust was set up to administer the future of the site. The third season's excavation, carried out at the desire of this committee, was again organized by the Chichester Civic Society.1 About fifty volunteers a day were employed from 24th July to 3rd September. Excavation concentrated upon three main areas; the orchard south of the east wing excavated in 1962, the west end of the north wing, and the west wing. In addition, trial trenches were dug at the north-east and north-west extremities of the building and in the area to the north of the north wing. The work of supervision was carried out by Miss F. Pierce, M.A., Mr. B. Morley, Mr. A. B. Norton, B.A., and Mr. J. P. Wild, B.A. Photography was organized by Mr. D. B. Baker and Mrs. F. A. Cunliffe took charge of the pottery and finds.

The voluntary intake of acetate by dairy cows given ammonium salts of short-chain fatty acids in their drinking water

1968 ◽  
Vol 10 (4) ◽  
pp. 473-481 ◽  
Author(s):  
P. Jackson ◽  
J. Hodgson ◽  
J. A. F. Rook
Keyword(s):  
Fatty Acids ◽  
Drinking Water ◽  
Acetic Acid ◽  
Water Intake ◽  
Daily Intake ◽  
Short Chain Fatty Acids ◽  
Sole Source ◽  
Ammonium Salts ◽  
Short Chain ◽  
Chain Fatty Acids

A solution of ammonium salts of a mixture of short-chain fatty acids (mainly acetic acid) was added to the sole source of drinking water of 10 lactating Jersey cows. There was considerable variation in the concentration of salts tolerated without depression in water intake. Some animals refused solution offered at a concentration of 0·5% (w/w) whereas one animal accepted solution at a concentration of 8% (w/w) and had a mean daily intake of salts equivalent to 836 g acetic acid.2. Adjustment of the pH of the drinking solution to 6·5–7·5 increased the tolerance to the salts solution of animals which showed a low tolerance to the unadjusted solution. A mean daily intake equivalent to 480 g acetic acid was achieved without a significant depression of water intake. Replacement of 50 % of the ammonium ions by calcium increased the intake of salts by some cows but two out of eight refused the solution at a concentration of 0·5% (w/w).3. The addition of saccharine, vanilla or aniseed to a solution of the ammonium salts gave little or no improvement in acetate intake but sodium cyclamate, ethyl acetate or molasses reduced the variability between animals in their tolerance to the solution and increased the mean intake of salts. With an addition of molasses, which gave the most marked response, there was a mean daily intake of salts equivalent to 495±26 g acetic acid.

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